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The document discusses the properties and reactions of lanthanides and transition metals, focusing on their similarities and differences. It includes various chemical equations and reactions involving manganese and other elements, highlighting their behavior in different conditions. Additionally, it touches on the electronic configurations and magnetic properties of these elements.
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0% found this document useful (0 votes)
63 views20 pagesYe Le Pagal
The document discusses the properties and reactions of lanthanides and transition metals, focusing on their similarities and differences. It includes various chemical equations and reactions involving manganese and other elements, highlighting their behavior in different conditions. Additionally, it touches on the electronic configurations and magnetic properties of these elements.
Uploaded by
Dimpy NishadCopyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
/ 20
ti)
E
Simibily Arrong lonlhanaids
Benue op the very _simior peperhes 4 lonthanatals — there hemi
proPetties ane smilox.
Limpog ton} Question : bets
ake fe N*M ystem ‘Whe EB vehues fer_sime metals one a5 gallows
GO] egy GER @tt 7 e4y
Met} Cr oO 2y-Mn3t] Mn 4S
— fe fe ogy. RS J ett po BY
WR Use Inns Sab }o_cornment apc a _
he sly gy ee vh_otiel ena sol le Weg at ot
Peon
The case: with shidh itch con be. Stidiged) a5; cmporal fo 9 simihy
pieces a0 either _cauminimam _o& wroghese Mrangonase meal,
Bigher the aeluchon rae 99-9 epecies - gieler i Ihe. ake av
with 1s_ib hips wie
Among. these _phies Pn] Hot gel We deduction. poketid
Bed = Sv
| Hence, _P Pl eon le coals. mehie ae lees pine 5 frosh sieble p 9f S805 + Adenoids
~__ Abonie_no - B94 to. log)
Genetal_ Elclaonic
" -chorrie_ eli pecia_Lewthtnam
| due helium Clu) 6 tinea, Ona ute Hho (Lo) fo
_ cr Lonthano id Cocon
| "Aces | te lonhatide « “20ie5 Hhe_rucke ¢ “dhoige ‘nor He) heo_e- _
_ oe _eclled fe Ihe —Seme_innet 4¢ eubshell. Due | bo the me ees a
ofp Oibital the Ap £9 cb mah sheild vey © ae cls
SPA Wut the _nuckna Olge- is incense, ie, * nears Ag)
sealt the hele o df e© shee embaocks at enc!
h_ Successive
—_elemenk, Haugh the tease_is_Vedy_serall.
—| Gorsiquences 9p Jonlhonoicl Ghiachon
1. Reseinblance op 2hel_ Barc! Thohsi fist Seaies
1 - — — — ——
| As we mare don Hee _gpcup Se Cd series) fe le (ddl Seaies) fo lalsd.
T sesien) The size_tincacs?s -_Hewetiee ope Ihe_lenthanaids fhe thoaate_ in
El soli 20m hel fe Grd _feonsilion series. Alcins) clecaecses
- i» lly. Hred's why pate x element Zr 3 HE love simile 1
a o — opin teem
and aad § | The Inne Tonsilion Element ( p beck)
a
ample | _(
General. _elechiohie corgiquemben_ (N=2)p
| Clanttano iols ond Actahvials)
lhe elemenks ih ach the fst e~ a the f enn « the
atom sone altel p blecie elements
| The bs} @~ is edad tothe anikpenubimale shell: n~2p
The 2 ‘blocx eleinanks qe _alg,_called_ihhet leensilian element becug ”
Occoaditg fs _hert lemme numsLet Shey He cuppoksed te le ipbced yy °
be group Fea & uk ore place! ele the o block os there ask e-
enlegs into the £ —Subshell - oe ——
The g Lick ekments carsist SP fun’ setieg
4F Series or _lohlhatcids
Atomic ne - (88 + 2) : a .
7 the “b ne
ee Corum > 182, 282, 2pb, sz, Spb, 452, Spt, Al?
pt, Sst, ae Sst ae ae
682 eas af
— - = oA a4
Reson = Eregy kvel_p 4F nal Solis rrestly some alae) <<
__b _bnthaneidls Ohleaction fo Ves e- - e- wepulsyh
Uler_fov_electioh th ff | e9 1s Shifter pe Bd. 0 Carbon 9 Ti be bno, WY RENO th teufel obeline ruin
: | ondelion Mn — Mnoa_-
Mnd> — Tino,
|“ Radechen? Mot — Mind, ad
Kr? + 2hO— IMO,
Mn? + Wo MnOz + 4yt
Nit + 20 40H > Mas 410 2) ade
“a + 40H Tho? THO
zal Ad lal dh Soden
fe)
D_—MnOe + Iho + 3c M0,
| Mi 440 > MnO. + 20 + de X3e@
§ 40}4~
toa” + 20 + 2c" > Phos + 4oH=—@ x 2 © Odedatomsg.-Thvadphale (S08?) fe Sebphle (sof)
4,0" —> 29047"
G08 SIO > 1904"
Sade" + Go > 207% 4 JOH!
QOH 4 lOpH > 2eoF" + SHO
$2032° 4 (00H ©» 7904 + SHO! Be F Reochon 4
| MnOQa7 + 2420 + 3e°> Mc 4ay Jetes
k 7
3820327 + 30019 = ‘(S047 = + ISH20 + 24e2
BMnd4. 4 MihO# 408 —> Brwd 4 OHO T Rerclin 2
Add both Ranckon
8Mn047 Lx + AS 8320s “ son 8MnO% + ROH
3 z: L +6904" + foe 4
1 HO Remain
2OH®. Remar “yysoge sulphide i is, “ovidisal, sulphur: sty: eeieible:
“gH PSS “THT | eo
2Mnda + IbHt + [9eO —> 2Myr+ + Bho + |oht
SiS + QMbA" +t —> BS t+ OMHt # BIO
spl. oad or eulphie “oridwal ba wilphele ot sulphuiy ced.
| gs" + SHO —> 53047 + lot + Joco
+ opnoa FICH + foe® —> 9Mntt + gity -
maa erly aialne shin: =
we A uplle: aaclon 6 the @xidahin se ‘relide 8 ible oe
yor Peo
MnO + 20 Mr 4
MnO" +720 + 3° —> Mndr OHO 1x9 -
[arin + Ot b+ Dros + gHo’ ae i — » KMras at poroerfd onidising agent in aticlic mecliorm ih
| fNlowing casey
i
MnO4” +8H tHBe- —> Ant + AHO ~°@ *2
a Tadicle jo Iodine Me
2° = B+ ee |x6
\2 ley-—> 6h, + foe?
| Ars TNO ~—=> ! Ht —> WM? + SHO + SL?
Gi} Fe ion ren) is omerlel & * Cylled)
fet > Rt > be | ee
M047 > Pin2t > ain BeO
Skt + Mngt St > Mt + 4H + Set
Wid) Onealak on a axcolie ocid is aridisel of 333 K.
—— 802+ 2e2 4 20
a+ (292 2°
| COOK
l
- 24
BC0ae + WnOa~ + ILHt—> Mr8* + 8H2d + 10002 eet RM demerethancke na neuitel or ceric tlulen fe gee pape perme
aMna” 4 AN —? DMnO? + M2 + yo
(fesmepnet
ton)
(Rarple cua)
Roparbies
+ The MnO? (Pega ion) 3 MnO9™ permarat jon ce fellarbedicl
; ;
a a a)
609 Oo
Reomragne t a4 xf Drmregnehc
Mnda?> Mroe
x+ Ub 4 ==)
_ 249) xe
| : : p
Nh? 4B at dy Mn~ d's 4s!
tre a> fT) Mat > ade
°K aReormpose, by gue Haha, Mn onl O. ci,
Te onddises sulphur te Sd phic onice
|
Qy2+ —+ 3p 44 46 €9
bet (Re + bee
CyOqt- 4 ME» be2t > 2C24 FORE 4 1N@
Uv th oxickes Tyetisyen sulphate C3) fe
| hk@——> 9+ Ie tINt\+3
w Tk onidise! fodicle p fedire
| Craor® 4 bets AW + > 243 + be THO
| 104% + BibS + SHIP IG* + BSL + THO
Gro 07 FbT~ + AH 293* + 802 + 10.
Repaation ‘ 4
|
OD Blessium Rarmret (HOA)
Eis prepevel yy fusion op MrO2 with Alrali (ese) y HOH jp the
presence Poh Siclisng gent lke KMnOs
|
TMrOa+ ARON + 02—> 2haMnO4"t 20
_ ler on)_
i - —_____Gieenokuy)
$$ —— [pas : dicorele 1H is bosie
pan Quimale jon
: TA\
[ Qomde pn
_* Ne and K diaunoles wwe song onda agent
eG + lay* + feo 20° ho [ F-vay)
oO — D Ons as — feasie (2)
|e —— a _
A — es ee
G07" + AHF + be? —> 20214 LR5ty THO
—w| 1 owidiss ster b Sie
= (nO + HBT: +. (et 20 FINO
8 net |
#
|
t
Ss
Some Tmnpoalont cmpeunds of Fansilion Elemente
| Blossium Dicorale CHa Cy.01)
HD rh + C14 = 46
Bepyakion.
Tk is paepered gocm the cxvmvle ore (feGr204)
c Yells cokue
| Slee I: Fusion ep Comide ote _toith NaC@@ ond htcoe
AB Ca204_ + SNa2l03 *10.—> 8 Nor Gat 2ROs*
Sep IL: Filleaakton ond meinen op tHe NexCrO4 i
~JNa2GOa + 14t ——> NesG Or +2No? LO
“Sep: - Reackion wilh fel —pealy ait of wil “Teh ©
—_NeaGn, +9 RL —> a i
en oe) ee
Sopetligg us ee
The Cromale on (CrOa") orel_dicomale wn (G08) me in
con vedtalle in oqueauis—Solulicin ong up aa g the
golalions _ a —
| Pk qf he teraon relax that_copoinde
4 Rensan= A, _Tensi Hon demerls “an_ hae
Jon tat elecWone - ONGourclion, 2d
Pople? ane caburless
“Gleiydelic Alga -
es cle
-oidch_akle- she fe dc
on atin a iohly of unatile inlaid patie. ~
_-| su fore etal cme cbse enchalher fochilolig
| pctess ( perriolly piled d tila)
| 2 Inage. Subgoce Org —Thot_the reaclonls cop bscted an: the
he rece lion
Fastnokion of Dbleisililid_Gmpaurds a "i 7
—+| Thlesitel Gopunds cre these _m_wohich _attall_aloms like HC we
——| Nu Boe faoppel_insce the caysial Whee a
“| Boos 6 the Ga in ally ond Bune Gy
Bexar Due bb Inamplley_ filet calle _Sme_lotides cepa Yom
1) tonsiah. tele hee a9 smilie ec ond veel begat oles |
wv
AY)
uit |
*
el owls BS
Mn = 2s - cy
es $e, 24S 4B Ls
“mths jst, 2st, 2pt, 38, pb As» 2 29
3s 4p 4
We Vols) _ Pg
> as = 5-7. 8h -
Complen mein — ou ee tee
; the lender qh laonsilion elements fe foam — comple ton is_olte bo
The high Chatge_on_ the hronailion. mefol ion, fits ;
The _avaticlilily cl cabilols pa eccomedaling eo clara bel Wy She ler)
akms, a
Smparolively sredler swe op She meal ton
| Formation gy ckutel ions
|
|
|
Most p the ltonsilin melol tan in sal? as well as in selicl stoke one
Glourel .
| Reason = Mhen oh e® pom a lewer enensgy th _d_arlital 1s: eect tel
@ feo higher enesgy d oeblol the energy g erictahion
Covvesnond fo (he fom. 94 igh} olsrlal__this greq. gererolly
Wie th the visible tapion oP light the ebuted alssaCrexl Cleespenc!
Ute fhe cmplementety ckur The light olsatele]
aS, the elec frOhie ‘omsilioh actuts tol th the d= alike) Mansi
/ omelet isn they ore d/d tronsition, Bis Veccue op Ald teonsilich
Occ Sing fm be frorsiton_melel ion Ly _abseaivy q__ visible ight + [ Magrehic Ropeslies
“When o_maghd nae
Ppa eee alent ~ applied too SUbslonKes math feo Wee a Inghelic
al diomaghehsin
« Raamagne hsm
> Ststarces emloney unpoitel e© gue
one Olatele. ly the opted feicl
toicl fe be (tarreaeie subslenced
+ Qulskenca which ave. allsacled Shrongly oe _soid_b Le pele
magne
7 Mong op Re substances are jh which oll The substances core {
fig? anf Gat, SETTSEVSE Gro, pa a
The which se all the. 2° eo. paital _ : a
- [sn a pay A e
Gat at BB cae _demepehe t_relute hove _gelly guile 2d ort fal
te lc_oren (10 dering he w= uno
22(h) ord _ils_cleuldle using [he —Spin Only _ poate
em Mall werense MM Gil ake nace
[oT eh 3
—— Unit < _Bohax_magneloh ‘ , sih,
& | Explain wahy Gut ton_is. tek shUle 9 renis
“ans Th aqueous. calulign Gut Under gees dispagpsuration farm. g
made stelle Galt en
| Yat eq» at Cu)
0 ll anu leg
the byighea slalitly, of (adh in aqucas salh ry Ge alleruitey
i cL greales: at hyctaaslion onhely ( Alys HO) ond Nhat ¥
Get. fh @mpansate the Ind CE g inca iN the gem
C2 ton.
fre Prolue ves _ gen ley b_aght ocooss the series
Mn» Niond_2r_hae higher vale then. expected lenuse
ther hole gtlleal wblab» 8 comple lely _ filled loa bib!
wn_cose_op Mn? ond Zt tespechively
aus | Cake (ML tlBe 2h ie highs
a —- Ihe__semoval op one prom the_slable_dP_ampiquaakon 3
ay the campeto tively high _£° (M3t] met, gor Mh js cee. fo by
| towel qp-on 2© grein the stolle_d® _empiguenkion -
w EU ge et
rm Leu _velte gis en ae ee .
Pe ahaa
| whh lead $243 Chole gitsd) ey — - | Metallic Chotackey
| Tronsition clement cho. geal . 4
i detsease in, el ul
+ Moving fom _Lepl_ te aphl nthe seaies \ Sechronesitive cheterley th
2 AL bonsilon eemenls ane relate ——-
T im the Ni
wetol ere ueay Skong che by gemtey Meteltic_Nend jh Foes \ien
echve Wey lows [eb
- % byge muamler @ cont atubls nthe seaman de “HY.
Gnsmrerce ° Wonshion melals
wre hen S, ‘
ane PRS Neer dea at pe
| As the te ungairee| 29 Nes the _lerelencty fo gern Tretellic ord covclas
Lent_ols inten Ai a ee ‘ ones
Mh son excep lion with low MP § BP Reese ne “shUte -
ss nee tiguston bese? one hel tig by mens 5 a
_____}he__deksaligntion is _less, Ark _the_Ineblie bord “is nich oenker a
__=# Shorchiel_Eleclinde _@lenliel “ie wit a
— G*_ Is more_ekWe then Cet tn oqueaus medium -
When _the_melal_evhibits mate_\on 10.6 thet _xela
——— On le_tehgton —_faotn their Stoncletel Electiede Qtenkol
live shelslibeiee
2b tes 4 a
Ot oh® > Cues) a A
4, +e > Gia. eg,
Gut eg) 2 Ga ces Egg OSV
| lower BRP ireliales Get ts reote stole the CF In aque
reediuye o | Renson- Cr auachalls
as
| ad5 45!
fe- Lu
rt Ca Ailie 653
| ads :
_| Cy? IE 48 Ai. = 1892
Ait < Dita Becruse-
|
la
“Tn_tee. very hp Cer teemee tn Sel gevies
Receon ! ‘the €? ne be be remgve prom 48 | ebbi tol _o 3g | “the atoll
| ad? 4e2 Congigutakion _
_| the Te LE pe elemmls ore + eth Von these 3 ado
4d elements
Reason Due groler_ Zep ockiny. on the _ader dene 08 fr the
elements _veccuse gy the ineppeclive =e Stetey the nacless
ye 4p 22 Clenthatnid emfrachion) he Amperpect sheildny poe -dechen Ly “orolher th We same set
ep _orlalalg + However _ rare pone re ee Wy oho ther i less
than Hop 29 by ombhet and os the Nc Tes the
| _seiteS there te_sequlor_clecdeage th_the_ = ¢ the enkoo 4f orlatals.
_ Greecusences sp Lenovo td la cf) 4 ard SA be we elias
| thet by Zr tes 2 No Ae sees) a
Hg + |S1_pm_(3A_sesies) _ _ _
|_Tenizalion_ a ee
Te. 6 te _enetgy aqui ls termaue CO gtem ile gpseous stake
“tha parhonkr fionsilion eves fenizclion anthely Tes ely wath
| Bes on alerme number foom lept te tight et Es
LReassn 7 the es in LE te due > Ses m_N Nc with fes th atomic
tumbler ushigh lene fb oltock the e@© cloucle carl gtenter pete
he gr “anak gp Lond T LB om be pol fonsrbioh seas
| Romany a alue to ny “epee ¥ Stolality gy dy. 3d at cegiger ——chatge fer ly unlly ee
| Sheildy Eyech- S>psdap ol
“1 S£ fa deo is nol tok eechve hence tte ek ey
—|fatice_Uo_the nuclear charge —ainel_ Ure outers eleclen gy
the sediug es = 2 : =o
= Becuse the neo_e8 enlese the d_ovbital_evh Nm Ne hucley
| The gractsal increase in foclius—inthe—lastelemenks_@ a pele
| sedies is oe fo ee ~ 29 sepulstan lhe poiding 9p £9
| the al_orbital ep the. pehullimate shell Ohlig —_agler he
ol_gubshell hal _gitled tt a
at| The ThnexTronsilion._Elemenb- {fs 3 copied
| the carves shnos_om_ncsese_piom the fis (2i)ie lhe 489 Seon
—| deh settes gf the- element. tut the soalei op: He thitel (ed ) Seti
—e_vithally jhe some as these
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