Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH), amended by

2015/830/EU
·'TCARE
.A. RINE

Jersion number: GHS 8.0

.. CAREClEAN ALKALINE
revision: 29.11.2018
eplaces version of: 20.09.2018 (GHS 7)

Trade name Careclean Alkaline

Registration number (REACH) not relevant (mixture)
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses IMO approved
cleaning agent
. heavy~duty detergent
Tank Cleaning - MEPC 590 Approved
According Marpol MEPC 63/23/Add. 1, Annex 24
Resolution MEPC.219(63) - Anne'S V
1.3 . Details of the supplier of the safety data sheet
Marine Care B.V .
. Oude Maasweg 35, Port number 4005
3197 KJ Rotterdam-Botlek
Netherla~(js

Telephone: +(31) 102950342

e-mail: .operations@marinecare.nl
Website: www.marinecare.nl
Emergency tel~phone number
Emergency information service
\- .
+(31) 102950342
For USA/CANADA: INFOTRAC 1-800-535-5053.

2.1 Classification of. the Substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

2.16 substance or mixture corrosive to metals Cat. 1 (Met. corr. 1) 'H290

3.2 skin corrosion/irritation Cat.1A (Skin Corr. 1A) H314

3.3 serious eye damage/eye irritation Cat. 1 (Eye Dam. 1) H318

Remarks
For full text ofH·phrases: see SECTION 16.

The most important adverse physicochemical, human health and environmental effects
Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epidermis and
into the dermis.
2.2 Label elements
Labelling.according to Regulation (EC) No 1272/2008 (CLP)
Signal word Danger
Pictograms .
GHS05

Hazard statements
H290 May be corrosive to metals.
H314 Causessevere skin .burns and eye damage.

Netherlands Page 1/13

MARINECARE 147 SOS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
MARINE 2015/830/EU
CARE

CARECLEAN ALKALINE '

Version number: GHS 8.0 revision: 29.11.2018
Replac~s ve~sion of: 20.09.2018 (GHS 7)

Precautionary. statements
Precautionary statements - prevention
P260 Do not breathe dustlfume/gas/mistlvapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statements - response
. P303+P361+P353 IF ON SKIN (or hair): RemovelTake off immediately all contaminated clothing. Rinse
skin with water/shower.
P305+P351 +P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P390 Absorb spillage to prevent material damage.
Precautionary statements - disposal
P501 Dispose of contents/container to industrial combustion plant.
Hazardous ingredients for labelling: Potassium Hydroxide
2.3 Other hazards
There is no additional information.
\

3.1 Substances
not relevant (mixture) .
3.2 Mixtures
Description of the mixture

Butylglycol CAS No
111-76-2

ECNo
203-905-0
5-<10 Acute Tox. 4 / H302
Acute Tox. 4 / H312
Acute Tox. 41 H332
Skin Irrit. 21 H315
Eye Irrit. 21 H319
¢
'!$M
~.

~¢
Potassium Hydroxide CAS No 5-<10 Met. Corr. 1 / H290
1310-58-3 Acute Tox. 4 / H302
Skin Corr. 1A / H314
ECNo
215-181-3

~
Hexyl O-glucoside CAS No 1-<5 Eye Dam. 11 H318
54549-24-5
.
ECNo
259-217-6

For full text of abbreviations: see SECTION 16.

4.1 Description of first aid measures

General notes
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm,
still and covered. Take off immediately allcontamina.ted clothing. In all cases of doubt, or when symptoms per-·.
sist, seek medical advice. In case of unconsciousness place person in the recovery pOSition. Never give any­
thing by mouth.

Netherlands Page 2/13

MARINECARE 147 SOS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended bX
MARINE 2015/830/EU
CARE
CARECLEAN ALKALINE
Version number: GHS 8.0 revision: 29.11 .2018
Replaces version 01:20.09.2018 (GHS 7)

Following· inhalation
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case of
respiratory tract irritation, consult a physician. Provide fresh air.
Following skin contact
Wash with plenty of soap and water.
Following eye contact
Remove contact lenses, if present and easy to go. Continue rinsing. Irrigate copiously with clean, freshwater
for at least 10 minutes, holding the eyelids apart.
Following ingestion
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
)
4.2 Most important symptoms and effects, both acute and delayed
Symptoms and effects are not known to date.
4.3 Indication of any immediate medical attention and special treatment needed
none

5.1 Extinguishing media

5;1.1 Suitable extinguishing media
water spray, fire extinguishing powder, carbon dioxide (C02)
Unsuitable extinguishing media
water jet
5.2 Special haz~rds arising from the substance or mixture
Substance or mixture corrosive to metals.
Hazardous combustion products
nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (C02)
5.3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surround­
ings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water
separately. Fight fire with normal precautions from a reasonable distance.

~.1 Personal precautions: protective equipment and emergency procedures

For non-emergency personnel
Remove persons to safety.
Foremerg~ncy responders
Wear breathing apparatus if exposed to vapours/dustlspray/gases.
6~2 Environmental precautions
Keep away from drains, surface and ground water. Retain contaminated washing water and dispos;e oUt.
6.3 Methods and material for containment and cleaning up
Advices on how to contain a spill
Covering of drains.
Adviceson how to cl.ean up a spill ~
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage (sawdust, kieselgur (diatomite), sand, uni­
versal binder).

Netherlands Page 3/13

MARINECARE 147 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
MARINE 2015/830/EU
CARE

CARECLEAN ALKALINE
Version number: GHS 8.0 revision: 29.11.2018
Replaces version of: 20.09.2018 (GHS 7)

Appropriate containment techniques

Use of adsorbent materials.
Other Information relating to spills and releases
Place inappropriate containers for disposal. Ventilate affected area.
~

6.4 Reference to other sections

Hazardous combustion products: see section 5. Personal protective equipment see section 8. Incompatible
materials: see section 10. Disposal considerations: see section 13.

7.1 Precautions for safe handling

Recommendations
• Measures to prevent fire as well as aerosol and dust generation
Use local and general ventilation. Use only in well-ventilated areas.
• Handling of incompatible substances or mixtures
Do not mix with acids.
Advice on general occupational hygiene
Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protect­
ive equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place
chemicals in containers that ar,e normally used for food or drink. Keep away from food, drink and animaJ feed­
ingstuffs. .
7.2 Conditions for safe storage, including any incompatibilities
Managing of associated risks
• Corrosive conditions
Store in corrosive resistant container with a resistant inner liner.
Incompatible substances ormixtures
Observe hints for combined storage.
• Control of effects
• Protect against external exposure,such as
frost
Consideration of other advice
• Packaging compatibilities
Only packagings which are approved (e.g. acc. to ADR) may be used.
7.3 Specific end use(s)
See section 16 for a general overview.

8.1 Control parameters

National limit values
Occupational exposure limit values (Workplace Exposure Limits)

Netherlands Page 41'13

MARINECARE 147 SOS-01
 Safety Data Sheet··
according to Regulation (EC) No. 190712006 (REACH), amended by
MARINE 2015/830/EU

CARE
CARECLEAN ALKALINE
Version number:GHS8.0 revision: 29.11.2018
Replaces version of: 20.09,2018 (GHS 7)

Notation
Ceiling-C Ceiling value is a limit value above which exposure should not occur.
STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15~minute period
(unless otherwise specified). .. . . .
TWA Time-weighted average(long-term exposure limit): measured or calculated in relation to a reference period of 8 hourstime­
weighted average (unless otherwise specified).

Relevant DNELs/DMELs/PNECs and other threshold levels

• relevantDNELs of components of the mixture

Butylglycol 111-76-2 DNEL 75 mg/kg human, dermal worker (in­ chronic ­ systemic ef­
dustry) fects

Butylglycol 111-76-2 DNEL 98 mg/m3 human, inhalatory worker (in­ chronic ­ systemic ef­
dustry) fects-

Potassium Hydroxide 1310-58­ DNEL 1 mg/m3 human, inhalatory worker (in­ chronic - local effects
3 dustry)

Hexyl D-glucoside 54549­ DNEL 595.000 mgikg human, dermal worker (in­ chronic - systemic ef­
24-5 dustry) fects

Hexyl D-glucoside 54549­ DNEL 420 mg/m3 human, inhalatory worker (in­ chronic - systemic ef­
24-5 dustry) fects

• relevant PNECsof components of the mixture

,~

Butylglycol 111-76c 2 PNEC 8,8 m9f1 aquatic organisms freshwater short-term (single in­
stance)

Butylglycol 111-76-2 PNEC 0,88 mg/l aquatic organisms marine water short-term (single in­
stance)

Butylglycol 111-76-2 PNEC 463 m9/1 microorganisms sewage treat­ short-term (single in­
mentplant stance)
(STP)

Butylglycol 111-76-2 PNEC 34,6 m9jkg benthic organisms sediments short-term (single in­
stance)

Butylglycol 111-76-2 PNEC 3,13 mg/ kg terrestrial organisms soil short-term (single in­
stance)

Butylglycol 111-76-2 PNEC 9,1 mWI aquatic organisms water intermittent release

Hexyl D-glucoside 54549­ PNEC 0,1 n19j1 aquatic organisms freshwater short-term (single in­
24-5 stance)

Hexyl D-glucoside 54549­ PNEC 0,01 m9j1 aquatic organisms marine water short-term (single in­
24-5 stance)

Hexyl D"glucoside 54549­ PNEC 100 m9f1 microorganisms sewage treat­ short-term (single in­
24-5 ment plant stance)
(8TP)

Netherlands Page 5/ 13
MARINECARE 147 8D8-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
MARINE 2015/830/EU
CARE
CARECLEAN ALKALINE
Version number: GHS 8.0 revision: 29.11.2018
Replaces version 01:20.09.2018 (GHS 7)

Hexyl D-glucoside 54549- PNEC 0,041 mg/kg pelagic organisms sediments short-term (single in~
24-5 stance)
Hexyl D-glucoside 54549- PNEC 111,1 mg/ kg (top) predators water short-term (single in­
24-5 stance)

Hexyl D-glucoside 54549- . PNEC 0,654 terrestrial organisms soil short-term (single in­
24-5 stance)

Hexyl D-glucoside 54549- PNEC 4,2 m9f1 aquatic organisms water intermittent release
24-5

8.2 Exposure controls

Appropriate engineering controls
General ventilation.
Individual protection measures (personal protective equipment)
Eye/face protection
Wear eye/face protection.
Skin protection
• hand protection
.Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check
leak-tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them before
taking off and air them well. For special purposes, it is recommended to check the resistance to chemicals of
the protective gloves mentioned above together with the supplier of these gloves.
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recom­
mended. Wash hands thoroughly after handling.
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground
water.

9.1 Information on basic physical and chemical properties

Appearance
Physical state liquid
Colour transparent
Odour characteristic
Other physical and chemical parameters
pH (value) > 12 (base)
Melting poinVfreezing point -8°C
Initial boiling point and boiling range 103°C
Flash point not determined
Evaporation rate not determined
Flammability (solid, gas) not relevant (fluid)

Netherlands Page 6/13

MARINECARE 147 8D8-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
MARINE 2015/830/EU
CARE
CARECLEAN ALKALINE
Versiol1l1umber: GHS 8.0 revision: 29.11.2018
Repiacesversion of: 20.09.2018 (GHS7)

Explosive limits not determined

Vapour pressure not determined
Density 1,09 9/ cm 3
Solubility(ies) not determined
Partition coefficient
n-octanollwater (log KOW) This information is not available.
Auto-ignition temperature not determined
Viscosity not determined
Explosive properties none
Oxidi'sing properties none
9.2 Other information There is no additional information.

10.1 Reactivity
Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". substance or mix­
ture corrosive to metals
10.2 Chemical stability
See below "Conditions to avoid".
10.3 Possibility of hazardous reactions
No known hazardous reactions.
10.4 Conditions to avoid
There areno.specific conditions known whicn have to be avoided.
Physical stresses which might result in a h~zardous sitUation and have to be avoided
strong shocks
10.5 Incompatible materials
oxidisers
Release of flammable materials with
light metals (due to the release of hydrogen in an acid/alkaline medium)
10.6 Hazardous decomposition products
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and
heating are not known. Hazardous combustion products: see section 5.

11.1 Information on toxicological effects

Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity formula)

Classification according to GHS (1272/200S/EC, CLP)

Acute toxicity
I Shall not be classified as acutely toxic.

Netherlands Page 7/13

MARINECARE 147 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
MARINE 201 5/830/EU
CARE
CARECLEAN ALKALINE
Version number: GH8 8.0 revision: 29.11.2018
Replaces version 01:20.09.20t8 (GHS 7)

• Acute toxicity of components of the mixture

Butylglycol 111·7fr·2 . dermal

Butylglycol 111·76·2 inhalation: vapour

Potassium Hydroxide 1310·58·3 oral

Skin corrosion/irritation
Causes severe skin burns and eye damage.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensltisation
Shall not be classified as a respiratory or skin sensitiser.
Sum,mary ofevaluation of the CMR properties
.Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant.
Specific target organ toxicity (STOT)
Shall not be classified as a specific target organ toxicant.
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

12.1 Toxicity
Shall not be classified as hazardous to the aquatic environment.
Aquatic toxicity (acute)
Aquatic (acute) of components of the mixture

Butylglycol 111·76·2 LC50 1.474 mg" fish 96 h

Butylglycol 111·76·2 EC50 1.550 mgt, aquatic inverteb· 48 h

rates

Butylglycol 111·76·2 ErC50 1.840 mgt, algae 72h

Hexyl O·glucoside 54549·24·5 LC50 420 mgt, . fiSh 96 h

Hexyl O·glucoside 54549·24·5 EC50 490 mgt, aquatic inverteb· 48 h

rates

12.2 Persistence and degradability

Degradabilityof components of the mixture

~ Hexyl D·glucoside 54549·24·5 oxygen depletion 71 % 28d

12.3 Bioaccumulative potential

Data are not available.

Netherlands Pa~e 8/13

MARINECARE 147808·01
 Safety Data Sheet
according toRegulation (EC) No. 1907/2006 (REACH), amended by
MARINE 2015/830/EU

CARE
CARECLEAN ALKALINE
Version number: GHS 8.0 revision: 29.11.2018
Replaces version 01: 20.09.2018 (GHS 7)

Bioaccumulative potential of components of the mixture

Butylglycol 111-76-2 0,81 (pH value: 7, 25 °C)

0,57 (pH value: 7, 20 °C)

Hexyl D-glucoside 54549-24-5 1,72 (pH value: 6,5, 40 °C)

12.4 Mobility in soil

Data are not available.
12.5 Results of PBT and "PvB assessment
Data are not available.
~----\ 12.6 Other adverse ef-fects

13.1 Waste treatment methods

Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used. Completely
emptied packages can be recycled. Handle contaminated packages in tile same way as the substance itself.
Remarks
Please consider the relevant national or regional provisions. Waste shall be separated into the categories that
can be handled separately by the local or national waste management facilities.

14.1 UN number 1814

(""'. 14.2 UN proper shipping name POTASSIUM HYDROXIDE SOLUTION
14.3 Transport hazard class(es)
Class 8 (corrosive substances)
14.4 Packing group II (substance presenting medium danger)
14.5 Environmental hazards none (non-environmentally hazardous acc. to the dangerous
goods regulations)
14.6 Special precautions for user
Provisions for dangerous goods (ADR) should be complied within the premises.
14.7 Transportin bulk according to Annex II of MARPOL and the IBC Code
The cargo is not intended tp be carried in bulk.
• Transport of dangerous goods by road, rail and inland waterway (ADRIRID/ADN)
UN number 1814
Proper shipping name POTASSIUM HYDROXIDE SOLUTION
Particulars in the transport document UN1814, POTASSIUM HYDROXIDE SOLUTION,
(contains: Potassium Hydroxide), 8, II, (E)
Class 8
Classification code C5
Packing group II
Danger label(s) 8

Netherlands Page 9/13

MARINECARE 147 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
2015/830/EU
MARINE
CARE
CARECLEAN ALKALINE
Version number: GH8 8.0 revision: 29.11.2018
Replaces version of: 20.09.2018 (GH8 7)

Excepted quantities (EQ) E2

Limited quantities (LQ) 1L
Transport category (TC) 2
Tunnel restdction code (TRC) E
Hazard identification No 80
-International Maritime Dangerous Goods Code (IMDG)
UN number , 1814
Proper shipping name POTASSIUM HYDROXIDE SOLUTION
Particulars in the shipper's declaration UN1814, POTASSIUM HYDROXIDE SOLUTION,
(contains: Potassium Hydroxide), 8, II
Class 8
Packing group II
Danger label(s) 8

Special provisions (SP)

Excepted quantities (EQ) E2
Limifedquantities (LQ) 1L
EmS F-A, S-B
Stowage category A
"Separated from" acids
Segregation group 18 - Alkalis
- International Civil Aviation Organization (ICAO-IATAlDGR)
UN number 1814
Proper shipping name Potassium hydroxide solution
Particulars in the shipper's declaration UN1814, Potassium hydroxide solution, (contains: Po­
tassium Hydroxide), 8, II
Class 8
Packing group II '"
Dangerlabel(s) 8

Special provisions (SP) A3

Excepted quantities (EQ) E2
Limited quantities (LQ) 0,5 L

Netherlands Page 10 113

MARINECARE 147 8D8-01
 Safety Data Sheet
according to Regulation (EC)No. 1907/2006 (REACH). amended by
MARINE 2015/830/EU
. CARE

CARECLEANALKALINE
Version number: GHS 8.0 revision: 29.11.2018
Replaces version of: 20.09.2018 (GHS 7)

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
• Limitation of emissions of volatile organic compounds due to the use of organic solvents in
certain paints and varnishes and vehicle refinishing products (2004/42/EC, Deco-Paint Directive)
VOC content 8%
• Directive on industrial emissions (VOCs, 2010/75/EU)
VOC content 8%
15.2 Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.

Abbreviations and acronyms

lAtA Iriternational Air Transport Association

Netherlands Page 11 1 13
MARINECARE 147 SOS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amen.ded by
MARINE 2015/830/EU
CARE
CARECLEAN ALKALINE
Version number: GHS 8.0 revision: 29.11.2018
Replaces version of: 20.09.2018 (GHS 7)

Key literature references and sources for data

- Re.gulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
- Regulation (EC) No. 1272/2008 (CLP, EUGHS)

Classification procedure
Physical and chemical properties:The classification is based on tested mixture. .
Health hazards/en~ironmental hazards: The method for classification of the mixture is based on ingredients of
the mixture (additivity formula).

List of relevant phrases (code and full text as stated in chapter 2 and 3)

Netherlands Page12/13
MARINECARE 147 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
MARINE 2015/830/EU
CARE
CARECLEAN ALKALINE
Version number: GHS 8.0 revision: 2,9.11.2018
Replaces version of: 20.09.2018 (GHS 7)

Disclaimer
This information is based upon the present state of our knowledge. This SOS has been compiled and is solely
intended for this product.

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MARINECARE 147 SDS-01