Elements of wood cell walls
The chief constituent of woody plant cell walls are cellulose, hemicellulose and lignin.
Cellulose comprises about 40-45% of wood, hemicellulose about 25-30% in soft wood and 20-
35% in hard wood and lignin about 20-30%.
Cellulose
• Cellulose is an organic compound with the formula (C 6H10O5)n, a polysaccharide
consisting of a linear chain of several hundred to over ten thousand linked glucose units.
• Cellulose is the structural component of the primary cell wall of green plants.
• About 33% of all plant matter is cellulose (the cellulose content of cotton fiber is 90%,
wood is 40–50% and dried hemp is approximately 45%)
• Cellulose is a straight chain polymer.
Hemicellulose
• They are associated with the cellulose in the cell wall and are carbohydrate polymers.
• Hemicellulose belongs to a group of heterogeneous polysaccharides.
• Like cellulose most hemicellulose function as supporting material in the cell wall.
• The amount of hemicellulose of the dry weight of wood is usually between 20 and
30%.
• The composition and structure of the hemicellulose in the softwood differ in a
characteristic way from those in the heartwood.
• Hemicellulose in Softwood - Mannose is the most important hemicellulosic monomer
followed by xylose, glucose, galactose and arabinose.
• Hemicellulose in Hardwood - Xylose is the most important hemicellulosic monomer
followed by mannose, glucose, galactose, with small amount of arabinose and
rhamnose.
Lignin
• Lignin is a class of complex organic polymers.
• Lignins are one of the main classes of structural materials in the support tissues of
vascular plants and some algae.
• Lignins are particularly important in the formation of cell walls, especially in wood
and bark, because they lend rigidity and do not rot easily.
• Chemically lignins are cross-linked phenol propane polymers.
• Lignin fills the spaces in the cell wall between cellulose, hemicellulose, and pectin
components, especially in xylem tracheids, vessel elements and sclereid cells.
• Lignin plays a significant role in the carbon cycle, sequestering atmospheric carbon into
the living tissues of woody perennial vegetation.
• Lignin is one of the most slowly decomposing components of dead vegetation,
contributing a major fraction of the material that becomes humus as it decomposes.