Introduction to
Carbohydrates
• Carbohydrates are the most important source of energy.
• They contain the element of carbon, hydrogen and oxygen.
• The very first part of the name carbo means that they
contain carbon.
• The second part hydr suggests that they contain hydrogen.
• The third part of the name ate means that they contain
oxygen.
• It’s general formula is Cn(H2O)n.
• The hydrogen and oxygen are in the ratio 2:1.
CLASSIFICATION
1.Simple carbohydrates 2.Complex Carbohydrates
•Monosaccharides •Polysaccharides
•Disaccharides
•Oligosaccharides
Monosaccharides
Single sugar unit which cannot be hydrolyzed
further as they are the simplest form.
They maybe further classified depending on the
number of carbon atoms.
Glucose is an example of monosaccharides.
Triose (C3H6O3)
Tetrose (C4H6O4)
Disaccharides
Two monosaccharides combine to form a disaccharide.
The two are joint by a glycoside bond.
Disaccharides are of two types:-
Reducing sugar Non-reducing sugar
These two sugars are joint These are joint by alpha, beta,
together by beta-1,4 glycosidic glycosidic linkage.
bond.
Lactose = Glucose+ galactose
Sucrose= Glucose+ Fructose
Maltose = Glucose+ Glucose
it is joined together by alpha-1,4
glycosidic bond
Oligosaccharides
Carbohydrates formed by the condensation of 3-10 monomers are called oligosaccharides.
Examples:- Raffinose, stachyose, rhamnose
Polysaccharides
Polysaccharides are complex carbohydrates formed by the
polymerization of a large number of monomers.
1. Homopolysaccharides:- Same sugar unit.
Example;
• Starch (amylose + amylopectin)
• Glycogen (animal starch)
• Insulin (polymer of fructose)
• Chitin (found in exoskeleton of insects)
2. Hetropolysaccharides :- Different sugar unit.
Examples;
• Agar
• Heparin (in blood as anticoagulant)
NOMENCLATURE
The generic nomenclature of carbohydrates ends with ‘-ose’ thus the term
pentose is used for compund having chemical formula C5 H10 O5
Carbohydrates have two functional groups: an aldehyde or a ketone and an
alcohol.
We will specify this by adding keto or aldo in the prefix of carbohydrate
names.