Conductivity
Conductivity
This article is about electrical conductivity in general. For other types of conductivity, see
Conductivity. For specific applications in electrical elements, see Electrical resistance and
conductance.
Resistivity
Common symbols ρ
SI unit ohm metre (Ω⋅m)
Other units s (Gaussian/ESU)
In SI base units kg⋅m3⋅s−3⋅A−2
Derivations from
other quantities
Dimension
Conductivity
Common symbols σ, κ, γ
SI unit siemens per metre (S/m)
Other units (Gaussian/ESU)
Derivations from
other quantities
Dimension
Definition [ edit ]
In an ideal case, cross-section and physical composition of the examined material are uniform
across the sample, and the electric field and current density are both parallel and constant
everywhere. Many resistors and conductors do in fact have a uniform cross section with a uniform
flow of electric current, and are made of a single material, so that this is a good model. (See the
adjacent diagram.) When this is the case, the resistance of the conductor is directly proportional to
its length and inversely proportional to its cross-sectional area, where the electrical resistivity
ρ (Greek: rho) is the constant of proportionality. This is written as:
where
The resistivity can be expressed using the SI unit ohm metre (Ω⋅m)—i.e. ohms multiplied by square
metres (for the cross-sectional area) then divided by metres (for the length).
Both resistance and resistivity describe how difficult it is to make electrical current flow through a
material, but unlike resistance, resistivity is an intrinsic property and does not depend on geometric
properties of a material. This means that all pure copper (Cu) wires (which have not been subjected
to distortion of their crystalline structure etc.), irrespective of their shape and size, have the same
resistivity, but a long, thin copper wire has a much larger resistance than a thick, short copper wire.
Every material has its own characteristic resistivity. For example, rubber has a far larger resistivity
than copper.
In a hydraulic analogy, passing current through a high-resistivity material is like pushing water
through a pipe full of sand - while passing current through a low-resistivity material is like pushing
water through an empty pipe. If the pipes are the same size and shape, the pipe full of sand has
higher resistance to flow. Resistance, however, is not solely determined by the presence or
absence of sand. It also depends on the length and width of the pipe: short or wide pipes have
lower resistance than narrow or long pipes.
The above equation can be transposed to get Pouillet's law (named after Claude Pouillet):
The resistance of a given element is proportional to the length, but inversely proportional to the
cross-sectional area. For example, if A = 1 m2, = 1 m (forming a cube with perfectly conductive
contacts on opposite faces), then the resistance of this element in ohms is numerically equal to the
resistivity of the material it is made of in Ω⋅m.
If the geometry is more complicated, or if the resistivity varies from point to point within the material,
the current and electric field will be functions of position. Then it is necessary to use a more general
expression in which the resistivity at a particular point is defined as the ratio of the electric field to
the density of the current it creates at that point:
where
For example, rubber is a material with large ρ and small σ — because even a very large electric
field in rubber makes almost no current flow through it. On the other hand, copper is a material with
small ρ and large σ — because even a small electric field pulls a lot of current through it.
This expression simplifies to the formula given above under "ideal case" when the resistivity is
constant in the material and the geometry has a uniform cross-section. In this case, the electric
field and current density are constant and parallel.
When the resistivity of a material has a directional component, the most general definition of
resistivity must be used. It starts from the tensor-vector form of Ohm's law, which relates the
electric field inside a material to the electric current flow. This equation is completely general,
meaning it is valid in all cases, including those mentioned above. However, this definition is the
most complicated, so it is only directly used in anisotropic cases, where the more simple definitions
cannot be applied. If the material is not anisotropic, it is safe to ignore the tensor-vector definition,
and use a simpler expression instead.
Here, anisotropic means that the material has different properties in different directions. For
example, a crystal of graphite consists microscopically of a stack of sheets, and current flows very
easily through each sheet, but much less easily from one sheet to the adjacent one.[4] In such
cases, the current does not flow in exactly the same direction as the electric field. Thus, the
appropriate equations are generalized to the three-dimensional tensor form:[5][6]
where the conductivity σ and resistivity ρ are rank-2 tensors, and electric field E and current
density J are vectors. These tensors can be represented by 3×3 matrices, the vectors with 3×1
matrices, with matrix multiplication used on the right side of these equations. In matrix form, the
resistivity relation is given by:
where
In either case, the resulting expression for each electric field component is:
Since the choice of the coordinate system is free, the usual convention is to simplify the expression
by choosing an x-axis parallel to the current direction, so Jy = Jz = 0. This leaves:
or
Looking at the two expressions, and are the matrix inverse of each other. However, in the
most general case, the individual matrix elements are not necessarily reciprocals of one another;
for example, σxx may not be equal to 1/ρxx. This can be seen in the Hall effect, where is
nonzero. In the Hall effect, due to rotational invariance about the z-axis, and
, so the relation between resistivity and conductivity simplifies to:[8]
If the electric field is parallel to the applied current, and are zero. When they are zero, one
number, , is enough to describe the electrical resistivity. It is then written as simply , and this
reduces to the simpler expression.
Conductivity and current carriers [ edit ]
The relation between current density and electric current velocity is governed by the equation
where
= drift velocity (m/s) — the average velocity of charge carriers in the direction of the electric
field.
Which can be rearranged to show current velocity's inverse relationship to the number of charge
carriers at constant current density.
According to elementary quantum mechanics, an electron in an atom or crystal can only have
certain precise energy levels; energies between these levels are impossible. When a large number
of such allowed levels have close-spaced energy values—i.e. have energies that differ only
minutely—those close energy levels in combination are called an "energy band". There can be
many such energy bands in a material, depending on the atomic number of the constituent atoms[a]
and their distribution within the crystal.[b]
The material's electrons seek to minimize the total energy in the material by settling into low energy
states; however, the Pauli exclusion principle means that only one can exist in each such state. So
the electrons "fill up" the band structure starting from the bottom. The characteristic energy level up
to which the electrons have filled is called the Fermi level. The position of the Fermi level with
respect to the band structure is very important for electrical conduction: Only electrons in energy
levels near or above the Fermi level are free to move within the broader material structure, since
the electrons can easily jump among the partially occupied states in that region. In contrast, the low
energy states are completely filled with a fixed limit on the number of electrons at all times, and the
high energy states are empty of electrons at all times.
Electric current consists of a flow of electrons. In metals there are many electron energy levels near
the Fermi level, so there are many electrons available to move. This is what causes the high
electronic conductivity of metals.
An important part of band theory is that there may be forbidden bands of energy: energy intervals
that contain no energy levels. In insulators and semiconductors, the number of electrons is just the
right amount to fill a certain integer number of low energy bands, exactly to the boundary. In this
case, the Fermi level falls within a band gap. Since there are no available states near the Fermi
level, and the electrons are not freely movable, the electronic conductivity is very low.
In metals [ edit ]
A metal consists of a lattice of atoms, each with an outer shell of electrons that freely dissociate
from their parent atoms and travel through the lattice. This is also known as a positive ionic
lattice.[9] This 'sea' of dissociable electrons allows the metal to conduct electric current. When an
electrical potential difference (a voltage) is applied across the metal, the resulting electric field
causes electrons to drift towards the positive terminal. The actual drift velocity of electrons is
typically small, on the order of magnitude of metres per hour. However, due to the sheer number of
moving electrons, even a slow drift velocity results in a large current density.[10] The mechanism is
similar to transfer of momentum of balls in a Newton's cradle[11] but the rapid propagation of an
electric energy along a wire is not due to the mechanical forces, but the propagation of an energy-
carrying electromagnetic field guided by the wire.
Most metals have electrical resistance. In simpler models (non quantum mechanical models) this
can be explained by replacing electrons and the crystal lattice by a wave-like structure. When the
electron wave travels through the lattice, the waves interfere, which causes resistance. The more
regular the lattice is, the less disturbance happens and thus the less resistance. The amount of
resistance is thus mainly caused by two factors. First, it is caused by the temperature and thus
amount of vibration of the crystal lattice. Higher temperatures cause bigger vibrations, which act as
irregularities in the lattice. Second, the purity of the metal is relevant as a mixture of different ions is
also an irregularity.[12][13] The small decrease in conductivity on melting of pure metals is due to the
loss of long range crystalline order. The short range order remains and strong correlation between
positions of ions results in coherence between waves diffracted by adjacent ions.[14]
In metals, the Fermi level lies in the conduction band (see Band Theory, above) giving rise to free
conduction electrons. However, in semiconductors the position of the Fermi level is within the band
gap, about halfway between the conduction band minimum (the bottom of the first band of unfilled
electron energy levels) and the valence band maximum (the top of the band below the conduction
band, of filled electron energy levels). That applies for intrinsic (undoped) semiconductors. This
means that at absolute zero temperature, there would be no free conduction electrons, and the
resistance is infinite. However, the resistance decreases as the charge carrier density (i.e., without
introducing further complications, the density of electrons) in the conduction band increases. In
extrinsic (doped) semiconductors, dopant atoms increase the majority charge carrier concentration
by donating electrons to the conduction band or producing holes in the valence band. (A "hole" is a
position where an electron is missing; such holes can behave in a similar way to electrons.) For
both types of donor or acceptor atoms, increasing dopant density reduces resistance. Hence,
highly doped semiconductors behave metallically. At very high temperatures, the contribution of
thermally generated carriers dominates over the contribution from dopant atoms, and the
resistance decreases exponentially with temperature.
In electrolytes, electrical conduction happens not by band electrons or holes, but by full atomic
species (ions) traveling, each carrying an electrical charge. The resistivity of ionic solutions
(electrolytes) varies tremendously with concentration – while distilled water is almost an insulator,
salt water is a reasonable electrical conductor. Conduction in ionic liquids is also controlled by the
movement of ions, but here we are talking about molten salts rather than solvated ions. In
biological membranes, currents are carried by ionic salts. Small holes in cell membranes, called ion
channels, are selective to specific ions and determine the membrane resistance.
The concentration of ions in a liquid (e.g., in an aqueous solution) depends on the degree of
dissociation of the dissolved substance, characterized by a dissociation coefficient , which is the
ratio of the concentration of ions to the concentration of molecules of the dissolved substance
:
where : module of the ion charge, and : mobility of positively and negatively charged ions,
: concentration of molecules of the dissolved substance, : the coefficient of dissociation.
Superconductivity [ edit ]
Plasma [ edit ]
Plasmas are very good conductors and electric potentials play an important role.
The potential as it exists on average in the space between charged particles, independent of the
question of how it can be measured, is called the plasma potential, or space potential. If an
electrode is inserted into a plasma, its potential generally lies considerably below the plasma
potential, due to what is termed a Debye sheath. The good electrical conductivity of plasmas
makes their electric fields very small. This results in the important concept of quasineutrality, which
says the density of negative charges is approximately equal to the density of positive charges over
large volumes of the plasma (ne = ⟨Z⟩ > ni), but on the scale of the Debye length there can be
charge imbalance. In the special case that double layers are formed, the charge separation can
extend some tens of Debye lengths.
The magnitude of the potentials and electric fields must be determined by means other than simply
finding the net charge density. A common example is to assume that the electrons satisfy the
Boltzmann relation:
Differentiating this relation provides a means to calculate the electric field from the density:
(∇ is the vector gradient operator; see nabla symbol and gradient for more information.)
It is possible to produce a plasma that is not quasineutral. An electron beam, for example, has only
negative charges. The density of a non-neutral plasma must generally be very low, or it must be
very small. Otherwise, the repulsive electrostatic force dissipates it.
In astrophysical plasmas, Debye screening prevents electric fields from directly affecting the
plasma over large distances, i.e., greater than the Debye length. However, the existence of
charged particles causes the plasma to generate, and be affected by, magnetic fields. This can and
does cause extremely complex behavior, such as the generation of plasma double layers, an object
that separates charge over a few tens of Debye lengths. The dynamics of plasmas interacting with
external and self-generated magnetic fields are studied in the academic discipline of
magnetohydrodynamics.
Plasma is often called the fourth state of matter after solid, liquids and gases.[18][19] It is distinct
from these and other lower-energy states of matter. Although it is closely related to the gas phase
in that it also has no definite form or volume, it differs in a number of ways, including the following:
Maxwellian: collisions
usually lead to a Often non-Maxwellian: collisional interactions are
Velocity Maxwellian velocity often weak in hot plasmas and external forcing can
distribution distribution of all gas drive the plasma far from local equilibrium and lead to
particles, with very few a significant population of unusually fast particles.
relatively fast particles.
Binary: two-particle
Collective: waves, or organized motion of plasma, are
collisions are the rule,
Interactions very important because the particles can interact at
three-body collisions
long ranges through the electric and magnetic forces.
extremely rare.
The degree of semiconductors doping makes a large difference in conductivity. To a point, more
doping leads to higher conductivity. The conductivity of a water/aqueous solution is highly
dependent on its concentration of dissolved salts and other chemical species that ionize in the
solution. Electrical conductivity of water samples is used as an indicator of how salt-free, ion-free,
or impurity-free the sample is; the purer the water, the lower the conductivity (the higher the
resistivity). Conductivity measurements in water are often reported as specific conductance,
relative to the conductivity of pure water at 25 °C. An EC meter is normally used to measure
conductivity in a solution. A rough summary is as follows:
Superconductors 0
Metals 10−8
Semiconductors Variable
Electrolytes Variable
Insulators 1016
Superinsulators ∞
This table shows the resistivity (ρ), conductivity and temperature coefficient of various materials at
20 °C (68 °F; 293 K).
7.00 × 10−3[30]
Cobalt[i] 6.24 × 10−8 16.0 × 106 [unreliable source?]
6.70 × 105
Nichrome[k] 110 × 10−8 [citation needed]
0.40 × 10−3 [21]
Carbon (graphite)
perpendicular to basal 3.0 × 10−3 3.3 × 102 [4]
plane
3.3 × 10−1 to
Swimming pool water[o] 0.25 to 0.30 [43]
4.0 × 10−1
5 × 10−4 to
Drinking water[p] 2 × 101 to 2 × 103 [citation needed]
5 × 10−2
The effective temperature coefficient varies with temperature and purity level of the material. The
20 °C value is only an approximation when used at other temperatures. For example, the
coefficient becomes lower at higher temperatures for copper, and the value 0.00427 is commonly
specified at 0 °C.[53]
The extremely low resistivity (high conductivity) of silver is characteristic of metals. George Gamow
tidily summed up the nature of the metals' dealings with electrons in his popular science book One,
Two, Three...Infinity (1947):
The metallic substances differ from all other materials by the fact that the outer shells of
their atoms are bound rather loosely, and often let one of their electrons go free. Thus the
interior of a metal is filled up with a large number of unattached electrons that travel
aimlessly around like a crowd of displaced persons. When a metal wire is subjected to
electric force applied on its opposite ends, these free electrons rush in the direction of the
force, thus forming what we call an electric current.
More technically, the free electron model gives a basic description of electron flow in metals.
Wood is widely regarded as an extremely good insulator, but its resistivity is sensitively dependent
on moisture content, with damp wood being a factor of at least 1010 worse insulator than oven-
dry.[46] In any case, a sufficiently high voltage – such as that in lightning strikes or some high-
tension power lines – can lead to insulation breakdown and electrocution risk even with apparently
dry wood.[citation needed]
The electrical resistivity of most materials changes with temperature. If the temperature T does not
vary too much, a linear approximation is typically used:
Metals [ edit ]
See also: Bloch–Grüneisen temperature and Free electron model § Mean free dependence of
the resistivity of gold, copper and silver.
where is the residual resistivity due to defect scattering, A is a constant that depends on the
velocity of electrons at the Fermi surface, the Debye radius and the number density of electrons in
the metal. is the Debye temperature as obtained from resistivity measurements and matches
very closely with the values of Debye temperature obtained from specific heat measurements. n is
an integer that depends upon the nature of interaction:
n = 5 implies that the resistance is due to scattering of electrons by phonons (as it is for simple
metals)
n = 3 implies that the resistance is due to s-d electron scattering (as is the case for transition
metals)
n = 2 implies that the resistance is due to electron–electron interaction.
The Bloch–Grüneisen formula is an approximation obtained assuming that the studied metal has
spherical Fermi surface inscribed within the first Brillouin zone and a Debye phonon spectrum.[56]
If more than one source of scattering is simultaneously present, Matthiessen's rule (first formulated
by Augustus Matthiessen in the 1860s)[57][58] states that the total resistance can be approximated
by adding up several different terms, each with the appropriate value of n.
As the temperature of the metal is sufficiently reduced (so as to 'freeze' all the phonons), the
resistivity usually reaches a constant value, known as the residual resistivity. This value depends
not only on the type of metal, but on its purity and thermal history. The value of the residual
resistivity of a metal is decided by its impurity concentration. Some materials lose all electrical
resistivity at sufficiently low temperatures, due to an effect known as superconductivity.
An investigation of the low-temperature resistivity of metals was the motivation to Heike Kamerlingh
Onnes's experiments that led in 1911 to discovery of superconductivity. For details see History of
superconductivity.
The Wiedemann–Franz law states that for materials where heat and charge transport is dominated
by electrons, the ratio of thermal to electrical conductivity is proportional to the temperature:
where is the thermal conductivity, is the Boltzmann constant, is the electron charge, is
temperature, and is the electric conductivity. The ratio on the rhs is called the Lorenz number.
Semiconductors [ edit ]
In general, intrinsic semiconductor resistivity decreases with increasing temperature. The electrons
are bumped to the conduction energy band by thermal energy, where they flow freely, and in doing
so leave behind holes in the valence band, which also flow freely. The electric resistance of a
typical intrinsic (non doped) semiconductor decreases exponentially with temperature following an
Arrhenius model:
Extrinsic (doped) semiconductors have a far more complicated temperature profile. As temperature
increases starting from absolute zero they first decrease steeply in resistance as the carriers leave
the donors or acceptors. After most of the donors or acceptors have lost their carriers, the
resistance starts to increase again slightly due to the reducing mobility of carriers (much as in a
metal). At higher temperatures, they behave like intrinsic semiconductors as the carriers from the
donors/acceptors become insignificant compared to the thermally generated carriers.[59]
In non-crystalline semiconductors, conduction can occur by charges quantum tunnelling from one
localised site to another. This is known as variable range hopping and has the characteristic form of
Kondo insulators are materials where the resistivity follows the formula
where , , and are constant parameters, the residual resistivity, the Fermi liquid
When analyzing the response of materials to alternating electric fields (dielectric spectroscopy),[60]
in applications such as electrical impedance tomography,[61] it is convenient to replace resistivity
with a complex quantity called impedivity (in analogy to electrical impedance). Impedivity is the
sum of a real component, the resistivity, and an imaginary component, the reactivity (in analogy to
reactance). The magnitude of impedivity is the square root of sum of squares of magnitudes of
resistivity and reactivity.
Conversely, in such cases the conductivity must be expressed as a complex number (or even as a
matrix of complex numbers, in the case of anisotropic materials) called the admittivity. Admittivity is
the sum of a real component called the conductivity and an imaginary component called the
susceptivity.
An alternative description of the response to alternating currents uses a real (but frequency-
dependent) conductivity, along with a real permittivity. The larger the conductivity is, the more
quickly the alternating-current signal is absorbed by the material (i.e., the more opaque the material
is). For details, see Mathematical descriptions of opacity.
Even if the material's resistivity is known, calculating the resistance of something made from it may,
in some cases, be much more complicated than the formula above. One example is
spreading resistance profiling, where the material is inhomogeneous (different resistivity in different
places), and the exact paths of current flow are not obvious.
where E and J are now vector fields. This equation, along with the continuity equation for J and the
Poisson's equation for E, form a set of partial differential equations. In special cases, an exact or
approximate solution to these equations can be worked out by hand, but for very accurate answers
in complex cases, computer methods like finite element analysis may be required.
In some applications where the weight of an item is very important, the product of resistivity and
density is more important than absolute low resistivity – it is often possible to make the conductor
thicker to make up for a higher resistivity; and then a material with a low resistivity–density product
(or equivalently a high conductivity/density ratio) is desirable. For example, for long-distance
overhead power lines, aluminium is frequently used rather than copper (Cu) because it is lighter for
the same conductance.
Silver, although it is the least resistive metal known, has a high density and performs similarly to
copper by this measure, but is much more expensive. Calcium and the alkali metals have the best
resistivity-density products, but are rarely used for conductors due to their high reactivity with water
and oxygen, and lack of physical strength. Aluminium is far more stable. Toxicity excludes the
choice of beryllium;[62] pure beryllium is also brittle. Thus, aluminium is usually the metal of choice
when the weight or cost of a conductor is the driving consideration.
History [ edit ]
In a 1774 letter to Dutch-born British scientist Jan Ingenhousz, Benjamin Franklin relates an
experiment by another British scientist, John Walsh, that purportedly showed this astonishing fact:
Although rarified air conducts electricity better than common air, a vacuum does not conduct
electricity at all.[63]
Mr. Walsh ... has just made a curious Discovery in Electricity. You know we find that in
rarify’d Air it would pass more freely, and leap thro’ greater Spaces than in dense Air; and
thence it was concluded that in a perfect Vacuum it would pass any distance without the
least Obstruction. But having made a perfect Vacuum by means of boil’d Mercury in a long
Torricellian bent Tube, its Ends immers’d in Cups full of Mercury, he finds that the Vacuum
will not conduct at all, but resists the Passage of the Electric Fluid absolutely.
However, to this statement a note (based on modern knowledge) was added by the editors—at the
American Philosophical Society and Yale University—of the webpage hosting the letter:[63]
We can only assume that something was wrong with Walsh’s findings. ... Although the
conductivity of a gas, as it approaches a vacuum, increases up to a point and then
decreases, that point is far beyond what the technique described might have been
expected to reach. Boiling replaced the air with mercury vapor, which as it cooled created
a vacuum that could scarcely have been complete enough to decrease, let alone
eliminate, the vapor’s conductivity.
Notes [ edit ]
a. ^ The atomic number is the count of electrons in an atom that is electrically neutral – has no net electric
charge.
b. ^ Other relevant factors that are specifically not considered are the size of the whole crystal and
external factors of the surrounding environment that modify the energy bands, such as imposed electric
or magnetic fields.
c. ^ The numbers in this column increase or decrease the significand portion of the resistivity. For
example, at 30 °C (303 K), the resistivity of silver is 1.65 × 10−8. This is calculated as Δρ = α ΔT ρ0
where ρ0 is the resistivity at 20 °C (in this case) and α is the temperature coefficient.
d. ^ The conductivity of metallic silver is not significantly better than metallic copper for most practical
purposes – the difference between the two can be easily compensated for by thickening the copper
wire by only 3%. However silver is preferred for exposed electrical contact points because corroded
silver is a tolerable conductor, but corroded copper is a fairly good insulator, like most corroded metals.
e. ^ Copper is widely used in electrical equipment, building wiring, and telecommunication cables.
f. ^ Referred to as 100% IACS or International Annealed Copper Standard. The unit for expressing the
conductivity of nonmagnetic materials by testing using the eddy current method. Generally used for
temper and alloy verification of aluminium.
g. ^ Despite being less conductive than copper, gold is commonly used in electrical contacts because it
does not easily corrode.
h. ^ Commonly used for overhead power line with steel reinforced (ACSR)
i. ^ a b Cobalt and ruthenium are considered to replace copper in integrated circuits fabricated in
advanced nodes[29]
j. ^ 18% chromium and 8% nickel austenitic stainless steel
k. ^ Nickel-iron-chromium alloy commonly used in heating elements.
l. ^ Graphite is strongly anisotropic.
m. ^ a b The resistivity of semiconductors depends strongly on the presence of impurities in the material.
n. ^ Corresponds to an average salinity of 35 g/kg at 20 °C.
o. ^ The pH should be around 8.4 and the conductivity in the range of 2.5–3 mS/cm. The lower value is
appropriate for freshly prepared water. The conductivity is used for the determination of TDS (total
dissolved particles).
p. ^ This value range is typical of high quality drinking water and not an indicator of water quality
q. ^ Conductivity is lowest with monatomic gases present; changes to 12 × 10−5 upon complete de-
gassing, or to 7.5 × 10−5 upon equilibration to the atmosphere due to dissolved CO2
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Wikibooks has a book on the topic of: A-level Physics (Advancing Physics)/Resistivity and
Conductivity
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https://edu-physics.com/2021/01/07/resistivity-of-the-material-of-a-wire-physics-practical/
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