Safety Data Sheet according to Regulation (EC) No
1907/2006
Product
9-035 PLUS
SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1 Product identifier: 9-035 PLUS
1.2 Relevant identified uses of the substance or mixture and uses advised against:
1.3 Details of the supplier of the safety data sheet:
COMPANY IDENTIFICATION LOCAL COMPANY IDENTIFICATION
NALCO EUROPE B.V.
Postbus 627
2300 AP Leiden, The Netherlands
TEL: +31 71 5241 100
For additional copies of an MSDS visit www.nalco.com and request access.
For Product Safety information please contact: EUProductSafety@nalco.com
1.4 Emergency telephone number: +32-(0)3-575-5555 Trans-European
Date of Compilation/Revision:: 24.02.2012
Version Number: 1.0
SECTION 2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture:
Classification according to Regulation (EC) No 1272/2008
Flammable liquids - Category 3 H226
Acute toxicity - Category 3 H301
Acute toxicity - Category 3 H331
Acute toxicity - Category 3 H311
Skin corrosion/irritation - Category 1B H314
Skin sensitization - Category 1 H317
Carcinogenicity - Category 1B H350
Acute aquatic toxicity - Category 1 H400
Chronic aquatic toxicity - Category 1 H410
Classification according to EU Directives 67/548/EEC or 1999/45/EC
This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.
T, TOXIC R45, R34, R43, R50/53, Also, R23/24/25
N, DANGEROUS FOR THE ENVIRONMENT
Refer to Section 16 for full details of the risk phrases, hazard statements and Notas.
2.2 Label elements:
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Safety Data Sheet according to Regulation (EC) No
1907/2006
Product
9-035 PLUS
Labelling according to Regulation (EC) No 1272/2008
Contains: Hydrazine
Hazard pictograms:
Signal Word: Danger
Hazard Statements:
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H350 May cause cancer.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary Statements
P201 Obtain special instructions before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P281 Use personal protective equipment as required.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse
skin with water/ shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P310 Immediately call a POISON CENTER or doctor/ physician.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
2.3 Other hazards:
None known
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
3.0 Type of substance: No data available.
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Safety Data Sheet according to Regulation (EC) No
1907/2006
Product
9-035 PLUS
The details below include all impurities and by-products that contribute to the product classification or that havea
occupational exposure limit.
No data available.
Refer to Section 16 for full details of the risk phrases, hazard statements and Notas.
SECTION 4. FIRST AID MEASURES
4.1 Description of necessary first-aid measures:
In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt,
contact emergency
SKIN CONTACT
Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes. For a large
splash, flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with
plenty of water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.
EYE CONTACT
Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush
eye with water for at least 15 minutes while holding eyelids open.
INGESTION
Get immediate medical attention. DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to
drink.
PROTECTION FOR FIRST AID PERSONNEL
Wear adequate personal protective equipment.
4.2 Most important symptoms and effects, both acute and delayed:
A review of available data does not identify any symptoms from exposure not previously mentioned. A review of
available data does not identify any symptoms from exposure not previously mentioned.
4.3 Indication of immediate medical attention and special treatment needed:
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the
patient, the physician's judgement should be used to control symptoms and clinical condition.
SECTION 5. FIRE-FIGHTING MEASURES
5.1 Extinguishing media:
SUITABLE EXTINGUISHING MEDIA
Not expected to burn. Use extinguishing media appropriate for surrounding fire.
5.2 Special hazards arising from the substance or mixture:
Not flammable or combustible. May evolve oxides of nitrogen (NOx) under fire conditions.
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Safety Data Sheet according to Regulation (EC) No
1907/2006
Product
9-035 PLUS
In the event of a spill, prevent material and fire water from entering sewers or waterways.
5.3 Advice for firefighters:
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures:
ADVICE FOR NON-EMERGENCY PERSONNEL
This material may be hazardous by contact, do not attempt to clean up the spill. Call trained emergency
responders immediately. Clean up only to be done by Emergency responders/personnel. Restrict access to area
as appropriate until clean-up operations are complete.
Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).
ADVICE FOR EMERGENCY RESPONDERS
Restrict access to area as appropriate until clean-up operations are complete. Use personal protective
equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is
safe to do so. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Do not
touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify
appropriate government, occupational health and safety and environmental authorities.
6.2 Environmental precautions:
In the event of a spill, prevent material from entering sewers or waterways. Do not allow material to contaminate
ground water system. Prevent product from entering drains. If drains, streams, soil or sewers become
contaminated, notify local authority. Spilled product may pose a risk to the aquatic ecosystem if released.
6.3 Methods and materials for containment and cleaning up:
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or
by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated
surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated
recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal
Considerations).
6.4 Reference to other sections:
Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).
Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
SECTION 7. HANDLING AND STORAGE
7.1 Precautions for safe handling:
HANDLING
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe
vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills,
leaks, etc.) readily available. Ensure all containers are labeled. Do not mix with acids. Use personal protective
equipment recommended in Section 8 (Exposure Controls/Personal Protection).
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Safety Data Sheet according to Regulation (EC) No
1907/2006
Product
9-035 PLUS
Refer to section 6.2 for Environmental Precautions
HYGIENE RECOMMENDATIONS
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a
safety shower available. Always wash thoroughly after handling chemicals. When handling this product never
eat, drink or smoke.
7.2 Conditions for safe storage, including any incompatibilities:
STORAGE CONDITIONS
Store in suitable labeled containers. Store the containers tightly closed. Store separately from acids.
SUITABLE CONSTRUCTION MATERIAL
Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use.
7.3 Specific end uses:
Specific use(s) :
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters:
OCCUPATIONAL EXPOSURE LIMITS
Exposure guidelines have not been established for this product. Available exposure limits for the substance(s)
are shown below.
Source Substance(s) Category: ppm mg/m3
United Kingdom Hydrazine TWA 0.02 0.03
STEL 0.1 0.13
Skin*
* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and
the eyes.
MONITORING MEASURES
A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed or removed and analyzed
as referenced below:
Substance(s) Method Analysis Absorbant
Hydrazine US OSHA: 108 High pressure liquid Glass fibre treated with
chromatography Sulphuric acid
8.2 Exposure controls:
ENGINEERING MEASURES:
The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples
should be handled in a fumehood. Provide mechanical ventilation of confined spaces.
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Safety Data Sheet according to Regulation (EC) No
1907/2006
Product
9-035 PLUS
PERSONAL PROTECTIVE EQUIPMENT
GENERAL ADVICE
The use and choice of personal protection equipment is related to the hazard of the product, the workplace and
the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area
where this product is handled should at least wear safety glasses with side-shields.
EYE/FACE PROTECTION
Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166.
SKIN PROTECTION
When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends
on work conditions and what chemicals are handled, but we have positive experience under light handling
conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are
observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable
European standard can be found in EN 374.
Wear impervious apron and boots. The applicable European standard can be found in EN ISO 20345.
RESPIRATORY PROTECTION
Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air
supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of
chemicals being handled. Consider the use of filter type: K-P The applicable European standard can be found in
EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown concentrations a
positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete
respiratory protection program including selection, fit testing, training, maintenance and inspection.
ENVIRONMENTAL EXPOSURE CONTROLS
Consider the provision of containment around storage vessels.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Note: These physical properties are typical values for this product and are subject to change.
9.1 Information on basic physical and chemical properties:
9.1 Information on basic physical and chemical properties:
PHYSICAL STATE Liquid
APPEARANCE Colorless Light yellow
Odour Ammoniacal
Odour Threshold No data available.
pH (100 %) 12.5
MELTING POINT / FREEZING No data available.
POINT / POUR POINT
BOILING POINT 109 °C
FLASH POINT Not flammable
EVAPORATION RATE No data available.
FLAMMABILITY (solid, gas) No data available.
LOWER EXPLOSION LIMIT 9.3 V%
UPPER EXPLOSION LIMIT 83.4 V%
VAPOR PRESSURE No data available.
VAPOR DENSITY No data available.
Relative density 1.02 - 1.04 (20 °C)
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Safety Data Sheet according to Regulation (EC) No
1907/2006
Product
9-035 PLUS
9.1 Information on basic physical and chemical properties:
DENSITY No data available.
SOLUBILITY IN WATER Complete
OCTANOL/WATER COEFFICIENT No data available.
(log Kow)
AUTOIGNITION TEMPERATURE No data available.
DECOMPOSITION TEMPERATURE No data available.
VISCOSITY 1.26 cps (20 °C)
EXPLOSIVE PROPERTIES Not applicable
OXIDIZING PROPERTIES Not applicable
9.2 Other information:
Not applicable
SECTION 10. STABILITY AND REACTIVITY
10.1 Reactivity:
No data available.
10.2 Chemical stability:
Stable under normal conditions.
10.3 Possibility of hazardous reactions:
Hazardous polymerization will not occur.
10.4 Conditions to avoid:
Avoid extremes of temperature.
10.5 Incompatible materials:
Acids Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate
heat, splattering or boiling and toxic vapors. Contact with strong oxidizers (e.g. chlorine, peroxides, chromates,
nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic
vapors.
10.6 Hazardous decomposition products:
Under fire conditions: Oxides of nitrogen, ammonia, Flammable gases/vapors
SECTION 11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects:
Product:
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Safety Data Sheet according to Regulation (EC) No
1907/2006
Product
9-035 PLUS
Acute oral toxicity : LD50: 185 mg/kg, Rat, Test substance: Product
Acute inhalation toxicity : LD50: 2.1 mg/l, Rat, Test substance: Product
Acute dermal toxicity : LC50: 420 mg/kg, Rabbit, Test substance:
Product
Respiratory or skin : May cause sensitization by skin contact.
sensitization
SECTION 12. ECOLOGICAL INFORMATION
12.1 Toxicity:
The following results are for the product.
Product:
Toxicity to fish : LC50: 0.75 mg/l, 96 hrs, Gold Orfe, Test substance: Product
Toxicity to daphnia and other : LC50: 0.81 mg/l, 48 hrs, Daphnia magna, Test substance:
aquatic invertebrates. Product
12.2 Persistence and degradability:
12.3 Bioaccumulative potential:
Product:
Bioaccumulation : This preparation or material is not expected to bioaccumulate.
12.4 Mobility in soil:
Product:
Environmental fate and : The environmental fate was estimated using a level III fugacity
pathways model embedded in the EPI (estimation program interface)
Suite TM, provided by the US EPA. The model assumes a
steady state condition between the total input and output. The
level III model does not require equilibrium between the
defined media. The information provided is intended to give
the user a general estimate of the environmental fate of this
product under the defined conditions of the models.
If released into the environment this material is expected to
distribute to the air, water and soil/sediment in the
approximate respective percentages;,<5%,30 - 50%,50 -
70%,The portion in water is expected to be soluble or
dispersible.
12.5 Results of PBT and vPvB assessment:
12.6 Other adverse effects:
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Safety Data Sheet according to Regulation (EC) No
1907/2006
Product
9-035 PLUS
SECTION 13. DISPOSAL CONSIDERATIONS
If this preparation becomes a waste, the final user must define and assign the appropriate European Waste
Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations.
13.1 Waste treatment methods:
Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable
regulations. Do not dispose of wastes in local sewer or with normal garbage. This product is ashless and can be
burned directly in appropriate equipment. Any chemical waste is a potential environmental pollutant and is NOT
suitable for disposal via ground, municipal sewers, drains, natural streams or rivers.
Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed
contractor.
EUROPE WASTE CODE:
16 03 03* - OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Inorganic wastes containing
dangerous substances. If this product is used in any further processes, the final user must redefine and assign
the most appropriate European Waste Catalogue Code.
SECTION 14. TRANSPORT INFORMATION
The information in this section is for reference only and should not take the place of a shipping paper (bill of
lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT
14.1 UN number: UN 3293
14.2 UN proper shipping name: HYDRAZINE, AQUEOUS SOLUTION
14.3 Transport hazard class(es): 6.1
14.4 Packing group: III
14.5 Environmental hazards: Yes
14.6 Special precautions for user: not applicable
AIR TRANSPORT (ICAO/IATA)
14.1 UN number: UN 3293
14.2 UN proper shipping name: HYDRAZINE, AQUEOUS SOLUTION
14.3 Transport hazard class(es): 6.1
14.4 Packing group: III
14.5 Environmental hazards: Yes
14.6 Special precautions for user: not applicable
MARINE TRANSPORT (IMDG/IMO)
14.1 UN number: UN 3293
14.2 UN proper shipping name: HYDRAZINE, AQUEOUS SOLUTION
14.3 Transport hazard class(es): 6.1
14.4 Packing group: III
14.5 Environmental hazards: Yes (Marine Pollutant)
14.6 Special precautions for user: not applicable
14.7 Transport in bulk according to not applicable
Annex II of MARPOL 73/78 and the IBC
Code:
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Safety Data Sheet according to Regulation (EC) No
1907/2006
Product
9-035 PLUS
SECTION 15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
INTERNATIONAL CHEMICAL CONTROL LAWS
EUROPE
Safety Data Sheet according to Regulation (EC) No 1907/2006.
Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals
(REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import into
European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment.
Should you require any further information on Nalco's REACH programme please contact us at
reach@nalco.com or visit our website.
CANADA
The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been
reported in accordance with the New Substances Notification Regulations.
UNITED STATES
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
15.2 Chemical Safety Assessment:
SECTION 16. OTHER INFORMATION
LIST OF RELEVANT R-PHRASES, NOTAS AND HAZARD STATEMENTS IN SECTION 2.1 AND 3
Also - Also
H226 - Flammable liquid and vapour.
H301 - Toxic if swallowed.
H311 - Toxic in contact with skin.
H314 - Causes severe skin burns and eye damage.
H317 - May cause an allergic skin reaction.
H331 - Toxic if inhaled.
H350 - May cause cancer.
H400 - Very toxic to aquatic life.
H410 - Very toxic to aquatic life with long lasting effects.
R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.
R34 - Causes burns.
R43 - May cause sensitization by skin contact.
R45 - May cause cancer.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
REVISED INFORMATION: section(s): 15 11
This product Safety Data Sheet provides health, safety, and regulatory information. The information contained in
this Safety Data Sheet is based on data available to us at the date of issue , and is provided in good faith, and
believed to be accurate and reliable at the date of issue, however, no warranty, express or implied is provided,
and Nalco disclaims all liability for reliance on such information. The product is to be used in applications
consistent with Nalco’s product literature. For any other uses, exposures should be evaluated so that the
appropriate handling practices and training programs can be established to ensure safe working conditions and
operations. It is the buyer’s/user’s responsibility to satisfy itself that the product is suitable for the intended use,
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Safety Data Sheet according to Regulation (EC) No
1907/2006
Product
9-035 PLUS
and to ensure that its activities comply with all federal, state, provincial, or local laws and regulations.
Regulatory requirements are subject to change and may differ between European Member States and Nations.
Individuals handling this product should be informed of the recommended safety precautions and should have
access to this information. Please consult your local sales representative for any further information.
REFERENCES
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health
Organization, International Agency for Research on Cancer.
Ariel Insight™ (An integrated guide to industrial chemicals covered under major regulatory and advisory
programs), North American Module, Western European Module, Chemical Inventories Module and the Generics
Module (Ariel Insight™ CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The possible key literature references and data sources which may have been used in conjunction with the
consideration of expert judgment to compile this Safety Data Sheet: European regulations/directives (including
(EC) No. 1907/2006, (EC) No. 1272/2008, 67/548/EEC, 1999/45/EC), supplier data, inter-net, ESIS, IUCLID,
Ariel InsightTM, ERIcards, Non European official regulatory data and other data sources.
Date issued : 24.02.2012
Version Number : 1.0
Prepared By: SHE Department
Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1
tenth and 0.001 = 1 thousandth
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