Hss05 Unit 3
Hss05 Unit 3
Unit 3
Environmental pollution:
● Sources of pollution- Natural sources, & Anthropogenic
● Pollutants- Classification & their effects on environment
● Air pollution-Composition of clean air, Sources of air pollution & Air pollutants, Effect
of air pollution on humans, animals and plants & climate
● Water quality–Potable water, Wholesome water, Sources of water pollution Polluted
water & Contaminated water,
● Common impurities in water (physical, chemical and bacteriological), Effects of
impurities on humans & industrial use
● Soil Pollution-Sources, Effects & its control
● Noise pollution- Sources of noise, Effects on human health & its control
Environmental pollution
The word “pollution” is from Latin word pollutionem (make dirty).”Pollution is an
undesirable change in the physical, chemical or biological characteristics of water, air and
land (soil) which may cause potential health hazard of any living being or species or loss of
cultural and natural assets”.
Pollution of the environment directly leads to the ecological imbalance of the world. Progress
in science and technology is leading to the pollution of environment. In the long run it may
leads to the disaster of mankind and other living organisms. Speedy exploitation of natural
resources by man disturbed the sensitive ecological balance between living and non-living
component of biosphere.
Now a days it is becoming common to find warning boards in public places, stating “Water
unfit for drinking”, Do not eat fish caught here”, “Water is unfit for recreation”, “Air unfit for
breathing”, and so on.
The rapid progress in Industry, Agriculture, Transportation etc, are taken as the general
criterion to measure the development of any nation.. All these activities have created adverse
effect on the biosphere in one or the other way. Rapid industrialization and urbanization leads
to depleted natural resource, contaminated surface (rivers) and ground water, contaminated
soil, contaminated air (atmosphere) and depleted forest resources (animals, plant etc).
Polluant: Polluant is a substance that causes pollution. Pollution is caused by the addition of
substances by human activity to the environment. When these substances are not removed,
assimilated or decomposed by the nature (physical or biological process), the accumulation of
these pollutants causes pollution. A pollutant may include any activity (sound) chemical,
geochemical (dust), substances, biotic component or product, physical factor (light, heat) etc.
that is released into the environment in such a concentration that may have harmful or
unpleasant effects.
Pollutant is also defined as “any liquid, solid or gaseous substance present in such
concentration as may be or tend to be injurious to the environment”. Pollutants are the
remaining of the things we make use and throw.
Sources of pollution: The sources of pollution is broadly classified into two groups
(a) Natural sources: The pollution originates from the natural calamities and processes
such as volcanic eruptions (releases gases and ash), earthquake, forest fire, dust storm
(deserts), cyst and pollens, spores decay of organic matter etc.
(b) Manmade (artificial) or Anthropogenic sources: The pollution originates due to the
activities of man. Anthropogenic sources cover a wide range of sources. Since man
has aggravated the problem of pollution due to multiple activities for his comfort and
enjoyment. The sources are deforestation, industrialization, automobiles, nuclear
explosions, over population, quarrying and mining, construction activities, wars
agriculture (fertilizers and pesticides) etc.
(i) Primary pollutants: These persist in the form in which they are added to the
environment. Eg.DDT, Plastic.
(ii) Secondary pollutants: These are formed by interaction among the primary
pollutants. For example, peroxy acetyl nitrate (PAN) is formed by the reaction of two
primary pollutants, namely nitrogen oxides and hydrocarbons released from the motor
vehicles in presence of sunlight.
Human activities and technological advancements made to enjoy luxurious life have caused
severe in balances and disturbances in natural environment.
Although there are several individual human activities, which may cause environmental
imbalances, they can be grouped in to the following four major types of actions.
(1) Agriculture: The development of agriculture has been the most important single event in
the evolution of human culture. With the development and increase in human population, the
agriculture on more and more land has been practiced to grow crops. Initially the humans
have grown only food crops to eat but later on they have started growing several kinds of
cash crops. Not only they have brought a large part of the forest land under agriculture, but
also they have started using fertilizers and pesticides to increase the crop production per unit
of agricultural area. The present mode of agriculture is highly mechanized as the modern
technology is constantly inventing new & newer machines for agriculture. This has infact
become virtually imperative as the human population is increasing day by day especially in
developing countries.
(3) Urbanization: The urbanization is the process of urban development, under which mass
migration of people from rural areas to the industrialized urban areas take place due to the
increased job opportunities. With such a fast urbanization taking place lot of land have been
consumed to build giant urban centers. Precious farming land had been lost to urbanization.
Urbanization changes the green, wet and earthen land to concrete and asphalt paved land.
These increases the rain’s run off thereby increasing floods and reducing ground water
recharge.
Urbanized areas produce enormous quantities of sewage and domestic waste waters, which
on being discharged into the rivers, either in untreated or partly treated condition pollute the
rivers and can totally modify the aquatic ecosystem.
Air pollution and land pollution, prevailing in urban centers, can also modify the ecosystem.
Urbanization modifies the nearby areas. For example, large amount of sand is removed from
the rivers in construction activity which makes the river ecosystem unstable due to abnormal
large pits created in the river bed.
Hills are destroyed to get stones for construction purposes. The removal of hills may change
and modify the climate, not only locally but even regionally over vast areas, as the rainfall in
plains becomes difficult to occur.
Another major requirement of urbanization is wood for furniture, doors. Windows, amirahs,
cupboards etc. This demand is met by destroying the forest, which causes serious
consequences for forest eco system. Any loss of forest will lead to the loss of beneficial
effects of forest.
(4) Mining: Mining is the extraction of minerals & ores from the earth’s crust. Mining
provides coal for the energy, metals for making machines & engines, ores for making
chemicals & fertilizers, clays for making crockery, rocks & stones for buildings, bridges &
dams, the gold, diamond & other precious stones for jewelleries.
The exploitation of mineral resources has increased several times leading to large scale
mining activities.
Mining whether it is at the surface or underground alters the whole landscape & the eco
system existing at the place of mining which cannot be shifted any where.
The removal of minerals from the earth naturally upsets the existing land conditions and
waste tailing produced in this process contain toxic chemicals like mercury & sulphides of
iron. The waters in these areas have become very acidic. No plant grows & no animal
survives in such areas. Mining activity has given rise to vast areas of waste land that are now
useless from the point of view of agriculture or agro forestry.
Air pollution:
The atmosphere is the thin layer of gases (air) that surrounds the earth surface. Air is defined
as the invisible, tasteless and elastic mixture of gases. Air pollution is assuming global
magnitude and it is not confined to any particular part of earth or country. Under ideal
conditions, the air in the atmosphere has a qualitative and quantitative balance that maintains
the well being of human, plants and materials. When the balance among the air components
are disturbed, then air is said to be polluted.
Definitions:
(1) Air pollution is the presence in the ambient atmosphere of substances, generally resulting
from the activity of humans, in sufficient concentration, present for a sufficient time and
under circumstances which interfere significantly with the comfort, health or welfare of
persons or with the full use or enjoyment of property (Indian standard institution).
(2) The presence in the outdoor atmosphere, of one or more contaminants such as fumes,
dust, gases, mist, grit, odour, smoke or vapors in considerable quantities and of
duration which is injurious to human, animal or plant life or which unreasonably
interferes with the comfortable enjoyment of life and property (Perkins 1974).
(3) Substances introduced into the air by the activity of mankind in such concentrations
sufficient to cause serious effects on his health, plants, property or interfere with the
enjoyment of his property (Sharma and Haur 1997).
Composition of Air: Various gases are present in the atmosphere as shown in the table. The
nitrogen gas is biologically inert but some bacteria and plants utilize it.
The oxygen is essential for all living beings.
Carbon dioxide is utilized in photosynthetic process of plants.
Trace gases (helium, neon, krypton, xenon, etc.) have little or no role with the living
organisms. Atmospheric pollution is the addition of harmful gases by human activities.
Types of air pollutants: On the basis of physical state, air pollutants are of two types-
gaseous and particulate.
(1) Gaseous pollutants: These pollutants are in gaseous state at normal temperature and
pressure.
(2) Particulate pollutants: These pollutants occur as solid and liquid particles. They are of
two types-settleable and suspended.
Settleable: The particles larger than 10 m in diameter such as water drops, sand etc which
settle down rapidly in still air, are called settleable pollutants.
Suspended: The smaller particles such as dust, smoke, etc. which remain suspended for long
periods in the air are called suspended pollutants. These include soot, asbestos fibers,
pesticides, some metals (including Hg, Pb, Cu and Fe) and also biological agents like tiny
dust, mites and pollen. The larger suspended particles with more than 1m in diameter are
often called dust (solid) and mist (liquid). Aerosols, smokes and fumes are also suspended
particles with a diameter less than 1m.
Sources of air pollution: The sources that contribute pollutants to the air are as follows
some incombustible minerals, sulphur and nitrogen. Therefore, when fossil fuels are burnt
they produce a mixture of oxides of carbon, nitrogen and sulphur and water vapor. Burning of
coal also produce mineral ash, some of which is discharged as fly ash.
(II) Mobile combustion sources: These include locomotives, automobiles, aircrafts, etc.
With the rapid increase in vehicular traffic, automobiles have become the largest source of air
pollution in cities.
(III) Industrial processing and other sources: The industrial processes involve
metallurgical processing, welding, grinding, synthesis of chemicals, etc. These processes
release several gaseous and particulate pollutants into the air. Gaseous pollutants of different
types are released from the industries that process organic chemicals at high temperatures.
(IV) Secondary air pollutants: These are formed from primary pollutants by photochemical
reaction.
Chronic pulmonary diseases like bronchitis and asthma are aggravated by a high
concentration of SO2, NO2, particulate matter and photochemical smog.
Carbon monoxide combines with the hemoglobin in the blood and consequently
increases stress on those suffering from cardio vascular and pulmonary diseases.
Hydrogen fluoride causes dieses of bone (fluorisis) and mottling of teeth.
Carcinogenic agents cause cancer.
Dust particles cause respiratory diseases. Diseases like silicosis, asbestosis etc, result
from specific dusts.
Certain heavy metals like lead may enter the body through the lungs and cause
poisoning.
Effect air pollution on animals: Air pollution causes large-scale damage to livestock. The
general effects of air pollution on domestic animals in and around industrial area are similar
to those on human beings
Ingestion of fluorine compounds deposited from the air on fodder causes fluorosis
(excessive calcinations of bones and teeth). It also results in lameness, frequent diarrhea
and loss of weight.
Several airborne microbes cause diseases.
Effect air pollution on materials: Various material damage due to air pollution is as
follows.
Materials Principle air Effects
pollutants
Metals SO2, acid gases. Corrosion, spoilage of surface, loss of metal
tarnishing.
Building SO2, acid gases and Discoloration and leaching
materials particulates.
Paint SO2, H2S and Discoloration.
particulates.
Textiles and SO2, acid gases and Deterioration, reduced textile strength and
textile dyes NO2 and ozone. fading.
Rubber Oxidants and ozone. Cracking and weakening.
Leather SO2, acid gases. Disintegration and powdered surface.
Paper SO2, acid gases. Embitterment.
Ceramics Acid gases. Change in surface appearance.
Aesthetic loss due to air pollution: Air pollution has strong bearing on the aesthetic side of
human life.
A clear transparent atmosphere is aesthetically pleasing but is necessary for clear vision.
A dust haze or hanging smoke blurs our views
Foul odour emitted by industries, automobiles, dirty drains and garbage heaps make urban
life unpleasant.
Coal dust and their materials discharged from the industries settle down on the flour and
other objects of houses and give dirty look.
Water quality:
Water is essential to human life and to health of the environment. As a valuable natural
resource, it comprises marine, estuarine, fresh water (river and lakes) and ground water
environment, across coastal and inland areas. Water quality is commonly defined by its
physical, chemical, biological and aesthetic characteristics. A healthy environment is one in
which the water quality supports a rich and varied community of organisms and protects
public health.
Water quality in a body of water depends upon the way in which communities use the water
for activities such as drinking, swimming or commercial purposes.
Definitions:
Potable water: Water that is free from apparent turbidity, colour, and odour and free from
any objectionable taste so that it consumed in any desired amount without concern for
adverse effects on health is known as potable water.
Wholesome water: Water that does not contain harmful impurities and does contain other
salts and minerals that are useful to health is known wholesome water.
Polluted water: Water containing any foreign matter (solid, liquid or gaseous) that is
infectious or non-infectious and toxic or non-toxic that affects its beneficial usage is known
as polluted water.
Contaminated water: Water that contains infectious agents or toxic matter that affects the
health of the community and make the water unfit for its beneficial usage is known as
contaminated water.
Common impurities in water and their effect on human health:
The various impurities present in water may be classified into the following three categories.
Physical impurities: The physical impurities are those impurities that affect the physical
characteristics of water such as colour, odour, taste and turbidity.
Chemical impurities: The chemical impurities are those impurities that affect the
chemical characteristics of water such as total dissolved solids and suspended solids
present in water, pH value, hardness, chloride content, nitrogen content, etc.
Bacteriological impurities: The bacteria are minute singe cell organisms that are
universally found in water obtained from any source. They are very small measuring only
1 to 4 micron in length (1 micron = 10-6 m). As such they have to be examined under a
microscope. The bacteria are usually classified according to their shapes, their oxygen
requirements and their effect on mankind.
According to shape the bacteria are classified as cocci (round shaped), bacilli (rod shaped)
and spiralla (spiral shaped).
According to oxygen requirements the bacteria are classified as aerobic bacteria, anaerobic
bacteria and facultative bacteria.
Aerobic bacteria are those which require free oxygen for their survival, thus if present in
water they consume dissolved oxygen from the water and decompose the organic matter
present in water.
Anaerobic bacteria are those that flourish or thrive in the absence of free oxygen.
Facultative bacteria are those that can survive with or without free oxygen.
According to the temperature they flourish, the bacteria are classified as Psychrophilic,
Mesophilic and Thermophilic.
Psychrophilic which can persist at low temperatures of 100 C and 200C.
Mesophilic which can persist at temperature of 200 C and 400C.
Thermophilic which can persist at temperature of 400 C and 650C.
According to effect on mankind the bacteria may be classified as harmless bacteria and
harmful bacteria. The harmless bacteria are called non-pathogenic bacteria or non-pathogens.
These bacteria besides being harmless, under certain conditions are beneficial to human
beings, animals and crops. The harmful bacteria are called pathogenic bacteria or pathogens.
The pathogenic bacteria are the real foes of mankind, which may cause serious water borne
diseases such as cholera, typhoid, dysentery, infectious hepatitis, etc. Generally non-
pathogenic and pathogenic bacteria occur together, and hence the presence of large amount of
non-pathogenic bacteria in a water sample indicates the possibility of the pathogenic bacteria
being also present in the water sample.
Water pollution:
(1) Water pollution is the contamination of water by foreign matters such as physical matters,
chemicals, microorganisms, sewage, industrial wastes or other wastes. Such matters
deteriorate the quality of the water and renders it unfit for its best uses.
(2) Water pollution is change in physical, chemical and biological characteristics of water
that may cause harmful effects on human, animal and aquatic biota.
Types of water pollution: Water pollution can be classified into the following three
categories.
(1) Physical pollution: The physical pollution of water is due to change in colour, turbidity,
odour, taste, foam, thermal properties and conductivity.
(2) Chemical pollution: The chemical pollution of water is due to change in total solids, PH ,
chlorides, nitrogen, phosphorous, fats, sulphates dissolved oxygen, chemical oxygen
demand, biochemical oxygen demand, gases, metals etc. Pollution is caused by organic or
inorganic or by both.
(3) Biological pollution: Biological pollution of water is caused by excretory products of
humans, animals, birds, sewage and industrial waste water (tanneries, slaughter house,
dairy etc). The main biological pollutants are bacteria, viruses, algae, protozoa, parasitic
worm, fecal colifarms, streptococci etc. Contaminated water causes infection of intestinal
system (dysentery, typhoid, cholera etc) infectious hepatitis etc.
Indicator of polluted water: Following are the important indicators of water pollution
Colour and bad taste of drinking water.
Increase in turbidity and floating solids (oil and grease).
Offensive odour from water bodies.
Growth of aquatic weeds (eutrophication) in water bodies.
Decrease in aquatic animals (fish).
Increase in temperature of water.
Effects of water pollution: The effects of water pollution depend on the type of pollutants
present in water. Pollutants brings about physical and chemical changes that make the water
unfit for drinking and harmful to aquatic life. The main effects of pollutants are as mentioned
below.
(1) Effects on aquatic ecosystem: Presence of organic and inorganic wastes in water
decreases the dissolved oxygen (DO) content of the water. Water having DO content
below 8.0 mg/l may be considered as contaminated. Water having DO content below
4.0 mg/l is considered to be highly polluted. DO content of water is important for the
survival of aquatic organisms. A number of factors like surface turbulence,
photosynthetic activity, oxygen consumption by organisms and decomposition of
organic matter determine the amount of DO present in water.
(2) Biological magnification: The phenomenon through which certain pollutants get
accumulated in the tissue in increasing concentration along the food chain is called
biological magnification. Many of the pesticides are non-degradable and their
residues have long life. The organic chlorine compounds such as DDT, radionuclides
etc are the most persistent pesticides. Once they are absorbed by an organism, they
cannot be metabolized and broken down or excreted out. These pollutants get
accumulated in fat containing tissues of the organisms. A classic example of
biological magnification is the accumulation of DDT in the tissues of organisms of
aquatic food chain.
(3) Eutrophication: The addition of inorganic compounds and decomposition of organic
wastes in water bodies increase the nutrient content of water. It could profuse growth
of algae especially the blue-green-algae, and may totally cover the water surface.
This type of algal growth is called algal boom. The algal boom often releases toxins
in water and inhibits the growth of other algae. Aquatic animals (fish) may also die
due to toxicity or lack of oxygen. The process of nutrient enrichment of water, which
often leads to the loss of species diversity, is called eutrophication.
(4) Effect on human health: A number of health hazards are caused due to various
types of pollutants present in water. The important human health hazards related to
water pollution are as follows:
The water polluted with sewage usually contains pathogens like virus, bacteria,
parasitic protozoa and worms. The sewage-contaminated water, therefore, is a
source of water borne diseases like jaundice, cholera, typhoid, amoebiasis etc.
The water contaminated with heavy metals can cause serious health problems.
Mercury compounds wastewater converted by bacterial action into extremely
toxic methyl mercury, which can cause numbness of limbs, lips and tongoue,
deafness, blurring of vision etc.
Presence of excess nitrate in drinking water is dangerous for human health and
may be fatal for infants. It reacts with hemoglobin to form non-functional
methaemoglobin and impairs oxygen transport. This condition is called
methaemoglobinemia or blue baby diseases.
Excess fluoride in drinking water causes dental fluorosis and skeletal fluorosis.
Over exploitation of ground water may lead to leaching of arsenic from soil and
rock sources and contaminate ground water. Chronic exposure to arsenic causes
black foot disease. It also causes diarrhea, peripheral neuritis, hyperkerotosis and
also lung and skin cancer.
Water borne diseases: Water borne diseases are those that are transmitted by contaminated
water. Water is a good carrier. Lot of disease causing bacteria will contaminate water.
Communicable disease that may be transmitted by water includes bacterial, viral and
protozoal infections.
(i) The disease caused by bacterial infection:
Typhoid fever
Paratyphoid
Bacillary dysentery
Cholera
Salmonellosis
Shigellosis.
(ii) The disease caused by viral infections:
Infectious hepatitis
Poliomyelitis
(iii)The disease caused by protozoal infections:
Amoebic dysentery
Giardiasis
Typhoid, paratyphoid, dysentery, gastroenteritis and cholera are transmitted by the fecal and
urinary discharges of sick persons and carriers. Through careless disposal of the discharges or
inadequate treatment of city sewage underground water may be contaminated to endanger
well water supplies or streams and lakes may be affected to contaminate surface supplies.
Prevention of water borne outbreaks of these diseases is primarily a matter of treating the
water by different methods.
Taste and odour: The taste of water may be bitter, salty, sour and sweet. Similarly water
may possess odour such as unpleasant, earthy, fishy, grassy, muddy, peaty and sweetish.
Taste and odour are closely related and these may be imparted to water by the presence of
dissolved gases such as H2S, CH4, CO2, O2 etc, combined with organic matter, mineral
substances like NaCl, iron compounds, carbonates and sulphates of other elements, and
phenol and other tarry or oily matter. It is evident that water to be supplied from a public
water supply scheme should not have any undesirable taste and odour.
Turbidity: Turbidity in water is caused by suspended matter, such as clay, silt, finely divided
organic and inorganic matter, soluble coloured organic compounds and plankton and other
microscopic organism. Turbidity is an important consideration in public water supplies for
three major reasons, such as aesthetic, filterability and disinfection. A turbid water has muddy
or cloudy appearance and it is aesthetically unattractive. Filtration of water is rendered more
difficult and costly with the increase in turbidity. In cases where turbidity is caused by
sewage solids the disinfection of public water supplies may not be effective because many of
the pathogenic organisms may be encased in the particles and protected from the disinfectant.
As such the water supplied to the consumers from a public water supply scheme should be
free from turbidity.
Total solids: The total solids present in water comprise total dissolved solids (TDS) and
suspended solids. Out of the two the dissolved solids usually predominate and these mainly
consist of inorganic salts and small amounts of organic matter. The suspended solids are
usually present in small amounts.
For drinking water the amount of total dissolved solids should not exceed 500 mg/l.
However, the amount total dissolved solids present in water in excess of 500 mg/l may be
tolerated but it should not exceed 1500 mg/l, which is the maximum permissible limit for the
total dissolved solids in water to be considered suitable for human consumption.
pH: pH is defined as the logarithm of the reciprocal of hydrogen ion (H+ ions) concentration.
The pH value of water is a measure of acidity and alkalinity of water.
The acidity in water is caused by the presence of mineral acids, free carbon dioxide, sulphates
of iron, aluminium etc. The alkalinity in water is caused by the presence of bicarbonates of
calcium and magnesium or by the presence of carbonates or hydroxides of sodium,
potassium, calcium and magnesium.
Figure shows the pH scale. The pH scale varies from 0 to 14 with 0 to 7 as acidic range, 7 as
neutral and 7 to 14 as alkaline range. It may be observed from the pH scale that when the
value of pH is equal to zero there is maximum acidity in water and when the value of pH is
equal to14 there is maximum alkalinity in water.
For drinking water the value pH should be between 7.0 and 8.5.However, water having pH
value less than 7.0 or more than 8.5 may also be accepted but the one having pH <6.5 or >9.2
is not suitable for human consumption and it should be rejected. Further from general
considerations the waters having lower values of pH (i.e., acidic waters) may cause
tuberculation and corrosion, while those waters having higher values of pH (i.e., alkaline
waters) may cause incrustation, sediment deposits, difficulties in chlorination, certain
physiological effects in human system, etc.
Hardness: Hardness is that characteristic of water that prevents the formation of sufficient
lather or foam with soap. The presence of bicarbonates, sulphates, chlorides and nitrates of
calcium and magnesium cause the hardness of water. The hardness caused by the presence of
carbonates and bicarbonates of calcium and magnesium is known as carbonate hardness. The
carbonate hardness is also known as temporary hardness because it can be removed by
boiling the water or by adding lime to the water.
On the other hand the hardness caused by the presence of sulphates, chlorides and nitrates of
calcium and magnesium is known as non-carbonate hardness. The non-carbonate hardness is
also known as permanent hardness because it cannot be removed by simply boiling. It
requires special treatment of water softening. The hardness of water is usually expressed in
mg/l. A scale of hardness showing different levels of hardness of water is as follows.
The excess hardness of water is undesirable because it causes more consumption of soap,
modifies colour if used in dyeing work, carbonate hardness produces scale in boilers, causes
corrosion and incrustation of pipes and makes food tasteless.
Chloride content: Chlorides are usually present in water in the form of sodium chloride
(common salt). These impart a salty taste to water. The chlorides may be added to water due
to solvent power of water dissolving salts from topsoils as well as from underground
formations, intrusion of seawater into fresh water in the coastal regions, disposal of industrial
and domestic wastes and human excreta into streams or rivers, etc. The presence of large
quantity of chlorides in water indicates its pollution due to sewage, minerals, etc. The
chloride concentrations of raw waters being used for public water supplies should therefore
be tested regularly, so as to detect any sudden increase in their chloride contents and
possibility of the organic pollution of the source of water.
Nitrates: The amount of nitrates in drinking water should not exceed 45 mg/l. The presence
of excess amount of nitrates in drinking water may adversely affect the health of infants,
causing a disease called ‘methemoglobinemia’ (commonly known as ‘blue baby disease’)
which may result in the death of the child in extreme cases.
Fluorides: Fluoride is a mineral cation that is beneficial and as well as harmful to human.
Desired concentration of fluorides in drinking water is 1 to 1.5 mg/l. A fluoride concentration
of less than 1 mg/l may be harmful and may cause ‘dental carries’ (tooth decay) due to
formation of excessive cavities in the teeth of young children during calcinations of
permanent teeth. Therefore a minimum amount of fluoride is beneficial to fight against
‘dental carries’ (tooth decay). On the other hand excessive concentration of fluorides (greater
than 1.5 mg/l) may be harmful, causing spotting and discolorations of teeth leading to a
disease called ‘dental fluorisis’. Consumption of excessive fluorides for long periods causes
crippling of bones, a disease called ‘skeletal fluorisis’. Hence fluoride is called as doubled
edged weapon.
Soil pollution:
Soil: Soil is one of the most significant ecological factors. It is an aggregation of
unconsolidated mineral and organic particles produced by physical and biological process. It
is a medium that supports the growth of plants, water, mineral supply and anchorage. Soil is
also defined, as a highly generalized structure of the shallow upper layers of land surface of
the earth, which by weathering of underlying rocks, intimate association with organic matter
and with living organisms, has become a suitable habitat for the living beings.
Sources of soil pollution:
Solid wastes
Industrial wastes
Agricultural practices
Radioactive wastes
Biological pollutants
Effects of soil pollution:
Industrial wastes consist of chemicals that are extremely toxic and hazardous to living
beings. Industries such as steel, fertilizers, pesticides, pulp and paper, refineries etc,
discharge suspended solids, oil and greases, solvents, heavy metal, organic and
inorganic pollutants, hazardous wastes and nondegradable compounds into soil. The
toxicants are transferred to organisms present in soil and enter food chain, which leads
to undesirable effects.
Discharge of metallic compounds (Hg, Zn, Cd, Cr, Na, K, Cu, As etc) effects the
beneficial microorganisms, worms and bacteria in the soil. Accumulation of these in
the soil for long period may kill the living organisms and contaminate water.
Utilization of sewage, septic tank effluent, sludge of municipal wastewater treatment
for irrigation and manure for longer period will decrease the agricultural production
and effects soil fertility.
Radiation from radionuclides affects the soil fertility. This intense radiation affects the
plant growth, production etc.
A particular sound may be a pleasure to one but may be a noise to another. Whether a given
sound is as pleasant as music or a noise depends on its loudness, duration, rhythm and the
mood of the person. Loudness is the most significant criterion, which makes sound into noise.
Noise is a physical form of pollution and its effects are more on the receiver (human). The
noise may be classified by its occurrence in time as, steady state noise (continuous), impact
noise (single impulse of short duration at regular or irregular intervals) and intermediate
noise.
Damage to heart, brain and liver has been reported in animals due to prolonged noise
pollution.
(c) Other effects: Noise interferes with our conversation, disturb concentration and
upsets mood.
Control of noise pollution: Noise pollution can be minimized by the following measures.
Reduction at source: The best method of controlling noise pollution is to reduce the
noise at the source itself. Measures should be planned such that it can generate less
noise. The measures are installing noisy machines in sound proof chambers, covering
the noise producing machines with sound absorbing materials, use of silencer to
control noise from ducts, automobiles etc. Providing vibrating machine by vibration
damping ( rubber, neoprene cock etc), use quieter machines(designing & fabricating)
to replace noisy ones, better lubrication methods and maintenance of machines.
Reduction at receivers end: The workers working in the area of noisy machines
should be provided with ear protection aids such as ear-muffs, head phones, ear plugs
etc. By using these aids noise can be controlled effectively.
Acoustic zoning: A rational town planning can help to reduce outdoor noise
pollution. A city or town can be divided into residential area, industrial area, bus
terminals area, aerodromes area, railway station area, hospital area etc so that
sufficient distance can be maintained between the noisy area and residential areas. A
silence zone can be maintained near residential areas, hospital area and educational
institution.
Problem 2: If the concentration of OH- in a water solution is 0.008, find the value of pH.
Solution:
We know that
Problem 3: In a water treatment plant, the pH value of entering and leaving water is 6.5 and
8.5 respectively. Assuming linear variation of pH with time, calculate the average pH value
of water.
Solution:
= 1.596 x 10-7
Solution:
Only divalent cat-ion causes hardness.
Sl.No. Divalent Cat-ion Concentration (mg/l) Eq.wt of Hardness
Cat-ion (mg/l)
1 Ca2+ 50 20 (50x 50)/20 = 125.00
2 Mg2+ 16 12.2 (16 x 50)/12.2 =65.57
Total hardness in mg/l 190.57 Ans
Problem 5:- An analysis of a sample of water with pH 7.5 has produced the following
concentrations(mg/L). Calculate the total hardness of water. Assume Equivalent weight. of
CaCO3 as 50, Mg2+ as 12.2 and Ca2+ as 20
Ions Ca2+ Mg2+ Na+ k+
Concentration 80 30 72 6
(mg/l)
Solution:
Only divalent cat-ion causes hardness.
Sl.No. Divalent Cat-ion Concentration Eq.wt of Hardness
(mg/l) Cat-ion (mg/l)
1 Ca2+ 80 20 (80x 50)/20 = 200
2 Mg2+ 30 12.2 (30 x 50)/12.2 =122.95
Total hardness in mg/l 322.95 Ans
Problem 6:-A River water was proposed as the raw water suitable for a city. Chemical
analysis of the water indicated the constituents given below. Calculate the hardness of water.
Assume Eq wt. of CaCO3 as 50, Mg2+ as 12.2 and Ca2+ as 20
Ions Zn- Na+ Mg2+ Ca2+ Cl-
Concentration (mg/l) 4 18 16 50 68
Solution:
Only divalent cat-ion causes hardness.
Sl.No. Divalent Cat-ion Concentration (mg/l) Eq.wt of Hardness
Cat-ion (mg/l)
1 Ca2+ 50 20 (50x 50)/20 = 125.00
2 Mg2+ 16 12.2 (16 x 50)/12.2 =65.57
Total hardness in mg/l 190.57Ans
Problem 7: Calculate the hardness of the water sample with the following analysis.
Assume Eq wt. of CaCO3 as 50, Mg++ as 12.2, Ca++ as 20 and Sr++ as 43.80.
Ions Sr++ Na+ Mg++ Cl- SO4- - Ca++
Concentration 03 20 12 54 15 15
(mg/l)
Solution:
Only divalent cat-ion causes hardness.
Sl.No. Divalent Cat-ion Concentration (mg/l) Eq.wt of Hardness
Cat-ion (mg/l)
1 Ca++ 15 20 (15 x 50)/20 = 37.5
2 Mg++ 12 12.2 (12 x 50)/12.2 = 49.2
3 Sr++ 03 43.8 (3 x 50)/43.8 = 3.4
Total hardness in mg/l 90.1 Ans
Problem 8:-A lake water has been proposed as a raw water source for a town. Chemical
analysis of the water indicates the constituents given below. Calculate the total hardness of
water. Assume Eq wt. of CaCO3 as 50.
Ions Na+ Cl- Sr2+ Mg2+ Ca2+ K+
Eq. Wt. 23 35.5 43.8 12.2 20.0 40.0
Concentration 10 52 14 40 72 40
(mg/l)
Solution:
Only divalent cat-ion causes hardness.
Sl.No. Divalent Cat-ion Concentration Eq.wt of Hardness(mg/l)
(mg/l) Cat-ion
1 Ca2+ 72 20 (72x 50)/20 = 180
2 Mg2+ 40 12.2 (40 x 50)/12.2 =163.9
3 Sr2 14 43.8 (14 x 50)/43.8 =15.98
Total hardness in mg/l 359.88 Ans
Equivalent noise level (Leq):- Equivalent noise level also called the equivalent continuous
equal energy level is the statistical value of sound pressure level that can be equated to any
fluctuating noise level.
Eg. A sound of 100 dB lasting for 10 minutes, followed by a sound of 110 dB for the next 80
minutes and then followed by a sound of 120 dB for the next 5 minutes, will compose a
fluctuating noise level, which can be represented by a certain dB value which is indicative of
producing the same effect over the entire time period of 10+80+5 = 95 minutes, as the
original fluctuating noise.
Leq is thus defined as the constant noise level, which over a given time, expands the same
amount of energy, as is expanded by the fluctuating levels over the same time. This value is
expressed by the equation:
Problem 9:- A sound of 80 dB lasted for 10 minutes, followed by a sound of 60 dB lasted for
next 80 minute and then followed by a sound of 100 dB lasting for the next 5 minutes will
compose a fluctuating noise level. Calculate the equivalent noise level which is indicative of
producing the same effect over the entire time period of 95 minutes.
Solution:
We know that Equivalent noise level (Leq) is given by equation