8.
0 CALCULATIONS
Experiment 1: Boyles Law Experiment
A) Condition 1
V1 0.025m3
V2 0.01237m3
By using Boyles law,
P1V1 P2V2
P1V1 P2V2 before P1V1 P2V2 after
152.00.025 (102.7)(0.01237)kPa.m3 134.60.025 133.70.01237kPa.m3
5.0704 5.0189
The difference is only 0.0515. Therefore, the Boyles law is verified.
B) Condition 2
V1 0.025m3
V2 0.01237m3
By using Boyles law,
P1V1 P2V2
P1V1 P2V2 before P1V1 P2V2 after
103.50.025 52.60.01237kPa.m3 86.20.025 85.10.01237kPa.m3
3.2382 3.2077
The difference is only 0.0305. Therefore, the Boyles law is verified.
C) Condition 3
V1 0.025m3
V2 0.01237m3
By using Boyles law,
P1V1 P2V2
P1V1 P2V2 before P1V1 P2V2 after
152.20.025 54.80.01237kPa.m3 118.60.025 117.60.01237kPa.m3
4.4829 4.4197
The difference is only 0.0632. Therefore, the Boyles law is verified.
Experiment 2: Gay-Lussac Law Experiment
TemperatureTrial1 TemperatureTrial 2 TemperatureTrial 3
Averagetemperature
3
Pressure (kPa) Average temperature (C)
Pressure vessel Depressurise
vessel
103.9 (28.3 28.5 28.7)C (28.4 28.8 29.0)C
28.5C 28.7C
3 3
110 (28.8 28.6 28.7)C (28.7 29.6 29.9)C
28.7C 29.4C
3 3
120 (29.3 29.0 29.1)C (29.4 30.6 30.0)C
29.1C 30.0C
3 3
130 (30.0 29.7 29.9)C (30.4 31.9 30.1)C
29.9C 30.8C
3 3
140 (30.9 30.6 30.7)C (31.5 32.7 33.0)C
30.7C 32.4C
3 3
150 (31.8 31.6 31.6)C (32.2 33.3 33.3)C
31.7C 32.9C
3 3
160 (32.5 32.4 32.5)C (32.6 33.4 33.1)C
32.5C 33.0C
3 3
The pressure is directly proportional to temperature. Hence, the Gay-Lussacs Law is
verified.
Experiment 3: Isentropic Expansion Process
For isentropic process,
k 1
T2 P2 k
T1 P1
k 1
31.8C 103.8kPa k
33.4C 16.11kPa
31.8C k 1 103.8kPa
ln ln
33.4C k 161.1kPa
k 1
0.1116791478
k
k 1 0.1116791478k
0.8883208522k 1
k 1.1257
Theoritical value of k:
kJ
C p ,air 1.000
kg.K
kJ
Cv ,air 0.718
kg.K
C p ,air
k
Cv ,air
kJ
1.000
kg.K
k
kJ
0.718
kg.K
k 1.3928k 1.4
Difference of the theoritical value and experimental value= 1.3928 1.1257
=0.2671
kexp erimental ktheoritical
%error 100%
ktheoritical
1.1257 1.3928
%error 100%
1.3928
%error 19.177%
The difference is 0.2671 and the % error is below 50%. Hence, the expansion process
is proven as isentropic.