ASCC (NZ) Pty.
Ltd
MSDS Summary Information
For further information : Please refer to the ASCC SDS
PRODUCT:
Issue: September, 2008
UN No. -
MEG
Other Names: Ethylene glycol, 1,2
Ethanediol, 1,2-Dihydroxyethane,
Monoethylene glycol
Dangerous Goods Class: Subsidiary Risk: -
Uses:
Coolant and antifreeze;
heat-transfer agent; brake fluids; solvent;
humectant
Hazardous Nature:
Exposure Standards:
Environmental Standards:
Packing Group: III
HAZCHEM:
This product is classified as hazardous under HSNO criteria
TWA ceiling 127 mg/m3 (50 ppm)
STEL : Not available
EEL : Not available
Physical Characteristics (Typical)
Appearance
Boiling Point/Range (0C)
Flashpoint (0C)
Specific gravity/Density (g/ml @ 150C
Chemical Stability
Reactivity
Section 9 of SDS
Clear, colourless, slightly viscous liquid
197
110
1.12
Stable at room temperature and pressure
Strong oxidising agents, strong acids and
bases, perchloric acid, chromyl chloride
Product Ingredients
Ethylene glycol
107-21-1
For further ingredients information, please refer to the SDS
Section 3 of SDS
100
Hazardous Statements
Section 2 of SDS
H304 May be harmful if swallowed
H320 Causes eye irritation
H362 Causes damage to organs through
prolonged or repeated exposure
H433 Harmful to terrestrial vertebrates
For further Hazard and Precautionary information, please refer to the SDS
Dangerous Goods
Hazardous Substance
HSNO Act
Products that are classified as Dangerous for Storage and Transport: these products are allocated a UN
No., with accompanying Class, Pack Group, and Sub. Risk, if required. Products that do not have a
specific description under the code, but have low flash points, or such, must be classified under their most
significant risk, e.g. Flammable Goods N.O.S. (Not otherwise specified), UN 1993
Products are considered to be Hazardous if they pose an intrinsic risk to human or environmental health,
such as mutagens (able to change DNA), teratogens (able to result in birth defects), carcinogens (able to
generate cell abnormalities), etc.
Hazardous Substance and New Organisms Act limits and manages the transaction of hazardous
substances in New Zealand and her territories.
SUMMARY INFORMATION ONLY
Safety Data Sheet
MEG
1. IDENTIFICATION
Product Name:
Other Names:
Chemical Family:
Molecular Formula:
Recommended Use:
Supplier:
Address:
Telephone:
Emergency phone:
All other inquiries:
MEG
Ethylene glycol , 1,2 Ethandiol, 1,2-Dihroxyethane,
Monoethylene glycol
Glycol
C2H6CO2
Coolant and antifreeze; heat-transfer agent; brake fluid;
solvent; humectant
Australasian Solvents and Chemicals Company Pty. Ltd
PO Box 8340, Symonds Street, Auckland, N.Z.
0800 754 767
CHEMCALL: 0800 243 622
0800 754 767
2. HAZARDS IDENTIFICATION
Product is classified as hazardous according to Schedules 1 to 6 of the Hazardous
Substances (Minimum Degrees of Hazard) Regulations 2001 of the HSNO Act, 1996.
HSNO Classifications:
Signal word:
Hazard Statements :
6.1D, 6.4A, 6.9A, 9.3C
DANGER
H304 May be harmful if swallowed
H320 Causes eye irritation
H433 Harmful to terrestrial vertebrates
H363 Causes damage to organs through
prolonged or repeated exposure
Precaution Statements :
P102 Keep out of reach of children
P103 Read label before use
P273 Avoid release to environment
P260 Do not breathe mist, vapours or spray
P264 Wash hands thoroughly after using
P270 Do not eat, drink or smoke when using this product
3. COMPOSITION : Information on Ingredients
Chemical Ingredient
Ethylene glycol
CAS No.
107-21-1
Proportion (% w/w)
100
4. FIRST AID MEASURES
For advice, contact National Poison Centre (Phone New Zealand: 0800 764 766)
or a doctor.
Swallowed
Rinse mouth with water. Do not induce vomiting. Give plenty of water to drink if person
is conscious. If vomiting occurs, give more water to drink. Seek medical advice.
Skin Contact
If skin or hair contact occurs, remove contaminated clothing and flush skin and
hair with running water. If irritation occurs seek medical advice. Wash
contaminated clothing before re-use.
Date of Issue: 3 September, 2008
Date of Review: September, 2013
page 2 of 8
Emergency Number: CHEMCALL: 0800 243 622
MEG
Safety Data Sheet
Eye Contact
Hold eyelids apart and flush the eye continuously with running water. Continue flushing
for at least 15 minutes. Get medical attention.
Inhalation
Move the victim to fresh air immediately and keep at rest and warm in a position
comfortable for breathing. Begin artificial respiration if breathing has stopped. Get
immediate medical attention.
First Aid facilities
Provide eye baths and safety showers close to areas where splashing may occur.
Medical Attention
Treat according to symptoms. Ethylene glycol can cause central nervous system
depression and metabolic acidosis. Consider management actions of :gastric
decontamination, correction of metabolic acidosis with bicarbonate, inhibition of ethylene
glycol metabolism by giving ethanol )100 mg/dL or higher) or fomepizole as antidotes
and haemodialysis to remove ethylene glycol and its major metabolite glycolic acid.
5. FIRE FIGHTING MEASURES
Suitable extinguishing media :
For large fires use water fog, fine water spray or foam. Do not use water jets. For small
fires use foam, dry chemical, carbon dioxide or water spray.
Hazards from combustion products:
Combustible liquid. On burning will emit toxic fumes including carbon dioxide and carbon
monoxide.
Precautions for fire fighters and special protective equipment:
Full protective clothing and self-contained breathing apparatus.
Heating can cause expansion or decomposition leading to violent rupture of containers.
Keep containers cool with water spray. If safe to do so, remove containers from path of
fire.
Hazchem Code: None assigned
6. ACCIDENTAL RELEASE MEASURES
Emergency Procedures:
Slippery when spilt. Avoid accidents, clean up immediately. Do not touch or walk through
spilled material. Wear protective equipment to prevent skin and eye contamination and
inhalation of vapours.
Date of Issue: 3 September, 2008
Date of Review: September, 2013
page 3 of 8
Emergency Number: CHEMCALL: 0800 243 622
MEG
Safety Data Sheet
Methods and materials for containment:
For small spills, prevent run off into drains or waterways. Use absorbent material (soil,
sand or other inert material). Collect and seal in properly labeled drums for disposal.
Wash area down with excess water to remove residual material and any slip hazard.
Major Land Spill
Prevent liquid from entering sewers, watercourses, or drains.
Keep the public away from the area.
Shut off the source of the spill if possible and safe to do so.
Remove or isolate sources of ignition.
Advise authorities if substance has entered a watercourse or sewer
or has contaminated soil or vegetation.
Take measures to minimize the effect on the ground water.
Contain the spilled liquid with sand or earth or other inert material.
Recover by pumping into labeled drums or with a suitable absorbent material.
Consult an expert on disposal of recovered material and ensure
conformity to local disposal regulations.
See First Aid Measures and Stability and Reactivity
Major Water Spill
Notify the port or relevant authority and keep the public away from the
area.
Shut off the source of the spill if possible and safe to do so.
Confine the spill if possible.
Monitor spill area in consultation with relevant authority.
Consult an expert on disposal of any recovered material and ensure
conformity to local disposal regulations.
See First Aid Measures and Stability and Reactivity.
7. HANDLING AND STORAGE
Precautions for safe handling:
Avoid eye contact and repeated or prolonged skin contact. Avoid inhaling vapours or
spray mists. Use local exhaust ventilation. Always wash hands before smoking, eating,
drinking or using the toilet. Wash contaminated clothing and other protective equipment
before storage or re-use. Do not dispose of material to sewers or waterways.
Conditions for safe storage:
Store in a cool place out of direct sunlight. Store away from oxidizing agents and
foodstuffs. Keep containers closed at all times. Check regularly for leaks.
Incompatible materials:
None identified.
Chemical incompatibility with strong oxidising agents, strong acids and bases, perchloric
acid, chromyl chloride
Date of Issue: 3 September, 2008
Date of Review: September, 2013
page 4 of 8
Emergency Number: CHEMCALL: 0800 243 622
Safety Data Sheet
MEG
8. EXPOSURE CONTROLS : PERSONAL PROTECTION
Health Exposure Standards:
The following Tolerable Exposure Limit (TEL) Workplace Exposure Standards (WES),
2002 have been set by the Occupational Safety and Health Service , NZ Department of
Labour for components in this substance:
WES-TWA (ceiling)
WES-STEL
Ethylene glycol, vapour & mist
50 ppm, 127 kg/m3
Biological limit values :
None established
Engineering Controls:
Ventilation:
Ensure ventilation is adequate to maintain air concentrations below the TWA ceiling limit.
If used at elevated temperatures or as aerosol, mist or spray, use with local exhaust
ventilation or while using respirator.
Personal Protective Equipment:
Respiratory Protection: Where an inhalation risk exists, wear a filter respirator suitable
for organic vapours/particulates meeting the requirements of AS/NZS 1715 and AS/NZS
1716.
Eye Protection: Always use safety glasses or a face shield when handling this product.
Skin/ Body Protection: Always wear long sleeves and long trousers or coveralls,
and enclosed footwear or safety boots when handling this product. It is recommended
that chemical resistant gloves, e.g. nitrile, neoprene or natural rubber, be worn when
handling this product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Property
Appearance
Boiling Point/Range
Melting Point
Autoignition Temperature
Flash Point
Density @ 200C
Vapour Pressure @ 250C
Relative Vapour Density
Autoignition Temperature
Explosive Limits in Air
Viscosity @ 200C
Volatiles
Solubility in Water
Unit of measurement
0
C
0
C
0
C
0
C
g/ml
kPa
Air = 1
0
C
%
cP
%
% w/w
Typical value
Clear, colourless liquid
197
-13
412
110
1.12
0.092
2.14
412
3.2 15.3
21
Nil
Miscible
The values listed are indicative of this products physical and chemical properties.
For a full product specification, please consult the Product Data Sheet.
Date of Issue: 3 September, 2008
Date of Review: September, 2013
page 5 of 8
Emergency Number: CHEMCALL: 0800 243 622
Safety Data Sheet
MEG
10. STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal conditions of use.
Conditions to avoid:
Excessive heat will lead to accelerated oxidative
degradation.
Hazardous decomposition products: No decomposition products except on burning.
See "Fire Fighting Measures".
Hazardous reactions:
Strong oxidizing agents, strong alkalis, strong acids,
perchloric acid, chromyl chloride
11. TOXICOLOGICAL INFORMATION
Acute Effects
Ingestion
Symptoms following large dose (> 100 mL) are those of alcohol intoxication (but
without odour of ethanol) which progresses to vomiting, headache, stupor,
convulsions and unconsciousness. Respiratory system may be affected 12 -24
hours after ingestion. Symptoms may include hyperventilation and rapid shallow
breathing. From 24 to 72 hours after exposure, the patient may experience a
decrease in urine output, flank pain progressing to renal failure which may be
permanent. Death may occur from respiratory failure or pulmonary oedema.
Eye Contact
Eye irritant.
Skin Contact
May cause skin irritation. Prolonged or repeated exposure may cause defatting resulting
in dryness or cracking of the skin (irritant contact dermatitis). Can be absorbed through
skin but not readily absorbed in toxic amounts. Note symptoms described under
Ingestion heading.
Inhalation
The inhalation of vapours (from heating), mists or spray, can produce respiratory
irritation and may result in headaches, dizziness and possible nausea.
Chronic Effects
Exposure effects the central nervous system and may aggravate existing kidney
disorders. Animal studies have shown that long term repeated exposure to high doses
of ethylene glycol in the diet causes kidney injury.
High doses of ethylene glycol in rats and mice have resulted in reproductive and
developmental toxicity following exposure by oral and inhalation (respirable aerosol)
routes. However ethylene glycol is not classified as a reproductive/development toxicant
according to HSNO criteria. There is no evidence of mutagenic or carcinogenic effects.
Date of Issue: 3 September, 2008
Date of Review: September, 2013
page 6 of 8
Emergency Number: CHEMCALL: 0800 243 622
Safety Data Sheet
MEG
Toxicological Information:
Oral LD50 cat
1650 mg/kg
Oral LD50 rat
5890 mg/kg
Dermal LD50 rabbit
9530 mg/kg
12. ECOLOGICAL INFORMATION
Ecotoxicity:
Aquatic toxicity:
Not identified as hazardous to aquatic organisms.
Persistence/degradability: Expected to be readily biodegradable.
Mobility: No data available.
Environmental Exposure Standards:
EEL (WATER):
Not set
EEL (SOIL)
EEL (SEDIMENTS)
Not set
Not set
13. DISPOSAL CONSIDERATIONS
Disposal Methods:
Empty packaging should be taken for recycling, recovery or disposal through a suitably
qualified or licensed contractor. Care should be taken to ensure compliance with
national and local authority regulations. Avoid discharge of product to sewer.
Special Precautions for Landfill or Incineration:
Suitable for disposal by either incineration or to landfill through an approved agent.
14. TRANSPORT INFORMATION
Road and Rail
Marine Transport
Transport
UN No.
Proper
Shipping
Name
DG Class
Sub. Risk
Pack Group
Hazchem
UN No.
Proper
Shipping
Name
DG Class
Sub. Risk
Pack Group
Hazchem
Air Transport
UN No.
Proper
Shipping
Name
DG Class
Sub. Risk
Pack Group
Dangerous Goods
This product is not classified as a Dangerous Goods for transport.
Date of Issue: 3 September, 2008
Date of Review: September, 2013
page 7 of 8
Emergency Number: CHEMCALL: 0800 243 622
Safety Data Sheet
MEG
15. REGULATORY INFORMATION
Country/ Region: Australia, New Zealand
Inventory: AICS, NZCIL
Status: Listed
ERMA New Zealand Approval Code: HSR001534
Ethylene glycol
HSNO Controls: Codes: T1 T5, T7,
P1, P3, PI3, PG3, D4 -D8, EM1, EM6 - EM8, EM11 EM 13, I1, I8, I9, I11, I16 - I21,
I28 - I30, GN35A.
Refer to www.ermanz.govt.nz for information on Controls.
16. OTHER INFORMATION
Reasons for Issue: New product name identifier.
Abbreviations:
AICS: Australian Inventory of Chemical Substances
NZCI: New Zealand Chemical Inventory
CAS Number: Chemical Abstracts Number
IARC: International Agency for Research on Cancer
NOHSC: National Occupational Health and Safety Council
References:
Supplier Material Safety Data Sheets
Concise International Chemical Assessment Document Number 45-Ethylene Glycol. International
Programme on Chemical Safety 9IPCS), World Health Organization Geneva 2002. Available at:
http://www.inchem.org/documents/cicads/cicads/cicad45.htm#6.0
IUCLID data set; Ethylene Glycol, 2000. Available at :
http://www.oecd.org/dataoecd/26/37/39199559.pdf
Poisons Information Monograph 227 Ethylene Glycol, International Programme on Chemical
Safety (IPCS), World Health Organization, Geneva, 09/2005. Available at :
http://www.inchem.org/documents/pims/chemical/pim227.htm#10%20TREATMENT
Saxs Dangerous Properties of Industrial Materials, Richard J. Lewis Snr., pub. Canada (2000)
The information sourced for the preparation of this document was correct and complete at the time of
writing to the best of the writers knowledge. The document represents the commitment to the
companys responsibilities surrounding the supply of this product, undertaken in good faith. This document
should be taken as a safety guide for the product and its recommended uses, but is in no way an absolute
authority. Please consult the relevant legislation and regulations governing the use and storage of this
type of product. For further information, please contact Australasian Solvents and Chemicals Company
(NZ) Pty. Ltd.
Date of Issue: 3 September, 2008
Date of Review: September, 2013
page 8 of 8
Emergency Number: CHEMCALL: 0800 243 622
