Date: 18/06/2025

Sr. No.7 in 301st Part –I meeting of SEAC-1, Maharashtra

Proposal No. SIA/MH/IND3/483900/2024

COMPLIANCE PRESENTATION FOR GRANT OF

ENVIRONMENTAL CLEARANCE
for
M/s. Benzochem Industries Private Limited
Plot no. E-13,E-14 & E-15, MIDC Jalgaon, Maharashtra

Project Name:
Proposed expansion project for Manufacturing of specialty chemicals,
pharma intermediates & API

Project Activity (As per Schedule of EIA Notification, 2006):

5 (f) Synthetic Organic Chemicals Industry, Category B-1

NABET Accredited Consultant:

Goldfinch Engineering Systems Private Limited (NABET/EIA/23-
26/RA 0314 valid till June 08,2026)
1 1
 Chronology of the Application

Sr.
Particulars Details
No.

1 Date of EC Application Submission 27th June 2024

2 Considered in SEAC Meeting 284th meeting of SEAC-l dt. 22nd November 2024

Date of the ADS raised : 19/05/2025

3 ADS if any including date of reply
Reply to the ADS : 12/06/2025

2
The proposal was discussed in the 284th SEAC-1 meeting
held on 22nd November 2024 for appraisal under
Category 5 (f) B-1.

After detailed discussion committee decided to defer the

proposal and asked us to submit the compliance
mentioned in the MoM.

Herewith, we are presenting the compliance of the

conditions in following slides;

3
 ADS Point No.1
Point No.1: Committee noted that, the project was received earlier EC dated: 12/05/2015 for plot area of
12,150 Sq.Mtrs.& it is mentioned that 33% i.e.4009.5 Sq.Mtrs.area as green belt area.During deliberation
PP & their accredited environment consultant argued that it is not clear that green belt area of 4009.5
Sq.Mtrs.mentioned in earlier EC was proposed inside or periphery of the plot area.However, they have not
produced any document/layout submitted before then SEAC/SEIAA in support of this. Therefore,
committee is of opinion that PP & their accredited environment consultant should justify the greenbelt area
proposed (inside & outside the plot area) in earlier EC with layouts (conceptual /approved) submitted
before then SEAC/SEIAA to obtain earlier EC.

Compliance:

As per earlier EC total plot area of the unit mentioned was 12,150.00 sq.m and total green belt area
mentioned was 4045 sq.m. which is around 33% of total plot area. However, in issued EC area of
green belt inside and outside the premises was not mentioned separately. As per the conceptual
layout submitted before SEAC/SEIAA to obtain earlier EC shows that green belt mentioned around
the periphery was actually the outside the compound wall. In the area statement mentioned in the
layout there is no bifurcation of green belt inside and oust side the premises. Upon reviewing the
layout submitted during the previous EC, it has been observed that approximately 10% of the
greenbelt area was provided within the premises, and around 23% was located outer side
periphery of the plot.

Layout submitted to SEAC/SEIAA to obtain earlier EC is presented in upcoming slide;

4
Layout Submitted during Earlier EC obtained dated 12th May 2015 ADS Point No.1

Layout 5
 ADS Point No.1

Area statement as per Earlier EC

Area Statement Sq. m.

Total Plot Area 12150.00

Green Belt Area 4045.00

Open Area 5822.00

Layout 6
 ADS Point No.1
Compliance:

• Now, in the current EC proposal, green belt area is 10% of total plot area i.e.1,215.0 sq.m. which is
already been developed within the premises. 365 Nos. of tress planted in inside premises.

• PP has developed 526.16 Sq.m Green Belt on MIDC land near the main gate adjacent to Plot Premises
on NE boundary. 100 No. of trees are planted on the land.

• Now, Benzochem has procured a land at Gut Number 61 in Kusumbe Kh, Jalgaon, situated
approximately 3.5 km from the project site, exclusively for the development of green belt.

• Green belt to the tune of 25% i.e 3,037.5 sq.m. will develop on said land to meet the requirement of
33% of green belt. So, total greenbelt area will be 4,252.5 sq.m. which is 35 % of total plot area. 911
Nos. of trees will be planted on Gut Number 61.

• Total no. of trees will becomes 1276 nos. on 4,252.5 sq.m of land meeting the standard norm of 2500
trees per hectare considering survival rate of the trees to be 80%.

• EMP budget of green belt development will be Rs. 4.5 Lacs as a capital cost and Rs. 2.0 Lacs per
Annum.
• Greenbelt will be developed on Gut Number 61 in Kusumbe Kh, Jalgaon within 1 year as per the CPCB
guidelines and with the provision of drip irrigation system.
• Detailed layout mentioning the greenbelt area inside the premises presenting in upcoming slide.
• List of trees species already planted & to be planted along with the Ownership document of the land
along with the undertaking that the land will be utilised exclusively for the development of green belt
presenting in upcoming slide.
Layout Undertaking 7
 Layout Submitted in the current Application

Main
CCOE API Production ETP area
Ware house
area Production PESO Area building
building

Parking
area Hazardous waste
Utility Exit gate UGW tank Storage Area
area Entry Green Belt Exit gate Layout 8 8
 ADS Point No.1

Area statement as per Current EC Proposal

Area Statement Sq. m.

Total Plot Area 12150.00

Green Belt Area (Inside the 1215.00

Premises 10%)
Deficit Green Belt Area (Outside 3037.5
the Premises 25 %)
Total Green Belt Area 4252.5

Parking Area 691.80

Note: There is no additional construction involved in the proposed project.

Layout 9
 Existing Plantation details
Existing No. of
Sr. No. Botanical Name / Scientific Name Common Name
Trees
1 Polyalthia longifolia Ashok 25
2 Azadirachta indica Neem 20
3 Eucalyptus globulus Nilgiri 10
4 Ficus religiosa Peepal 5
5 Cocos nucifera Coconut 10

6 Magnolia champaca Chafa 15

7 Terminalia Catappa Badam 10

8 Ficus sp. Ficus 10
9 Ailanthus altissima Maharukh 25
10 Ficus hispida Katumbar 25
11 Holoptelia integrifolia Wavli 15
12 Lagerstroemia speciosa Taman 40
13 Aegle marmelos Bel 15
14 Ficus benjamina Nandrukh 20
15 Albizzia amara Shirish 30
16 Ficus religiosa Pimpal 5
17 Pongamia pinnata Karanj 35
18 Acacia catechu Khair 30
19 Azadirachta indica Neem 15
20 Ficus Benghalensis Wad 5
Total 365
10
Proposed Plantation details (outside premises at Gut No. 61 in
Kusumbe Kh, Jalgaon)

High Carbon
Scientific Name Common Name Nos
Sequestration Species
Ailanthus altissima Maharukh 47 Yes
Ficus hispida Katumbar 40 yes
Flacourtia indica Kakai 41 --
Garuga pinnata Kakad 40 --
Syzygium cumini Jamun 51 Yes
Holoptelia integrifolia Wavli 37 Yes
Lagerstroemia parviflora Lendia 41 yes
Lagerstroemia speciosa Taman 53 yes
Aegle marmelos Bel 25 --
Madhuca latifolia Moha 25 --
Ficus benjamina Nandrukh 65 Yes
Albizzia amara Shirish 40 yes
Mitragyna parviflora Kalamb 42 --
Tectona grandis Teak 150 yes
Ficus religiosa Pimpal 10 Yes
Pongamia pinnata Karanj 38 yes
Acacia catechu Khair 25 yes
Azadirachta indica Neem 84 Yes
Ficus Benghalensis Wad 10 yes
Butea monosperma Kadamb 47 yes 11
 Condition No.1
Land Ownership Document of Gut No. 61 in Kusumbe Kh, Jalgaon

Land Ownership Document12

 ADS Point No.1
Distance between Benzochem Industries Pvt. Ltd. at Jalgaon MIDC
and Gut No. 61, Kusumbe Kh, Jalgaon

13
 Condition No.1
Undertaking for Development of Greenbelt at Gut No. 61 in Kusumbe Kh, Jalgaon

14
Undertaking
 ADS Point No.1
Photographs of Gut No.61 at Kusumbe Kh., Jalgaon

Layout 15
 Details about availability of documents mentioned in 301st SEAC-1
agenda for Industrial Proposal
Sr.
Particulars Details
No.
1 Project consultant & EIA Coordinator (UT): Yes
2 EC, EMP & CER Implementation (UT): Yes
3 Non coverage in western ghat notification (UT): Yes
4 GSDA- Geological Report: No, Not Applicable
5 Forest Department Letter: No, Not Applicable
NOC’s are required if any from (Irrigation /PWD/ Water supply Yes, from MIDC
6
etc.): Jalgaon
7 Copy of Water Supply NOC/ Water lifting Permission: Yes
8 Copy of Permission granted to connect CETP: No, Not Applicable
9 MOM of public hearing attached: No, Not Applicable
10 Copy of CTO/CTE with conditions: Yes
Copy of Certified Compliance report (Latest): Yes, Available
(Certified CTO
11 compliance report,
Certified EC
compliance report )

CTO compliance report from SRO IRO Closure Report 16

I. Project name, Location and with
Executive Summary of Project

17 17
 PROJECT SUMMARY

Sr. No. Item Details

1 Name of Industry Benzochem Industries Private Limited.

2 Project Location Plot No. E-13, E-14 & E-15, MIDC Jalgaon, Maharashtra

3 Plot Area 12150 m2

Total: 4252.5 m2. (35.00 % of the total plot area)

4 Green Belt Area 1215 m2 (10.00 % already developed green belt inside the premises
3037.5 m2 (25.00 % of total plot area outside the premises on own land
located at aerial distance 3.58 km at Gut Number 61 in Kusumbe kh, Jalgaon )

Existing: 53.63 TPM

Production details
5 Additional proposed: 81.65 TPM
Total Products: 135.28 TPM

Water 281 CMD (Existing: 111 CMD, Additional Proposed: 170 CMD)
6 Requirement & its Source of Water is Jalgaon MIDC.
approval NOC for water requirement from MIDC is available with us.

Wastewater Trade: 112.8 CMD (Existing 21.7 CMD + Proposed 91.1 CMD)
7
Generation Domestic: 17.0 CMD (Existing 6 CMD + Proposed 11 CMD)

18 18
 PROJECT SUMMARY
Sr. No. Item Details

Effluent from process plant will be fed treated in primary treatment,

followed by stripper along with RO reject will be fed to Four Stage
Treatment of Multiple Effect Evaporator. Utility blow down & washing along with
8 Wastewater & Its condensate from Multiple Effect Evaporator will be fed to secondary
Disposal treatment, tertiary treatment. Tertiary treated effluent pass through
proposed RO, RO permeate will be reused & reject will be fed to MEE.
This will be complete Zero Liquid Discharge (ZLD) project.

Equipment Type of Fuel APC System

Proposed 6 TPH boiler Coal /Briquette

Multicyclone followed by Bag
Existing Thermopack of capacity 1 Nos. Filter and common stack
Coal /Briquette
Fuel x 8 lakhs Kcal /hr
requirement
Existing D.G set of capacity 1x 400 KVA HSD Stack and acoustic enclosure
9 and APC
system
Stack and acoustic enclosure
provided Existing D.G set of capacity 1x 500 KVA HSD

•Note: Fuel quantity for existing and proposed Boilers & Thermopack is calculated for full
load 24 hours working.
•*Existing 4 TPH Boiler will be dismantled during proposed expansion and 6 TPH Boiler is
to be Proposed in expansion. 19 19
 PROJECT SUMMARY

Sr.
Item Details
No.

Generation of electricity from Solar: 110 KWP

Renewable Source of
10 % Of saving due to installation of Solar: 13.75 % of operational
energy
load

Total capital Cost: Rs.69.5 Cr. (Existing: Rs. 48.55 Cr. + Additional
11 Estimated Project Cost
Proposed: Rs. 20.95 Cr.)

Corporate Environmental The Company has earmarked Rs. 20.95 Lacs (1 % of the
12
Responsibility (CER) expansion cost) for undertaking the CER activities.

Capital Cost: Rs.1285 lakhs

13 EMP Budget
Operation and Maintenance: Rs.617.9 lakhs / Annum

Scrutiny Fees Details Rs. 1,50,000/- paid on 10th July 2024

14

20 20
2 &3 TOR conditions & General conditions
compliance

21
 4. Certified Compliance from R.O. (For
Expansion case)
 Benzochem had obtained EC for existing production activity vide letter no. SEAC-
2013/CR-265/TC-2 dated 12th May 2015 from State Environmental Impact Assessment
Authority (SEIAA), Maharashtra

 The compliance of the existing EC conditions was monitored by Regional Office of MoEF &
CC by visiting the site on 20th November 2023 and Certified compliance of existing EC
conditions is available with us.

 BCIPL has valid Consent to Operate (CTO) vide No. Format 1.0/AS (T) /UAN No.
0000192646/CR/2402001853 dated 23/02/2024 and valid till 28/02/2028

 The compliance of the latest CTO condition was monitored by Sub Regional Officer of
MPCB Jalgaon on 3rd January 2024 . The Certified Compliance of Existing CTO is available
with us. As per the report, unit is complying all the consent conditions.

IRO Closure Report 22

 II. Industrial Production Process
5. Approval lay out plan with area details and 6 mts internal road and 9 mts
turning radius,No of buildings etc.

The Proposed layout is not yet submitted to MIDC for approval . It will be done
after obtaining confirmation from SEAC-1.

However the Benzochem Industries is having the MIDC approval for its existing
facility dated 10th July 2020.

23
6. Storage spaces for Raw material, chemicals, Hazardous material and finished
products. Details of Chemical Compatibility Chart for all chemicals and finished
products handled, stored on site.

Layout is already discussed in earlier slides

 COMPATIBILITY/ REACTIVITY HAZARD
Chemicals , Mixing With  1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
1 Acetone.
2 Acetyl Chloride. C
3 Aluminum Chloride, Anh. N N

4 Azodi Iso Butyro Nitrile. N N N

5 Benzene. Y C N Y
6 Benzoyl Chloride. C Y N N C
7 Hydrogen Peroxide. N N N N N N
8 Methyl Chloroformate. C Y N N C Y N
9 Methyl Isobutyl Ketone. Y C N N Y C N C

10 PhosphorusPentachloride. N N N N N N N N N

11 Propyleneimine. C N N N Y N N N C N SR
12 Sodium Borohydride. N N N N Y N N N N N N
13 Sodium Hydroxide Solution. N N N N Y N N N N N N N

14 Sodium Methylate. N N N N
CHARTYLEGEND
N N N N N N N C
15 Sulfuric Acid, Fuming. N N N N N N N N N N N N N N
16 Sulfuryl Chloride. C Y N N C Y N Y C N N N N N N
17 Titanium Tetrachloride. Y N N N Y N N N Y N N N N N N N

18 Water. Y N N N Y N N N Y N C N C C C N C
Y Compatible :No hazardous reactivity issues expected. C Caution: May be hazardous under certain conditions.

N Incompatible: Hazardous reactivity issues expected. SR Self Reactive: Potentially self reactive e.g. polymerizable.

Risk Mitigation:
a) Chemicals storage considering the compatibility/reactivity hazards at warehouse.
b) Leak detector and smoke detector at storage area.
PP Herewith commits that the Storages of chemicals will be strictly as per the MSDS and by following the
Compatibility Chart. Also the leak detection and smoke detection system will be installed at the storage
area.
25
 7. Sample material balance of 4/5 products.
Product Name: 1-Chloro methyl naphthalene

CH 2-Cl

+ HCHO + HCl + H2O

Naphthalene Paraformaldehyde 1-Chloromethyl Naphthalene Water

C10H8 CH 2O HCl C11H9Cl H2O
MW: 128.17 MW: 30.03 MW: 36.46 MW: 176.64 MW: 18.01

Process Description: Refined naphthalene is chloromethylated with

para formaldehyde and Hydro chloric acid in presence of TEAB and PEG-
400 to make

26
7. Sample material balance of 4/5 products.
Product Name: 1-Chloro methyl naphthalene

27
 7. Sample material balance of 4/5 products.
Product Name: 4-Methoxyphenyl acetone
O O O

H Cl O
+ + NaOCH 3 + NaOH Toluene H CH3 O Na + 2CH 3OH + NaCl
H3CO H3C O CH3
H3CO
p-Anisaldehyde Methyl 2-Cl-Propionate Sod Methoxide Sodium Salt of Epoxy Ester Methanol Sod Chloride
MW: 136.15 MW: 122.55 MW:54.02 MW: 230 MW:32.04 MW:58.44
C8H8O 2 C4H7ClO 2 CH 3NaO NaOH C11H11NaO 4 CH 4O NaCl
136.15 + 122.55 + 54.02 + 40.0 230.19 + 64.08 + 58.44

O O
O

H CH3 O Na + HCl
CH3 + NaCl + CO 2
H3CO H3CO

Sodium Salt of Epoxy Ester Hyd Chloric acid 4-Methoxy Phenyl Acetone (4MPA ) Sod.Chloride C.Dioxide
MW:98.07 MW: 164.2 MW:142.02 MW:44.0
MW: 230
C11H11NaO 4 HCl C10H12O 2 NaCl CO 2
230.19 + 36.46 164.20 + 58.44 + 44.0

Process Description:
p-Anisadehyde and Methyl-2-chloropropionate is reacted in presence
of Sodium methoxide and Caustic flakes to make sodium salt of epoxy
ester followed by hydrolysis and distillation to get 2-Methoxy
phenylacetone.

28
 7. Sample material balance of 4/5 products.
Product Name: 4-Methoxyphenyl acetone

29
 7. Sample material balance of 4/5 products.
Product Name: 4-Hydroxybenzyl alcohol

O Reduction OH
2x + NaBH 4 + 3H2O 2x + NaH 2BO3 + 2 H2
NaOH soln
HO HO

C7H6O 2 BH4Na H2O C 7H8O 2 BH2NaO 3 H2

4-Hydroxybenzaldehyde (PHB) Sod.borohydrate 4-Hydroxybenzyl alcohol (PHBL) Sod.dihydrogenborete Hydrogen
MW:122.12 MW:37.83 MW:124.14 MW: 83.81 MW: 2.02

244.24 + 37.83 + 54.05 248.28 + 83.81 + 4.04

Process Description:

Para hydroxy benzaldehyde is reduced with Sodium borohydride in presence of

caustic solution to make para hydroxybenzyl alcohol. Mass is acidifed with acetic acid
and purified.

30
 7. Sample material balance of 4/5 products.
Product Name: 4-Hydroxybenzyl alcohol

31
 7. Sample material balance of 4/5 products.
Product Name: Alpha Bromo-4- chlorophenylacetic acid

Process Description:
4-Chlorophenylacetic acid is bromminated in presence of MCB to make alpha bromo-
4-Chlorophenylacetic acid, After washing and crystalization, MCB is recovered for
recycle.

32
 7. Sample material balance of 4/5 products.
Product Name: Alpha Bromo-4- chlorophenylacetic acid

33
 8. Raw material consumption and hazard category quantity

Max.
No. Consu
Capacity stora
No. of of mptio Transport
Means of each ge Source
Sr. Tanks/Ve days n in Hazard ation (by
Chemicals/Items State Location of UOM storage capa (Local/I
No. ssels/Ba of Month Category Road/Air/
Storage tank/Ves city mport)
gs stor (Kgs/ Sea)
sel/Bag in
age M)
Kgs

1 2 Amino Benzamide Solid Godown Bags 13 kgs 50 10 667 1950 Corrosive Road Local

2 2 Amino Ethanol Liquid Godown Drum 9 kgs 50 20 1000 453 Toxic Road Local

2(4-Hydroxy-
3 Solid Godown Drum 20 kgs 25 20 1000 510 - Road Local
phenyl)acetamide

2,3-Dichlorobenzyl
4 Liquid Godown Drum 3 kgs 250 20 1000 762.5 Corrosive Road Local
chloride

5 2,3-Dichlorotoluene Liquid Godown Drum 3 kgs 200 20 1000 562.5 Flammable Road Local

2,4-Dichlorobenzyl
6 Liquid Godown Drum 4 kgs 200 10 1000 2600 Corrosive Sea+Road Import
chloride

2,6-Bis(hydroxy methyl)
7 Liquid Godown Drum 9 kgs 50 20 1000 440 - Sea+Road Import
pyridine

8 2,6-Dichlorotoluene Liquid Godown Drum 3 kgs 200 20 1000 600 Flammable Sea+Road Import

Semi
9 2,6-Xylenol Godown Drum 2 kgs 200 10 667 1345 Corrosive Road Local
Solid

34 34
 Max.
No. Consu
Capacit stora Transpor
of mption
Means No. of y of each ge Hazard tation Source
Sr. Locatio UO days in
Chemicals/Items State of Tanks/Ves storage capa Category (by (Local/I
No. n M of Month
Storage sels/Bags tank/Ves city Road/Air mport)
stor (Kgs/M
sel/Bag in /Sea)
age )
Kgs

2-Bromo benzyl
10 Solid Godown Drum 9 kgs 25 10 333 665 Toxic Road Local
bromide
11 2-Chloro Aniline Liquid Godown Drum 1 kgs 200 10 333 750 Toxic Road Local

Flammabl
12 2-Chloro phenol Liquid Godown Drum 2 kgs 200 20 500 347.5 Road Local
e

13 2-Chloro acetic acid Solid Godown Bags 18 kgs 25 10 500 1325 Toxic Road Local

2-Methoxy-phenol Sea+Roa
14 Liquid Godown Drum 2 kgs 200 20 500 340 Toxic Import
(Guaiacol) d

2-Tert Butyl-5-Methyl-
15 Liquid Godown Drum 5 kgs 200 10 1167 3150 Corrosive Road Local
Phenol

3- Chloro Phenyl Acetic

16 Solid Godown Bags 5 kgs 50 10 333 707.5 Corrosive Road Local
Acid

3 Hydroxy Benzoic
17 Solid Godown Drum 6 kgs 50 10 333 940 Toxic Road Local
Acid

18 3,5 Dimethyl Phenol Solid Godown Drum 7 kgs 50 10 500 1100 Toxic Road Local

35 35
 Max.
No. Consu
Capacit stora Transpor
of mption
Means No. of y of each ge Hazard tation Source
Sr. Locatio UO days in
Chemicals/Items State of Tanks/Ves storage capa Category (by (Local/I
No. n M of Month
Storage sels/Bags tank/Ves city Road/Air mport)
stor (Kgs/M
sel/Bag in /Sea)
age )
Kgs

19 3,5 Xylenol Solid Godown Drum 8 kgs 200 20 2000 1650 Toxic Road Local

Flammabl Sea+Roa
20 3-Chloro Anisol Liquid Godown Drum 2 kgs 200 10 500 1175 Import
e d

3-Hydroxy
21 Solid Godown Drum 14 kgs 50 20 1000 700 Corrosive Road Local
Benaldehyde

22 4-Bromo anisole Liquid Godown Drum 3 kgs 200 20 1000 650 Toxic Road Local

4-Bromo Benzyl
23 Solid Godown Drum 9 kgs 50 20 1000 462.5 Toxic Road Local
Cyanide

4-Bromo phenyl acetic

24 Solid Godown Drum 20 kgs 50 10 1000 3060 Toxic Road Local
acid

4-Chloro 4-Hydroxy
25 Solid Godown Drum 39 kgs 50 25 2000 1950 - Road Local
Benzophenone

26 4-Chloro benzaldehyde Solid Godown Drum 12 kgs 200 25 2000 2400 Corrosive Road Local

4-Chloro Benzyl
27 Liquid Godown Drum 3 kgs 200 20 1000 610 Toxic Road Local
chloride

36 36
 Max.
No. Consu
Capacit stora Transpor
of mption
Means No. of y of each ge Hazard tation Source
Sr. Locatio UO days in
Chemicals/Items State of Tanks/Ves storage capa Category (by (Local/I
No. n M of Month
Storage sels/Bags tank/Ves city Road/Air mport)
stor (Kgs/M
sel/Bag in /Sea)
age )
Kgs

4-chloro phenyl Acetic

28 Solid Godown Bags 15 kgs 25 20 500 377.5 Corrosive Road Local
acid
4-Cyanide benzyl
29 Solid Godown Drum 3 kgs 50 10 167 415 Toxic Road Local
cyanide
Toxic/
30 4-Isopropyl phenol. Solid Godown Bags 7 kgs 25 10 167 500 Flammabl Road Local
e

4-Methoxy
31 Solid Godown Drum 2 kgs 200 10 667 1450 Toxic Road Local
Acetophenone

4-Methyl Benzyl Sea+Roa

32 Liquid Godown Drum 3 kgs 200 20 1000 622.5 Toxic Import
chloride d

4-Methyl
33 Liquid Godown Drum 2 kgs 200 20 1000 465 Toxic Road Local
benzylcyanide

34 4-Methyl catechol Solid Godown Drum 33 kgs 25 25 1000 825 Toxic Road Local

Sea+Roa
35 4-Propylguaiacol Liquid Godown Drum 9 kgs 200 25 1500 1785 Toxic Import
d

9-Oxa-10-phospha-
36 Solid Godown Bags 42 kgs 20 20 1000 844.5 Toxic Road Local
phenanthrene 10-oxide

37 37
 Max.
No. Consu
Capacit stora Transpor
of mption
Means No. of y of each ge Hazard tation Source
Sr. Locatio UO days in
Chemicals/Items State of Tanks/Ves storage capa Category (by (Local/I
No. n M of Month
Storage sels/Bags tank/Ves city Road/Air mport)
stor (Kgs/M
sel/Bag in /Sea)
age )
Kgs

37 Acetic acid Liquid Godown Drum 69 kgs 35 10 1667 7275 Corrosive Road Local
Flammabl
38 Acetone Liquid Godown Drum 17 kgs 160 10 1667 7950 Road Local
e

39 Acetophenone Liquid Godown Drum 2 kgs 200 20 500 333.5 - Road Local

Flammabl
40 Acetyl Chloride Liquid Godown Drum 4 kgs 200 25 500 722 Road Local
e

Sea+Roa
41 Adamantane Solid Godown Drum 19 kgs 50 25 1000 950 Toxic Import
d

Hazardou
42 Alluminium Chloride Solid Godown Drum 13 kgs 200 10 1667 7748 Road Local
s

Ammonium
43 Solid Godown Drum 52 kgs 25 10 1000 3900 Toxic Road Local
bicarbonate

Flammabl
44 Anisole Liquid Godown Drum 2 kgs 200 15 500 350 Road Local
e

AIBN
45 Solid Godown Drum 1 kgs 25 15 100 23 Toxic Road Local
(Azobisisobutylonitrile)

38 38
 Max.
No. Consu
Capacit stora Transpor
of mption Hazard
Means No. of y of each ge tation Source
Sr. Locatio UO days in Category
Chemicals/Items State of Tanks/Ves storage capa (by (Local/I
No. n M of Month
Storage sels/Bags tank/Ves city Road/Air mport)
stor (Kgs/M
sel/Bag in /Sea)
age )
Kgs

Base oil.
Polyisocyanate based
on
46 hexamethylenediiscoya Godown Drum 2 kgs 150 20 500 281 - Road Local
nate
(HDI) Hydrophilically
(MPEG) modified HDI
(base 100 oil)
Flammabl
47 Benzene Liquid Godown Drum 3 kgs 200 20 1000 600 Road Local
e
Hazardou
48 Benzophenone Solid Godown Bags 20 kgs 25 20 500 500 Road Local
s

49 Benzoyl Chloride Liquid Godown Drum 1 kgs 250 10 333 690 Toxic Road Local

50 Benzyl Cyanide Liquid Godown Drum 4 kgs 200 10 667 2400 Toxic Road Local

Flammabl
51 Bromobenzene Liquid Godown Drum 2 kgs 200 20 500 425 Road Local
e

52 Calcium Hydroxide Solid Godown Bags 300 kgs 50 25 5000 15000 Corrosive Road Local

39 39
 Max.
No. Consu
Capacit stora Transpor
of mption
Means No. of y of each ge tation Source
Sr. Locatio UO days in Hazard
Chemicals/Items State of Tanks/Ves storage capa (by (Local/I
No. n M of Month Category
Storage sels/Bags tank/Ves city Road/Air mport)
stor (Kgs/M
sel/Bag in /Sea)
age )
Kgs

Plat
53 Carbon dioxide Gas Cylinder 6 kgs 50 10 83 885 Toxic Road Local
Form
54 Caustic Soda Flakes Solid Godown Bags 244 kgs 50 10 3333 36575 Corrosive Road Local

55 Copper Bromide Solid Godown Bags 1 kgs 25 10 33 110 Toxic Road Local

Hazardou
56 Copper Sulphate Solid Godown Bags 3 kgs 25 10 100 195 Road Local
s

57 Cuprous chloride Solid Godown Bags 1 kgs 25 10 33 85 Toxic Road Local

Flammabl
58 Cyclohexane Liquid Godown Drum 12 kgs 150 10 1000 5550 Road Local
e

Sea+Roa
59 Cynuric Chloride Solid Godown Drum 46 kgs 25 10 833 3420 Toxic Import
d

Hazardou
60 Diethylene Glycol Liquid Godown Drum 2 kgs 200 25 500 350 Road Local
s

61 Diethyl sulphate Liquid Godown Drum 4 kgs 250 10 667 2859.8 Toxic Road Local

RM list 40 40
 9. Production Process (Flow chart)

Product Name: 1-Chloromethyl naphthalene

(Sample is presented)

41
 10. Water consumption for process, Industrial cooling, Boiler use green belt
and Domestic use etc.

Particulars Consumption (CMD)

Water Requirement Existing Proposed Total

Industrial process, Scrubber 20 23 43

Vessel/Reactor /Drum/Floor
2 2 4
washing,

Cooling Tower makeup 60 108 168

Boiler makeup/DM 20 21 41

Sub Total (A) 102 154 256

Domestic (B) 9 12 21
Gardening (C) 0 4 4

Grand Total (A+B+C) 111 170 281

42
 11. Effluent generation and disposal / CETP/ ZLD

Particulars Effluent (CMD)

Water Requirement Existing Proposed Total

Industrial process, Scrubber 3.6 46.4 50

Vessel/Reactor /Drum/Floor
1.1 1.1 2.2
washing,

Cooling Tower makeup 9 17 26

Boiler makeup/DM 8 11 19

Live Steam Condensate from MEE 0 15.6 15.6

Sub Total (A) 21.7 91.1 112.8

Domestic (B) 6 11 17
Gardening (C) 0 0 0
Grand Total (A+B+C) 27.7 102.1 129.8

Proposed project will be Zero Liquid Discharge (ZLD).

43
 12. Hazardous waste generation, disposal and Solid Waste Management
Plan (Use/Reuse & Disposal of ETP sludge, Yeast sludge)
Additional
Category Existing
Sr No Name of Haz. Waste UoM Proposed Total Disposal
No. Quantity
Quantity
Process Residue and
1 28.1 MT/M 1.65 3.20 4.85 CHWTSDF
wastes

2 Distillation Residue 36.1 MT/M 1.5 14.89 16.39 CHWTSDF

Residue & waste

3 28.1 MT/M 0 0.03 0.03 CHWTSDF
(Hyflow)
Sale to authorised Party /
4 Spent Solvent 20.2 MT/M 0 16.90 16.90 CHWTSDF

Sale to authorised Party /

5 Hydrochloric Acid 28.1 MT/M 9.75 44.09 53.84 CHWTSDF

Sale to authorised Party /

Hydro bromic Acid
6 28.1 MT/M 0 22.07 22.07 CHWTSDF
(48 %)

Sale to authorised Party /

Liquor Ammonia
7 28.1 MT/M 0 5.54 5.54 CHWTSDF
(20 %)

Sale to authorised Party /

Sodium Bromide
8 28.1 MT/M 0 54.72 54.72 CHWTSDF
(20%)

Sale to authorised Party /

9 Crysalic acid 28.1 MT/M 1 0 1 CHWTSDF

CHWTSDF Membership 44 44
 12. Hazardous waste generation, disposal and Solid Waste Management
Plan (Use/Reuse & Disposal of ETP sludge, Yeast sludge)
Additional
Category Existing
Sr No Name of Haz. Waste UoM Proposed Total Disposal
No. Quantity
Quantity

Sale to authorised Party /

10 Sodium Bi sulfite 28.1 MT/M 2.5 16.08 18.58
CHWTSDF

Sodium Sulphate Sale to authorised Party /

11 28.1 MT/M 0 4.8 4.8
(30%) CHWTSDF

Poly Aluminium Sale to authorised Party /

12 28.1 MT/M 0 77.04 77.04
Chloride CHWTSDF

Chemical Sludge
13 from Waste water 35.3 MT/M 7 9 CHWTSDF
2
treatment
14 MEE Salts 37.3 MT/M 129 129 CHWTSDF

Spent Solvent from Sale to authorised Party /

15 20.2 MT/M 0 10 10
stripper CHWTSDF

Spent carbon from Co-processing to cement

16 35.3 MT/M 0 5 5
ETP Manufacturer/CHWTSDF
Sale to authorised Party /
17 Used or spent oil 5.1 MT/M 0 1.50 1.50
CHWTSDF
Contaminated
18 33.2 MT/M 0 1 1 CHWTSDF
cotton rags

CHWTSDF Membership 45 45
 12. Hazardous waste generation, disposal and Solid Waste Management
Plan (Use/Reuse & Disposal of ETP sludge, Yeast sludge)
Other Waste

Additional
Sr. Existing Total
Description Unit Proposed Disposal method
No. Quantity Quantity
Quantity

Sale to authorized dismantlers/

1 E-Waste TPA 0.0 1.0 1.0
Recyclers

Returned to battery manufacturer

2 Battery waste TPA 0.0 1.0 1.0 through authorized dealer on buy back
procurement

Disposed to authorized Biomedical

3 Biomedical Waste TPA 0.0 0.1 0.1
Waste site

4 Plastic waste TPA 0.0 10 10 Sale to authorized recycler

46 46
 12. Hazardous waste generation, disposal and Solid Waste Management
Plan (Use/Reuse & Disposal of ETP sludge, Yeast sludge)

Additional
Sr. No. Type of Waste Unit Existing Total Disposal
Proposed
Quantity Quantity
Quantity

1. Paper Bags MT/M 0.1 0.4 0.5 Sale as Scrap

2. Coal Ash MT/M 54 134 188 Sale to Brick Manufacturer

3. Briquette Ash MT/M 0 60 60 Sale to Brick Manufacturer

4. Discarded Drums Nos./M 50 100 150 Sale as Scrap

5. Empty Drums Nos./M 100 100 200 Reused / Sale

47 47
 13. Sewage generation, Treatment and disposal

Proposed Sewage treatment

Domestic waste water 17.00 CMD will be treated in proposed STP of 20 CMD and
treated waste water will be reused for gardening purpose during the non monsoon

season and for flushing during the monsoon season after disinfection.

48
 14. Pollution control system Air, Noise, Water, ETP, boiler, Fuel, Stack,
Incinerator
Boiler (TPH) Thermopack D.G (KVA)
(LacKCal/hr.)
(Proposed) (Existing) (Existing) (Existing)

Capacity 6 TPH 8 Lac Kcal/Hr. 400 KVA 500 KVA

Fuel type Coal / Briquette Coal / Briquette Diesel Diesel

Fuel quantity 20.50 TPD / 26.50 TPD 4.5 TPD / 7.20 TPD 84 Lit/Hr 108 Lit/Hr

MOC MS MS MS

Shape Cylindrical Cylindrical Cylindrical

Diameter (m) 0.8 0.3 0.3

Height (above 3 m above 3 m above

30 m enclosure enclosure
ground level)
Gas temperature 185 oC 140 oC 140 oC

Control Equipment Stack and acoustic Stack and acoustic

Multicyclone followed by Bag Filter enclosure enclosure

Note:
 Fuel quantity for existing and proposed Boilers & Thermopack is calculated for full load 24 hours working.
 Existing 4 TPH Boiler will be dismantled during proposed expansion and 6 TPH Boiler is to be Proposed in
expansion.
 DG set will be used only in case on Power Failure
49
 14. Pollution control system Air, Noise, Water, ETP, boiler, Fuel, Stack,
Incinerator
Parameter Process Scrubber

No of Scrubbers HCl Scrubber HBr Scrubber HCl Scrubber

Existing / Proposed Existing Existing Proposed

Scrubbing media Water Water Water

Random Column Packing

Pall Ring(25mm) HDPE Tellerates 2" Dia 2" PP LTHA Grade "S" type
telerates

Packing type MOC- PP MOC-HDPE MOC- PP

Temp 50 50 50
300 mm X 3150 mm X 2
Nos
400 mm 500 mm
350 mm X 3150 mm X 1
Diameter No
MOC PPH + FRP HDPE PP FRP

APC Equipment Caustic Tank NA Caustic Tank

Shape Cylindrical Cylindrical Cylindrical

Height 6500 mm 6970 mm 6950 mm

HCl Hydro bromic acid HCl

Pollutant
5050
 Pollution control system for Effluent

• Existing ETP capacity of 30 CMD will be scraped & new ETP having capacity 170 CMD
will be installed at site.
• Effluent will be segregated in High TDS/COD from process and Low TDS/COD stream
from process, utility blow down & washing activity.
• Effluent from process plant (50 CMD) will be fed to primary treatment. This primary
treated effluent followed by stripper along with RO reject (28.2 CMD), totaling to (78.2
CMD) will be fed to MEE followed by centrifuge.
• Utility blow down & washing (47.2 CMD) along with condensate from Multiple Effect
Evaporator (93.84 CMD), totaling to (141.04 CMD) will be fed to secondary treatment.
This treated waste water will be fed to tertiary treatment.
• Tertiary treated effluent (141.04 CMD) will be passed through proposed RO, RO
permeate (112.8 CMD) will be reused & reject (28.2 CMD) will be fed to MEE.
• Salts from MEE will be disposed to CHWTSDF. This will be complete Zero Liquid
Discharge (ZLD) project.

51 51
 Characterization
A) Characterization of the MEE unit
Raw High After Primary After Inlet to
Parameters Unit RO Reject Outlet from MEE
TDS Stream Treatment stripper MEE

93.84
Flow m3/day 50 50 50 28.2 78.2 (78.2+15.64 Live steam
condensate)
pH ---- 6-7.5 7-7.5 7-7.5 7-7.5 7-7.5 7-7.5
7500-
COD mg/lit 35000-45000 30000-40000 10000-20000 500-1000 3500-4500
12500
TSS mg/lit 300-400 80-100 80-100 80-100 80-100 80-100
50000-
TDS mg/lit 80000-90000 80000-90000 80000-90000 2000-3000 <200
60000
Notes: Live steam condensate from MEE will be mixed in secondary treatment.

Mixed solvent from stripper are considered in hazardous waste. So there will be minor reduction in the flow after
stripper.

B) Characterization of LOW COD & LOW COD Stream from Process,& Utility:
Raw Low Outlet Outlet
from Inlet to Inlet to Inlet to
Parameters Unit TDS from from from
utilities primary Secondary tertiary
washing primary tertiary
141.04
FLOW m3/day 45 2.2 47.2 47.2 (47.2 +93.84 141.04 141.04
MEE Outlet )
pH ---- 6.0-7.0 6.0-7.0 6.0-7.0 7-7.5 7-7.5 7-7.5 7-7.5
COD mg/lit 200-300 350-450 250-350 200-300 2000-3000 500-550 150-250
BOD3, 27°C mg/lit 100-150 150-250 100-200 100-150 1000-1500 50-70 30-50
TSS mg/lit 300-400 350-450 300-400 80-100 80-100 80-100 50-80
TDS mg/lit 1200-1400 400-500 1150-1350 1150-1350 500-600 500-600 52
500-600 52
C) Characterization of Reverse Osmosis:

Permeate Reject
Parameters Unit Inlet to RO
(90%) (10%)

FLOW m3/day 141.04 112.8 28.24

pH ---- 7-7.5 7-7.5 7-7.5

COD mg/lit 150-250 30-50 500-1000

TDS mg/lit 500-600 <150 2000-3000

53 53
 Units and Equipment Required for the new ETP
Capacity
Sr. No. Description Quantity MOC Remarks
Required
A) Civil Units & M.S Units
1 Screening Chamber 3.93 m3 1 No. AR-RCC Proposed
2 Oil & Grease Trap 3.93 m3 each 1 Nos. AR-RCC Proposed
3 Equalization Tank 7.87 m3 each 1 Nos. AR-RCC Proposed
4 Flash Mixer 0.16 m3 each 1 Nos. -- Proposed
5 Settling Tank 6.88 m3 each 1 Nos. RCC Proposed
6 1st Stage Bioreactor 255 m3 1 Nos. RCC Proposed
7 2nd Stage Bioreactor 77 m3 1 Nos. RCC Proposed
8 Intermediate Tank 11.75 m3 1 No. -- Proposed
1.23 m 1 No.
9 Pressure sand filter FRP Proposed
Diameter
1.11 m 1 No.
10 Activated carbon filter FRP Proposed
Diameter
B) MS Fabricated, Mechanical & Bought out Equipment List
8 Total Alum Dosing Tank Capacity 1646 Lit/day 1 Nos. PP/FRP Proposed
9 Alum dosing pump for flash mixer 10 Lit/hr. 1 No. PP Proposed
C) Instrumentation
10 Magnetic Flow meter Suitable 3 Nos. -- Proposed
11 pH indicator 0-14 pH 2 Nos. -- Proposed
12 Pressure Gauges Suitable -- -- Proposed
13 Level Switches -- -- -- Proposed

54 54
PROCESS FLOW DIAGRAM OF ETP

ETP 55 55
 15.Life cycle assessment (cradle to gate) for all products and
mitigation measures to reduce the impact

• Objective of this study is to quantify the environmental impacts of activities carried

out on site
• The study has been carried out by using SimaPro Software.
• Though the scope of an LCA include Cradle-to-Grave approach, we have
considered Cradle-to-gate approach while assessing the impact on environment
due to proposed activity.
• Environmental impacts, only due to the on-site activities of the company are
considered and mitigation measures are suggested accordingly.
• All the products are selected for the study.
• In the LCA, the analysis was considering major parameters such as consumption of
fuel, electrical energy.

LCA Calculation
56
 ENVIRONMENTAL INDICATORS FOR 2-Amino-2-phenylbutyric acid per
ton of product

Impact category Unit Process Heating Electricity Gate to Gate

Global warming kg CO2 eq
(GWP100a)
248.0894 1669.448 1917.538
Ozone layer depletion kg CFC-11 eq
(ODP)
3.12E-06 1.23E-05 1.55E-05
Human toxicity kg 1,4-DB eq
41.90862 583.1115 625.0201
Terrestrial ecotoxicity kg 1,4-DB eq
1.584763 2.162852 3.747615
Photochemical oxidation kg C2H4 eq
0.080525 0.266957 0.347482
Acidification kg SO2 eq
1.985403 6.020023 8.005425
Eutrophication kg PO4--- eq
0.079921 2.648614 2.728536

57
ENVIRONMENTAL INDICATORS FOR 2-Amino-2-phenylbutyric acid
per Ton of product

58
 GWP (KG CO2 EQUIVALENT) INDICATOR FOR ALL PRODUCTS

Kg CO2equi./Kg
Sr. No. Product Name
of product

1 Group A (Para Chloro Meta Xylenol, Biclothymol) 3.59

2 Group B (2-Phenylbutyric acid, 2-Bromo-5-hydroxybenzoic acid) 4.70
3 Group C (4-Isopropyl catechol, 1-Bromo-2-chloro-Benzene) 7.48
4 Group D (2-(4-Chlorophenyl)-1,3-dioxolane, 2,4-Dihydroxybenzoic acid) 4.37
5 Group E (4-Propylcatechol 60% solution, 3-Methoxybenzoic acid) 3.73
6 Group F (1-Naphthylacetonitrile, 1-Naphthaldehyde) 5.04
7 Group G (3-Chlorophenol, 2-Aminobenzonitrile) 5.97
8 Group H (4-Methyl Benzyl Alcohol, 3-Coumaranone) 12.70
9 Group I (4-Bromophenylacetic acid) 2.77
10 Group J (4-Methylbenzyl chloride, 4-Methylphenylacetic acid) 4.80
11 Group K (5-Chloro-2-Hydroxybenzophenone, 2-Phenoxyacetic acid) 4.82
12 Group L (Para chlorobenzyl alcohol) 3.59
13 Group M (4-Methylcatechol diacetic acid dimethyl ester, 4-Methylguaiacol) 7.53
14 Group N (Para chloro ortho cresol ) 2.08
15 Group O (2,6-Dichlorobenzylchloride, 2-Chlorodiphenyl ether) 16.90
16 Group P (5-Bromo 2-methoxy phenol, 5-Bromo 2-chlorobenzaldeyhde) 7.41
17 Group Q (1-Acetylnaphthalene) 3.63
18 Group R (4-Methyl Benzaldehyde, DOPO -EDA) 7.42

59
 GWP (KG CO2 EQUIVALENT) INDICATOR FOR ALL PRODUCTS

Kg CO2equi./Kg
Sr. No. Product Name
of product

19 Group S (1,4-Dibromonaphthalene) 1.77

20 Group T (2-Methylanisole, 7-Methoxy-1-tetralone) 2.30
21 Group U (3,4,5-Trimethoxybenzoic acid & ester) 6.69
22 Group V (Oligo-x-100) 3.19
23 1-Chloromethyl naphthalene 2.08
24 2-Amino-2-phenylbutyric acid 1.92
25 2-Amino-2-phenylbutyric acid sodium salt (TR1600) 2.05
26 2-Dimethylamino-2-phenyl-1-butanol 4.58
27 4-Hydroxybenzyl alcohol 3.70
28 4-Methoxyphenyl acetone 1.20
29 6-Chloro-4-Hydroxy-5-Methylpyridin-2-(1H)-one 2.14
30 Alpha bromo-2-Chloro phenyl acetic acid methyl ester. 1.17
31 Ortho Phthalaldehyde 5.65
Tributylethylammonium ethyl sulphate solution(68-72% in Isobutyl
32 0.21
alcohol)
33 2 4 Dichlorobenzyl alcohol 2.06
34 Para chloro meta cresol 2.19
Total 151.4

From each group product worst case scenario is considered while calculating Carbon footprint
60
 CO2 reduction can be achieved by following methods
Reduce Electricity Consumption by use of Variable Frequency Drives (VFD) & IE-3 Motors.

Proposed After mitigation

Total Reduction in
Power generating CO2 emission
Power CO2 Generation CO2 Generation
after adopting VFD (A-B)
Consumption (A) (B)
and IE3 motors

800 kW 1309 Kg CO2 560 kW 917 Kg CO2 392 Kg CO2

Reduction in CO2 emission due to renewable energy:-

Benzochem will install Solar Plant of capacity 110 kWp at the site.

Proposed After mitigation

Total Reduction in
Power generation CO2 emission
Power CO2 Generation CO2 Generation
after installation of (A-B)
Consumption (A) (B)
Solar

800 kW 1309 Kg CO2 690 kW 1129 Kg CO2 180 Kg CO2

61
 CALCULATION OF CARBON FOOTPRINT
Carbon Offset Measures:-

Total Number of trees which will be planted in Greenbelt (35%) =1276 nos.

Also besides the above trees planted, additional 2500 trees will be planted as a
part of the CER activities which will further offset the CO2 footprint.

Thus the total trees will be 3776nos.

CO2 absorbed by trees is 3776 x 20 = 75520 Kg of CO2 Annually i.e. 75520 / 365=
207 Kg of CO2 per day

Thus the reduction of CO2 emission by providing the trees will be 207 kg of
CO2 per day after trees will be fully grown up

Note for assumptions assumed for above calculation:

o Average lifespan of tree assumed: 40 years
o Average carbon absorption by a tree assumed: 20 kg/ year
Source: https://www.grow-trees.com/

Fully grown matured tree will absorb 20 kg of CO2/year.

62
 CALCULATION OF CARBON FOOTPRINT

Total Reduction in CO2 emission =

Reduction in CO2 emission due to use of VFD & IE3 + due to renewable energy + Tree
Plantation
Total Reduction in CO2 emission = 392 + 180 + 207
= 779 Kg= 0.779 Ton

Carbon footprint without mitigations = 2.993 kg/kg (13584.9 kg CO2 per day/
4538.5 kg per day production)

Carbon footprint with mitigations = 2.821 kg/kg (12805.2 kg CO2 per day)/
4538.5 kg per day production)
Percentage reduction in CO2 = 5.74 %

63
16. Firefighting system, equipment’s and guidelines instruction
during accident emergencies for hazardous material and risk
assessment
Fire Hydrant System
TOTAL
SN. ITEM/ TYPE (Nos.)

1 Fire water;
 Fire water storage. m3
 Fire water catchment pit.
2 Fire water pumps;
 Electric motor driven pump. 1
(410/273 m3/hr, 88 Mtr. head, 2900/1800 rpm).
 Diesel engine driven pump. 1
(410/273 m3/hr, 88 Mtr. head, 2900/1800 rpm).
 Electric motor driven jockey pump. 1
(25 m3/hr, 88 Mtr. head, 2900/1800 rpm).

3 Automatic sprinkler system with alarm;

 Pendant Sprinkler - type (65°C temp.). 184
4 Water curtain. 0
64
 16. Firefighting system, equipment’s and guidelines instruction during
accident emergencies for hazardous material and risk assessment
Fire Hydrant System
Existing
SN. ITEM/ TYPE
(Nos.)
Fire Hydrants & Accessories.
Fire Hydrants:
 Single Headed Hydrant (External). 13
 Fire Internal Hydrant (Internal). 35
M.S. hose boxes;
 External. 13
 Internal. 37
Hoses (as per IS:636);
 15 Mtr. Long (External). 83
 7.5 Mtr. Long (Internal). 0
5  Hose reel drum (as per IS: 884). 30
 Branch pipe with nozzle. 50
 Water monitors to achieve a throw of 60 m horizontally & 45 m 02
vertically.
 Foam monitor to achieve a throw of 60 m horizontally & 45 m 03
vertically.
 Fire brigade 4-way inlet connection. 1
 Tank filling 2-way connection. 1
 Foam for Foam Monitor. 03
 Sweeping Machine 01

65
 List of Fire Extinguishers

Capacity
SN. ITEM/ TYPE Total (Nos.)
(Kg.)

1 DCP. 10 Kg. 28
06 Kg. 33
02 Kg. 06
TOTAL 64
2 CO2. 02 Kg. 05
4.5 Kg. 06
09 Kg. 05
TOTAL 16
3 Sand Buckets. - 34
4 Foam Extinguisher 04 Kg. 0
05 Kg. 0
09 Kg. 38
TOTAL 38

66
 Safety System (Detector, Alarms & Warning Siren)

Additional/
Existing TOTAL
SN. ITEM/ TYPE Proposed
(Nos.) (Nos.)
(Nos.)

1 Fire detection system;

 Fire alarm control panel with battery backup. 02 0 02

 Beam detector. 09 0 09
 Smoke detector. 35 0 35
 Manual Call Point. 37 0 37
 Gas detector. 0 0 0
 Sounder (Hooter). 10 0 10
2 Siren - Range: 1.5 Km. 01 0 01
3 Wind direction sock. 03 0 03
4 Sign indicators, Posters. 32 0 32
5 Back up battery. 8 0 8
6 Oxygen meter. 02 0 02
7 Safety shower & eye wash fountain. 13 0 13

8 Fire suit. 02 0 02

67
 Risk & HAZOP Study

THE PROPOSAL AT GLANCE

PROPOSED PRODUCTS FOR ENVIRONMENTAL CLEARANCE

SR.
DESCRIPTION EXISTING CAPACITY PROPOSED CAPACITY TOTAL CAPACITY
NO.

1 Products. 53.63 MT/M 81.65 MT/M 135.28 MT/M

Group wise number of products and production capacity change;

GROUP A B C D E F G H I J K L M N O P Q R S T U V * Total
Eliminate - - - - - - - 1 - - - - - - - - - - - 1 - 1 - 3
d
Scale 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 2
Down
Scale Up 1 2 0 0 0 2 1 0 0 2 2 0 0 0 0 0 1 1 0 1 0 1 6 20
New 3 1 4 3 4 1 3 3 3 1 1 3 4 2 4 4 4 5 5 5 6 6 7 82
TOTAL 4 3 4 3 4 3 4 4 3 3 3 3 4 2 4 4 5 6 5 7 6 8 15 107

*Individual products .
 Proposed scale up factor of 1.52
 Increase in manpower by 72 nos.
68
 IDENTIFICATION OF HAZARDS: HAZARDOUS CHEMICALS
Max. Qty.
Sr. MODE OF Ref.
NAME CAS NO. Stored REMARK
No. STORAGE No.*
(Kg.)
1 Acetic Acid. 64-19-7 35 Kg. Drum. 1667 2 -
2 Acetone. 67-64-1 160 Kg. Drum. 1667 4 Very highly flammable liquids.
3 Aluminum Chloride. 7446-70-0 200 Kg. Drum. 1667 22 -
4 Benzene. 71-43-2 200 Kg. Drum. 1000 56 Very highly flammable liquids.
5 Benzophenone. 119-61-6 25 Kg. Bags. 500 63 -
6 Benzoyl Chloride. 98-88-4 250 Kg. Drum. 333 65 Highly toxic.
7 Benzyl Cyanide. 100-44-7 200 Kg. Drum. 667 67 Extremely toxic.
8 Bromine. 7726-95-6 3 Liters Bottle 603 84 Toxic.
9 Chlorine. 7782-50-5 Cylinder/ Tuner. 900 119 Highly toxic.
10 Mono ChloroBenzene. 108-90-7 225 Kg. Drum. 1000 128 Highly flammable liquids.
11 Copper Sulphate. 7758-99-8 25 Kg. Bags. 100 146 -
12 Diethylene Glycol. 111-46-6 200 Kg. Drum. 500 197 -
13 Ethyl Acetate. 141-78-6 160 Kg. Drum. 1667 247 Very highly flammable liquids.
14 Ethanol. 64-17-5 200 Kg. Drum. 1667 248 Very highly flammable liquids.
15 Ethylene Diamine. 107-15-3 200 Kg. Drum. 500 264 -
16 Ferric Chloride. 107-15-3 50 Kg. Drum. 100 264 -
17 Mono Ethylene Glycol. 107-21-1 250 Kg. Drum. 1000 267 -
18 Ethylene Dichloride. 107-06-2 250 Kg. Drum. 1000 271 Very highly flammable liquids.
19 Formic Acid. 64-18-6 35 Kg. Drum. 667 287 -
20 Hydrogen Peroxide. 7722-84-1 50 Kg. Drum. 1000 318 -
* Reference No. is the Sr. No. of hazardous chemical as listed in Schedule 1 Part II of
“The MSIHC Rules, 1989” and amendments. 69
 IDENTIFICATION OF HAZARDS: HAZARDOUS CHEMICALS
Max. Qty.
SR. MODE OF REF.
NAME CAS NO. Stored REMARK
NO. STORAGE NO.*
(Kg.)
21 Isopropyl Alcohol. 67-63-0 200 Kg. Drum. 1000 334 Very highly flammable liquids.
22 Methanol. 67-56-1 Storage Tank. 20000 377 Very highly flammable liquids.
23 Mono Methyl Amine gas. 74-89-5 50 Kg. 150 378 Flammable gas & highly toxic.
Cylinder.
24 Methyl Chloroformate. 79-22-1 250 Kg. Drum. 500 382 Very highly flammable liquids
Extremely toxic.
25 Methyl Isobutyl Ketone. 108-10-1 200 Kg. Drum. 1000 388 Very highly flammable liquids.

26 Refined Naphthalene. 91-20-3 25 Kg. Bags. 1333 417 -

27 Ortho Cresol. 95-48-7 200 Kg. Drum. 667 439 -
28 Phenol. 108-95-2 200 Kg. Drum. 1000 481 Extremely toxic.
29 Phosphorus 10026-13-8 25 Kg. Drum. 667 507 -
Pentachloride.
30 Phthalic Anhydride. 85-44-9 25 Kg. Drum. 1000 508 -
31 Potassium Hydroxide. 1310-58-3 50 Kg. Bags. 667 522 -
32 Propionitrile. 107-12-0 160 Kg. Drum. 500 535 Very highly flammable liquids &
toxic.
33 Propyleneimine. 75-55-8 200 Kg. Drum. 100 541 Very highly flammable liquids.
34 Sodium Cyanide. 143-33-9 50 Kg. Bags. 667 569 -
35 Sodium Hydroxide. 1310-73-2 50 Kg. Bags. 10000 571 -
36 Sulfuric Acid. 7664-93-9 Storage Tank. 20000 591 -
37 Thionyl Chloride. 7719-09-7 300 Kg. Drum. 1667 620 Toxic.
38 Thiourea (2-Methyl 614-78-8 50 Kg. Drum. 50 624 -
Phenyl)/ 85344-82-1 623
(2-Chloro-Phenyl).
39 Titanium Tetrachloride. 7550-45-0 50 Kg. Drum. 17 627

40 Toluene. 108-88-3 Storage Tank. 20000 628 Very highly flammable liquids.
* Reference No. is the Sr. No. of hazardous chemical as listed in Schedule 1 Part II of 70
“The MSIHC Rules, 1989” and amendments.
 IDENTIFICATION OF HAZARDS: HAZARDOUS CHEMICALS

Max. Qty.
Sr. No. NAME CAS NO. Mode Of Storage Remark
Stored (Kgs)
1 AIBN 78-67-1 25 Kg. Drum. 100 *Auto-ignition temperature 64oC &
(Azo Bis Iso Butylo Nitrile). decomposition temperature 105oC.
2 Cynuric Chloride. 108-77-0 25 Kg. Drum. 833 Extremely toxic.
3 Dimethyl Sulphate. 77-78-1 250 Kg. Drum. 2000 Extremely toxic.
4 Mono Chloro Acetic Acid. 79-11-8 50 Kg. Drum. 667 Extremely toxic.
5 Sodium Borohydride. 16940-66-2 50 Kg. Drum. 3333 Extremely toxic.
6 Para Methyl Benzyl Chloride. 104-82-5 200 Kg. Drum. 500 Flammable liquids.
7 Iso Propyl Alcohol 25% HCl. 67-63-0 40 Kg. Drum. 500 Very highly flammable liquids.
7647-01-0
8 Iso Butyric Acid. 79-31-2 200 Kg. Drum. 500 Highly flammable liquids & highly toxic.
9 Anisole. 100-66-37 200 Kg. Drum. 500 Highly flammable liquids.
10 Di Methyl Formamide. 68-12-2 200 Kg. Drum. 1500 Highly flammable liquids.
11 Ethyl Chloroacetate. 105-39-5 200 Kg. Drum. 1667 Highly flammable liquids.
12 Iso Butyl Alcohol. 78-83-1 200 Kg. Drum. 1667 Highly flammable liquids.
13 Para Xylene. 106-42-3 200 Kg. Drum. 1000 Highly flammable liquids.
14 Sodium Methoxide. 124-41-4 110 kg Drum. 1333 Highly flammable liquids.
15 Para Cresol. 106-44-5 200 Kg. Drum. 833 Highly toxic.
16 Para Formaldehyde. 30525-89-4 25 Kg. Bags. 2000 Highly toxic.
17 Hydrochloric Acid. 7647-01-0 Storage Tank. 20000 Toxic.
18 Acetyl Chloride. 75-36-5 200 Kg. Drum. 500 Very highly flammable liquids.
19 Cyclohexane. 110-82-7 150 Kg. Drum. 1000 Very highly flammable liquids.
20 Mintroleum. 109-66-0 150 Kg. Drum. 2000 Very highly flammable liquids.
110-54-3
21 Vitride/ Sinhydride. 22722-98-1 200 kg Drum. 1000 Very highly flammable liquids.
71
 INVENTORY ANALYSIS

Applicability of The Manufacture Storage and Import of Hazardous Chemicals (MSIHC) Rules, 1989 and amendments.

Maximum
Threshold Quantity Mt
Storage
GROUP Material For application of MSIHC Rules 1989*
Capacity

Mt. 5, 7-9, 13-15 10 - 12

2 Toxic substance. Bromine. 5 40 500

Chlorine. 3 10 25
Very Highly Flammable Flash Point ≤ 23oC & < threshold 1,500 10,000
Liquids. Initial Boiling Point >35oC
5.3

5.5 Highly Flammable 23oC < Flash Point ≤ 60oC < threshold 2,500 20,000
Liquids.

5.6 Flammable Liquids. 60oC < Flash Point < 900C < threshold 5,000 50,000

Applicability of “The Public Liability Insurance (PLI) Act, 1991”

The inventory of hazardous chemicals is less than threshold specified in the list of chemicals with
quantities for application of “The PLI Act, 1991”.
(Ref. Criteria used: MOEF notification New Delhi the 24th March 1992).

As the proposed revised inventory is less than the threshold the site is not
classified as MAH installation.

72
 COMPATIBILITY/ REACTIVITY HAZARD
Chemicals , Mixing With  1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
1 Acetone.
2 Acetyl Chloride. C
3 Aluminum Chloride, Anh. N N

4 Azodi Iso Butyro Nitrile. N N N

5 Benzene. Y C N Y
6 Benzoyl Chloride. C Y N N C
7 Hydrogen Peroxide. N N N N N N
8 Methyl Chloroformate. C Y N N C Y N
9 Methyl Isobutyl Ketone. Y C N N Y C N C

10 PhosphorusPentachloride. N N N N N N N N N

11 Propyleneimine. C N N N Y N N N C N SR
12 Sodium Borohydride. N N N N Y N N N N N N
13 Sodium Hydroxide Solution. N N N N Y N N N N N N N

14 Sodium Methylate. N N N N
CHARTYLEGEND
N N N N N N N C
15 Sulfuric Acid, Fuming. N N N N N N N N N N N N N N
16 Sulfuryl Chloride. C Y N N C Y N Y C N N N N N N
17 Titanium Tetrachloride. Y N N N Y N N N Y N N N N N N N

18 Water. Y N N N Y N N N Y N C N C C C N C
Y Compatible :No hazardous reactivity issues expected. C Caution: May be hazardous under certain conditions.

N Incompatible: Hazardous reactivity issues expected. SR Self Reactive: Potentially self reactive e.g. polymerizable.

Risk Mitigation:
a) Chemicals storage considering the compatibility/reactivity hazards at warehouse.
b) Leak detector and smoke detector at storage area.

PP herewith confirms that the Storages of Chemicals will be done as per MSDS & by following
Compatibility chart, also the leak detection system and smoke detectors will be installed at the location.
73
 MITIGATION MEASURES - EVENT FREQUENCY REDUCTION

1. Loading - unloading platform & over head chain pulley block arrangement to avoid abuse of cylinders
handling.
2. Leak detection and alarm system at storage, plant, scrubber vent and compound wall with signal at ECC.
3. Use standard Copper tube, connector and key.
4. Barometric leg & NRV in feed line to plant.
5. Ensure tonner valve protection caps in place.
6. Periodic safety inspection/ checking of cylinders in storage for general condition and leakages.
7. Full cylinders should be stored such that the oldest stock will be used first.
8. Preventive maintenance.
9. Work area monitoring Chlorine exposure at work place within TWA: 1 ppm & STEL: 3 ppm.
10. Safety Audit.
11. Emergency power supply.
12. Work permit.
13. Safety Training.
14. Community safety awareness programs.
15. Mock Drills involving external emergency respondents and LCG members.
16. Display safety posters & cautionary notice.
17. Chlorine seamless pipe, minimum flange joints in piping, storage and periodic pressure equipments testing as
per statutory requirements.

74
 MITIGATION MEASURES - CONSEQUENCE REDUCTION

1. Totally closed room for Chlorine storage, blower and Caustic scrubber.
2. Roller supports for tonners.
3. Chlorine leak control kit and tonner hood.
4. Area access restricted to authorized persons only.
5. Stock of neutralizing materials.
6. Safety shower and eye wash fountain.
7. Fire fighting system.
8. Wind direction sock.
9. PPE & canister type gas masks and SCBA (Self Contained Breathing
Apparatus).
10. Display emergency instructions.
11. Medical Oxygen cylinder at first aid room.
12. Emergency vehicle.

75
CHLORINE RELEASE - INDIVIDUAL RISK CONTOUR - WITHOUT RISK MITIGATION

INDIVIDUAL RISK PER YEAR

Contour 1 9.1  10-4

Contour2 9.1  10-5

Contour 3 9.1  10-6

Worst Case Scenario/ MCA:

Loss of containment of Chlorine tonner - Chlorine 900 Kg. release.
Assumptions:
Wind: 1.5 meters/second from WSW at 3 meters. Ground Roughness: open country.
Cloud Cover: 5 tenths. Air Temperature: 30° C. Stability
Class: F; No Inversion Height. Relative Humidity: 50%.

76
Risk mitigation measures for chlorine release
 MARPLOT – BROMINE RELEASE

Event A: Instantaneous release of

liquid Bromine 3.5 Mt.
Event B: Bromine 35 Kg.
evaporating pool of 1 m2
size.
Event C: Minor leak.

ERPG 3
Event Loss of containment
Distance
A Off Site Emergency 310 m
(MCA).
B On Site Emergency 105 m
(MCLS).
C Plant Emergency. <10 m

77
Risk mitigation measures for Bromine release
 MITIGATION MEASURES - EVENT FREQUENCY REDUCTION

1. Dry, well-ventilated, protected from moisture and excessive heat or cold Bromine store.
2. Leak detection and alarm system at storage, plant, scrubber vent and compound wall with signal
at ECC.
3. Avoid storage with reducing agents.
4. Protect containers against physical damage and check regularly for leaks.
5. Preventive maintenance.
6. Work area monitoring Bromine exposure at work place within TWA:0.1 ppm & STEL: 0.3 ppm.
7. Procedure for handling and safe disposal of shock sensitive Dry Bromates (Bromine neutralization
products).
8. Safety Audit.
9. Emergency power supply.
10. Work permit.
11. Safety Training.
12. Community safety awareness programs.
13. Mock Drills involving external emergency respondents and LCG members.
14. Display safety posters & cautionary notice.

78
 MITIGATION MEASURES – EVENT CONSEQUENCE REDUCTION

1. Spill collection pit with sand at store.

2. Blower and Caustic scrubber.
3. Area access restricted to authorized persons only.
4. Stock of neutralizing materials such as Sodium Thio Sulphate, Sodium Meta Bi Sulphate,
Sodium Carbonate.
5. Safety shower and eye wash fountain.
6. Fire fighting system.
7. Wind direction sock.
8. PPE & canister type gas masks and SCBA (Self Contained Breathing Apparatus).
9. Display emergency instructions.
10. Medical Oxygen cylinder at first aid room.
11. Emergency vehicle.

79
 MARPLOT: FIRE AND EXPLOSION – MMA RELEASE

FLAMMABLE VAPOR CLOUD

VAPOUR CLOUD EXPLOSION

80
 SOLVENT STORAGE AND HANDLING
Mitigation Measures -Spill, Fire/Explosion Event Frequency Reduction
i. Layout: Dedicated storage as per PESO guidelines.
ii. Detection and warning: Leak detection system.
iii. Prohibition of sources of ignition:
i. Explosion-proof electrical equipment and lighting.
ii. Vehicles be fitted with spark arrestor.
iii. Flame arrestor at vent of condenser.
iv. Static charge control:
i. Earthing and bonding to control static charge.
ii. Avoid free fall of static sensitive solvents in the tank/ reactor.
iii. Use of antistatic belt for drive.
v. Design:
i. Dedicated pipe work, minimum number of flanges, joints and valves in pipelines.
ii. Adequate capacity condenser for solvent recovery.
iii. Secondary condenser with chilled water as cooling medium for solvent recovery.
iv. Emergency cooling water connection to condenser from overhead water storage tank.
vi. Procedures/ permits and safety system:
i. Nitrogen for inerting and breaking vacuum during solvent recovery by distillation.
ii. Checking quality of Nitrogen used for inertization. (especially for oxygen content).
iii. Monitoring of impurity profile of solvent Recycle stream by QC laboratory.
iv. Regular safety inspection.
v. Preventive maintenance.
81
vi. Work permit.
 SOLVENT STORAGE AND HANDLING

MITIGATION MEASURES - CONSEQUENCE REDUCTION

SPILL;
 Spill control kit.
 PPE – protective gloves, protective clothing, face shield, or eye protection in
combination with breathing protection.
 Collection and routing of spill/ floor washings, sprinkler water to ETP.
 Safety shower and eye wash fountain.

FIRE/ EXPLOSION;
 Smoke detector, heat detector, fire break glass alarm system.
 Sprinkler system.
 Portable fire extinguishers.
 Fire hydrant system with fire water runoff collection system.
 Emergency power.
 Emergency action plan.
82
 MITIGATION MEASURES - FUGITIVE EMISSION

1. Vent of the tank connected to condenser for recovery improvement.

2. VOC absorption media, activated Carbon filter connected to the receiver vents.
3. Work place monitoring for air born concentration of chemicals within the prescribed
limits.
4. Entire process will be carried out in the closed system and piping system.
5. Provision of double mechanical seals in pumps.
6. Monitoring and preventive maintenance of pumps, valves, flanges, joints etc.
7. Drums will be capped properly.
8. Breather valves over solvent receivers/ tank.
9. Fugitive emission over reactors, formulation areas, centrifuges, chemical loading and
transfer area shall be collected through hoods and ducts by induced draft and
controlled by dust collector.
10. Spraying water to control dust or providing enclosures.
11. Provision of double mechanical seals in transfer pumps.
12. Use AODP or peristaltic pump for transfer of solvent at reactor.
13. Minimize transfer by hoses.
83
 PROCESS EMISSION CONTROL

PROCESS EMISSIONS AT REACTOR PRODUCT (NO. AS PER EIA REPORT)

VENT
Sulfur Di Oxide. Product No. 2 & 23 release of Sulfur Di Oxide.
Hydrogen Sulfide. Product No. 84 release of Hydrogen Sulfide.
Carbon Di Oxide. Product No. 1, 3, 5, 13, 14 & 27 release of
Carbon Di Oxide.
Nitrogen. Product No. 9 release of Nitrogen.
Methyl Bromide. Product No. 3 release of Hydrogen.
Product No. 16 & 25 release of Methyl Bromide.
Hydrogen. Product No. 3 release of Hydrogen.
MMA Gas. Product No. 84 unreacted MMA.
(as 30 % stiochometric excess gas used).
Hydrogen Chloride & Chlorine. Existing Product No. 34 & 85.
New Product No. 47, 50, 60, 62, 63, 69 & 80.
Hydrogen Bromide & Bromine. New Product No. 40, 52, 53, 54, 55, 57, 67 & 87.
Existing Product No. 100.
Hydrogen Chloride & Sulfur Di Oxide. Product No. 48, 70, 92, 99, 103 & 104.

Risk Mitigation:
Provide interlocks to stop feed to Chlorine & Bromine scrubber and source in case the vent
emission to atmosphere exceeds set value.

84
STORAGE AND HANDLING OF HAZARDOUS CHEMICALS INDIVIDUALLY
All hazardous chemicals are covered in the QRA report in the following format as example
two chemicals are reproduced here;
1 Sulfuric 7664-93-9 20000 591 Water  Spill containment dyke for tank.
Acid. reactive.  Face shield, or eye protection, apron.
Corrosive.  Safety shower and eye wash fountain.
 Splash guards on flange guards in transfer line.
 Piping color code.
 Training.
 Acid proof tile flooring in handling area.
 Work permit.
 When diluting, always add the acid to water; never
add water to the acid.
 Neutralize with alkaline material (soda ash, lime),
then absorb with an inert material (e.g., vermiculite,
dry sand, earth).
2 Benzene. 71-43-2 1000 56 Very highly  Fire hydrant system & fire extinguishers.
flammable.  Ventilation.
Human  PPE.
carcinogen.  Explosion - proof electrical equipment.
 Prevent build-up of electrostatic charges.
 Spill containment and collection pit.
 Spill control kit.
 Medical Surveillance: OSHA mandates the
following: complete blood count: leukocyte count,
thrombocyte count, hematocrit, hemoglobin,
erythrocyte count; pulmonary function tests.

85
SITE EVACUATION PLAN

Risk Mitigation

Prepared

On Site Emergency Plan as per

Schedule 11 [Rule 13(1)]
&
Off-Site Emergency Plan (as per
Schedule 12 [Rule 14(1)]

of “The MSIHC Rules, 1989 “and

amendments.

86
 EMERGENCY RESPONDENTS CONTACT NUMBERS

FIRE BRIGADE POLICE HOSPITAL

Name Contact Name Contact Name Contact
Jalgaon Fire Brigade, 0257 - MIDC Jalgaon Police 02582 - District Civil Hospital, 0257 -
Jaikisan Wadi, 2224444 Station. 222200, Jilhapeth, Jalgaon. 2226611
Jalgaon. 2210500

87
 RISK ASSESSMENT RESULTS
SN DESCRIPTION RISK EVALUATION
1 Prevailing individual risk from existing 2.227  10-5 Yr-1 Acceptable
facilities.

2 Perceived individual risk from the proposed 2.227  10-4 Yr-1 Acceptable
facilities.

3 Societal risk. 1.5 : 100000 Acceptable

4 Cumulative av. individual risk. 1.21  10-5 Yr-1 Acceptable

CONCLUSION
The study reveals that the risk posed by the proposed site activities are at reasonably acceptable
level after implementation of the risk mitigation measures suggested.

As the risk level it depends heavily upon the maintenance of the hardware and of the
management procedures; neglect of either will lead to loss of protection and the rating will rise to
the higher level that is from MCLS level to MCA level.

LIMITATIONS:
Any inaccuracy in inputs of inventory data may affect the accuracy of the risk estimates. Apart from the maximum credible
releases, the conservative approach appears in adoption of atmospheric conditions, used in the dispersion calculation. In the
case of absence of adequate data assumptions are made; the assumptions/ conditions will result in the largest damage
distances. Hence, it must be remembered that this analysis will be pessimistic & conservative in approach & is only a planning
tool. Its use should not be extended without understanding its limitations.

88
 17. Fuel requirement / Consumption, Power demand etc.
Equipment Type of Fuel Quantity of Fuel

Proposed 6 TPH boiler Coal /Briquette 20.50 TPD / 26.50 TPD

Existing Thermopack of capacity 1 Nos. x 8

Coal /Briquette 4.5 TPD / 7.20 TPD
lakhs Kcal /hr

Existing D.G set of capacity 1x 400 KVA HSD 84 Lit/Hr

Existing D.G set of capacity 1x 500 KVA HSD 108 Lit/Hr

Power demand

Demand load: 1174 kW

(Existing: 1174 kW + additional proposed: 0 kW)
Operating load: 800 kW
(Existing: 480 kW + additional proposed: 320 kW)
Source: MSEDCL

89
 18. Plan for using Renewable energy and locations

 Generation of electricity from Solar: 110 KWP

 % of saving due to installation of Solar: 13.75 %

 The electricity generated from the solar rooftop harvesting

system will be used for the illumination of the street lights,
parking and Admin building etc.

90
 19. Plan for Rain water harvesting facilities and storage and usage

Rooftop water Generation Calculations:

• As from IMD records annual rainfall data for Jalgaon District is 747 mm or 0.747 m

• Total rooftop Building Terrace Sizes where RWH is possible: 178.43 Sq. m

• Water Collected: 0.747 X 178.43 X 0.9 = 119.96 m3/season

Surface runoff Generation Calculations:

• For calculations of surface runoff, the following area and runoff is considered-

• Road and paved parking 6827.00 Sq.m.

• Water Collected: 6827 X 0.747x 0.8 = 4079.82 m3/season

• Hence total rainwater collected: 119.96+4079.82 = 4199.78 m3/season

• Rain water will be collected in proposed rain water tank of 50 KL capacity. Rain water will be use daily

to reduce fresh water consumption during rainy season. Excess rain water will be drained to natural

drain. During rainy season water requirement will get reduced.

91
 20. EMP along with budget provision for all environmental parameters
Environment management plan (During Operation phase)
Responsibili
Capital cost Recurring Purchase/
Sr. Pollution Per Cost (In ty in
Mitigation Measures/Details (In Rs. cost (Rs. Implementation
No. Activity Rs. Lacs.) Organizatio
Lacs.) Lacs./yr) Schedule
n
Provision of stack of adequate height Existing will be
Existing APC is in
Installation of Bag Filter use
place&for additional
Multicyclone 6 40 lacs 4 lac
Boiler, Thermopac,
Ultra low NOx burners for Boiler & (Existing: 10 (Existing: 1
5 Low NOx burners
Air Thermopack lacs + lacs +
1 EHS Team and multicyclone
pollution Online monitoring system for additional additional
14 followed by
Process Stack proposed 30 proposed
bagfilter will be
lacs) 3 lacs)
installed during
HCl Scrubber 5
commissioning

Installation of New Effluent Treatment 900 lacs 431 lacs Existing are in place
Plant, RO, Stripper & MEE, Online (Existing: 350 (Existing: Existing are in place
500
2 Water monitoring system applicable for lacs + 110 lacs + &for additional for
EHS Team
Pollution ZLD unit additional additional the augmentation in
proposed proposed the MEE capacity
Proposed Sewage Treatment Plant 50
550 lacs) 321 lacs) and ETP capacity
0.4 lacs
(Existing: Existing are in place
Noise Existing Acoustic encl./ Anti Considered in 0.2 lacs + and for additional
3 EHS Team 0 lacs
pollution vibration pads to DG sets equipment cost additional DG during
proposed commissioning
0.2 lacs)
92
 20. EMP along with budget provision for all environmental parameters
Responsibil
Capital cost Recurring Purchase/
Sr. Pollution Per Cost (In ity in
Mitigation Measures/Details (In Rs. cost (Rs. Implementation
No. Activity Rs. Lacs.) Organizatio
Lacs.) Lacs./yr) Schedule
n
Medical checkup
Health insurance policy 35 lacs 4 lacs
Medical staff charges (Existing: 25 (Existing: 1
Occupatio
HR/Admin/ lacs + lacs + During operation
4 nal health First aid facilities consumables --
EHS Team additional additional phase
In-house first aid room, Other proposed 10 proposed 3
infrastructure , equipment and OHC lacs) lacs)
room
5 lacs 2.5 lacs
Potholes digging, Saplings, labor
(Existing: (Existing:
cost, Fertilizers, Drip irrigation
Green Rs. 500/ per HR/ EHS 0.5 lacs + 0.5 lacs + During
5 facility & maintenance for the
belt plant Team additional additional Commissioning
existing and the additional
proposed proposed 2
proposed trees
4.5 lacs) lacs)
Segregation & Storage of existing 30 lacs 168 lacs
Existing
Hazardou Waste, Disposal to CHWTSDF site, (Existing: 25 (Existing: Existing are in
storage facility
s & Non- also segregate wet and dry lacs + 15 lacs + place and for
6 will be used EHS Team
Hazardou muncipal solid waste.Wet waste additional additional additional during
with minor
s Waste converted into compost and will be proposed 5 proposed Operation
modifications
utilized as a manure for greenbelt lacs) 153 lacs)
Environm 4.5 lacs
ental Regular monitoring of Ambient (Existing: Existing are in
monitorin Environmental Conditions & 0.5 lacs + place and for
7 -- EHS Team 0 lacs
g and Pollution Control Equipments from additional additional during
Manage NABL/MoEFCC approved lab proposed 4 Operation phase
93
ment lacs)
 20. EMP along with budget provision for all environmental parameters
Responsibil
Per Cost Recurring Purchase/
Sr. Pollution ity in Capital cost
Mitigation Measures/Details (In Rs. cost (Rs. Implementati
No. Activity Organizatio (In Rs. Lacs.)
Lacs.) Lacs./yr) on Schedule
n
Conversion of Halogen lamps with LED
4
fixtures 60 lacs 1 lacs Existing are in
Measures taken to reduce carbon footprint. (Existing: 2 (Existing: place and for
Energy Project
Annual audit will be conducted and will try to 2 lacs + 0.1 lacs + additional
8 conservation Team/ EHS
reduce the carbon footprint further additional additional during
measures Team
Installation of new solar panels (110 kWp). 50 proposed 58 proposed Operation
Reduction of fuel consumption by using well lacs) 0.9 lacs) phase
2
efficient insulation to heating equipment
Existing Rain water harvesting & use of rain 0.5 lacs
Rain Water -- 15 (Existing:
water in utilities & domestic purpose (Existing:
Harvesting Project 10 lacs + During
Regular maintaince of equipments to reduce 0.1 lacs +
9 and Strom 3 Team/ EHS additional Operation
wastage of water due to leaks additional
water Team proposed 5 phase
proposed
management Maintanance of Storm water drainage 2 lacs)
0.4 lacs)
Dyke for accidental spill containment for
ground storage tanks available at site for
existing and for proposed will be installed.
Flame proof electrical in flammable solvent
Implementati 200 lacs 2 lacs
/gases handling area is already in place and
on (Existing: 50 (Existing:
additional will be provided as per Project During
recommenda lacs + 0.5 lacs +
10 requirement. -- Team/ EHS Operation
tion additional additional
Existing Fire hydrant system is in place and Team phase
hazop/Risk proposed 150 proposed
additional will be provided as per
Assessment lacs) 1.5 lacs)
requirement.
Personnel Protective Equipment (PPE) 94
 20. EMP along with budget provision for all environmental parameters

Responsibil
Capital cost Recurring Purchase/
Sr. Pollution Per Cost (In ity in
Mitigation Measures/Details (In Rs. cost (Rs. Implementation
No. Activity Rs. Lacs.) Organizatio
Lacs.) Lacs./yr) Schedule
n
Recurring:
Capital:
617.9 lacs
1285 lacs
(Existing:
(Existing:
128.90
SUB-Total 472.5 lacs +
lacs +
additional
additional
proposed
proposed
812.5 lacs)
489 lacs)
Corporate
Environm
within 1 years
ental CER activities will be done in
11 EHS Team 20.95 0 after obtaining
Responsi surrounding villages.
EC
bility
(CER)

Grand 1305.95
617.9 lacs
Total lacs

95
 21. CER Activities and implementation budget
Proposed break up of CER budget

Amount
Sr. No. Description of Activities Cost per
Nos. in Lakhs
unit in Rs.

Tree-plantation on large scale in adjourning areas

1. 2500 500 12.50
nearby to MIDC

Provision of Rain water Harvesting along with ground

2. water recharge at ZP schools in Tarsod village & Khedi 2 200000 4.00
Bk

Organic Waste composter having capacity 150 lit at ZP

3. 2 22500 0.45
schools in Kusumbe Kh & Nashirabad

2 (Solar) 150000 3.00

Rooftop Solar system (2 KWP) & Clean drinking water
2 (RO
4. (with RO system and water cooler) facility for ZP
system and
schools at Nashirabad village & Kusumbe Kh 50000 1.00
water
cooler)
Total Amount 20.95

CER will be implemented within 1 years after obtaining EC CER Ack

96
 22. Public Hearing and compliance

The location of the unit is at plot no. E-13, E-14 & E-15, MIDC Jalgaon, Maharashtra This
industrial plot is located in MIDC Jalgaon , a zone approved for chemicals manufacturing.

In view of above fact and as specified in MoEF circular no

11011/321/2016-IA.II(I) dated 27th April 2018; the proposed project
is exempted from public hearing.

97
 23. Staff welfare, Health checkup, and other amenities
• In order to ensure good health of workers, regular health check-up of the plant workers is being carried out.
• Occupational health surveillance program is being taken as a regular exercise for all the employees and their
records maintained.
• Proper storage and handling precautions is being taken. The storage area is cool, dry and well ventilated
away from any source of heat, flame or oxidizers.
• Use of Personal Protective Equipment (PPEs) will be compulsory. Proper training on use of PPEs,
characteristics of the material handled and safety precautions to be adopted is given to the workers.

Fund allocation to ensure the occupational health & safety

Recurring Purchase/
Sr. Capital cost
Component Description cost (Rs. Implementation
No . (In Rs. Lacs.)
Lacs./yr) Schedule
Medical checkup
Health insurance policy
Medical staff charges 35 lacs (Existing:
4 lacs (Existing:
First aid facilities 25 lacs +
Occupational 1 lacs + During operation
4 consumables additional
health care additional phase
In-house first aid room, proposed 10
proposed 3 lacs)
Other infrastructure, lacs)
equipment and OHC
room
98
III. Undertakings, Reports & Letters to be attached with
presentation

99
 1. Project consultant & EIA Coordinator (UT)

Environmental Consultant : Goldfinch Engineering Systems Private Limited

Telephone : 7208579136/8097093007

Email : mktg@goldfinchengg.com, info@goldfinchengg.com

NABET Accreditation No. : NABET/EIA/23-26/RA0314 valid till June 08,2026

EIA Coordinator

Mr. Siddhesh Karangutkar appointed as an EIA Coordinator

Undertaking NABET MOM NABET accreditation

100
2. EC, EMP & CER Implémentation (UT)

101
3. Non coverage in western ghat notification (UT)

102
 4. Industries Approved layout plan copy

The Proposed layout is not yet submitted to MIDC for approval . It will be
done after obtaining confirmation from SEAC-1.

However the Benzochem Industries is having the MIDC approval for its
existing facility dated 10th July 2020.

103
 5. Public Hearing’s MoM and Compliance report

The location of the unit is at plot no. E-13, E-14 & E-15, MIDC Jalgaon, Maharashtra This
industrial plot is located in MIDC Jalgaon , a zone approved for chemicals manufacturing.

In view of above fact and as specified in MoEF circular no 11011/321/2016-IA.II(I)

dated 27th April 2018; the proposed project is exempted from public hearing.

104
6. Water Supply NOC/ water lifting permission letter from
concern authority

Water permission letter

105
 7. Consent to use CETP

Consent letter from CETP is not applicable.

Unit is Zero Liquid Discharge

106
8. Structural stability Certificate

Structure Stability Certificate

107
9. RO, MoEF & CC Nagpur (in case of previous EC) & Compliance
Report of latest consent to operate received from MPCB

 Certified Compliance of Existing CTO is available with us. As per the report, unit is complying
all the consent conditions.

 The compliance of the existing EC conditions was monitored by Regional Office of MoEF & CC
by visiting the site on 20th November 2023 and Certified compliance of existing EC conditions is
available with us.

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10. Green belt development plan with maintenance details

Greenbelt development plan is already discussed in Earlier Slide

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11. Consent letters from School, health Centre and Gram
panchayat for implementation of CER Activities

Consent letters
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11. Consent letters from School, health Centre and Gram
panchayat for implementation of CER Activities

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12. Details of Environment Monitoring Cell

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Thank You

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