BM 03 Summer Task Chemistry
BM 03 Summer Task Chemistry
1. Covalent bonds are formed when electrons are ……1…… . Covalent compounds have ……2……
electrical conductivity.
X Y
3. Which diagram does not show the outer shell electrons in the molecule correctly?
A B C D
H H H Cl H C H Cl Cl
1
2
e e key
e = electron
e
e
e e
1 sodium chloride
2 methane
3 lead bromide
2
3
e
e e key
e e e e = electron
= nucleus
e e
P e Q e
e e
e e
e
A B C D
8. In the molecules CH4, HCl and H2O, which atoms use all of their outer shell electrons in bonding?
3
4
Which row shows how many electrons there could be in the outer shell of an atom of X?
conducts electricity
volatile
when solid when molten
A
B
C
D
11. The diagrams show the electron arrangements in the atoms of four elements.
A B C
key
e ee ee ee
e electron
ee ee ee ee
e e e nucleus
e e
ee ee ee
4
5
12. Which statement about the bonding in a molecule of water is not correct?
e e key
e = electron
e
e
e e
14. Electrons from each element are shared by both of the elements in a compound.
A lead bromide
B sodium chloride
C water
D zinc oxide
5
6
16. Caesium chloride and rubidium bromide are halide compounds of Group I elements.
Caesium chloride has the formula ……1……, a relative formula mass ……2…… that of rubidium
bromide and bonds that are ……3…… .
1 2 3
17. Element X is in Group I of the Periodic Table. X reacts with element Y to form an ionic compound.
Which equation shows the process that takes place when X forms ions?
A X + e – → X+
B X – e – → X–
C X + e – → X–
D X – e – → X+
6
7
X Y
Which diagram correctly shows the arrangement of outer electrons in a molecule of methane?
A B C D
Y Y Y
X Y X Y Y X Y Y X Y
Y Y Y Y
1 methane
2 lead bromide
3 sodium chloride
7
8
8
9
What is Q?
A calcium
B potassium
C strontium
D yttrium
A Cl 2 B CO2 C N2 D O2
H H
C C
H H
9
10
Which row shows how many electrons there could be in the outer shell of an atom of X?
28. Which diagram does not show the outer shell electrons in the molecule correctly?
A B C D
H H H Cl H C H Cl Cl
10
11
29 Substances with giant covalent structures can be used as lubricants and as cutting tools for hard
materials.
The diagram shows how the atoms are arranged in two giant covalent substances, X and Y.
X Y
key
strong
covalent
bond
weak
attraction
30 Which dot-and-cross diagram shows the outer shell electron arrangement in a molecule of
nitrogen?
A B C D
N N N N N N N N
11
12
31 Which dot-and-cross diagram shows the outer shell electron arrangement in a molecule of
carbon dioxide?
A B
O C O O C O
C D
O C O O C O
32 Which dot-and-cross diagram shows the outer shell electron arrangement in a molecule of
carbon dioxide?
A B C D
O C O O C O O C O O C O
12
13
34 Which electron arrangement for the outer shell electrons in a covalent compound is correct?
A B C D
H Cl H Cl H N H H N H
H H
What is M?
A ammonia, NH3
B hydrogen chloride, HCl
C methane, CH4
D water, H2O
13
14
37 Solid F is an element.
Solid G is a compound.
Neither solid conducts electricity but G conducts electricity when dissolved in water.
These properties suggest that F is ……1…… and that G is ……2…… with ……3…… bonds.
38 Compound X melts at 801 °C and is a good electrical conductor when dissolved in water.
Compound Y boils at 77 °C, is insoluble in water and is a non-conductor of electricity.
14
15
electrical conductivity
melting point type of bonding
when liquid
40 The diagrams, X, Y and Z, show part of a polymer and two giant covalent structures.
X Y Z
Which of X, Y or Z could be used as a cutting tool and which of X, Y or Z could be used to reduce
friction?
15
16
1 Carbon and silicon are elements in Group IV. Both elements have macromolecular
structures.
(a) Diamond and graphite are two forms of the element carbon.
....................................................................................................................................
....................................................................................................................................
.............................................................................................................................. [2]
eb
(ii) Give one use of diamond.
nz
.............................................................................................................................. [1]
ha
Ja
za
az
on
M
16
17
....................................................................................................................................
.............................................................................................................................. [2]
............................................................................................................................. [1]
(b) Two of the oxides of these elements are carbon dioxide, CO2, and silicon(IV) oxide,
SiO2.
(i) Draw a diagram showing the arrangement of the valency electrons in one molecule
of the covalent compound carbon dioxide.
Use x to represent an electron from a carbon atom.
Use o to represent an electron from an oxygen atom.
eb
nz
ha
Ja
[3]
za
O
on
Si
M
O O
O
Use this diagram to explain why the formula is SiO2 not SiO4.
....................................................................................................................................
.............................................................................................................................. [2]
(iii) Predict two differences in the physical properties of these two oxides.
....................................................................................................................................
.............................................................................................................................. [2]
17
[Total: 13]
18
+ –
K Cl H O H
(a) In a water molecule, each hydrogen atom is bonded to the oxygen atom by sharing a pair
of electrons.
Why does an oxygen atom share two pairs of electrons rather than just one pair?
...........................................................................................................................................
..................................................................................................................................... [1]
eb
(b) Describe how a potassium atom becomes a potassium ion.
nz
..................................................................................................................................... [1]
ha
(c) Why is there a bond between the ions in potassium chloride?
Ja
...........................................................................................................................................
za
..................................................................................................................................... [1]
az
(d) Solid potassium chloride is a poor conductor of electricity. When dissolved in water it is
a good conductor. Explain.
on
...........................................................................................................................................
M
..................................................................................................................................... [2]
[Total: 5]
18
19
eb
nz
ha
Ja
za
(i) Draw a diagram that shows the formula of this compound, the charges on the ions
az
and the arrangement of the valency electrons around the negative ion.
Use o to represent an electron from an atom of C.
on
[3]
[2]
19
[Total: 10]
20
4 There are three types of giant structure – ionic, metallic and macromolecular.
(a) Sodium nitride is an ionic compound. Draw a diagram that shows the formula of the
compound, the charges on the ions and the arrangement of the valency electrons
around the negative ion.
eb
[3]
nz
(b)
b) Describe metallic bonding.
ha
[3]
Ja
[1]
az
[2]
M
[3]
[2]
20
[Total: 14]
21
electrical electrical
type of
particles present conductivity conductivity of example
structure
of solid liquid
eb
nz
metallic and good
ha copper
Ja
[Total: 6]
za
az
on
M
21
22
(a) Magnesium bromide is an ionic compound. Draw a diagram that shows the formula of
the compound, the charges on the ions and the arrangement of outer electrons around
the negative ion.
The electron distribution of a bromine atom is 2, 8, 18, 7.
eb
Use o to represent an electron from a bromine atom. [3]
nz
(b) In the lattice of magnesium bromide, the ratio of magnesium ions to bromide ions is
1:2. ha
(i) Explain the term lattice.
Ja
[2]
za
[1]
on
(iii) The reaction between magnesium and bromine is redox. Complete the sentences.
electrons.
electrons.
lec
[Total: 10]
22
23
7 The table shows the melting points, boiling points and electrical properties of the six
substances A to F.
electrical
electrical conductor
conductor of
substance melting point / oC boiling point / oC at room
substance
temperature
dissolved in water
eb
E –5 to -1 102 to 105 good good
nz
F -8 -6 does not conduct does not dissolve
ha
(i) Which three substances are solids at room temperature?
Ja
[1]
za
[1]
az
on
[1]
M
[1]
[1]
[1]
23
24
– + – +
+ – + –
+ – + –
– + – +
– + – +
+ – + –
[1]
eb
(ii) Give two physical properties of ionic compounds.
nz
ha [2]
Ja
(b) Ions are formed by electron loss or gain. The electron distribution of a magnesium
atom is 2 + 8 + 2 and of a nitrogen atom is 2 + 5.
za
[1]
on
[1]
[1]
(iv) In this compound there is an ionic bond. Why are the two ions attracted to each
other?
[1]
24
25
A It gains electrons.
B It gains protons.
C It loses electrons.
D It loses protons.
S2– Ca2+
A
B
C
D
3 When sodium chloride is formed from its elements, each chlorine atom ……1…… one ……2…….
25
26
6 The element rubidium, Rb, is immediately below potassium in the Periodic Table.
26
27
key
P Q = electron
Which row shows the electron change taking place for rubidium and the correct formula of the
rubidium ion?
P Q
type of bonding
substance
ionic
onic cova metallic
A chlorine
B potassium bromide
C sodium
D sodium chloride
28
29
13 Caesium chloride and rubidium bromide are halide compounds of Group I elements.
Caesium chloride has the formula ……1……, a relative formula mass ……2…… that of rubidium
bromide and bonds that are ……3…… .
1 2 3
X Y
What is the type of bonding in the compound and what is the formula of the compound?
15 Element X is in Group I of the Periodic Table. X reacts with element Y to form an ionic compound.
Which equation shows the process that takes place when X forms ions?
A X + e – → X+
B X – e – → X–
C X + e – → X–
D X – e – → X+
29
30
16 Compound X melts at 801 °C and is a good electrical conductor when dissolved in water.
17 Q+ is an ion of element Q.
30
31
19 Lithium is in Group I of the Periodic Table. Nitrogen is in Group V of the Periodic Table.
Lithium reacts with nitrogen to form the ionic compound lithium nitride.
What happens to the electrons when lithium atoms and nitrogen atoms form ions?
31
32
A B
Na– Cl + Na– Cl + + – + –
Cl + Na– Cl + Na– – + – +
Na– Cl + Na– Cl + + – + –
Cl + Na– Cl + Na– – + – +
C D
– – –
– + – + + + + +
– – –
– – – –
+ – + – + + + +
– – – –
–
–
– + – + + + + +
– – – – –
+ – + – + + + +
– – –
–
23 Magnesium nitride is formed when magnesium burns in air. Magnesium nitride is an ionic
compound.
32
33
element
element electronic structure
R 2,4
T 2,8
X 2,8,1
Z 2,8,7
substance 1 substance 2
electrical conductivity
melting point type of bonding
when liquid
33
34
Which statements describe what happens to the sodium atoms in this reaction?
Q R
34
35
30 Solid F is an element.
Solid G is a compound.
Neither solid conducts electricity but G conducts electricity when dissolved in water.
These properties suggest that F is ……1…… and that G is ……2…… with ……3…… bonds.
31 The nucleon number and proton number of the lithium atom are shown by the symbol 73 Li.
What is the correct symbol for the lithium ion in lithium chloride?
6 6 7 7
A 2
Li– B 3
Li+ C 3
Li+ D 3
Li–
particle
articl nucleon number of number of number of
number number protons neutrons electrons
Mg 12 24 12 W 12
Mg2+ X 24 12 12 10
F 9 19 9 Y 9
F– 9 19 9 10 Z
W X Y Z
A 10 10 9 9
B 10 12 10 9
C 12 10 9 10
D 12 12 10 10
35
36
33 Which element does not form a stable ion with the same electronic structure as argon?
A aluminium
B chlorine
C phosphorus
D potassium
36
37
................................... ...................................
B
ZE
neutralisation nitric acid ................................... copper(II) nitrate
AN
...................................
................................... ...................................
...................................
[6]
AZ
(b)
b) Write an ionic equation with state symbols for the preparation of silver(I) chloride.
N
.............................................................................................................................. [2]
O
M
[Total: 10]
37
38
2 Soluble salts can be made by the neutralisation of an acid by a base. Insoluble salts can be
made by precipitation.
(a) The following is a brief description of the preparation of the soluble salt,
nickel(II) chloride-6-water, from the insoluble base nickel(II) carbonate.
Nickel(II) carbonate is added in small amounts to hot dilute hydrochloric acid until it is
in excess. The mixture is filtered. The filtrate is partially evaporated and then allowed to
cool until crystals of nickel(II) chloride-6-water form.
....................................................................................................................................
.............................................................................................................................. [1]
B
(ii) Explain why it is necessary to filter.
ZE
.............................................................................................................................. [1]
AN
(iii) Why partially evaporate rather than evaporate to dryness?
....................................................................................................................................
H
JA
.............................................................................................................................. [1]
....................................................................................................................................
AZ
.............................................................................................................................. [2]
(b) Potassium chloride can be made from hydrochloric acid and potassium carbonate.
N
O
(i) Why must a different experimental method be used for this preparation?
M
....................................................................................................................................
.............................................................................................................................. [1]
(ii) Give a description of the different method used for this salt preparation.
....................................................................................................................................
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....................................................................................................................................
.............................................................................................................................. [4]
38
39
(iii) Two salts of phosphorus acid are its sodium salt, which is soluble in water, and its
calcium salt which is insoluble in water. Suggest a method of preparation for each of
these salts from aqueous phosphorus acid. Specify any other reagent needed and
briefly outline the method.
....................................................................................................................................
....................................................................................................................................
.............................................................................................................................. [2]
....................................................................................................................................
B
....................................................................................................................................
ZE
.............................................................................................................................. [2]
...................................................................................................................................................
ZA
...................................................................................................................................................
...................................................................................................................................................
AZ
...................................................................................................................................................
...................................................................................................................................................
N
O
...................................................................................................................................................
M
...................................................................................................................................................
...................................................................................................................................................
.............................................................................................................................................. [4]
(a) Write the ionic equation for the reaction between an acid and an alkali.
...............................................................................................................................................[1]
(b) Sodium sulfate is a soluble salt that can be prepared using a titration method.
(i) Name a sodium compound and the acid that can be used to make sodium sulfate by this
Method.
.............................................................................................................................................[1]
39
40
(ii) Describe how the titration method is used to prepare a colorless solution of
sodium sulfate.
...........................................................................................................................................
...........................................................................................................................................
...........................................................................................................................................
...........................................................................................................................................
...........................................................................................................................................
...........................................................................................................................................
............................................................................................................................................[3]
(iii) Describe how a sample of pure sodium sulfate crystals can be made from aqueous
sodium sulfate.
...........................................................................................................................................
B
...........................................................................................................................................
ZE
...........................................................................................................................................
AN
...........................................................................................................................................
.......................................................................................................................................[2]
H
JA
...........................................................................................................................................
O
...........................................................................................................................................
M
...........................................................................................................................................
.......................................................................................................................................[3]
(ii) Write the ionic equation, including state symbols, for this reaction.
.......................................................................................................................................[2]
40
41
1 2
A
B
C
D
2 Which property is not characteristic of a base?
X Y
41
42
4 Three liquids, P, Q and R, are added to a mixture of hydrochloric acid and Universal Indicator
solution.
42
43
Which row shows the colour of each solution after the indicator is added?
The acid reacts with the oxide layer on the surface of the metal, forming a salt and water.
A alloy
B base
C element
D indicator
43
44
10 Which equation for the reaction between sodium carbonate and dilute hydrochloric acid is
correct?
44
45
11 Three chemicals, P, Q and R, were each dissolved in water. The table shows some of the
reactions of these solutions.
P Q R
A 2 7 13
B 2 1 7
C 7 2 13
D 13
3 7 2
substance pH
A calcium hydroxide 12
B lemon juice 4
C i
milk 6
D washing up liquid 8
45
46
13 The graph shows how the pH of soil in a field changes over time.
11 A
pH of 7 B
soil D
5 C
time
A A piece of magnesium ribbon is added. Bubbles are seen and the magnesium disappears.
B A pungent smelling gas is produced when ammonium carbonate is added.
C Copper oxide powder is added and the mixed is warmed. The solution turns blue.
D The solution turns blue litmus red.
46
47
A ccabbage 6-
B p
potato 4-
C s
strawberry 5-
D wheat
w 6-
1 2
A
B
C
D
47
48
X Y
A H2 HCl
B H2 NaOH
C O2 HCl
D O2 NaOH
20 Ant stings hurt because of the methanoic acid produced by the ant.
substance pH
A baking soda 8
B car battery acid 1
C lemon juice 3
D oven cleaner 14
48
49
blue red
litmus paper litmus paper
aqueous
ammonium chloride
+
aqueous
sodium hydroxide
heat
49
50
22 Two indicators, bromophenol blue and Congo red, show the following colours in acidic solutions
and in alkaline solutions.
A They react with ammonium salts to form a salt and ammonia only.
B They react with metal carbonates to give a salt and carbon dioxide only.
C They react with metal hydroxides to give a salt and water only.
D They react with metals to give a salt, hydrogen and water only.
24 Which of these pairs of aqueous ions both react with dilute sulfuric acid to give a visible result?
A Ba2+ and Cl
C NH4+ and Cl
50
51
How does the pH of the hydrochloric acid change as an excess of aqueous barium hydroxide is
added?
substances X and Y
heat
51
52
A ammonia
B chlorine
C hydrogen
D sulfur dioxide
Which letter represents the area of the graph where both acid and salt are present?
A
14 B
pH
C
7
D
0
solid S gas G
A copper
opper hydrogen
B copper carbonate carbon dioxide
C zinc
inc hydrogen
D zinc carbonate carbon dioxide
52
53
30 An aqueous solution of copper(II) sulfate was made by adding excess copper(II) oxide to dilute
sulfuric acid. The mixture was heated, stirred and then filtered.
copper(II) oxide
heat
What was the pH of the acid before adding the copper(II) oxide and of the solution after filtration?
A greater than 7 7
B greater than 7 less than 7
C less than 7 7
D less than 7 greater than 7
A exothermic
B neutralisation
C oxidation
D polymerisation
53
54
What is the result of adding an excess of dilute sulfuric acid to the alloy?
54
55
35 The oxide of element X was added to an acid. It reacted to form a salt and water.
oxide of
element X
acid
What is the pH of the acid before the reaction and what type of element is X?
pH type of element X
55
56
A P only
B P and Q only
C Q, R and S only
D R and S only
38 The graph shows how the pH of soil in a field changed over time.
11 A
pH of 7 B
soil D
5 C
time
56
57
magnesium
hydrogen
copper(II) oxide
copper(II) sulfate
A an acid
B a base
C an element
D a salt
K process
A ethanol combustion
B ethanol neutralisation
C hydrochloric acid combustion
D hydrochloric acid neutralisation
57
58 SALTS PREPARATION WRKSHEET
step 3 step 4
A to ensure all of the acid has reacted to obtain solid copper(II) sulfate
B to ensure all of the acid has reacted to remove excess copper(II) oxide
C to speed up the reaction to obtain solid copper(II) sulfate
D to speed up the reaction to remove excess copper(II) oxide
2 What is the correct sequence of steps for the preparation of a pure sample of copper(II) sulfate
crystals from copper(II) oxide and sulfuric acid?
A copper(II) oxide
B magnesium
C sodium hydroxide
D zinc hydroxide
58
59
4 Four stages in the preparation of a salt from an acid and a solid metal oxide are listed.
A 1→3→4→2
B 2→1→3→4
C 4→1→3→2
D 4→2→1→3
6 Zinc sulfate is a soluble salt and can be prepared by reacting excess zinc carbonate with dilute
sulfuric acid.
Which piece of equipment would not be required in the preparation of zinc sulfate crystals?
A beaker
B condenser
C evaporating dish
D filter funnel
59
60
7 Four steps to prepare a salt from an excess of a solid base and an acid are listed.
1 crystallisation
2 evaporation
3 filtration
4 neutralisation
A 2→
B 3→
C 4→
D 4→
9 Which of the following methods are suitable for preparing both zinc sulfate and copper sulfate?
1 Reacting the metal oxide with warm dilute aqueous sulfuric acid.
A 1 and 2 only
B 1 and 3 only
C 2 and 3 only
D 1, 2
10 Which two processes are involved in the preparation of magnesium sulfate from dilute sulfuric
acid and an excess of magnesium oxide?
60
61
11 How many different salts could be made from a supply of dilute sulfuric acid, dilute hydrochloric
acid, copper, magnesium oxide and zinc carbonate?
A 3 B 4 C 5 D 6
13 Which acid reacts with ammonia to produce the salt ammonium sulfate?
A hydrochloric
B nitric
C phosphoric
D sulfuric
14 Copper carbonate reacts with dilute sulfuric acid to make copper sulfate.
Which row gives the correct order of steps for making copper sulfate crystals?
15 Which acid reacts with ammonia to produce the salt ammonium sulfate?
A hydrochloric
B nitric
C phosphoric
D sulfuric
61
62
What can be added to anhydrous copper(II) sulfate to turn it into hydrated copper(II) sulfate?
17 A compound is a salt if it
Samples of the solutions obtained are separately tested with dilute hydrochloric acid and with
aqueous sodium hydroxide.
In two of the tests, a gaseous product is formed. No precipitate is formed in any of the tests.
X Y
A AgNO3 BaSO4
B BaSO4 Na2CO3
C Na2CO3 NH4Cl
D NH4Cl AgNO3
19 A liquid turns white anhydrous copper sulfate blue and has a boiling point of 103°C.
A alcohol
B petrol
C salt solution
D pure water 62
63
A chromatography
B crystallisation
C distillation
D filtration
21 An excess of copper(II) oxide is added to dilute sulfuric acid to make crystals of hydrated
copper(II) sulfate.
The processes listed may be used to obtain crystals of hydrated copper(II) sulfate.
A 1, 2
B 1, 2
C 2, 1
D 2, 1
1 with a metal;
2 with a base;
3 with a carbonate.
A 1 and 2 only
B 1 and 3 only
C 2 and 3 only
D 1,
1, 63
64
1 The energy level diagram for the reaction between sodium hydrogen carbonate and dilute
hydrochloric acid is shown.
energy
sodium hydrogen carbonate +
dilute hydrochloric acid
Which row correctly describes the type of reaction and the energy of the reactants and products?
2 The energy level diagram for the reaction between magnesium and hydrochloric acid is shown.
Mg + 2HCl
energy
MgCl 2 + H2
3 The energy level diagram shows the energy of the reactants and products in a chemical reaction.
reactants
energy
products
Which row correctly describes the energy change and the type of reaction shown?
65
66
The mixture was stirred and the temperature recorded every 10 seconds.
25
20
15
temperature
/ °C
10
0
0 20 40 60 80 100
time / s
66
67
The graph shows the temperature before, during and after the reaction.
temperature
time
67
68
A B
steam flame
water
natural gas
calcium oxide
C D
final temperature
initial temperature
alkali
heat acid
68
69
Which row shows the correct description of each of the chemical reactions?
A no endothermic
B no exothermic
C yes endothermic
D yes exothermic
69
70
1 2
A If the reaction is endothermic, the temperature decreases and energy is taken in.
B If the reaction is endothermic, the temperature increases and energy is given out.
C If the reaction is exothermic, the temperature decreases and energy is given out.
D If the reaction is exothermic, the temperature increases and energy is taken in.
70
71
15 When anhydrous copper(II) sulfate is added to water a solution is formed and heat is given out.
thermometer
anhydrous
copper(II) sulfate
water
Which row correctly shows the temperature change and the type of reaction taking place?
A decreases endothermic
B decreases exothermic
C increases endothermic
D increases exothermic
16 When ammonium nitrate is added to water the temperature of the water decreases.
A The ammonium nitrate dissolves in the water and the process is endothermic.
B The ammonium nitrate reacts with the water and the process is endothermic.
C The ammonium nitrate dissolves in the water and the process is exothermic.
D The ammonium nitrate reacts with the water and the process is exothermic.
71
72
17 Some white anhydrous copper(II) sulfate powder is put into a beaker of water and stirred.
18 The diagrams show the difference in energies of the reactants and products in two types of
reaction.
diagram 1 diagram 2
heat taken in heat given out
products reactants
energy energy
reactants products
Which diagram and which type of energy change apply to a fuel burning in air?
A 1 endothermic
B 1 exothermic
C 2 endothermic
D 2 exothermic
72
73
reactants
energy
products
2 2H2 + O2 → 2H2O
3 C + O2 → CO2
A none of them
B 1 and 2 only
C 2 and 3 only
D all of them
73
74
21 The diagram shows the reaction between zinc oxide and dilute hydrochloric acid.
dilute aqueous
hydrochloric acid zinc chloride
20 °C 22 °C
pH 1 pH 7
before after
endothermic neut
A
B
C
D
22 Acetylene, C2H2, is a hydrocarbon. When acetylene and oxygen react, the hot flame produced
can be used to weld steel.
74
75
23 Which fuel needs oxygen in order to produce heat energy and which type of reaction produces
the energy?
A combustion
B endothermic
C exothermic
D neutralisation
A burning hydrogen
B distilling petroleum
C reacting potassium with water
D using petrol in a motor car engine
75
76
1 2 3
balance stop-clock thermometer
60
45 15
30
Which equipment is needed to find out whether dissolving salt in water is an endothermic
process?
27 Clouds are formed when water vapour evaporates from the sea.
clouds
water vapour
sea
What is the energy change and what name is given to the type of change when water
evaporates?
76
77
A B C D
ice sodium
rocket
candle
water
water
77