cARGUS Material Safety Data Sheet PROPHYLAXIS PASTE Page 1 of 6 ed ee Product Name: MARK3 Prophylaxis Paste Manufactured For: Cargus International Inc, Active Ingredient: Sodium Fluoride Cae rete Family: Prophylaxis Paste Product Use: Professional Dental Polishing Paste Product #: Various Section 2 — Hazards Identi EMERGENCY OVERVIEW Will eause eye irritation. May cause skin iritation, Prolong exposure may cause respiratory system irritation, Ingestion of large amounts may cause nausea, vomiting, headaches, or dizziness. Please read entire MSDS for additional information Potential Health Effects, Signs and Symptoms of Expost Primary Route of Entry Inhalation, skin, and ingestion. et Eye Vapors are irritating to the eyes. Splashes may cause redness of the eye. Repeated/prolonged contact may cause mild irritation of the skin, Symptoms include redness, burning, ae or itching ‘Swallowing small amounts during normal handling is not likely to cause harmful effects; swallowing Ingestion large amounts may be harmful. Symptoms include irritation of the throat, nausea, dizziness, and upset stomach, ee 2 fine smal parle are inhaled tion ofthe hoa with fing of ighinesin the best may NOTE: Refer to Section 11, Toxicological Information for Details om Chemical entity CAS, EINECSHINCIName Exposure OSHA Limits ACGIH Carcinogen > a a) Seas Gel Sears 20033 eerie win) mS Notled 2030 Sodium Fite 768-94 23-6018 Sedimuoie—ypan/Gqym_——«2.Smn/a3 ‘Nath 28 (items in parenthesis relate to 1999/45/EC) Revision A, Date of Issue: 10/17/2013cARGUS Material Safety Data Sheet PROPHYLAXIS PASTE Page 2 of 6 Meee ne Fitst Aid for Eye Flush with water for 15 minutes, including under eyelids, Get medical help if discomfort persists ‘Wash thoroughly with soap and water. Remove contaminated clothing. Get medical help if discomfort persists. greater than normal dose is swallowed, do not induce vomiting. Drink large quantity of water or milk. Seek medical attention. Move to fresh air. If having breathing difficulty persists. First Aid for Skin First Aid for Ingestion ive oxygen. Seek medical attention if discomfort Section Sriraen Flash Point CFPC) Flammable Limit (vol ‘Auto-ignition Temperature (vol%) NA NA NA [Met | Estinguishing Medi: Suitable extinguishing media for the surrounding fre shouldbe used, During a ft, iitating or highly txie gases may be generated by thermal decomposition. If potential Fire Fighting for exposure, wear complete personal protective equipment including self contained breathing Instructions: apparatus, with full face operated in pressure demand. Fight fire froma safe distance/protected location, ‘Unusual Hazards: Evacuate all personnel Mee Minor spills ~ Clean up immediately, avoid contact with skin and eyes. Mop area and clean with soapy water Spill or Release Major spills —Clear area of personnel. Restrict acess to area. Avoid contact with skin and eyes, and mop / sque Procedures with soapy water. Collet contaminated watcr and dispose of properly See section 8 & section 12. Handling Limit all unnecessary personal contact. Avoid breathing dust / vapors. Wear appropriate PPE. Store in a cool, well ventilated area away from heat, sparks and flame. Keep containers closed when not in use, Keep in original container provided by manufacturer. Explosion Havard None Storage 2a (aTear nearer Engineering cna General exhaust is adequate under normal operating conditions. To identify additional Personal Protective Equipment (PPE) requirements, it is recommended that a hhazard assessment in accordance with the OSHA PPE Standard (29CFR1910.132), or European Standard EN166 be conducted before using this product. Eye/Face Safty slases goggles o splash shield are required when handling. Ensre eye bath son hand No special equipment for minor exposure (., when handling small quantities) but i recommended to se Skin Potton inpemeable clang to prevent ANY contact with this prod, sch as gloves, pron, bos, or whole Dody su Respiratory sentation. w Kespirtory fs case of inficien ventilation, wear sable respiratory equipment Revision A, Date of Issue: 10/17/2013cARGUS | Safety Data Sheet PROPHYLAXIS PASTE Page 3 of 6 Section 9 — Physical and Chemical Properties “Appearance ‘Odor & Odor Threshold |__| Specie Gravity | Viscosity % Volatile Colored paste Odor ofSiaed Favor | 68 | G20=1-WA NA NA ‘Octanol/ Water Solubility Decomposition Vapor | Vapor | Evaporation Partitioning Coefficient ; a Tgnition | Tn Water ‘Temperature Honing Co Pressure: | Denst Rate pi NA NDA NDA, NA NA NA NA NA Flash Point CFPC) Flammable Limit (vol%) ition Temperature (v0l%) NA NA NA Section 10— Stability and Reactivity Stability Incompatibility (Materials to Avoid): Stable Strong Acids Hazardous Decomposition Products: Hazardous Polymerizat Toxic Fumes (HF) Will not occur Conditions to Avoid: Heat and incompatible materials Acute Oral Toxicity | Acute Dermal Toxicity | Acute Inhalation Toxieity | __ Irritation ~ skin Irritation - Eye NDA NDA NDA NDA NIDA “Mutagenicity NDA [nnn Ecotoxicological Information ‘Acute Toxicity to j Toxicity Bae Acute Toxicity to Invertebrates | Acute Toxicity to Algae | Bioconcentration | to teria NDA NIDA NIDA NDA NDA Chemical Fate Information Biodegradability Biodegradable. This material is not expected o significantly bioaccumulate ‘Chemical Oxygen Demand _| N/DA Section 13 — Disposal Considerations Dispose of in compliance with governmental regulation (state and federal). Dispose of container and unused contents in accordance with federal, state and local requirements. For EU Member States, please refer to any relevant Community provisions relating to waste, In th regional provisions may be in force sence, its useful to ind the user that national or Section 14 — Transport Information DOT (49 CFR 172) Proper Shipping Name Non-regulated material Revision A, Date of Issue: 10/17/2013cARGUS Material Safety Data Sheet PROPHYLAXIS PASTE Page 4 of 6 Tentfcation Number: NA Marin Potent No Special Provisions NA “Emergency Response Guidebook (ERG) # | NA IATA (DGR): Non-regulated mater Proper Shipping Name NA {Chass oF Division: NA UN or ID Number: NA Packaging Instructions NA ‘Emergency Response Guidance (ICAO)#: IMO dMDG): Proper Shipping Name: ‘Non-egulated material {Chass of Division: NA. UN oF ID Number: NA ‘Special Provisions & SiowagelSewrevation: | NIA ‘Emergency Schedule (EmS)#: NA Othe NA. US Federal Regulations (Clean Air Act: HAP/ODS This product contains the following HAP’s or ODS: © NONE, Clean Water Act: Priority Polfutant "This produet contains the following chemicals listed under the U, S. Clean Water Act Priority Pollutant and Hazardous Substance List: © None FDA: Food Packaging Status ‘This product has not been cleared by the FDA for use in food packaging and / or other applications as an indirect food-packaging additive This product is considered to be hazardous under the OSHA Hazard Communication Standard. Occupational Safety and Health | Jy Proeyet S Act © None This product coniains the following chemicals considered to be hazardous waste under RCRA RCRA (40 CFR 261). © None SARA Title IIT: Section 302 (RQ) This product contains no chemicals regulated under Section 302 as extremely hazardous substances, SARA Title III: Seetion 302 (TPQ) This product contains chemicals regulated under Section 304 as extremely hazardous ‘chemicals for emergency release notification (*CERCLA” List): ‘¢ Sodium Fluoride ~ CAS #7681-49-4 1000 #RQ ‘SARA Title IML: Section 311-312 ‘This product is considered to be hazardous under the OSHA Hazard Communication Standard and is regulated under Section 311-312 (40 CER 370). t's hazards ae: ‘© Sodium Fluoride ~ CAS# 7681-49-4 (Corrosive) SARA Title II: Section 313 ‘This product coniains the following chemicals which are subject to the reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: © None TSCA Section 8(b): Inventory: ‘TSCA Significant New Use Rule “This produet docs contain chemicals listed on the TSCA inventory or otherwise complies with ‘TSCA pre-manufacture notification requiremen ‘© Sodium Fluoride ~ CASI 7681-19-4 ‘None of the chemicals in this material have a SNUR under TSCA. Revision A, Date of Issue: 10/17/2013cAaRcus Material Safety Data Sheet PROPHYLAXIS PASTE Page 5 of 6 ‘State Regulations CA Right-to-Know Law: California No Significant Risk Rule: MA Right-to-Know Law: Sodium Fluoride ~ CAS# 7681-89-4 ‘None ‘Sodium Fluoride ~ CASP 7681-404 Glycerol — CAS # 56-81-58 NJ Right-to-Know Law. Sasium Fuse CASH TTT ‘Sodium Fluoride ~ CAS? 768-04 PA Right-to-Know Law eect FL Right-to-Know Law: ‘Sodium Fluoride ~ CAS# 7681-89-4 ‘Sodium Fluoride ~ CAS? 7681-494 Glycerol — CAS # 56-81-5 MN Right-to-Know Law: Sovium Fluoride — CAS? 7681-194 (on Canadian Transitional List) _| Glycerol - CAS # 56.815 Labeling according to EC directives — 1272/2008 {CLP} AND 1999/45/EC (items in parenthesis relate to 1999/45/EC) European Community For QartzProphy Past Inished product DANGER SYMBOLS: GHSO7 (Xi) ~ Warning | Irritant ‘© Hazan STATEMENT: H316 (N/A), Causes mild skin irritation. H319 (R36), Causes serious eye irvitation H33S (R37), May cause respiratory irritation. H303 (N/A), May bbe harmful if swallowed. © PRECAUTIONARY STATEMENT: P102 (S2), Keep out of reach of children, P261 (S24), Avoid breathing dust/fume/gas mist'vapor sprays. P280 ($36/37/39), Wear protective glovesiclothing/eye protection/face protection. P309+314 (S45), If exposed of you feel unwell, get medical advice/attention. Section 16— Other Information EU Classes and Risk / Safety Phrases for Referenced Ingredients (See Section 2): sms in parenthesis relate to 1999/45/EC) Danger Symbols: GHS06 (1) Toxie (GHSO7 (Xi) — Waring /Ivitants ‘Hazard Statement:H301 (R25), Toxi ifswallowed. H31S (R38), Causes skin vtaton. 1316 (N/A) Causes mild skin irritation. 11319 (R36), (Causes serious eye initation. H33S (R37), May cause respiratory itrtation. H336 (R67), May cause drowsiness or dizziness. EUHO32 (R32), Contact with seid liberates very toxic gas. H303 (N/A), May be harmful if swallowed Precautionary Statement: P102 (S2), Keep out ofreach of children. P260 ($23), Do not breathe dustfume/gas/mistvapors/spray. P261 (S24), Avoid breathing ‘+— Reactivity Revision A, Date of Issue: 10/17/2013cARGUS Material Safety Data Sheet PROPHYLAXIS PASTE Page 6 of 6 Prepared By: Gavin Gaba Revision History 10/17/2013. Revision A, Initial Issue ‘The information presented herein was obtained from sources considered to be reliable, However, this information is provided without any warranty, expressed or implied, regarding its correctness or suitability for consumers intended use and/or application. For this and other reasons, we assume no responsibility and expressly disclaim liability for loss, damage or expense arising out of any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared expressly for this product. Use the ‘materials only as directed. If the product is used as a component of another product, the information contained within the MSDS may not be applicable, Cargus. components are provided on an as is basis without warranties of any kind either expressed or implied. Cargus does not ‘warrant the use or the results of use of the materials sold on an as is basis since they are intended for remanufacturing or repackaging. Its the sole responsibility of the user to examine and determine appropriate application and regulatory requirements associated with said Cargus components. Revision A, Date of Issue: 10/17/2013