Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
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BioMed Durable Resin

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product Name: BioMed Durable Resin
Product code: FLBMDU01
UFI: QY30-F0HQ-000M-8Y6Q
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: For use in Formlabs SLA Printers
Uses advised against: Not determined or not applicable.
Reasons why uses advised against: Not determined or not applicable.
1.3 Details of the manufacturer/supplier of the safety data sheet
Manufacturer: Supplier:
United States Germany
Formlabs, Inc Formlabs GmbH
35 Medford St Nalepastr. 18
Suite 201 Somerville, MA 02143 Berlin, . 12459
+1 617 855 0762 +49 30 700 146 501
sds@formlabs.com

1.4 Emergency telephone number:

European Union
CHEMTREC (EMEA)
+44 20 3885 0382 (24/7)

SECTION 2: Hazard(s) identification

2.1 Classification of the substance or mixture:

Classification according to Regulation (EC) No. 1272/2008 (CLP):
Eye Irritation, category 2
Skin sensitization, category 1
Specific target organ toxicity - single exposure, category 3, respiratory tract irritation
Chronic aquatic hazard, category 2
Hazard-determining components of labeling:
Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
Urethane dimethacrylate
PEG dimethacrylate
Phenoxyethyl methacrylate
Additional Information: None
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008 (CLP)
Hazard pictograms:

Signal Word: Warning

Hazard statements:
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
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BioMed Durable Resin

H319 Causes serious eye irritation

H317 May cause an allergic skin reaction
H335 May cause respiratory irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary statements:
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves, protective clothing and eye protection.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P272 Contaminated work clothing should not be allowed out of the workplace
P271 Use only outdoors or in a well-ventilated area
P273 Avoid release to the environment
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention.
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P363 Wash contaminated clothing before reuse
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P312 Call a POISON CENTER/doctor/ if you feel unwell
P391 Collect spillage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents and container in accordance with local, regional, national, and international
regulations.
2.3 Other hazards: None known

SECTION 3: Composition/information on ingredients

3.1 Substance: Not applicable.

3.2 Mixture:
Identification EU REACH Name Classification Weight %
Registration No. according to
Regulation (EC) No.
1272/2008 (CLP)

CAS number: – Urethane dimethacrylate Skin Sens. 1; H317 55-75

72869-86-4 Aquatic Chronic 2;
EC number: H411
276-957-5

CAS number: – PEG dimethacrylate Skin Irrit. 2; H315 15-25

25852-47-5 Eye Irrit. 2; H319
STOT SE 3 (RI);
H335

CAS number: – Phenoxyethyl methacrylate Skin Irrit. 2; H315 10-20

10595-06-9 Skin Sens. 1A;
EC number: H317
234-201-1 Aquatic Chronic 2;
H411
Eye Irrit. 2; H319
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
Initial preparation date: 03.03.2023 Page 3 of 16
BioMed Durable Resin

CAS number: – Phenyl bis(2,4,6-trimethylbenzoyl)- Aquatic Chronic 4; <1

162881-26-7 phosphine oxide H413
EC number: Skin Sens. 1A;
423-340-5 H317
Additional information: None
Full Text of H and EUH statements: See section 16

SECTION 4: First aid measures

4.1 Description of first aid measures

General notes:
Show this Safety Data Sheet to the doctor in attendance.
Following inhalation:
If inhaled, remove person to fresh air and place in a position comfortable for breathing. If respiratory
symptoms develop or persist, seek medical advice/attention.
Following skin contact:
Wash affected area with plenty of soap and water. Remove contaminated clothing and launder before
reuse. If skin irritation develops or persists, seek medical advice/attention.
Following eye contact:
Immediately rinse eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for
and remove any contact lenses. Continue to rinse for at least 15 minutes. If eye irritation develops or
persists, seek medical advice/attention.
Following ingestion:
If swallowed, DO NOT induce vomiting unless told to do so by a physician or poison control center. Rinse
mouth with water. Never give anything by mouth to an unconscious person. If spontaneous vomiting
occurs, place on the left side with head down to prevent aspiration of liquid into the lungs. If symptoms
develop or persist, seek medical advice/attention.
Self-Protection of the first aider:
Not determined or not available.
4.2 Most important symptoms and effects, both acute and delayed
Acute symptoms and effects:
Eye contact may result in irritation, redness, pain, inflammation, itching, burning and tearing.
Dermal exposure may cause an allergic skin reaction. Symptoms may include irritation, redness, pain,
rash, inflammation, itching, burning and dermatitis.
Inhalation may have adverse effects on the respiratory tract. Symptoms may include cough, breathing
difficulties, sore throat and inflammation of the mucous membrane lining the respiratory tract.
Delayed symptoms and effects:
Effects are dependent on exposure (dose, concentration, contact time).
4.3 Indication of any immediate medical attention and special treatment needed
Specific treatment:
If respiratory symptoms persist, seek medical attention.
Notes for the doctor:
Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media:
Water mist/fog, carbon dioxide, dry chemical or alcohol resistant foam.
Unsuitable extinguishing media:
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
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BioMed Durable Resin

Do not use water jet.

5.2 Special hazards arising from the substance or mixture:
Thermal decomposition may produce irritating/toxic fumes/gases.
5.3 Advice for firefighters
Personal protection equipment:
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
(SCBA).
Special precautions:
Avoid contact with skin, eyes, hair and clothing. Do not breathe fumes/gas/mists/aerosols/vapors/dusts.
Move containers from fire area if safe to do so. Use water spray/fog for cooling fire exposed containers.
Avoid unnecessary run-off of extinguishing media which may cause pollution.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:

Evacuate unnecessary personnel. Ventilate area. Extinguish any sources of ignition. Wear recommended
personal protective equipment (see Section 8). Avoid contact with skin, eyes and clothing. Avoid
breathing mist, vapor, dust, fume and spray. Do not walk through spilled material. Wash thoroughly after
handling.
6.2 Environmental precautions:
Prevent further leakage or spillage if safe to do so. Prevent from reaching drains, sewers and waterways.
Discharge into the environment must be avoided.
6.3 Methods and material for containment and cleaning up:
Do not touch damaged containers or spilled material unless wearing appropriate personal protective
clothing. Stop leak if you can do it without risk. Contain and collect spillage and place in suitable
container for future disposal. Dispose of in accordance with all applicable regulations (see Section 13).
6.4 Reference to other sections:
For personal protective equipment see Section 8. For disposal see Section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling:

Use appropriate personal protective equipment (see Section 8). Use only with adequate ventilation.
Avoid breathing mist/vapor/spray/dust. Do not eat, drink, smoke, or use personal products when
handling chemical substances. Avoid contact with skin, eyes and clothing. Wash affected areas
thoroughly after handling. Keep away from incompatible materials (See Section 10). Keep containers
tightly closed when not in use.
7.2 Conditions for safe storage, including any incompatibilities:
Store in cool, dry, well-ventilated location out of direct sunlight. Keep away from food and beverages.
Protect from freezing and physical damage. Store away from heat, open flames and other sources of
ignition. Keep container tightly sealed. Store away from incompatible materials (See Section 10).
7.3 Specific end use(s):
Refer to Section 1 (Recommended Use).

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Only those substances with limit values have been included below.
Occupational Exposure limit values:
No occupational exposure limits noted for the ingredient(s).
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
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BioMed Durable Resin

Biological limit values:

No biological exposure limits noted for the ingredient(s).
Derived No Effect Level (DNEL):
Ingredient Name: Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
CAS #: 162881-26-7
Acute - Oral Not determined or not applicable.
Acute - Inhalation Not determined or not applicable.
Workers - Systemic Acute - Dermal No hazard identified
Effects Chronic - Oral Not determined or not applicable.
Chronic - Inhalation 21 mg/m³
Chronic - Dermal 3 mg/kg bw/day
Acute - Oral Not determined or not applicable.
Acute - Inhalation Not determined or not applicable.
Workers - Local Acute - Dermal Hazard identified but no DNEL available
Effects Chronic - Oral Not determined or not applicable.
Chronic - Inhalation Not determined or not applicable.
Chronic - Dermal Hazard identified but no DNEL available
Acute - Oral No hazard identified
Acute - Inhalation Not determined or not applicable.
General Population - Acute - Dermal No hazard identified
Systemic Effects Chronic - Oral 1.5 mg/kg bw/day
Chronic - Inhalation 5.2 mg/m³
Chronic - Dermal 1.5 mg/kg bw/day
Acute - Oral Not determined or not applicable.
Acute - Inhalation Not determined or not applicable.
General Population - Acute - Dermal Hazard identified but no DNEL available
Local Effect Chronic - Oral Not determined or not applicable.
Chronic - Inhalation Not determined or not applicable.
Chronic - Dermal Hazard identified but no DNEL available
Ingredient Name: Urethane dimethacrylate
CAS #: 72869-86-4
Acute - Oral Not determined or not applicable.
Acute - Inhalation No exposure expected
Workers - Systemic Acute - Dermal No hazard identified
Effects Chronic - Oral Not determined or not applicable.
Chronic - Inhalation 3.3 mg/m³
Chronic - Dermal 1.3 mg/kg bw/day
Acute - Oral Not determined or not applicable.
Acute - Inhalation No exposure expected
Workers - Local Acute - Dermal Hazard identified but no DNEL available
Effects Chronic - Oral Not determined or not applicable.
Chronic - Inhalation No exposure expected
Chronic - Dermal Hazard identified but no DNEL available
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
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Acute - Oral No hazard identified

Acute - Inhalation No exposure expected
General Population - Acute - Dermal No hazard identified
Systemic Effects Chronic - Oral 0.3 mg/kg bw/day
Chronic - Inhalation 0.6 mg/m³
Chronic - Dermal 0.7 mg/kg bw/day
Acute - Oral Not determined or not applicable.
Acute - Inhalation No exposure expected
General Population - Acute - Dermal No exposure expected
Local Effect Chronic - Oral Not determined or not applicable.
Chronic - Inhalation No exposure expected
Chronic - Dermal Hazard identified but no DNEL available
Ingredient Name: Phenoxyethyl methacrylate
CAS #: 10595-06-9
Acute - Oral Not determined or not applicable.
Acute - Inhalation Not determined or not applicable.
Workers - Systemic Acute - Dermal No hazard identified
Effects Chronic - Oral Not determined or not applicable.
Chronic - Inhalation 12 mg/m³
Chronic - Dermal 3.5 mg/kg bw/day
Acute - Oral Not determined or not applicable.
Acute - Inhalation Not determined or not applicable.
Workers - Local Acute - Dermal Hazard identified but no DNEL available
Effects Chronic - Oral Not determined or not applicable.
Chronic - Inhalation 84 mg/m³
Chronic - Dermal No hazard identified
Acute - Oral No hazard identified
Acute - Inhalation No hazard identified
General Population - Acute - Dermal No hazard identified
Systemic Effects Chronic - Oral No hazard identified
Chronic - Inhalation No hazard identified
Chronic - Dermal No hazard identified
Acute - Oral Not determined or not applicable.
Acute - Inhalation No hazard identified
General Population - Acute - Dermal No hazard identified
Local Effect Chronic - Oral Not determined or not applicable.
Chronic - Inhalation No hazard identified
Chronic - Dermal No hazard identified
Predicted No Effect Concentration (PNEC):
Ingredient Name: Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
CAS #: 162881-26-7
Environmental Protection Target PNEC
Fresh water 0.8 µg/L
Freshwater sediments 0.712 mg/kg
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
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Marine water 0.8 µg/L

Marine sediments 0.712 mg/kg
Microorganisms in sewage treatment Not determined or not available.
Soil (agricultural) 0.012 mg/kg soil dw
Air No hazard identified
Oral (Secondary Poisoning) No exposure expected
Ingredient Name: Urethane dimethacrylate
CAS #: 72869-86-4
Environmental Protection Target PNEC
Fresh water 0.01 mg/L
Freshwater sediments 4.56 mg/kg sediment dw
Marine water 0.001 mg/L
Marine sediments 0.46 mg/kg sediment dw
Microorganisms in sewage treatment 3.61 mg/L
Soil (agricultural) 0.91 mg/kg soil dw
Air No hazard identified
Oral (Secondary Poisoning) No exposure expected
Ingredient Name: Phenoxyethyl methacrylate
CAS #: 10595-06-9
Environmental Protection Target PNEC
Fresh water 14.2 µg/L
Freshwater sediments 0.665 mg/kg sediment dw
Marine water 1.42 µg/L
Marine sediments 0.067 mg/kg sediment dw
Microorganisms in sewage treatment 1.77 mg/L
Soil (agricultural) 0.125 mg/kg soil dw
Air No hazard identified
Oral (Secondary Poisoning) No exposure expected
Information on monitoring procedures:
Not determined or not applicable.
8.2 Exposure controls
Appropriate engineering controls:
Emergency eye wash stations and safety showers should be available in the immediate vicinity of use or
handling. Provide adequate ventilation to maintain the airborne concentrations of vapor, mists, and/or
dusts below the applicable workplace exposure limits, while observing recognized national standards (or
equivalent).
Personal protection equipment
Eye and face protection:
Safety glasses or goggles. Use eye protection equipment that has been tested and approved by
recognized national standards (or equivalent).
Skin and body protection:
Chemical resistant, impervious gloves approved by the appropriate standards. Gloves must be
inspected prior to use. Avoid skin contact with used gloves. Appropriate techniques should be used to
remove used gloves and contaminated clothing. Personal protective equipment for the body should
be selected based on the task being performed and the risks involved and should be approved by a
specialist before handling this product. Ensure that all personal protective equipment is approved by
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
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BioMed Durable Resin

recognized national standards (or equivalent).

Respiratory protection:
If engineering controls do not maintain airborne concentrations below the applicable workplace
exposure limits, or to an acceptable level (if exposure limits have not been established), a respirator
approved by recognized national standards (or equivalent) must be worn.
General hygienic measures:
When handling chemical products, do not eat, drink or smoke. Wash hands after handling, before breaks,
and at the end of the workday. Avoid contact with skin, eyes and clothing. Wash contaminated clothing
before reuse. Perform routine housekeeping.
Environmental exposure controls:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the
requirements of environmental protection legislation.

Product (substance / mixture) related measures to prevent Not determined or not applicable.
exposure:
Instruction measures to prevent exposure: Not determined or not applicable.
Organisational measures to prevent exposure: Not determined or not applicable.
Technical measures to prevent exposure: Not determined or not applicable.

Risk management measures to control exposure:

Not determined or not applicable.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical State Liquid
Color Not determined or not available.
Odor/Odor threshold Characteristic acrylate
pH Not determined or not available.
Melting point/freezing point Not determined or not available.
Initial boiling point/range > 100°C
Flash point (closed cup) > 93.5°C
Flammability Not flammable
Upper flammability/explosive limit Not determined or not available.
Lower flammability/explosive limit Not determined or not available.
Vapor pressure Not determined or not available.
Relative vapor density Not determined or not available.
Density Not determined or not available.
Relative density Not determined or not available.
Solubilities Not determined or not available.
Partition coefficient (n-octanol/water) Not determined or not available.
Auto/Self-ignition temperature Not determined or not available.
Decomposition temperature Not determined or not available.
Kinematic viscosity Not determined or not available.
Particle characteristics Not determined or not available.

9.2 Other information

9.2.1 Information with regard to physical hazard classes
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
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Explosives No data available/Not applicable

Flammable gases No data available/Not applicable
Aerosols No data available/Not applicable
Oxidizing gases No data available/Not applicable
Gases under pressure No data available/Not applicable
Flammable liquids No data available/Not applicable
Flammable solids No data available/Not applicable
Self-reactive substances and No data available/Not applicable
mixtures
Pyrophoric liquids No data available/Not applicable
Pyrophoric solids No data available/Not applicable
Self-heating substances and No data available/Not applicable
mixtures
Substances and mixtures, which emit No data available/Not applicable
flammable gases in contact with
water
Oxidizing liquids No data available/Not applicable
Oxidizing solids No data available/Not applicable
Organic peroxides No data available/Not applicable
Corrosive to metals No data available/Not applicable
Desensitized explosives No data available/Not applicable

9.2.2 Other safety characteristics

None.

SECTION 10: Stability and reactivity

10.1 Reactivity:
Not reactive under recommended handling and storage conditions.
10.2 Chemical stability:
Stable under recommended handling and storage conditions.
10.3 Possibility of hazardous reactions:
Hazardous reactions are not anticipated under recommended conditions of handling and storage.
Stable under recommended handling and storage conditions.
10.4 Conditions to avoid:
Extreme heat, open flames, hot surfaces, sparks, ignition sources and incompatible materials.
Avoid storage >38°C (100°F) and exposure to light/direct sunlight and heat.
10.5 Incompatible materials:
Polymerization initiators, including peroxides, strong oxidizing agents, alcohols, copper, copper alloys,
carbon steel, iron, rust, and strong bases.
10.6 Hazardous decomposition products:
Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity
Assessment: Based on available data, the classification criteria are not met.
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
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Product data: No data available.

Substance data:
Name Route Result
Phenyl bis(2,4,6- oral LD50 Rat: >2000 mg/kg
trimethylbenzoyl)-phosphine
oxide dermal LD50 Rat: >2000 mg/kg
Urethane dimethacrylate oral LD50 Rat: >5000 mg/kg
dermal LD50 Rat: >2000 mg/kg
Phenoxyethyl methacrylate oral LD50 Rat: >5000 mg/kg
dermal LD50 Rat: >2000 mg/kg

Skin corrosion/irritation
Assessment: Based on available data, the classification criteria are not met.
Product data:
No data available.
Substance data:
Name Result
PEG dimethacrylate Causes skin irritation.
Phenoxyethyl methacrylate Causes skin irritation.

Serious eye damage/irritation

Assessment:
Causes serious eye irritation.
Product data:
No data available.
Substance data:
Name Result
PEG dimethacrylate Causes serious eye irritation.
Phenoxyethyl methacrylate Causes serious eye irritation.

Respiratory or skin sensitization

Assessment:
May cause an allergic skin reaction.
Product data:
No data available.
Substance data:
Name Result
Phenyl bis(2,4,6- May cause an allergic skin reaction.
trimethylbenzoyl)-phosphine
oxide
Urethane dimethacrylate May cause an allergic skin reaction.
Phenoxyethyl methacrylate May cause an allergic skin reaction.

Carcinogenicity
Assessment: Based on available data, the classification criteria are not met.
Product data: No data available.
Substance data: No data available.
International Agency for Research on Cancer (IARC):
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
Initial preparation date: 03.03.2023 Page 11 of 16
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Name Classification
Phenyl bis(2,4,6- Not Applicable
trimethylbenzoyl)-phosphine
oxide
Urethane dimethacrylate Not Applicable
PEG dimethacrylate Not Applicable
Phenoxyethyl methacrylate Not Applicable

Germ cell mutagenicity

Assessment: Based on available data, the classification criteria are not met.
Product data: No data available.
Substance data: No data available.
Reproductive Toxicity
Assessment: Based on available data, the classification criteria are not met.
Product data:
No data available.
Substance data: No data available.
Specific target organ toxicity (single exposure)
Assessment:
May cause respiratory irritation.
Product data:
No data available.
Substance data:
Name Result
PEG dimethacrylate May cause respiratory irritation.

Specific target organ toxicity (repeated exposure)

Assessment: Based on available data, the classification criteria are not met.
Product data:
No data available.
Substance data: No data available.
Aspiration toxicity
Assessment: Based on available data, the classification criteria are not met.
Product data:
No data available.
Substance data: No data available.
Information on likely routes of exposure:
No data available.
Symptoms related to the physical, chemical and toxicological characteristics:
No data available.
11.2 Information on other hazards
Endocrine disrupting properties:
Substance data: No data available.
Other information:
No data available.

SECTION 12: Ecological information

12.1 Toxicity
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
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Acute (short-term) toxicity

Assessment: Based on available data, the classification criteria are not met.
Product data: No data available.
Substance data:
Name Result
Phenyl bis(2,4,6- Aquatic Plants EC50 Green algae: >0.26 mg/L (72 hr [growth rate])
trimethylbenzoyl)-phosphine Fish LC50 Freshwater fish: >0.09 mg/L (96 hr)
oxide
Aquatic Invertebrates EC50 Not specified: >1.175 mg/L (48 hr
[mobility])
Urethane dimethacrylate Fish LC50 Danio rerio: 10.1 mg/L (96 hr)
Aquatic Invertebrates EC50 Daphnia magna: > 1.2 mg/L (48 hr)
PEG dimethacrylate Fish LC50 Not specified: 25.51 mg/L (96 hr [QSAR])
Aquatic Invertebrates EC50 Daphnia: 20.3 mg/L (48 hr [QSAR])
Aquatic Plants EC50 Green algae: <1 mg/L (72 hr [QSAR])
Phenoxyethyl methacrylate Fish LC50 Leuciscus idus: 10 mg/L (96 hr)
Aquatic Invertebrates EC50 Daphnia magna: 1.21 mg/L (48 hr [read-
across])
Aquatic Plants EC50 Desmodesmus subspicatus: 4.4 mg/L (72 hr [growth
rate])
Chronic (long-term) toxicity
Assessment:
Toxic to aquatic life with long lasting effects.
Product data: No data available.
Substance data:
Name Result
Urethane dimethacrylate Aquatic Plants NOEC Desmodesmus subspicatus: 0.21 mg/L (72 hr)
Phenoxyethyl methacrylate Aquatic Invertebrates EC10 Daphnia magna: 1 mg/L (21 d [read-across])
12.2 Persistence and degradability
Product data: No data available.
Substance data:
Name Result
Phenyl bis(2,4,6- This substance is not readily biodegradable. No degradation was
trimethylbenzoyl)-phosphine observed during 28 day test period.
oxide
Urethane dimethacrylate The substance is not readily biodegradable (22% degradation in 28
days).
Phenoxyethyl methacrylate The substance is not readily biodegradable. 22.3% degradation in water,
measured by O2 consumption, after 28 days.
12.3 Bioaccumulative potential
Product data: No data available.
Substance data:
Name Result
Phenyl bis(2,4,6- Bioaccumulation is not expected. BCF (aquatic species): 5 dimensionless
trimethylbenzoyl)-phosphine
oxide
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
Initial preparation date: 03.03.2023 Page 13 of 16
BioMed Durable Resin

Name Result
Phenoxyethyl methacrylate The substance has a low potential for bioaccumulation based on a log
Kow of <3.
12.4 Mobility in soil
Product data: No data available.
Substance data:
Name Result
Phenyl bis(2,4,6- Based upon the log Koc of 3.85 an adsorption to the soil is expected.
trimethylbenzoyl)-phosphine
oxide
Urethane dimethacrylate The substance has moderate potential to adsorb to organic soil and
sediment particles (log Koc: 3.66 dimensionless).
Phenoxyethyl methacrylate The substance is moderately mobile in soil with a moderate potential for
adsorption to soil and sediment. Calculated Koc: 432 L/kg
12.5 Results of PBT and vPvB assessment
Product data:
PBT assessment: This product does not contain any substances that are assessed to be a PBT.
vPvB assessment: This product does not contain any substances that are assessed to be a vPvB.
Substance data:
PBT assessment:
Phenyl bis(2,4,6- This substance is not PBT.
trimethylbenzoyl)-phosphine
oxide
Urethane dimethacrylate This substance is not PBT.
Phenoxyethyl methacrylate Substance is not PBT.
vPvB assessment:
Phenyl bis(2,4,6- This substance is not vPvB.
trimethylbenzoyl)-phosphine
oxide
Urethane dimethacrylate This substance is not vPvB.
Phenoxyethyl methacrylate Substance is not vPvB.
12.6 Endocrine disrupting properties
Substance data: No data available.
12.7 Other adverse effects: No data available.
12.8 Hazard to the ozone layer
Assessment: Based on available data, the classification criteria are not met.
Product data: No data available.
Substance data: No data available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

13.1.1 Product / Packaging disposal:
Dispose contaminated packages in a safe manner in accordance with local and national
regulations. Do not allow the product to be released into the environment.
Waste codes / waste designations according to LoW: Not determined or not available.
13.1.2 Waste treatment-relevant information: Not determined or not available.
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
Initial preparation date: 03.03.2023 Page 14 of 16
BioMed Durable Resin

13.1.3 Sewage disposal-relevant information: Not determined or not available.

13.1.4 Other disposal recommendations:
Do not discharge into public wastewater or surface waters. It is the responsibility of the waste
generator to properly characterize all waste materials according to applicable regulatory entities.

SECTION 14: Transport information

International Carriage of Dangerous Goods by Road/Rail (ADR/RID)

UN number or ID number UN 3082
UN proper shipping name Environmentally hazardous liquid, N.O.S. Urethane
dimethacrylate
UN transport hazard class(es) 9

Packing group III

Environmental hazards Marine Pollutant
Special precautions for user None
Additional Information This product is not regulated as a dangerous good when
transported in sizes of <5L provided the packaging meets the
general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.

International Carriage of Dangerous Goods by Inland Waterways (ADN)

UN number or ID number UN 3082
UN proper shipping name Environmentally hazardous liquid, N.O.S. Urethane
dimethacrylate
UN transport hazard class(es) 9

Packing group III

Environmental hazards Marine Pollutant
Special precautions for user None
Additional Information This product is not regulated as a dangerous good when
transported in sizes of <5L provided the packaging meets the
general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.

International Maritime Dangerous Goods (IMDG)

UN number or ID number UN 3082
UN proper shipping name Environmentally hazardous liquid, N.O.S. Urethane
dimethacrylate
UN transport hazard class(es) 9

Packing group III

Environmental hazards Marine Pollutant
Special precautions for user None
Additional Information This product is not regulated as a dangerous good when
transported in sizes of <5L provided the packaging meets the
general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
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BioMed Durable Resin

International Air Transport Association Dangerous Goods Regulations (IATA-DGR)

UN number or ID number UN 3082
UN proper shipping name Environmentally hazardous liquid, N.O.S. Urethane
dimethacrylate
UN transport hazard class(es) 9

Packing group III

Environmental hazards Marine Pollutant
Special precautions for user None
Additional Information This product is not regulated as a dangerous good when
transported in sizes of ≤5L provided the packaging meet the
general provisions of 5.0.2.4.1, 5.0.2.6.1 and 5.0.2.8.

Maritime Transport in Bulk according to IMO Instruments

Bulk Name None
Ship type None
Pollution category None
IMO hazard class None
Environmental hazards None
Material hazardous only in bulk None
Cargo Group None

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture.
European regulations
Inventory listing (EINECS):
162881-26-7 Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide Not
Listed
162881-26-7 Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide Not
Listed
72869-86-4 Urethane dimethacrylate Listed
25852-47-5 PEG dimethacrylate Not
Listed
10595-06-9 Phenoxyethyl methacrylate Listed
REACH SVHC candidate list: None of the ingredients are listed.
REACH SVHC Authorizations: None of the ingredients are listed.
REACH Restriction: None of the ingredients are listed.
Water hazard class (WGK) (Product): Not determined.
Water hazard class (WGK) (Substance):
Ingredient Name CAS Class
Phenyl bis(2,4,6- 162881-26-7 Water hazard class 1: slightly hazardous to water
trimethylbenzoyl)-
phosphine oxide
Urethane dimethacrylate 72869-86-4 Water hazard class 1: slightly hazardous to water
 Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP), as amended by Commission Regulation (EU) 2019/521 and
Commission Delegated Regulation (EU) 2020/217, and (EC) No. 1907/2006 (REACH), as amended by Commission
Regulation (EU) 2020/878.
Initial preparation date: 03.03.2023 Page 16 of 16
BioMed Durable Resin

Ingredient Name CAS Class

PEG dimethacrylate 25852-47-5 Water hazard class 1: slightly hazardous to water
Phenoxyethyl methacrylate 10595-06-9 Water hazard class 2: obviously hazardous to water
Other regulations
Germany TA Luft: None of the ingredients are listed.
Additional information: Not determined.
15.2 Chemical Safety Assessment
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

SECTION 16: Other information

Abbreviations and Acronyms: None

Classification procedure:
Classification according to Regulation (EC) No. 1272/2008 (CLP) Method Used
Eye Irritation, category 2 Calculation method
Skin sensitization, category 1 Calculation method
Specific target organ toxicity - single exposure, category 3, Calculation method
respiratory tract irritation
Chronic aquatic hazard, category 2 Calculation method
Summary of classification(s) in section 3:
Skin Sens. 1 Skin sensitization, category 1
Aquatic Chronic 2 Chronic aquatic hazard, category 2
Skin Irrit. 2 Skin irritation, category 2
Eye Irrit. 2 Eye Irritation, category 2
STOT SE 3 (RI) Specific target organ toxicity - single exposure, category 3, respiratory
tract irritation
Skin Sens. 1A Skin sensitization, category 1A
Aquatic Chronic 4 Chronic aquatic hazard, category 4
Summary of hazard statements in section 3:
H317 May cause an allergic skin reaction
H411 Toxic to aquatic life with long lasting effects
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H413 May cause long lasting harmful effects to aquatic life
Disclaimer:
This product has been classified in accordance with EC No. 1272/2008 (CLP), as amended by Commission
Regulation (EU) 2019/521 and Commission Delegated Regulation (EU) 2020/217, and EC No. 1907/2006
(REACH), as amended by Commission Regulation (EU) 2020/878. The information provided in this SDS is
correct, to the best of our knowledge, based on information available. The information given is designed
only as a guidance for safe handling, use, storage, transportation, and disposal and is not to be
considered a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials, unless
specified in the text. The responsibility to provide a safe workplace remains with the user.
Initial preparation date: 03.03.2023
Revision date:
End of Safety Data Sheet