Revision: 4.0 Revision date: 04.03.

2019
Supersedes date: 12.11.2010

SAFETY DATA SHEET

AKPEROX A60
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name AKPEROX A60
Chemical name Methyl Ethyl Ketone Peroxide
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Industrial use.
Uses advised against No specific uses advised against are identified.

1.3. Details of the supplier of the safety data sheet

Supplier AKPA KİMYA AMBALAJ SANAYİ VE TİCARET ANONİM ŞİRKETİ
Yenibosna Merkez Mah. Ladin Sok.
No:36/70 Kat:12 34197 Townofis Bahçelievler, İstanbul, TÜRKİYE
Web: www.akpakimya.com
TEL: +90 212 580 55 59
FAX: +90 212 580 55 21
E-mail: info@akpakimya.com
Contact person Export Department - export@akpakimya.com
1.4. Emergency telephone number
Emergency telephone AKPA Kimya : +90 212 580 55 59
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Org. Perox. D - H242
Health hazards Acute Tox. 4 - H302 Skin Corr. 1B - H314 Eye Dam. 1 - H318
Environmental hazards Not Classified

2.2. Label elements

Pictogram

Signal Word Danger

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AKPEROX A60
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

Hazard statements H242 Heating may cause a fire.

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.

Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. Nosmoking.
P220 Keep away from amine and cobalt accelerators, acids, alkalis and
heavy metalcompounds, combustible materials.
P234 Keep only in original container
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you
feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P411+P235 Store at temperatures not exceeding (5) – (30)°C. Keep cool.
P501 Dispose of contents/container in accordance with national
regulations.

Commission Regulation (EU) No 2015/830 of 28 May 2015.

Contains Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-2,2-diyl
dihydroperoxide

2.3. Other hazards

This substance is not classified as PBT or vPvB according to current EU criteria.
SECTION 3: Composition/information on ingredients
3.2. Mixtures

Dimethyl Phthalate %30-60

CAS Number 131-11-3 EC Number 205-011-6
Sınıflandırma T.C. 28848
Not Classified.

Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide %30-60

REACH Reg. No: 01-2119514691-43-0007
CAS Number 1338-23-4 EC Number 700-954-4
Classification
Org. Perox. D H242
Acute Tox. 4 H302
Acute Tox. 4 H332
Skin Corr. 1B H314
Eye Dam. 1 H318

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SAFETY DATA SHEET

AKPEROX A60
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

BUTANONE %1-5

CAS Number 78-93-3 EC Number 201-159-0

Classification
Flam. Liq. 2 H225
EUH066
Eye Irrit. 2 H319
STOT SE 3 H336
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
SECTION 4: First aid measures

4.1. Description of first aid measures

General information Effects may be delayed. Keep affected person under observation. Chemical burns
must be treated by a physician.

Inhalation Remove affected person from source of contamination. Keep affected person warm
and at rest. Get medical attention immediately.

Ingestion Rinse mouth thoroughly with water. DO NOT induce vomiting. Get medical
attention immediately.

Skin contact Remove affected person from source of contamination. Immediately remove
contaminated clothing. Wash skin thoroughly with soap and water. Get medical
attention promptly if symptoms occur after washing.

Eye contact Remove affected person from source of contamination. Remove any contact lenses
and open eyelids wide apart. Continue to rinse for at least 15 minutes. Get medical
attention immediately. Continue to rinse.

Protection of first aiders First aid personnel should wear appropriate protective equipment during any
rescue. Wash contaminated clothing thoroughly with water before removing it
from the affected person, or wear gloves. It may be dangerous for first aid
personnel to carry out mouth-to-mouth resuscitation.

4.2. Most important symptoms and effects, both acute and delayed

General information Move out of dangerous ares. Show this Safety data sheet to the doktor in
attendance. Do not leave the victim unattended. Symptoms of poisoning may
appear several hours later. Call a physician immediately.

Inhalation Nausea, vomiting. Dizziness.

Ingestion May cause stomach pain or vomiting. Chemical burns.

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AKPEROX A60
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

Skin contact May cause serious chemical burns to the skin.

Eye contact May cause severe eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed

Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
Media

5.2. Special hazards arising from the substance or mixture

Specific hazards Protection against nuisance dust must be used when the airborne concentration
exceeds 10 mg/m3. Vapours may form explosive mixtures with air. Forms explosive
mixtures with air. May explode when heated or when exposed to flames or sparks.
Containers can burst violently or explode when heated, due to excessive pressure
build-up.

Hazardous decomposition products

Thermal decomposition or combustion products may include the following
substances: Toxic gases or vapours.
5.3. Advice for firefighters

Protective actions during firefighting

Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate
protective clothing. Cool containers exposed to flames with water until well after
the fire is out. Fight fire from safe distance or protected location. Move containers
from fire area if it can be done without risk. Do not use water jet as an extinguisher,
as this will spread the fire. Control run-off water by containing and keeping it out
of sewers and watercourses. If risk of water pollution occurs, notify appropriate
authorities.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate
for firefighters protective clothing. Firefighter's clothing conforming to European standard EN469
(including helmets, protective boots and gloves) will provide a basic level of
protection for chemical incidents.

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SAFETY DATA SHEET

AKPEROX A60
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No
smoking, sparks, flames or other sources of ignition near spillage. Avoid inhalation
of vapours and contact with skin and eyes. Provide adequate ventilation.
6.2. Environmental precautions

Environmental precautions Avoid or minimise the creation of any environmental contamination.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Keep combustible materials away from spillage. Eliminate all sources of ignition. No
smoking, sparks, flames or other sources of ignition near spillage. Provide adequate
ventilation. Absorb in vermiculite, dry sand or earth and place into containers.
Wash thoroughly after dealing with a spillage. Do not touch or walk into spilled
material. Wear suitable protective equipment, including gloves, goggles/face
shield, respirator, boots, clothing or apron, as appropriate.

6.4. Reference to other sections

Reference to the other For personal protection, see Section 8. See Section 11 for additional information on
sections health hazards. For waste disposal, see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Keep away from heat, sparks and open flame. Avoid inhalation of vapours/spray
and contact with skin and eyes. Provide adequate ventilation. Avoid inhalation of
vapours. Use approved respirator if air contamination is above an acceptable level.
Do not handle broken packages without protective equipment.

Advice on general Eye wash facilities and emergency shower must be available when handling this
occupational hygiene product. Good personal hygiene procedures should be implemented. Wash hands
and any other contaminated areas of the body with soap and water before leaving
the work site. Good personal hygiene procedures should be implemented.
Mechanical ventilation or local exhaust ventilation may be required. Container
must be kept tightly closed when not in use.

7.2. Conditions for safe storage, including any incompatibilities

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SAFETY DATA SHEET

AKPEROX A60
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

Storage precautions Keep away from oxidising materials, heat and flames. Store in tightly-closed,
original container in a dry, cool and well-ventilated place. Avoid contact with
oxidising agents. Store away from the following materials: Acids. Alkalis. Keep away
from flammable and combustible materials.
7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

Occupational exposure limits

Dimethyl Phthalate
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³
Short-term exposure limit (15-minute): WEL 10 mg/m³

Methyl ethyl ketone peroxide

Short-term exposure limit (15-minute): WEL 0.2 ppm 1.5 mg/m³

BUTANONE
Long-term exposure limit (8-hour TWA): WEL 200 ppm(Sk) 600 mg/m3(Sk)
Short-term exposure limit (15-minute): WEL 300 ppm(Sk) 899 mg/m3(Sk)

WEL = Workplace Exposure Limit

Ingredient comments WEL = Workplace Exposure Limits

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate ventilation. Avoid inhalation of vapours. Observe any
controls occupational exposure limits for the product or ingredients.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment
indicates eye contact is possible. The following protection should be worn:
Chemical splash goggles or face shield.

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AKPEROX A60
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

Hand protection Wear protective gloves made of the following material: Neoprene. Nitrile rubber.
Rubber (natural, latex). The most suitable glove should be chosen in consultation
with the glove supplier/manufacturer, who can provide information about the
breakthrough time of the glove material.

Other skin and body Appropriate footwear and additional protective clothing complying with an
protection approved standard should be worn if a risk assessment indicates skin
contamination is possible.

Hygiene measures Provide eyewash station and safety shower. Do not smoke in work area. Wash
hands at the end of each work shift and before eating, smoking and using the toilet.
Promptly remove any clothing that becomes contaminated. Wash promptly with
soap and water if skin becomes contaminated. Use appropriate skin cream to
prevent drying of skin. When using do not eat, drink or smoke.

Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn. Check
that the respirator fits tightly and the filter is changed regularly.

Environmental exposure Residues and empty containers should be taken care of as hazardous waste
controls according to local and national provisions.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Clear liquid.

Colour Colorless.
Odour Characteristic.
Relative density 1,17±0,005 gr/cm3 @20°C
Solubility(ies) Partially soluble in water.
Flammability (solid, gas) Not applicable
Viscosity No data avaliable

9.2. Other information

Active Oxygen Content 9,9 - 10,1%

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

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AKPEROX A60
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Possibility of hazardous Not available.

reactions

10.4. Conditions to avoid

Conditions to avoid Avoid heat, flames and other sources of ignition.

10.5. Incompatible materials

Materials to avoid Strong alkalis. Strong acids. Strong reducing agents. Strong oxidising agents. Some
metals.

10.6. Hazardous decomposition products

Hazardous decomposition Oxides of carbon. Carbon monoxide (CO). Carbon dioxide (CO2). Hydrocarbons.
Products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicological information
ATE oral (mg/kg) 1,315.0

Serious eye damage/irritation: Corrosivity to eyes is assumed.

Skin corrosion/irritation: Causes burns.

Respiratory or skin sensitisation:

Respiratory sensitisation Based on available data the classification criteria are not met.

Germ cell mutagenicity:

Genotoxicity - In Vitro - In Vivo Based on available data the classification criteria are not met.

Carcinogenicity: Based on available data the classification criteria are not met.

Reproductive Toxicity: Based on available data the classification criteria are not met.

Reproductive Toxicity – Development Based on available data the classification criteria are not met.

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COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

Specific target organ toxicity - single exposure:

STOT - Single exposure Based on available data the classification criteria are not met.

Specific target organ toxicity - repeated exposure:

STOT - Repeated exposure Based on available data the classification criteria are not met.

Aspiration Hazard Based on available data the classification criteria are not met.

Inhalation Harmful by inhalation. May cause damage to mucous membranes in nose,

throat, lungs and bronchial system.

Ingestion Harmful if swallowed. May cause burns in mucous membranes, throat,

oesophagus and stomach.

Skin contact Causes burns. Harmful in contact with skin. May cause sensitisation or
allergic reactions in sensitive individuals.

Eye contact Causes burns.

Route of entry Ingestion Inhalation Skin and/or eye contact

Target organs Respiratory system, lungs

Medical considerations Skin disorders and allergies.

SECTION 12: Ecological Information

12.1. Toxicity
Ecological information on ingredients.
BUTANONE
Acute toxicity - fish LC₅₀, 96 hours: 3.22 g/l mg/l, Fish

12.2. Persistence and degradability

Persistence and degradability The product is readily biodegradable.

12.3. Bio accumulative potential

Bio accumulative potential No data available on bioaccumulation.

12.4. Mobility in soil

Mobility The product is partly miscible with water and may spread in the aquatic
environment.
12.5. Results of PBT and vPvB assessment

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AKPEROX A60
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects Not available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Waste should be treated as controlled waste. Dispose of waste to licensed waste
disposal site in accordance with the requirements of the local Waste Disposal
Authority. When handling waste, the safety precautions applying to handling of the
product should be considered.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the
requirements of the local Waste Disposal Authority. Containers should be
thoroughly emptied before disposal because of the risk of an explosion.
Environmental Manager must be informed of all majör spillages.

SECTION 14: Transport information

General information For limited quantity packaging/limited load information, consult the relevant modal
documentation using the data shown in this section.

14.1. UN number

UN No. (ADR/RID) 3105

UN No. (IMDG) 3105
UN No. (ICAO) 3105
UN No. (ADN) 3105

14.2. UN proper shipping name

Proper Shipping name ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
(ADR/RID) dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)

Proper Shipping name ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
(IMDG) dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)

Proper Shipping name ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
(ICAO) dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)

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SAFETY DATA SHEET

AKPEROX A60
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

Proper Shipping name ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
(ADN) dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)

14.3. Transport hazard class(es)

ADR/RID class 5.2

ADR/RID label 5.2
IMDG class 5.2
ICAO class/division 5.2
ADN class 5.2

Transport labels

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant
No

14.6. Special precautions for user

Always transport in closed containers that are upright and secure. Ensure that persons transporting the product
know what todo in the event of an accident or spillage.

EmS F-J, S-R

ADR transport category 2
Emergency Action Code 2WE
Hazard Identification Number -
(ADR/RID)
Tunnel restriction code (D)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport in bulk according Not Applicable.

to Annex II of MARPOL

SECTION 15: Regulatory information

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SAFETY DATA SHEET

AKPEROX A60
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations Health and Safety at Work etc. Act 1974 (as amended).
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI
2009 No. 716).
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment
Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"].
EH40/2005 Workplace exposure limits.

EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and
Restriction of Chemicals (REACH) (as amended).
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and
mixtures (as amended).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Key literature references This SDS is prepared based on the information received from the product owner.
and sources for data

Classification procedures Skin Corr. 1B - H314; Eye Dam. 1 - H318: Calculation Method. Org. Perox. D -
according to Regulation H242: Expert Judgement.
(EC) 1272/2008

Training advice Read and follow manufacturer's recommendations. Only trained personnel should
use this material.

Revision comments Added REACH Number.

Issued By Gökhan ARDIÇ / CRAD

gbf@crad.com.tr +90 216 335 46 00
Issued Date 12.11.2010
Revised By Simge ARIK
lab@akpakimya.com +90 282 361 80 99
Revision date 04.03.2019
Revision 4.0

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SAFETY DATA SHEET

AKPEROX A60
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.

Hazard statements in full H225 Highly flammable liquid and vapour.

H242 Heating may cause a fire.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
EUH066 Repeated exposure may cause skin dryness or cracking.

This information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process. Such information is, to the best of the company's
knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or
representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as
to the suitability of such information for his own particular use.

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