Techno-Economic Evaluation of Waste Oil Rerefining
Techno-Economic Evaluation of Waste Oil Rerefining
economics
ELSEVIER                            Int. J. Production Economics 42 (1995) 263-273
Abstract
   This paper discusses the secondary use of used automotive lubricating oils. Current technologies for processing
waste lube oil into new lubricants is outlined and the performance features of these products are compared with that
of virgin materials. Process technology of Meinken and Mohawk were selected for techno-economic evaluation. A
plant size of 50 000 TPA waste oil re-refining was considered for economic study of these processes. The estimated
production cost for Meinken process was found to be $348.8 per ton and for Mohawk process, assuming hydrogen
supply to be made available from adjacent refinery, it was estimated to be $198.4 per ton. Meinken process appears
to be more popular but profitability was found to be lower than Mohawk. Mohawk process is limited due to loca-
tion factor which requires hydrogen from an adjacent petrochemical plant.
performance    features of these products are com-                               seasonal basis. The inspection data in Table 1 sum-
pared with that of virgin materials.                                             marizes the typical analytical         results for 20 sam-
   In many countries the rerefining of the used oils                             ples collected        during    winter   and summer.      A
has become an important         industry. The objective                          comparison       of physical and chemical properties of
of recovering     high-quality    raffinates    is attained                      these samples (Table 1) showed few significant
through the use of widely differing techniques. The                              variations. The water content and fuel dilution can
processes concerned       can be classified according                            significantly     affect the viscosity and gravity and
to the chemical or physical method of used-oil                                   this should be considered           in drawing inferences
pretreatment     selected.     Process     technology      of                    based upon the properties.              The data provide
Meinken, Mohawk and KTI were selected for our                                    insight into the extent of contamination         of each oil
study. Meinken process is based on chemical pre-                                 and there are some striking similarities in the con-
treatment;    both Mohawk          and KTI processes                             taminant      levels. Pentane     insolubles   varied from
employ physical methods involving distillation and                               0.05 to 0.80 wt%. Water content were fairly con-
eliminates the use of sulfuric acid, thus providing                              sistent in their values from 0.5 to 2.0 ~01%. Fuel
a facility of safer operation than Meinken.                                      dilution varied from 0.6 to 5.0%.
                                                                                     The elemental       analysis (Table 2) was done to
                                                                                 determine Fe, Cr, Cu, Mg, Ni, Pb, Zn, Ca and Ba
2. Quality assessment          of available used oil                             in the used oils. These elements were selected as
                                                                                 indicators     for assessing the presence of oil addi-
   A wide variety of samples of used oil were col-                               tives, mechanical         wear and chemical corrosion.
lected from areas in the eastern region of Saudi                                 Lead is mostly derived from lead in gasoline. The
Arabia. The samples were evaluated on the basis                                  elemental analysis indicated that the principal con-
of physical and chemical properties to determine                                 taminates are lead, iron, zinc, magnesium           and cal-
any significant variations either on geographical or                             cium. Also, the data indicate an increase in wear
Table 1
Inspection   data for used lubricating      oils
Sample       Sp. gravity     Viscosity,     SUS         Viscosity     Carbon       BS&W       Flash pt    Pentane      TAN           Fuel
No.          60/60”F                                    index         residue      (VOM)      (“F)        insoluble    mg KOH/g      dilution
                             100°F          210°F                     wt’%,                               (wt%)                      (wt%)
2111         0.9030          622            77.7        122           I .25        < 0.5      385         0.29         2.10           1.1
2112         0.9020          628            78.7        124           I .05          0.5      310         0.39         2.16          1.7
2113         0.9080          657            78.9        119           1.26         < 0.5      180         0.78         3.20          5.0
2114         0.9075          721            84.7        124           1.21         < 0.5      340         0.19         2.10          1.6
2115         0.9035          634            78.6        123           I .22          0.8      300         0.21         2.20          2.6
2116         0.9030          635            78.3        122           1.26           0.6      310         0.25         2.45          I .4
2117         0.9100          761            84.3        116           1.17           2.0      370         0.42         1.75          1.2
2118         0.9020          657            82.3        130           1.14         < 0.5      340         0.10         1.10          1.5
2119         0.9065          691            78.6        119           1.29         < 0.5      345         0.15         I .50         I.5
2120         0.9080          696            82.4        122           1.28         < 0.5      350         0.24         2.72          I .4
2252         0.9032          568            75.9        129           1.12         < 0.5      305         0.10         0.95          1.8
2253         0.9067          658            80.1        123           1.20         < 0.5      355         0.12         0.95          1.2
2254         0.9062          650            78.5        119           1.06         < 0.5      330         0.09         I .20         I .6
2255         0.9057          616            76.6        120           0.95         < 0.5      340         0.09         0.95          I .4
2256         0.9047          646            72.2        100           I .35          0.8      180         0.13         1.30          4.2
2257         0.9032          685            79.4        118           0.85         < 0.5      315         0.08         0.84          1.7
2258         0.9057          550            73.6        126           0.78         < 0.5      335         0.08         0.89          1.6
2259         0.9047          561            72.8        123           0.95         < 0.5      315         0.09         I.15          1.7
2260         0.9050          655            77.0        113           1.10         < 0.5      380         0.11         1.12          0.9
2261         0.9040          659            74.0        119           1.06         < 0.5      300         0.11         1.15          1.9
                                       M. F. Ali et al. /ht.   J. Production   Economics   42 (1995) 263-273                           265
Table 2
Trace elements   in used oil samples    (ppm)
Sample No. Fe Cr CU Mg Ni Pb Zn Ca Ba
                                                                                                                     1
                                                                                                                  MOHAWK
                                                                                                               PRETREATMENT
DEHYDFlATK)N 6 1
DEHYDRATION
DEFUELlNG
                                                                                                                                            FUEL
                                                                                                                     rl
EVAPORATION
                                                                                                                                              1
                                                                                    HYDROGEN                                                RESIDUE
                                                                                                                     1
                                                                                                           HYDROTREATMENT
                                                                  t
                                                                 WASTE
GASTT ,
Science and Technology         Co. (Pittsburgh,        PA) has               The next step is hydrofinishing       of lube oil.
developed a new rerefining process for all types of                          Hydrogen rich gas is mixed with the oil and heated
waste lubricating    oils [3].                                               before passing through the reactor. The treated oil
   The KTI waste lube oil rerefining                    process              is then steam stripped or fractionated    into cuts
involves a series of proprietary           engineering     tech-             using a vacuum      in order to obtain    the right
nologies that affords high economic returns with-                            specification.
out resulting    in environmental          loads. The main
features of the KTI process include : (a) high recov-
ery yield up to 95% of the contained              lube oil; (b)              4. Economic         evaluation
excellent product      quality;      (c) flexible operation
with wide turndown capability; (d) no requirement                            4.1. Capital investment
for discharging     chemicals or treating agents; (e)
absence of non commercial              by-products;     and (f)                 The total fixed capital investment         to process
reliable, inexpensive treatment of waste water con-                          50000 TPA of waste oil was obtained                  from
tained in the wasted lube oil.                                               Meinken [l] and Mohawk [2] in 1991. Location
    The important     steps of this process are shown                        factor of 1.25 was used to estimate the fixed capi-
in Fig. 3. Atmospheric        distillation    removes water                  tal costs for Saudi location [4]. Table 3 lists the
and gasoline.     Vacuum       distillation     using special                total fixed capital investment       estimated for both
wiped film evaporators          separates      lube oil from                 the technologies. Working capital for the rerefinery
heavy residue containing         metals and asphaltenes.                     was estimated by itemizing the production            costs
                                                                             components     [5]. It varies with changes in raw mate-
                                                                             rial prices, product selling price and so on.
                                                                                 Economic evaluation       of KTI process could not
                                                                             be carried out because of non-availability        of com-
                                                                             plete cost data.
                          DEWATERING
                                                                                 Details of the cost-estimation        procedure     are
                                                                             given in Appendix A.
                                                                             Table 3
                                                                             Capital investment      of 50 000 TPA waste oil rerefining    plant in
includes $90.0 per ton for shipping. Local price was                        Table 5
used for sulfuric acid. Collection cost of waste oil                        Raw materials,        utilities and manpower     costs in Saudi Arabia
in Jeddah [I], Saudi Arabia               was estimated      as
                                                                            Item                                                      Cost ($/unit)
$53.52 per ton. By-product(gas            oil) price $110 per
ton was taken from Petroleum                  Economist,    for             RUN, Muirrids
Caltex, Bahrain location [7]. By-product               asphalt              Waste oil, ton                                                53.5
                                                                            Sulfuric Acid, ton                                           160
price $130 per ton was taken from CMR [6], but
                                                                            Activated sludge, ton                                        673
reduced by 15% as it needs some more processing.                            Lime, ton                                                    316
If the asphalt residue cannot be sold at interna-                           Ammonia water, (23%) ton                                     387
tional price due to low demand in this region, its                          Catalyst, kg                                                   3.41
price has to be further reduced. For economic                               Utililirs
analysis purposes, the price of asphalt residue was                         Fuel oil, ton                                                110
still lowered by 50”/0. This is an approximation           and              Cooling water, ton                                             0.019
the price used finally in the calculations          is $55 per              Process water, ton                                             0.803
                                                                            Electricity, ton                                               0.015
ton of asphalt residue.                                                     Hydrogen,    ton                                              65
    The raw materials,         utilities,    and manpower                   Steam, ton                                                     4.63
requirements     are given in Table 4 which were
                                                                            Manpower
obtained     from Meinken          [1] and Mohawk           [8].            One man year ($/yr)                                       18000
Table 5 lists raw materials, utilities and manpower
costs estimated for Saudi Arabian location [2,9].                           Source:      [I. 2, 3,9].
Natural gas price was taken as $0.50 per million
Btu [4] and the benefit of low price of natural gas
is reflected in utilities costs such as electricity and                    Saudi Arabia because it is produced from desali-
steam. However,         process water is expensive           in            nation plants.
                                                                              Operating costs which includes operating labor,
                                                                           supervision,   maintenance     and repairs and indirect
Table 4
Raw materials    utilities and manpower        requirements   per ton of   costs which includes overheads, storage and insur-
product                                                                    ance, and general expenses were estimated accord-
                                                                           ing to the standard procedures [lo-121.
Component                              Meinken                Mohawk
                                                                              Summation     of all direct costs, indirect costs and
                                       process                process
                                                                           general expenses results in a production      cost. Table
RUN, mureriuis                                                             6 illustrates production    cost of rerefining waste oil
Waste oil, ton                             1.27                 1.34       resulted from the two technologies.        The estimated
Sulfuric acid, ton                         0.095                _
                                                                           production    cost for Meinken process was $348.8
Activated clay, ton                        0.049
Lime, ton                                  0.214                _          per ton and for Mohawk process it is $198.4 per
Ammonia water, ton (23%)                   0.008                _          ton of rerefined oil.
Catalyst, kg                                                    3.76
31’-pFYdKY,~
                                                                            Table 6
Gas oil, ton                            -0.060                -0.135
                                           _                                Production       cost data
Asphalt                                                       -0.176
   For Meinken process the raw materials cost is                            were performed for 15 % lower and 15 %I higher raw
about 54% of the production         cost. Utilities is                      materials prices than prevalent in September 1991.
3.0%, operating cost is 17.2%, total indirect costs                            Since the rerefined oil is not segregated             into
is 20.4% and general expenses about 7.4”/0 of the                           different neutral oils and bright stock, following
total product cost. The share of raw materials cost                         typical composition         was assumed:    10% 300 SN,
in the total product cost is dominant.                                      80% 500 SN and 10% bright stock. Based on
   In case of Mohawk process the raw materials                              LUBREF,         Jeddah [13] base oil prices of various
cost is about 42.7% of the total product cost. By-                          grades, an estimated selling price of $415.60 per
products are 12.40/o, utilities are 8.8%, operating                         ton is used in the financial analysis.
cost 23.0%, total indirect costs are 25.4% and gen-                            The year-by-year       cash flow analysis for interna-
eral expenses are 12.5% of the total product cost.                          tional     raw     materials     prices  (base     case)    in
So, the production    cost will be sensitive to raw                         September        199 1 and for 15% lower and 15%
materials prices and sensitivity   analysis was per-                        higher raw materials prices have been carried out.
formed for different raw materials price.                                   The results of cash flow analysis are summarized
                                                                            in Table 8. Fig. 4 shows the effect of raw materi-
                                                                            als prices on internal rate of return (IRR).
5. Profitability       analysis                                                The total fixed capital investment          is very high
                                                                            for Meinken process ($28.8 million) as compared
   The profitability   of an industrial opportunity      is                 to Mohawk process ($17.7 million). The working
a function    of major economic variables such as                           capital amounts to a high value of 5.0 million US
product selling price, raw materials prices, capital                        Dollars for Meinken as compared to relatively low
investment,   energy prices and so on. Year-by-year                         value of 3.0 million Dollars for Mohawk.
cash flow analysis      has been carried out using                              The payback period (PBP) and break-even-point
assumptions    and financial arrangements      described                    (BEP) for Meinken Process are high as expected
in Table 7.                                                                 compared to Mohawk process, which are 8.16 yr
   From the analysis of production       costs (Table 6)                    and 53.8% of the full production.            The PBP for
components,     it is obvious that the raw materials                        Mohawk is 1.40 yr, and BEP is 28 %. The IRR for
cost is the dominant     item. So, sensitivity analyses                     Meinken and Mohawk are estimated to be 11.24%
                                                                            and 45.36%. Thus, the total positive annual cash
Table 7
                                                                            flow for Mohawk            process appears to be more
Basis of financial   calculations                                           attractive      than   that for Meinken.          The high
                                                                            profitabilities    of Mohawk process are due to lower
Item                                Calculated   basis                      capital costs as a result of (i) excluding hydrogen
                                                                            plant    and (ii) possibly         due to relatively      not
Project life                        20 yr
Construction  period                3 yr
Depreciation  method                Straight line                           Table 8
Salvage value                       Zero                                    Profitability   of rerefining   50000 TPA waste oil in Saudi Arabia
Equity/SIDF   loan                  50% each                                (I000 S)
SIDF loan fee                       3%
Loan payment                        7 equal instalments     starting                                                    Meinken       Mohawk
                                    2 years after plant    start-up                                                     process       process
Tax rate                            2.5%
Inflation                           0.0%                                    Total fixed capital                         28 750         17713
Capital expenditure:                                                        Working capital                               4999            3111
   1st year                         20% of fixed capital                    SIDF loan                                   16 875         I I 356
   2nd year                         45% of fixed capital                    Annual variable expenses                      7587           2873
   3rd year                         35% of fixed capital     plus           Annual fixed expenses                         4746            3852
                                    working capital                         Annual sales                                16410          15377
Capacity utilization:                                                       Payback period (yr)                               8.2             1.4
  1st year                          60%                                     Break-even-point    (‘XI capacity)               53.8           28.7
  2nd and subsequent       years    100%                                    IRR (%/yr)                                       11.2           45.4
270                                M.F. Ali et al. IInt. J. Prochtion   Economics   42 (1995) 263-273
                                                                         Acknowledgements
6. Conclusions
                                                                            The investigators    wish to acknowledge      King
   (1) The present yearly consumption          of automo-                Abdul Aziz City for Science and Technology
tive lubricating   oils have exceeded 80 million gal-                    (KACST) for funding this Research Project (AR-
lons in Saudi Arabia. Most of this oil is wasted                         10-60). The facilities and support      provided    by
because no suitable refining industry exists in the                      the Research Institute and Oil Testing Center of
country to utilize the waste lube oils. Therefore,                       King Fahd University of Petroleum and Minerals
rerefining of waste lube oil warrants the country’s                      (KFUPM)     is also gratefully acknowledged.
urgent attention     in order to solve the increasing
menace of environmental        pollution.
   (2) Five patented       rerefining     processes     were             Appendix A.       Cost estimation     procedure
duplicated on a laboratory       bench scale to produce
adequate samples of lube oils for comparison            with             A.1.   Investment    costs
new (virgin)     oils. The study proved           that the
rerefined oils were in general comparable           in qual-                Fixed upital: The total fixed capital investment
ity to the virgin base oils indicating that the com-                     to build a waste lube oil rerefining plant in Saudi
                                M.F. Ali et al./Int.   J. Production   Economics    42 (1995) 263-273                                       211
assets is usually fixed at 1% of the total fixed-                          9. the SIDF charges no interest but a fee of 3%
capital cost. All plant equipment,        buildings   and                      of the total loan is deducted from the loan;
utility and service facilities were depreciated      over                 10. the disbursement        of the loan is based on 50%
15 y using straight-line    depreciation   at an annual                        of the actual expenditure        of the capital cost;
rate of 6.67%. An interest rate of 10% was applied                        11. repayment of the SIDF loan starts in the third
to the working      capital. Three percent fee was                             year of production,      since a 2 yr grace period is
applied to Saudi Industrial         Development     Fund                       allowed;
(SIDF) loan. The SIDF loan was considered to be                           12. the repayment       is effected over 7 yr with equal
50% of the total investment       cost.                                        annual repayments         (actually      14 equal semi-
    The basis for estimation of these components        of                     annual repayments);
indirect costs is summarized      in Table 10.                            13. the fixed capital expenditure           is assumed to be
                                                                               20% for the first year, 45 % for the second year,
A.2.3. General expenses                                                        and 35% for the third year. The working cap-
    The general expenses of a plant include costs for                          ital expenditure     occurs in the third year; and
top-management        and administrative     activities, dis-             14. production      capacities are assumed to be 60%
tribution    and marketing     costs. In this study only                       for the first year, 80% for the second year, and
administrative     costs at 25% of plant overhead and                          100% for the years remaining.
distribution    and sales cost at 5% of product value                        Analysis methods: The common contemporary
                                                                          methods of estimating         profitabilities    : discounted
(excluding     by-products    credits) were taken into
                                                                          cash flow rate of return (DCFRR) and the net pre-
account in general expenses.
                                                                          sent value      (NPV)      were used in this study.
    The basis of administration,       distributions,    and
                                                                          Comparisons      of projects based on time are the pay-
sale costs is given in Table 10.
                                                                          back period (PBP) which is defined as the number
                                                                          of years required after start up to recover the
                                                                          undiscounted     total fixed capital.
A.3. Financial    evaluation
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      Services, London, UK.                                                        Process Design and Economics, Wiley, New York.
[IO] Bechtel,   L.R., 1960. Estimate    working     capital   needs.          [13] LUBEREF,      1991. Private  Communication,       Petromin
      Chem. Eng., 67(4): 127.                                                      Lubricating   Oil Refining   Company,     Jeddah,     Saudi
[l l] Axtell, O., 1986. Economic   Evaluation    in the Chemical                   Arabia.
      Process Industries. Wiley, New York.