ompound
campo common ' aH
Cyr OW CH CHE eth methyl ether onethory ethane
(7 isa — :
|e Om CH | meine isopropyl siren r ete
| L Perisonnt Dernettouy pyopane
| —
EHO - c " male “piers
low tT .
= Alky group piste be unhindyecl -
From nr _-Alleg? Tecticles
RX + AGO Los R-oH
Crvistue) J
AYG2© €v¥) p-o-R
Colirainate Ag x) ryt Wiamson Ayrrtheris }
DS vsed to “prepare beth Simple and mixed
ethers.
[=> Dt. gfellows, _SN” mechanten,
(e- =x" ——~—37]
pe + Naor’ —s p-o-p!
ve
but rot 3”,
S Gbyso pay
Ona on CH, cu
‘ 2? byl EM
ei CHy- CH-0-G)
cared ce y arty
@ Sco + Nao c, i —» cod, SH0-Ge
Dona + Ciel mes oc
1S HoNa + GM ef —s Ca 0 HO
Roe ee sos
~ a oy Cheha Nad —C- Ui
A AB > CcHs),C-0+ cre ele La
a 4 Cal As a He
A nal tralile - LOM veacti
pie nao rete CH -O-CU CH = CH, ————
cio cha cH ohm sy CH =cu o> CH
2 se }
3
> & HCH 6 ~cH,
-0O .
Hedy amt prepend
: to 1s gn coPr liar So
C,H O- CH= CH Sy ntterrs
* pi phenge- Divingl,
Cop, ¢-0-c CCH), phenyl, vinyl
3 prtonbiery , — x)
cn oS
5s "3?
alleye hetede
(Heres. ?f ae :
. Tk leads te obeminati or
on bot& nucleophile
HERON 3. alkoxide Week
7 oy ‘eet | O% SLO
poy exome\e — -
= SNL cH te
: pao L2H > ‘S 2 th |
cn, CHA ROS Ty Ls Cts
Fr 4
eMe og + Nao Cott SRy cH WnHOnG He
cH, oH St 2. z Cus:
* bats Cus c= CH
QV Nah
Ec; HLOH- Phystak properties of ethers ;
Sp
ee
Ang wlan j
=D Highat depole ponent ~Ho -wm H,e ~ogeln,
=> Ren Penan bat polan:
=S laghtey ethers ane Soluble fh water cee te
hay - form Intermoleculan hydiegen bond
wth water. ; :
RN
O-~- ~
Dott =O Hd
P
© Rp of ether ts] x
> ao Soluble. of Aw ' PR
\ h-Burtylaleshol — Erxtory e Hone.
ag|iomt — sg |rooml-
per dPh -
Buryl alcohol peteglewir Pentene
Bp o> B40} SOK Boqk+
sropeMgeerd ft -
cHEmiCcAL PreEe”
2 @® clemage of cC— oO bord -
algdvetoprs CBE th sod)
” p of ee Wwe Root + ROH — x
nel, cH, ot +O
CHO — Oo
p Roacfion orth HX [UT/HerT
Ro ope ‘Sy ee Rot RT
ae s+R eee PPT © HO.
5 3
Ughye 3) cagt > boar %
Ex da a cH, I
wm Cth, - 0 +
cH, 8 $5 aS 2 cot
®m . cert ots
S vr chow ete Ee
© cat, Fon CHL CH, >
ee ou
Gor Na OO ge eS Bish
® wees :
wey Baciu e cer
i) vs exer of #7 by etre
Phamecdn
: ai
sts
i
&
caste
“Sy
oy : aan
av or on fe
spy BESO z.
Tee
S ye et ae
a “tt a3 SH CuSER
— 8. gr =
C0. 2 a tHe
GB 0 — Ce He
Count e- wuetenD,. _
@F @ @
lf
Lv
x wi tL
Lo >-0- CH = cH, > %
i _ aw
a>-0-<=y 5s
one of the elte grouP is 3°
tL folfocos Sat! miechants ry,
SH as -
ati Ce me —2'D= on,
5 8
me da,
i ze ay
r CoBsye Et 04 <— ATC + CHO
ct 1 [
3
i] ® EiIe ony UD always SNO
oe Dorerpectve of size of— alkyl gooup.
CHS wT
CH—o-¢ CH, Sut G5), c-2 aa coe
dn eee.
3 jobs eat
s (etre o-ca, “2s © +O
os
Mad-c—cH,, \e
awe stg activatin
3 gee J
4M FOWLY (CF Powey) ~ OT SOL S-—oP
afriscle fs (ew yonctive an phenol ~ouorels
electrophiltc cab. 9WAct oy,
clue +0 :
TM Power omy —oR -
kh oct Gtr:
hel ne So i él A ey
A
ee
ocH ‘alt
wR tratio 5
ens [Terre
oc#. nc 4, Ccts Oe.
3 @ BSOy Ss core the Compound
howe (Sczo) os Fqrur
> Coabonyl Compourels.
O°
we) —é-4 pent C50 | OFS weeny
eae SS Aotkisfied by two
sala pee ego
° Aldehyde -
oe it _g 5 St CRO Greer yoke og
een Kalishred by Hoo alksl greure.
prdehydes ond keto ave. commonly >
own o>, Coybon yo compounds -
ul a a tt
L
O HH ey vw
g : cox. -coNY, — 2 —orR
conboryfit oxce Acyl hotides, Arvid & Bee
q 9 hia Tone ok
_ f-o- ¢—c4; coaborngl compares’ *
aynhagsdtid &
5 pidehgdes ancl fetus
wwe wsrdely Spread fe Uns ;
Pee vere ” amp wele an (pur Brochescal
fife +
S They.
dee noburec
CHO : pboine’d fro enila Be
> opts mn Vv
:
r OC Hf ‘
Vaniine
nonc es -
into
add Flevours ond 7g CH=CH —CHO
commamaldehy de Ccinnea prone)
OH
cor’ ° :
j 7 C0
Sabreytie olsehase * E _foallowent
Cmeadoer isiw0ek) + oct ay
on
Nomenclature of Garbony® Compounds
Comment name.
tenor” CH HCHO cue
| formaldehyde acetnldahste OC siatdalgle.
CHO
’ a
“V7 tno ae qe}
CAO, ‘ y
Epratdengde B CHO
di
DSS twcn | Fo Bromo velanstdohyde . qty Berraatdehyae
\ 7 .
ma = cy = < ZZ no T &
cue, HCH Ch — CHO . I= CH CHO
> chyotonatach la “Ae yolemn tr bon 8
x os G "TPS cg
crt, —cu GR cw a CHS eA .
. pcetone
tone
pi is rope He ” attheg Rrettgl ketone, combo
- a : “Hy QQ
CHO
Ge
we V5 —é-CH, ‘oS CHO ter“
CRS 6 ,
Lorde y ire hakdehy de - Acetopheroh_
merits)
at
propicphawna, B enzophonane— ean
tdehyde cH
a at. aldehyde « CeHo) presemt on PENG how
v word Corbaldehyde,” fs added. -to
ketones exh®bPe ~eT , FL, mm, pr, GT _
ee aed le ey cia CHa Stas cH,
ee cHo
er
in Canbonyf Com pound |
Tm, GI
; vt
EK CHL-c oe ct = cH —-oH
——~—— >
2 —Pentanone Fra Loamonr- mM SPL
Ex Glucose Fructose
Ce An Hi Me
foe
FL -
5 ° 12
EX * a ac
! = CH—c —H a ee
6 7 Was? :
hot tTAoress -
ex: Teme. ter" °
cHo' ¥ a
=, - cHO
I}
Byer eek . 2
“\"“\ AN 2-pentonone -
oO . a
7 } -—“cze
e Cehs *
qrapowetton tp
po toner ! i
method s
@ oxidation of
* alcohol “RES.
2° alcohol —PS 4
2° alcohol Pee
LV
cao
—-ot Pee
pehydowation
LP alcohol
Q° alohol
3° alcohol
—f-ou s A
D Reductive ozonolysis
Prom .tHydyocarkens I-
pee
S x
culAa
aula
Corl
ae
CHO CGeohubsiok
>
oy aekels
CAorteRz S72)
of beth aldehyolers and
_abcoho Is +
aldehyde
ketone
om:
Ceula , gla).
Se ss aldehyde
Iketone
XS alkenes
of tydrocanbors ;-
Ss Allanek Yeacts uty, the ozone and -fellowed by
hydvolyst gs IM the
fem Gonvongh
prerente
com pounds .
of zn to 2 HO
3 ts 8G
AST? po . cpo- G yorak »
Szlzn 5 fad
ok oR _ 3 2cHO t
3 xylene ape A 28 +, CH U—cHo
; cHo ?
rare . , :
eer)
3 ca,-€ aa oH, e
2 a 7 :
;
cH
Rotvo °
Cit ytCth, INCH CH, oe ste Ho + Cil,~CH ,~ CHO
rhs emf
_ NS Cth CHe it
Gl cH = a eevee
cH, aa °
& Gita ./ > AC a recto
CH, cH, — § = cH Ct Ss AN it
cH, a
SKK Bydrotion of Arges [kucherare
BOLN Sy Pew, = cH 0 |
I AHqSOy ,
: . Foutonenes}o7
N swacken|
* cHECu
HK Choc cy Sth Oy g
Agae av
*K Chic
co ScHcH, wil tbseoy
, Se A
g
A CHL cH, Ce cn cH, dol Ha5y AX Rai
“FgEP. A\A\
Crmodor) &
C4 a.)
KK Coyss c- cH, q |
Hy
Lilthsey | (oy Bre
: Hg t2 z
I [ecb CHa-SH a ctt= cH Crnaior’
ch nen CES a “cot a
ane, SS Osis | O
Ht DL H, Soy on
cae by
C2 ; '
—— QO CHy— CHO »
cued
eu een esti:
Preporatton methods for only fatdeheyder
oe corals
—D Rosenmond vyeductPon
_ © 5
SD hk ca, PartasoulGuelg? By
Tot end ex's Catalyys:
Acca chlovide - = aldehyde .
as Story
J
Gerwro ly ore ameteabs — act
*% Used Yo Prepare only Aldehyde -
Excepion: plo Fo Not PreRRIed by
Was method
°
who dHcl ts nrghly wnustable -
Forrnyl chlorPda- ~
°
ss PA ~ Base
CH eck FAT BeP Ca, CHO
qed
Ge t_cock Rdle . cH CHO.
@® Fromr eter + So
u DiBAl-y
CH cfo = cH, ae CH-CH Ot CHLOH
Lend Hy cn cH + CHOW
Ho > 3 {
CON.
@ From Nrivtle, ECan
* Popp Pipa —cH0.
# cicn PIBALHS ct,cHO
Ueatialees cays CH NAS
(2 sg0F CHW CoOH
Crabetps of — en 2s octal) +
» yeacktor *
@ Stephen. anak _ eno
Fenc han i! Se CH, gre pi\dekyde -
—C=n — imine "b
_ Foltowe
go, chat _oufdattor Lo! DY
@ By we
adydoolyets
* Etoaxd yeaction ‘Cctlvemn chlovede reaction].
3) “gH Cocrouchs), CHO
a 3 Cro, ch, wel
ra j
: non — oxédl?sable /
Cr —Complex D Bicterpeddote
2
Brmed—
CHO
cH
— > cra,cd, [CSE
who!
No, MO,
| 