SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
Product name: PAVECRYL™ SUPPRESS PLUS Issue Date: 06/18/2015
Print Date: 07/26/2019
THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.
1. IDENTIFICATION
Product name: PAVECRYL™ SUPPRESS PLUS
Recommended use of the chemical and restrictions on use
Identified uses: Chemical Specialty
COMPANY IDENTIFICATION
THE DOW CHEMICAL COMPANY
2030 DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES
Customer Information Number: 800-258-2436
SDSQuestion@dow.com
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: CHEMTREC +1 800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
This material is not hazardous under the criteria of the Federal OSHA Hazard Communication
Standard 29CFR 1910.1200.
Other hazards
no data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature: Acrylic Latex
This product is a mixture.
Component CASRN Concentration
Acrylic polymer(s) Not hazardous >= 49.0 - <= 51.0 %
® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 10
company of Dow
Product name: PAVECRYL™ SUPPRESS PLUS Issue Date: 06/18/2015
Residual monomers Not required < 500.0 PPM
Aqua ammonia 1336-21-6 <= 0.2 %
Water 7732-18-5 >= 49.0 - <= 51.0 %
4. FIRST AID MEASURES
Description of first aid measures
Inhalation: Move to fresh air.
Skin contact: Wash with water and soap as a precaution. If skin irritation persists, call a physician.
Eye contact: Rinse with plenty of water. If eye irritation persists, consult a specialist.
Ingestion: Drink 1 or 2 glasses of water. Consult a physician if necessary. Never give anything by
mouth to an unconscious person.
Most important symptoms and effects, both acute and delayed: Aside from the information found
under Description of first aid measures (above) and Indication of immediate medical attention and
special treatment needed (below), any additional important symptoms and effects are described in
Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed
Notes to physician: Treatment of exposure should be directed at the control of symptoms and the
clinical condition of the patient.
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Use extinguishing media appropriate for surrounding fire.
Unsuitable extinguishing media: no data available
Special hazards arising from the substance or mixture
Hazardous combustion products: no data available
Unusual Fire and Explosion Hazards: Material can splatter above 100C/212F. Dried product can
burn.
Advice for firefighters
Fire Fighting Procedures: no data available
Special protective equipment for firefighters: Wear self-contained breathing apparatus and
protective suit.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Use personal protective
equipment. Keep people away from and upwind of spill/leak. Material can create slippery conditions.
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Product name: PAVECRYL™ SUPPRESS PLUS Issue Date: 06/18/2015
Environmental precautions: CAUTION: Keep spills and cleaning runoff out of municipal sewers and
open bodies of water.
Methods and materials for containment and cleaning up: Contain spills immediately with inert
materials (e.g., sand, earth). Transfer liquids and solid diking material to separate suitable containers
for recovery or disposal.
7. HANDLING AND STORAGE
Precautions for safe handling: Avoid contact with eyes, skin and clothing. Wash thoroughly after
handling. Keep container tightly closed. Do not breathe vapors, mist or gas.
Conditions for safe storage: Keep from freezing - product stability may be affected. STIR WELL
BEFORE USE.
Storage stability
Storage temperature: 1 - 49 °C (34 - 120 °F)
Other data: Monomer vapors can be evolved when material is heated during processing operations.
See SECTION 8, for types of ventilation required. NOTE: Formaldehyde will be generated under
acidic conditions. Maintain adequate ventilation under these conditions to prevent exposure to
formaldehyde above the Rohm and Haas Co. recommended ceiling of 0.3 ppm.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure limits are listed below, if they exist.
Component Regulation Type of listing Value/Notation
Aqua ammonia Rohm and Haas TWA 10 ppm, As Ammonia
OSHA Z-1 TWA 35 mg/m3 50 ppm
ACGIH TWA 25 ppm, Ammonia
ACGIH STEL 35 ppm, Ammonia
Exposure controls
Engineering controls: Use local exhaust ventilation with a minimum capture velocity of 100 ft/min.
(0.5 m/sec.) at the point of vapor evolution. Refer to the current edition of Industrial Ventilation: A
Manual of Recommended Practice published by the American Conference of Governmental Industrial
Hygienists for information on the design, installation, use, and maintenance of exhaust systems.
Protective measures: Facilities storing or utilizing this material should be equipped with an eyewash
facility.
Individual protection measures
Eye/face protection: Safety glasses with side-shields Eye protection worn must be
compatible with respiratory protection system employed.
Skin protection
Hand protection: The glove(s) listed below may provide protection against
permeation. (Gloves of other chemically resistant materials may not provide adequate
protection): Neoprene gloves
Respiratory protection: A respiratory protection program meeting OSHA 1910.134 and ANSI
Z88.2 requirements or equivalent must be followed whenever workplace conditions warrant a
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Product name: PAVECRYL™ SUPPRESS PLUS Issue Date: 06/18/2015
respirator's use. None required if airborne concentrations are maintained below the exposure
limit listed in Exposure Limit Information. For airborne concentrations up to 10 times the
exposure limit, wear a properly fitted NIOSH approved (or equivalent) half-mask, air-purifying
respirator. Air-purifying respirators should be equipped with NIOSH approved (or equivalent)
ammonia/methylamine cartridges and N95 filters. If oil mist is present, use R95 or P95 filters.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state liquid Milky
Color white
Odor Ammonia
Odor Threshold no data available
pH 9 - 9.8
Melting point/range 0 °C ( 32 °F) Water
Freezing point no data available
Boiling point (760 mmHg) 100.00 °C ( 212.00 °F) Water
Flash point Noncombustible
Evaporation Rate (Butyl Acetate <1 Water
= 1)
Flammability (solid, gas) Not Applicable
Lower explosion limit Not applicable
Upper explosion limit Not applicable
Vapor Pressure 17 mmHg at 20.00 °C (68.00 °F) Water
Relative Vapor Density (air = 1) <1 Water
Relative Density (water = 1) 1.0 - 1.2
Water solubility Dilutable
Partition coefficient: n- no data available
octanol/water
Auto-ignition temperature Not applicable
Decomposition temperature no data available
Dynamic Viscosity 10 - 210 mPa.s
Kinematic Viscosity no data available
Explosive properties no data available
Oxidizing properties no data available
Molecular weight no data available
Percent volatility 49.000 - 51.000 % Water
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY
Reactivity: no data available
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Product name: PAVECRYL™ SUPPRESS PLUS Issue Date: 06/18/2015
Chemical stability: Stable
Possibility of hazardous reactions: None known.
Product will not undergo polymerization.
Conditions to avoid: no data available
Incompatible materials: There are no known materials which are incompatible with this product.
Hazardous decomposition products: Thermal decomposition may yield acrylic monomers.
11. TOXICOLOGICAL INFORMATION
Toxicological information appears in this section when such data is available.
Acute toxicity
Acute oral toxicity
LD50, Rat, > 5,000 mg/kg
Acute dermal toxicity
LD50, Rabbit, > 5,000 mg/kg
Acute inhalation toxicity
Product test data not available.
Skin corrosion/irritation
May cause transient irritation.
Serious eye damage/eye irritation
No eye irritation
Sensitization
Product test data not available.
Specific Target Organ Systemic Toxicity (Single Exposure)
Product test data not available.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Product test data not available.
Carcinogenicity
Product test data not available.
Teratogenicity
Product test data not available.
Reproductive toxicity
Product test data not available.
Mutagenicity
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Product name: PAVECRYL™ SUPPRESS PLUS Issue Date: 06/18/2015
Product test data not available.
Aspiration Hazard
Product test data not available.
Additional information
No data are available for this material. The information shown is based on profiles of compositionally
similar materials.
COMPONENTS INFLUENCING TOXICOLOGY:
Acrylic polymer(s)
Acute inhalation toxicity
The LC50 has not been determined.
Residual monomers
Acute inhalation toxicity
The LC50 has not been determined.
Aqua ammonia
Acute inhalation toxicity
LC50, Rat, male, 1 Hour, dust/mist, 9.850 mg/l
Sensitization
For skin sensitization:
No relevant data found.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause additional
significant adverse effects.
Carcinogenicity
Did not cause cancer in laboratory animals.
Teratogenicity
Available data are inadequate for evaluation of potential to cause fetotoxicity.
Reproductive toxicity
Available data are inadequate to determine effects on reproduction.
Mutagenicity
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
Water
Acute inhalation toxicity
The LC50 has not been determined.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
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Product name: PAVECRYL™ SUPPRESS PLUS Issue Date: 06/18/2015
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
No relevant data found.
Teratogenicity
No relevant data found.
Reproductive toxicity
No relevant data found.
12. ECOLOGICAL INFORMATION
Ecotoxicological information appears in this section when such data is available.
General Information
There is no data available for this product.
Toxicity
Acute toxicity to fish
LC50, Oncorhynchus mykiss (rainbow trout), 7 d, > 1,000 mg/l
Acute toxicity to aquatic invertebrates
LC50, Daphnia magna, 7 d, > 800 mg/l
Persistence and degradability
Biological oxygen demand (BOD)
Incubation BOD
Time
5d
Bioaccumulative potential
Acrylic polymer(s)
Bioaccumulation: No relevant data found.
Residual monomers
Bioaccumulation: No relevant data found.
Aqua ammonia
Bioaccumulation: Partitioning from water to n-octanol is not applicable.
Mobility in soil
Residual monomers
No relevant data found.
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Product name: PAVECRYL™ SUPPRESS PLUS Issue Date: 06/18/2015
13. DISPOSAL CONSIDERATIONS
Disposal methods: Coagulate the emulsion by the stepwise addition of ferric chloride and lime.
Remove the clear supernatant and flush to a chemical sewer. For disposal, incinerate or landfill at a
permitted facility in accordance with local, state, and federal regulations.
14. TRANSPORT INFORMATION
DOT
Not regulated for transport
Classification for SEA transport (IMO-IMDG):
Not regulated for transport
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Classification for AIR transport (IATA/ICAO):
Not regulated for transport
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
15. REGULATORY INFORMATION
OSHA Hazard Communication Standard
This product is considered non-hazardous under the OSHA Hazard Communication Standard
(29CFR1910.1200).
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
This product is not a hazardous chemical under 29CFR 1910.1200, and therefore is not covered by
Title III of SARA.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This product does not contain a chemical which is listed in Section 313 at or above de minimis
concentrations.
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Product name: PAVECRYL™ SUPPRESS PLUS Issue Date: 06/18/2015
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
Section 103
Releases of this material to air, land, or water are not reportable to the National Response Center
under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) or to
state and local emergency planning committees under the Superfund Amendments and
Reauthorization Act (SARA) Title III Section 304.
Pennsylvania
Any material listed as "Not Hazardous" in the CAS REG NO. column of SECTION 2,
Composition/Information On Ingredients, of this MSDS is a trade secret under the provisions of the
Pennsylvania Worker and Community Right-to-Know Act.
United States TSCA Inventory (TSCA)
All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
16. OTHER INFORMATION
Hazard Rating System
HMIS
Physical
Health Flammability
Hazard
1 0 0
Revision
Identification Number: 101102612 / A001 / Issue Date: 06/18/2015 / Version: 2.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
Rohm and Haas Rohm and Haas OEL's
STEL Short-term exposure limit
TWA Time weighted average
Information Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
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Product name: PAVECRYL™ SUPPRESS PLUS Issue Date: 06/18/2015
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
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