SAFETY DATA SHEET
Penetone® Corporation, 700 Gotham Parkway, Carlstadt, NJ 07072
CAGE 56883
PENAIR® M5704A Page: 1 of 8
MIL-PRF-85704C Type I Date Prepared: March 15, 2015
NSN 6850-01-7594/7597 (5/55 gal) MSDS No.: 4141
SECTION 1: IDENTIFICATION
Product name: PENAIR M5704A
Recommended use: Gas turbine compressor cleaning
Physcial Description: Clear amber liquid with mild solvent odor
Generic Ingredients: Aromatic hydrocarbons, surfactants, water, and glycol/glycol ether
Manufacturer: Business Contact:
Penetone Corporation Customer Service
700 Gotham Parkway 800-631-1652 x2602 or 2272
Carlstadt, NJ 07072 Product Safety
800-631-1652 or 201-567-3000 800-631-1652 x2211 or 2257
Emergency Phone Numbers: PENETONE 201-567-3000 CHEMTREC 800-424-9300
SECTION 2: HAZARDS IDENTIFICATION
GHS CLASSIFICATION:
Health: Specific target organ toxicity - repeated exposure:
Skin irritation: 2 2
Eye irritation: 2A Carcinogenicity: 2
Specific target organ toxicity - single exposure: 2 Aspiration hazard: 1
Specific target organ toxicity - single exposure: 3 Physical:
Flammable liquid: 4
DANGER!
May Be Fatal If Swallowed and Enters Airways.
Causes Skin and Serious Eye Irritation.
May Cause Drowsiness or Dizziness.
May Cause Damage to Organs (Central Nervous System,
Kidneys, and Liver) If Swallowed.
Suspected of Causing Cancer.
Combustible Liquid.
Precautionary Statements:
Prevention: contaminated clothing before reuse. If skin irritation
Obtain special instructions before use. Do not handle or rash occurs: Get medical advice/attention.
until all safety precautions have been read and If inhaled: Remove person to fresh air and keep
understood. comfortable for breathing. Call a pois on center,
Do not breathe fumes, vapors or mists if inhalable doctor, emergency room or 911 if you feel unwell.
mists occur during use. Use only outdoors or in a If swallowed: Immediately call a poison center, doctor,
well-ventilated area. W ear protective gloves, eye emergency room, or 911. Do NOT induce vomiting.
protection, and face protection. If exposed or concerned: Call a poison center, doctor,
Do not eat, drink or smoke when using this product. or emergency room.
Wash hands and exposed skin thoroughly after
handling. Storage:
Store locked up. Store in a well-ventilated place. Keep
Response: container tightly closed.
If in eyes: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and Disposal:
easy to do. Continue rinsing. If eye irritation Dispose of contents/container in accordance with local,
persists: Get medical advice/attention. regional, and national regulations (see Sections 13 and
If on skin (or hair): Take off immediately all 15 of SDS for disposal and reporting requirements).
contaminated clothing. Rinse skin with water or
shower. A mild soap may be used. Wash
SAFETY DATA SHEET
Penetone® Corporation, 700 Gotham Parkway, Carlstadt, NJ 07072
CAGE 56883
PENAIR® M5704A Page: 2 of 8
MIL-PRF-85704C Type I Date Prepared: March 15, 2015
NSN 6850-01-7594/7597 (5/55 gal) MSDS No.: 4141
SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name CAS# Concentration Wt% (1)
Aromatic petroleum naphtha 64742-94-5 45-65
Water 7732-18-5 10-25
Ethoxylated nonylphenol 127087-87-0 1-10
Coco diethanolamide 68603-42-9 1-10
1-Butoxyethanol 111-76-2 1-10
Diethylene glycol 111-46-6 1-10
Polyoxyethylene-polyoxypropylene block copolymer 9003-11-6 1-10
(1) Exact percentages being withheld under trade secret provision of OHSA HCS 1910.1200(i)
SECTION 4: FIRST-AID MEASURES
General Description of Symptoms & First-Aid Measures
Most likely work-place exposure routes will be skin contact or inhalation.
For skin contact, typically no immediate effects will be observed. Slight reddening or minor irritation could develop
some time after exposure if product is not quickly washed off. For sensitive individuals, a rash may appear.
Inhalation exposure may produce varied effects, particularly if exposure occurs above the recommended workplace
exposure limits (see SECTION 8). Typical symptoms would include headaches, dizziness, and drowsiness. In
extreme cases, unconsciousness and other central nervous effects may occur.
Eyes
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists or develops: Get medical advice or attention. Penetone recommends that
after any eye exposure a physician be seen immediately.
Ingestion
If swallowed: Immediately call a poison center, doctor, physician or other competent medical authority. Rinse
mouth. Product presents an aspiration hazard. DO NOT INDUCE VOMITING.
Inhalation
If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a pois on center, doctor, physician
or other competent medical authority if you feel unwell.
Skin
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. A mild soap
may be used to wash skin. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical
advice or attention.
Special Treatment / Other
None
SECTION 5: FIRE FIGHTING MEASURES
Flammable Properties
Classification: 4
Flash Point: 145oF TCC, 180oF COC
Autoignition Temperature: not determined
SAFETY DATA SHEET
Penetone® Corporation, 700 Gotham Parkway, Carlstadt, NJ 07072
CAGE 56883
PENAIR® M5704A Page: 3 of 8
MIL-PRF-85704C Type I Date Prepared: March 15, 2015
NSN 6850-01-7594/7597 (5/55 gal) MSDS No.: 4141
Lower Flammable Limit: not determined Upper Flammable Limit: not determined
Specific Hazards
Combustible liquid. Can form combustible mixtures at or above the flash point. Although the product is combustible,
it is water based and water dilutable and will self extinguish with addition of water.
Extinguishing Media
Suitable: SMALL FIRE: Use dry chemical, carbon dioxide (CO2), water spray or regular foam. LARGE FIRE: water
spray, water fog, or foam.
Unsuitable: Do not use solid water stream as this may spread fire.
Protection & Precautions for Firefighters
Protective Equipment & Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Structural
firefighters protective clothing will only provide limited protection.
Fire Fighting Guidance: Cool containers with flooding quantities of water until well after fire is out. Move
containers from fire area if you can do it safely. Dike fire control water for later disposal; do not scatter material.
Containers can expand and explode under fire conditions due to vapor buildup. Always stay away from containers
engulfed in fire.
Hazardous Combustion Products: Smoke, fumes, and oxides of carbon and nitrogen.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Land Spill
Eliminate sources of ignition. Do not touch or walk through spilled material. Stop leak if you can do it safely. For
large spills, dike and pump into properly labeled containers for reclamation or disposal. For small spill, soak up with
absorbent material and place in properly labeled containers for disposal.
Water Spill
Product forms emulsion with water which may make cleanup difficult. Avoid agitation to minimize emulsion
formation. Remove product from water surface by skimming or with suitable absorbents. Put into properly labeled
containers for reclamation or disposal. If allowed by local environmental regulatory agencies, you may use a
suitable dispersant. Check with local environmental regulatory agencies for reporting requirements.
See SECTION 8 for EXPOSURE CONTROLS and PERSONAL PROTECTION.
SECTION 7: HANDLING & STORAGE
Handling
Do not handle near heat, sparks, or flame. Avoid contact with oxidizing agents. Use only with adequate
ventilation/personal protection (SEE section 8). Avoid contact with eyes, skin and clothing. After handling, always
wash hands thoroughly with soap and water. Avoid personal contact with any residue. Dispose of empty containers
with care. Empty containers can contain flammable residue and explosive vapors. Do not cut, weld, or reuse
empty container.
Storage
Store in a well-ventilated place. Keep container tightly closed. Store locked up. Do not store near heat, sparks,
open flame, or other ignition sources. Do not store near strong oxidizing agents. Do not store in direct sunlight.
Avoid storing above 1200F (49oC).
SECTION 8: EXPOSURE CONTROLS and PERSONAL PROTECTION
SAFETY DATA SHEET
Penetone® Corporation, 700 Gotham Parkway, Carlstadt, NJ 07072
CAGE 56883
PENAIR® M5704A Page: 4 of 8
MIL-PRF-85704C Type I Date Prepared: March 15, 2015
NSN 6850-01-7594/7597 (5/55 gal) MSDS No.: 4141
Engineering Controls
Use process enclosures, local exhaust ventilation, or other engineering c ontrols to keep airborne levels below
recommended exposure limits.
Personal Protection
Inhalation A respiratory protection program that meets OSHA’s 29 CFR 1910.134 or ANSI Z88.2 requirements must
be followed whenever workplace conditions warrant respirator use. Use of an organic vapor mask or respirator is
recommended.
Skin Wear chemical resistant gloves such as: rubber, nitrile, neoprene, or latex when skin contact is possible.
Protective clothing including gloves, apron, sleeves, boots, head and face protection should be worn depending on
how the product is used. PPE should be cleaned thoroughly after each use.
Eyes Penetone recommends always wearing safety glasses as a minimum in any workplace. Conditions may
warrant the use of chemical goggles and possibly a face shield. Consult your standard operating procedure or
safety professional for advice. Use protective eye and face devices that comply with ANSI Z87.1-1987.
Additional Remarks
Selection of appropriate personal protective equipment should be based on an evaluation of the performance
characteristics of the protective equipment relative to the task(s) to be performed, conditions present, duration of
use, and the hazards and/or potential hazards that may be encountered during use.
Occupational Exposure Limits
Component Name Source Value Type Notation
Aromatic petroleum naphtha ACGIH 100 mg/m3 TWA Appendix H
NIOSH 350 mg/m3 TWA
1800 mg/m3 Ceiling 15 minutes
OSHA Z1 500 ppm TWA
1-Butoxyethanol ACGIH 20 ppm TWA A3; BEI
NIOSH 5 ppm TWA skin
OSHA 50 ppm TWA skin
SECTION 9: PHYSICAL & CHEMICAL PROPERTIES
Appearance: clear amber liquid
Odor: mild solvent
Odor Threshold: not determined
pH: about 9
Melting Point / Freezing: about 30 oF
Boiling Point / Boiling Point Range: about 212 oF
Flash Point: 145oF TCC, 180oF COC
Evaporation Rate: equal to water
Flammability: not applicable
Lower Flammable Limit: not determined
Upper Flammable Limit: not determined
Explosive Properties: not applicable
Vapor Pressure: equal to water
Relative Vapor Density: not determined
Relative Density: 0.95
Solubility (Water): forms emulsion (separate in one to 12 hours)
Partition Coefficient (K ow ): not determined
Auto-ignition temperature: not determined
SAFETY DATA SHEET
Penetone® Corporation, 700 Gotham Parkway, Carlstadt, NJ 07072
CAGE 56883
PENAIR® M5704A Page: 5 of 8
MIL-PRF-85704C Type I Date Prepared: March 15, 2015
NSN 6850-01-7594/7597 (5/55 gal) MSDS No.: 4141
Decomposition temperature: not determined
Viscosity: 15-22 centistokes at 80oF
SECTION 10: STABILITY & REACTIVITY
Reactivity
Product is stable and only reactive under extreme conditions (very high heat/pressure) or in the presence of specific
incompatible materials (see below).
Chemical Stability
Product is stable.
Hazardous Reactions
Hazardous polymerization will not occur.
Conditions to Avoid
Combustible liquid. Do not store near sources of heat, sparks, open flame, or other ignition sources.
Incompatible Materials
Strong oxidizing agents.
Hazardous Decomposition Products
Carbon monoxide and dioxide and nitrogen oxides when taken to dryness and burned.
SECTION 11: TOXICOLOGICAL INFORMATION
Product Summary
Product is irritating to the skin and eyes. Vapor/aerosol concentrations above recommended exposure levels are
irritating to the eyes and respiratory tract, and may cause headaches, dizziness, drowsiness, unconsciousness and
other central nervous system effects.
Acute Toxicity:
Dermal: Rabbits, LD50 > 2,000 mg/kg (estimated using additivity formula)
Inhalation: no data available
Oral: Rats, LD50 > 2,000 mg/kg (estimated using additivity formula)
Skin Corrosion/Irritation
Based upon component information, product is expected to be mildly irritating to the skin.
Serious Eye Damage/Irritation
Based upon component data, product is expected to cause moderate to serious eye irritation.
Sensitization - Respiratory or Skin
Based upon component data, not expected to be a skin sensitizer.
Germ Cell Mutagenicity
No data available. Based upon component data, product not expected to exhibit germ cell mutagenicity.
Carcinogenicity
1-Butoxyethanol is listed by ACGIH as Group A3: confirmed animal carcinogen with unknown relevance to humans
Cocodiethanolamide is listed by IARC as Group 2B: Possibly carcinogenic to humans.
Reproductive Toxicicty
SAFETY DATA SHEET
Penetone® Corporation, 700 Gotham Parkway, Carlstadt, NJ 07072
CAGE 56883
PENAIR® M5704A Page: 6 of 8
MIL-PRF-85704C Type I Date Prepared: March 15, 2015
NSN 6850-01-7594/7597 (5/55 gal) MSDS No.: 4141
No data available.
The nonionic surfactant used in this product has produced effects in the fetus only at levels that were toxic to the
parent animals.
1-Butoxyethanol has been toxic to the fetus lab animals at doses toxic to the mother. Effects on reproduction have
been seen only at doses that produced significant toxicity to the parent animal.
Diethylene glycol was found to be a reproductive and developmental toxicant when administered at high doses to lab
animals.
Specific Target Organ Effects - Single Exposure
No data available.
Ingestion of diethylene glycol has caused damage to the lungs, brain, pancreas and adrenal glands of lab animals.
Metabolic acidosis, hyperkalemia, elevated blood creatine and urea levels, and hypoglycemia were observed. May
cause central nervous system depression, gastrointestinal tract, liver, and kidney damage.
Specific Target Organ Effects - Repeated or Prolonged Exposure
No data available.
The aromatic hydrocarbon caused kidney effects in male rats which are not considered relevant to humans.
Repeated exposure to 1-butoxyethanol has caused hemolysis and secondary effects on the kidney and liver in lab
animals. Small but statistically significant increases in tumors were observed in mice but not rats. These effects are
not believed to be relevant to humans.
Repeated exposure to diethylene glycol may cause damage to the central nervous system, kidneys, and liver.
Aspiration Hazard
Based upon available data and comparison to similar materials, if swallowed, may pose a lung aspiration hazard
during vomiting. Lung aspiration may result in chemical pneumonitis, pulmonary edema, and damage to lung tissue
or death.
SECTION 12: ECOLOGICAL INFORMATION
Product Summary
Product is expected to be toxic to fish, aquatic invertebrates, algae, and microorganisms. (Acute aquatic toxicity
category 2 by European Union classification).
Ecotoxicity
LC/EC/IC 1-10 mg/l (estimated using additivity formula)
Persistence and Degradability
Based upon component data, product is expected to be inherently biodegradable.
Bioaccumulative Potential
No data available for the product. Aromatic solvent used in this product has the potential to bioaccumulate.
Mobility in soil
No data available for the product. Product is a complex mixture. Components will partition into water and soil
phases depending on inherent solubility of component in water.
Other Adverse Effects
None known
SAFETY DATA SHEET
Penetone® Corporation, 700 Gotham Parkway, Carlstadt, NJ 07072
CAGE 56883
PENAIR® M5704A Page: 7 of 8
MIL-PRF-85704C Type I Date Prepared: March 15, 2015
NSN 6850-01-7594/7597 (5/55 gal) MSDS No.: 4141
SECTION 13: DISPOSAL CONSIDERATIONS
Nonhazardous waste. Dispose of contents/container in accordance with all applicable federal, state, and local
regulations.
Note: Contaminated product, soil, water, container residues and spill cleanup materials may be hazardous wastes.
Appropriate hazardous waste designation is the responsibility of the user.
SECTION 14: TRANSPORT INFORMATION
ID No.: None
Proper Shipping Name: Nonhazardous (nonregulated) material
Hazard Class: None
Packing Group: None
Label: None
Marine Pollutant: No
RQ: No
Special Precautions: None
SECTION 15: REGULATORY INFORMATION
TSCA
The ingredients in this product are listed on the TSCA inventory.
RCRA HAZARD CLASS
Nonhazardous waste
SARA 311/312 REPORTABLE HAZARD CATEGORIES: Immediate (Acute) Health
REPORTING REQUIREMENTS (all quantities in pounds)
Component CAS / Section Section CERCLA Section CAA CWA
313 Code 302 (EHS) 304 EHS RQ 313 112(r) / OPA
TPQ RQ TQ
1-Butoxyethanol N230 Glycol ethers (1)
Diethylene glycol N230 Glycol ethers (1)
(1) CERCLA hazardous substance with no assigned RQ
NEW JERSEY RIGHT-TO-KNOW INFORMATION
This product contains aromatic petroleum naphtha (CAS 64742-94-5), water (CAS# 7732-18-5), ethoxylated
nonylphenol (CAS 127087-87-0), coco diethanolamide (CAS 68603-42-9), 1-butoxyethanol (CAS 111-76-2), and
diethylene glycol (CAS 111-46-6).
CALIFORNIA PROPOSITION 65 INFORMATION
This product contains a chemical recognized by the state of California to cause cancer: coco diethanolamide (CAS#
68603-42-9).
SCAQMD INFORMATION
Is there a photochemically reactive material present? Yes
What is the % by volume of photochemically reactive material? 58
What is the VOC content? 650 g/l
SAFETY DATA SHEET
Penetone® Corporation, 700 Gotham Parkway, Carlstadt, NJ 07072
CAGE 56883
PENAIR® M5704A Page: 8 of 8
MIL-PRF-85704C Type I Date Prepared: March 15, 2015
NSN 6850-01-7594/7597 (5/55 gal) MSDS No.: 4141
What is the vapor pressure of VOC's? approximately 1 mm Hg @ 20oC
SECTION 16: OTHER INFORMATION
REVISION SUMMARY SUPERSEDES ISSUE DATE
New GHS format February 24, 2004
HAZARD RATING SYSTEMS:
HMIS NFPA KEY
HEALTH 1 1 4 = Severe
FLAMMABILITY 2 2 3 = Serious
REACTIVITY 0 0 2 = Moderate
B 1 = Slight
0 = Minimal
FOR ADDITIONAL PRODUCT INFORMATION, CONTACT YOUR SALES ENGINEER
FOR ADDITIONAL HEALTH/SAFETY INFORMATION, CALL 201-567-3000
THE INFORMATION PRESENTED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED TO BE DEPENDABLE AND ACCURATE TO THE BEST OF
PENETONE'S KNOWLEDGE. THE INFORMATION RELATES TO THIS SPECIFIC MATERIAL. IT MAY NOT BE VALID FOR THIS MATERIAL IF USED IN COMBINATION
WITH ANY OTHER MATERIALS OR IN ANY PROCESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY ONESELF AS TO THE SUITABILITY AND COMPLETENESS
OF THIS INFORMATION FOR HIS OWN PARTICULAR USE.