Battery 01 Total
Battery 01 Total
Ø
COURSE OIL AND GAS TECHNOLOGY CODE
SUBJECT BATTERY P/TM/TRG/E.BA/001
Content:
1. General.
2. Different types of batteries.
3. Lead acid batteries.
4. Alkaline batteries.
5. Dry-type batteries.
6. Annex I (pictures)
1
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
1. GENERAL
Batteries are regarded as electrical devices used for energy storage. Batteries are charged
by a prime energy source and delivering its energy to the load on demand in following
applications:
Since this training document is offered to trainees of all disciplines during the common
course period, therefore, the technical subjects and information are regarded as general.
More detailed technical data and information on batteries shall be offered during the
specific course. Subjects and paragraphs that are marked with asterisk (*) are more or less
specialized, therefore might be skipped during the common course sessions and left for
later specific course sessions.
- Solid/liquid electrolyte.
- Electrolyte material used in the battery.
- Battery cells material.
- High power/low power capacity.
- Long/low cycle life.
- Good/poor temperature performance.
- High/low ruggedness.
- High/low reliability.
- Long/short shelf time.
- Domestic/industrial applications.
- Sealed/unsealed battery structure.
- High/low energy density.
- High/low current rate of charging and discharging.
2
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
Charge
Pb + PbO2 + 2H2 SO4 2Pb SO4 + 2H2O
Discharge
The state of charge of the battery can be determined by measuring the specific gravity
(relative density) of the electrolyte, which decreases on discharge and increases on the
charge.
3
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
FIG.1
4
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
FIG.2
5
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
3.2.3. Sediment space is provided under the cells assembly inside the container for
safe collection of any active material that dislodges from the electrodes. (Figure 3 on
page 7)
3.2.4. Sufficient headroom is provided above the cells assembly inside the container
to hold excess electrolyte. (Figure 3 on page 7)
3.5. Self-Discharge
3.5.1. Self-discharge in lead-acid batteries is caused by internal chemical reactions
between components of the cell plates and occurs almost entirely in the negative
electrode. Following factors influence in self-discharge of the battery:
6
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
FIG.3
7
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
3.5.2. The rate of discharge is normally around 15% per month at 25°C.
3.5.3. Capacity lost by self-discharge can be recovered by recharging the battery. It
is recommended that stored, standby batteries be recharged every 3 to 6 month,
since prolonged storage can cause irreversible damage and make the recharging
difficult due to sulfation of negative electrode.
3.7.1. For high-rate shallow discharge, the life of the battery ranges from 2 to 5
years (for automotive service)
3.7.2. Certain stationary-type batteries have been designed and manufactured for
long-term use, which offer a life expectancy from 15 to 25 years depending on their
construction.
8
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
lowered to about 25% to 40% of the starting current to avoid hard gassing which
would otherwise take place.
3.9.2. Constant potential charging
In this method, a fixed resistor is applied in series with the charger and the battery.
Appropriate charging voltage and resistor are selected to provide the proper initial
and finishing current rate.
No further adjustment of the potential would be required during the charging.
3.9.3. Taper method of charging
This method is the modified method of constant-potential method (3.9.2.), and is a
more desirable practice, as it limits the charging current and prevents overcharge
and electrolyte loss that could occur in the constant-current method if the battery is
not removed at the completion of charging.
3.9.4. Charging of maintenance-free cells
Recommended charging rate for these type of sealed batteries is lower than that of
liquid type. The initial rate would be C/10, tapering to around C/50 for an elapsed
charging time of 20 to 25 hours.
3.9.5. Boost charging
In an emergency case, boost charging (fast charging) can be used. In this type of
charging, the current should not exceed the “C” rate, and the battery should not be
allowed to reach high temperatures, otherwise the battery would suffer damage.
3.9.6. Float charging
In this mode of charging, the charger maintains a constant voltage (around 2.2 volts
per cell), providing sufficient current to the battery to keep it fully charged, but
without considerable overvoltage. Following a discharge, the battery automatically
draws a higher current that decreases as full charge approaches, until it is again
reduced to the low maintenance value.
3.9.7. Partial float charging
Under this mode of charging, such as in automotive applications, the battery is not
continuously charged, but can receive sufficient charge only when the engine is
running at sufficiently high speed.
3.9.8. Trickle charging
Trickle charging is a continuous-constant current method applied to the batteries in
storage or standby service in order to maintain it in a fully charged condition. Trickle
current rate value is around 50 to 100 ma/100 ah of the capacity of the battery.
Since gassing occurs when the battery is fully (or excessively) charged, therefore,
safety precautions should be taken, because a considerable amount of hydrogen
and oxygen are produced which can be hazardous.
Note: Overcharging of the lead-acid batteries would lead to electrolysis of water and thus
producing hydrogen at negative electrode and oxygen at positive electrode. Therefore, due
cautions should be taken to avoid overcharging for safety reasons.
9
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
The nominal voltage of nickel-cadmium cell is 1.2V in operation, and 1.4V for open circuited
cell.
10
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
11
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
FIG.4
12
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
4.5. Self-Discharge
4.5.1. Self-discharge rate in nickel-cadmium batteries is substantially much lower
than that of lead acid batteries.
4.5.2. The rate of discharge in sealed Ni-Cd batteries is approximately twice that of
the vented type.
13
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
FIG.5
14
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
4.9.1. Normally the C/10 rate is used and the battery is charged for 12 hours. At this
rate of charge, sealed batteries behave similarly to that of vented type.
4.9.2. Recent designs for sealed Ni-Cd batteries provide the charging rate of C/5.
But, however, due care should be taken not to overcharge the batteries and avoid
over temperatures.
4.9.3. Boost (fast) charging method is also applicable for sealed batteries, but
means must be provided to avoid overcharging and over temperature.
4.9.4. Sealed Ni-Cd batteries charging at temperatures between O and 40°C is best
recommended. Charging above 40°C in not advised. For charging below 0°C the
lower rate of charging should be selected.
4.9.5. Constant-potential charging is not recommended, as it can lead to thermal
runaway. It can be used if precautions are taken to limit the current at the end of the
charge.
4.9.6. Float charging is also possible for sealed Ni-Cd batteries, however similar
cautions, as constant-potential charging should be taken.
4.9.7. Trickle charging at a low constant-current rate normally is used to maintain
the battery in a state of full charge.
4.9.8. A periodic discharge every 6 months, followed by a discharge, is advisable to
ensure optimum performance.
15
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
4.10.5. Ni-Cd batteries are capable of working in very low temperature. With higher
electrolyte concentration (around 30%), Ni-Cd batteries can be used in
temperatures as low as -50°C.
4.10.6. Ni-Cd batteries can be maintained in fully charged and filled with electrolyte
for a long periods of time and capable of going into service directly from the storage
without recharging. Lead-acid cannot offer such reliable quick-applicable service.
4.10.7. Normally, less maintenance practice would be required for nickel-cadmium
batteries than that of advised and required for lead-acid batteries.
4.11.1. In this type of batteries, zinc (Zn) is the negative cathode, while the silver
oxide (Ago2) is the positive anode.
4.11.2. Zinc-silver oxide batteries are available in sizes from 0.1 to 300 Ah in “low”
or “high” rate constructions.
4.11.3. Zinc-silver oxide batteries are used in following areas.
- Lightweight radio and electronics.
- Submarine equipment.
- Areas where high energy density is a prime requisite.
4.11.4. These batteries are not used for general storage-battery applications due to
their high costs.
16
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
5.1. The high energy densities, 5 to 10 WH/IN3, particularly achieved with the light litium-
anode solid-electrolyte batteries.
5.2. Sealed structure, which provides protection against moisture and maintain a high-
density, void-free package.
5.3. Continuous discharge at high rates is not practical with solid-electrolyte batteries.
5.4. A significant characteristic of the solid-electrolyte batteries is their long shelf life, which
normally exceeding 15 years at 20°C.
5.5. The characteristics of several of the available types of solid-electrolyte cells are
summarized in the following table:
6.2. Vent plugs should be free from obstruction to avoid internal gas pressure. Naked lights
or sparking near batteries shall ignite the emerging gases.
17
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
FIG.6
18
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
6.3. Electrolyte level should always be maintained above the cell plates and never allow it
go lower.
6.4. Mechanical damage follows the chemical changes that occur under maloperation of the
batteries.
6.5. Topping-up of the electrolyte is best to be done when the batteries are under
recharging or on float charge condition.
6.6. Only distilled and deionised water should be used for topping-up. Tap water should
never be used for topping up due to its impurities, which could be harmful to the batteries.
6.7. A periodic maintenance testing of the batteries is advised, to be carried out on the
equipment for which they are intended.
6.8. Separate hydrometers (to check the relative density) should be used for different types
of batteries, and each battery uses its own hydrometer to avoid contamination.
6.9. Battery connections and leads should be protected against moisture and corrosion by
using recommended Vaseline or petroleum jelly.
6.11. Where both lead acid and alkaline (Ni-Cd) batteries are employed in a plant, it is best
to have separate battery rooms and under no account should an alkaline electrolyte be
added to a lead acid battery of vice versa.
6.12. Always ensure that the boxes and lids of the cells are thoroughly clean and dry.
6.13. The flat contact-making surfaces of the terminal pillars should be always cleaned
appropriately.
6.14. Do not scrape the surface of the battery leads and connectors because you may
damage the plating.
19
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
20
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
21
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
22
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
23
TSP-POGC-NIGC × T.T.F. Ø
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
24
TSP-POGC-NIGC × T.T.F.
SUBJECT BATTERY CODE
P/TM/TRG/E.BA/001
25