Iit Jee 2010 Paper 1
Iit Jee 2010 Paper 1
FIITJEE Solutions to
        IIT-JEE-2010
                                                     PAPER 1
                                                                                                  CODE
                                                                                                                    3
                                                                                                              Time: 3 Hours
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                                                INSTRUCTIONS
    A. General:
        1. This Question Paper contains 32 pages having 84 questions.
        2. The question paper CODE is printed on the right hand top corner of this sheet and also on the back
            page (page no. 32) of this booklet.
        3. No additional sheets will be provided for rough work.
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        9. Make sure the CODE on the ORS is the same as that on this booklet. If the Codes do not match, ask
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        10. Write your Registration No., Name and Name of centre and sign with pen in appropriate boxes. Do not
            write these any where else.
        11. Darken the appropriate bubbles below your registration number with HB Pencil.
    C. Question paper format and Marking scheme:
        12. The question paper consists of 3 parts (Chemistry, Mathematics and Physics). Each part consists of
            four Sections.
        13. For each question in Section I, you will be awarded 3 marks if you darken only the bubble
            corresponding to the correct answer and zero mark if no bubbles are darkened. In all other cases, minus
            one (−1) mark will be awarded.
        14. For each question in Section II, you will be awarded 3 marks if you darken only the bubble
            corresponding to the correct answer and zero mark if no bubbles are darkened. Partial marks will be
            awarded for partially correct answers. No negative marks will be awarded in this Section.
        15. For each question in Section III, you will be awarded 3 marks if you darken only the bubble
            corresponding to the correct answer and zero mark if no bubbles are darkened. In all other cases,
            minus one (−1) mark will be awarded.
        16. For each question in Section IV, you will be awarded 3 marks if you darken the bubble corresponding
            to the correct answer and zero mark if no bubble is darkened. No negative marks will be awarded for in
            this Section
Write your name, registration number and sign in the space provided on the back page of this booklet.
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IITJEE2010-Paper 1-CMP-2
                                                       Useful Data
         Atomic Numbers:      Be 4; C 6; N 7; O 8; Al 13; Si 14; Cr24; Fe 26; Zn 30; Br 35.
         1 amu =      1.66 × 10−27 kg                 R        =       0.082 L-atm K−1 mol−1
         h      =     6.626 × 10–34 J s               NA       =       6.022 × 1023
                              −31
         me     =     9.1 × 10 kg                     e        =       1.6 × 10−19 C
                                    −1
         c      =             8
                      3.0 × 10 m s                    F        =       96500 C mol−1
         RH     =     2.18 × 10–18 J                  4π∈0 =           1.11× 10−10 J−1 C2 m−1
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IITJEE2010-Paper 1-CMP-3
1.          The synthesis of 3 – octyne is achieved by adding a bromoalkane into a mixture of sodium amide and an
            alkyne. The bromoalkane and alkyne respectively are
            A) BrCH2CH2CH2CH2CH3 and CH3CH2C ≡ CH                 B) BrCH2CH2CH3 and CH3CH2CH2C ≡ CH
            C) BrCH2CH2CH2CH2CH3 and CH3C ≡ CH                    D) BrCH2CH2CH2CH3 and CH3CH2C ≡ CH
Sol.        (D)
            CH3 − CH 2 − C ≡ CH 
                                 NaNH 2
                                        → CH3 − CH 2 − C ≡ C− Na +
                3      2      2       2                         2       3          3      2      2       2              2        3
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IITJEE2010-Paper 1-CMP-4
Sol. (D)
                             O    CH3 
                                       HBr
                                           →                         OH + CH 3 Br
4.          Plots showing the variation of the rate constant (k) with temperature (T) are given below. The plot that
            follows Arrhenius equation is
              A)                                                     B)
                   K
                                                                                  K
                                  T                                                            T
             C)                                                           D)
                   K
T T
Sol.        (A)
             k = Ae− Ea / RT
            As T ↑; k ↑ exponentially.
                                                    K
5.          The species which by definition has ZERO standard molar enthalpy of formation at 298 K is
            A) Br2 (g)                                         B) Cl2 (g)
            C) H2O (g)                                         D) CH4 (g)
Sol.        (B)
            Cl2 is gas at 298 K while Br2 is a liquid.
Ans. (C)
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IITJEE2010-Paper 1-CMP-5
Ans. (C)
Sol.        (B)
            Cl – is replaced by NO −2 in ionization sphere.
H H
                      Y
            X and Y can respectively be
            A) H and H                                                    B) H and C2H5
            C) C2H5 and H                                                 D) CH3 and CH3
Sol.        (B, D)
                                 CH3
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IITJEE2010-Paper 1-CMP-6
10.         Aqueous solutions of HNO3, KOH, CH3COOH, and CH3COONa of identical concentrations are provided.
            The pair (s) of solutions which form a buffer upon mixing is(are)
            A) HNO3 and CH3COOH                                  B) KOH and CH3COONa
            C) HNO3 and CH3COONa                                 D) CH3COOH and CH3COONa
Sol.        (C, D)
            In option (C), if HNO3 is present in limiting amount then this mixture will be a buffer. And the mixture
            given in option (D), contains a weak acid (CH3COOH) and its salt with strong base NaOH, i.e.
            CH3COONa.
OH
                                                ( ) 2
                                               NaOH aq / Br
                                                 →
Br
                                                                                              Br   Br
                               Br
             C)                O                                                D)             O
                                                                                                         Br
                               Br
Sol.        (A, B, C)
            Phenoxide ion is para* and ortho directing. (* preferably)
                  O                     O                     O                           O                   O
                           →
                            Br2
                                                ←
                                                 →                                             →
                                                                                                Br2
                                                                           ←
                                                                            →
                                                                                  Br                    Br        Br
                                         Br                   Br
                  O                 O                  O               O
                                                                                 Br
                           +                 
                                              →                   +
            Br        Br
                                                       Br
12.         The reagent(s) used for softening the temporary hardness of water is(are)
            A) Ca3(PO4)2                                         B) Ca(OH)2
            C) Na2CO3                                            D) NaOCl
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IITJEE2010-Paper 1-CMP-7
Sol.        (B, C, D)
            Ca ( HCO3 )2 + Ca ( OH )2 
                                       → 2CaCO3 ↓ +2H 2 O
            [Clarke 's method ]
            NaOCl + H 2 O             HOCl + NaOH
                 −          −
                      → CO32 − + H 2 O
            OH + HCO      3
            Ca ( HCO3 )2 + Na 2 CO3 
                                     → CaCO3 ↓ +2NaHCO3
Sol.        (A, B)
            Resistance and heat capacity are mass dependent properties, hence extensive.
The concentration of potassium ions inside a biological cell is at least twenty times higher than the outside. The
resulting potential difference across the cell is important in several processes such as transmission of nerve impulses
and maintaining the ion balance. A simple model for such a concentration cell involving a metal M is:
M(s) M+(aq; 0.05 molar)M+(aq), 1 molar)M(s)
For the above electrolytic cell the magnitude of the cell potential Ecell= 70 mV.
15.         If the 0.05 molar solution of M+ is replaced by 0.0025 molar M+ solution, then the magnitude of the cell
            potential would be
            A) 35 mV                                            B) 70 mV
            C) 140 mV                                           D) 700 mV
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IITJEE2010-Paper 1-CMP-8
Sol.        (C)
                                         2.303RT
            From above equation                    = 0.0538
                                             F
                                    0.0538
            So, Ecell = E ocell   −        log 0.0025
                                       1
                  0.0538
            =0 −         log 0.0025
                     1
            ≈ 0.13988 V
            ≈ 140 mV
Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of
copper include chalcanthite ( CuSO 4 ⋅ 5H 2 O ) , atacamite ( Cu 2 Cl ( OH )3 ) , cuprite ( Cu 2 O ) , copper glance ( Cu 2S )
and malachite ( Cu 2 ( OH )2 CO3 ) . However, 80% of the world copper production comes from the ore of chalcopyrite
( CuFeS2 ) . The extraction of copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.
16.         Partial roasting of chalcopyrite produces
            A) Cu2S and FeO                                                            B) Cu2O and FeO
            C) CuS and Fe2O3                                                           D) Cu2O and Fe2O3
Sol.        (B)
             2CuFeS2 + O 2 → Cu 2S + 2FeS + SO 2 ↑
            2Cu 2S + 3O 2 → 2Cu 2 O + 2SO 2 ↑
            2FeS + 3O 2 → 2FeO + 2SO 2 ↑
Sol.        (D)
             FeO + SiO 2 → FeSiO3
                                  ( slag )
Sol.        (C)
            Cu 2S + 2Cu 2 O →             6Cu              + SO 2 ↑
                                      ( Blister copper )
            S2 − → S4+ is oxidation, i.e., S2− is reducing agent.
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IITJEE2010-Paper 1-CMP-9
19.         A student performs a titration with different burettes and finds titre values of 25.2 mL, 25.25 mL and 25.0
            mL. The number of significant figures in the average titre value is
Ans. 3
20.         The concentration of R in the reaction R → P was measured as a function of time and the following data is
            obtained:
               [R] (molar)         1.0          0.75         0.40          0.10
                 t (min.)          0.0          0.05         0.12          0.18
            The order of the reaction is
Sol.        0
            From two data, (for zero order kinetics)
                  x 0.25
            KI = =         =5
                  t 0.05
                  x 0.60
            K II = =       =5
                   t 0.12
                                                              235                                               142            90
21.         The number of neutrons emitted when                92   U undergoes controlled nuclear fission to    54   Xe and   38   Sr is
Sol.        3
            92   U 235 →54 Xe142 + 38 Sr 90 + 30 n1
22.         The total number of basic groups in the following form of lysine is
            H3 N        CH2   CH2 CH2 CH2                     O
CH C
H2N O
Sol.        2
                    O
23. The total number of cyclic isomers possible for a hydrocarbon with the molecular formula C4H6 is
Sol.        5
            In C4H6, possible cyclic isomers are
, , , ,
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IITJEE2010-Paper 1-CMP-10
24.         In the scheme given below, the total number of intra molecular aldol condensation products formed from
            ‘Y’ is
                                                             ( )
                                                     1. NaOH aq
                                  
                                   1. O3
                                   2. Zn, H 2 O
                                                → Y 
                                                     2. heat
                                                                 →
Sol.        1
                                                                                                          O
                                                                            O
                                                                                                  ( )
                                                                                           1. NaOH aq
                                        
                                         1. O3
                                         2.Zn, H 2 O
                                                     →                                   
                                                                                          2. heat
                                                                                                      →
25.         Amongst the following, the total number of compound soluble in aqueous NaOH is
            H3C         CH3
                                                                                     OH
                  N                    COOH                 OCH2 CH3
CH2 OH
CH2CH3
                                         N
                                H3C            CH3
Sol.        4
                  COOH            OH                      OH                              COOH
                                               N
                                         H3C        CH3
            These four are soluble in aqueous NaOH.
26.         Amongst the following, the total number of compounds whose aqueous solution turns red litmus paper blue
            is
               KCN     K2SO4 (NH4)2C2O4         NaCl Zn(NO3)2        FeCl3       K2CO3        NH4NO3 LiCN
Sol.        3
            KCN, K2CO3, LiCN are basic in nature and their aqueous solution turns red litmus paper blue.
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IITJEE2010-Paper 1-CMP-11
27. Based on VSEPR theory, the number of 90 degree F−Br−F angles in BrF5 is
Sol. 0
                 Br
            F          F
            F          F
                  F
            All four planar bonds (F−Br−F) will reduce from 90o to 84.8o after p − bp repulsion.
Sol.        3
            Be3Al2Si6O18 (Beryl)
            (according to charge balance in a molecule)
            2n + 6 + 24 − 36 = 0
            n=3
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IITJEE2010-Paper 1-CMP-12
This Section contains 8 multiple choice questions. Each question has four choices A), B), C) and D) out of which
ONLY ONE is correct.
29.         Let ω be a complex cube root of unity with ω ≠ 1. A fair die is thrown three times. If r1, r2 and r3 are the
            numbers obtained on the die, then the probability that ωr1 + ωr2 + ωr3 = 0 is
                 1                                                     1
            (A)                                                   (B)
                18                                                     9
                2                                                       1
            (C)                                                   (D)
                9                                                      36
Sol.        (C)
            r1, r2, r3 ∈ {1, 2, 3, 4, 5, 6}
            r1, r2, r3 are of the form 3k, 3k + 1, 3k + 2
                                        3! × 2 C1 × 2 C1 × 2 C1 6 × 8 2
            Required probability =                             =     = .
                                                6× 6× 6          216 9
30.         Let P, Q, R and S be the points on the plane with position vectors −2ˆi − ˆj, 4ˆi, 3ˆi + 3ˆj and −3ˆi + 2ˆj
            respectively. The quadrilateral PQRS must be a
            (A) parallelogram, which is neither a rhombus nor a rectangle
            (B) square
            (C) rectangle, but not a square
            (D) rhombus, but not a square
            PS = QR = −ˆi + 3ˆj
                                                                    P ( −2iˆ − ˆj)                    ˆ
                                                                                                  Q (4i)
            ⇒ PQ ⋅ PS ≠ 0
            PQ || SR, PS || QR and PQ = SR , PS = QR
            Hence, PQRS is a parallelogram but not rhombus or rectangle.
                                                                                                        x  1 
31.         The number of 3 × 3 matrices A whose entries are either 0 or 1 and for which the system A  y  = 0  has
                                                                                                        z  0 
            exactly two distinct solutions, is
            (A) 0                                               (B) 29 − 1
            (C) 168                                             (D) 2
Sol.        (A)
            Three planes cannot intersect at two distinct points.
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IITJEE2010-Paper 1-CMP-13
                                                       x
                                               1           t ln (1 + t )
32.         The value of lim
                                        x →0   x   3   ∫
                                                       0
                                                             t4 + 4
                                                                           dt is
                                                                                                             1
            (A) 0                                                                                       (B)
                                                                                                            12
                  1                                                                                          1
            (C)                                                                                         (D)
                  24                                                                                        64
Sol.        (B)
                           x
                   1           t ln (1 + t ) dt                     x ln (1 + x )
            lim
            x →0   x   3   ∫
                           0
                                    t +44
                                                       = lim
                                                            x →0   ( x 4 + 4 ) 3x 2
                   1 ln (1 + x )    1
            = lim                =    .
              x →0 3 x ( x + 4 )
                          4        12
33.         Let p and q be real numbers such that p ≠ 0, p3 ≠ q and p3 ≠ − q. If α and β are nonzero complex numbers
                                                                                     α      β
            satisfying α + β = − p and α3 + β3 = q, then a quadratic equation having   and     as its roots is
                                                                                     β      α
            (A) ( p3 + q ) x 2 − ( p3 + 2q ) x + ( p3 + q ) = 0                                         (B) ( p3 + q ) x 2 − ( p3 − 2q ) x + ( p3 + q ) = 0
            (C) ( p3 − q ) x 2 − ( 5p3 − 2q ) x + ( p3 − q ) = 0                                        (D) ( p3 − q ) x 2 − ( 5p3 + 2q ) x + ( p3 − q ) = 0
Sol.        (B)
            α3 + β3 = q
            ⇒ (α + β)3 − 3αβ (α + β) = q
                                       q + p3
            ⇒ − p3 + 3pαβ = q ⇒ αβ =
                                         3p
                 α β    α β
            x2 −  +  x + ⋅ = 0
                 β α    β α
            x2 −
                    ( α 2 + β2 ) x + 1 = 0
                               αβ
                      ( α + β )2 − 2αβ 
            ⇒ x 2 −                    x + 1 = 0
                             αβ         
                                3
                               p +q   
                     p2 − 2          
            ⇒ x2 −            3p  x + 1 = 0
                           p3 + q
                             3p
            ⇒ (p3 + q) x2 − (3p3 − 2p3 − 2q) x + (p3 + q) = 0
            ⇒ (p3 + q) x2 − (p3 − 2q) x + (p3 + q) = 0.
                                                                                                                                                       2       2
34.         Let f, g and h be real-valued functions defined on the interval [0, 1] by f ( x ) = e x + e − x , g ( x )
                       2            2                                  2           2
             = xe x + e − x and h (x) = x 2 e x + e − x . If a, b and c denote, respectively, the absolute maximum of f, g and
            h on [0, 1], then
            (A) a = b and c ≠ b                                          (B) a = c and a ≠ b
            (C) a ≠ b and c ≠ b                                          (D) a = b = c
Sol. (D)
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IITJEE2010-Paper 1-CMP-14
35.         If the angles A, B and C of a triangle are in an arithmetic progression and if a, b and c denote the lengths of
                                                                                              a         c
            the sides opposite to A, B and C respectively, then the value of the expression sin 2C + sin 2A is
                                                                                              c         a
                1                                                           3
            (A)                                                        (B)
                2                                                          2
            (C) 1                                                      (D) 3
Sol.        (D)
            B = 60°
               a     c
            ∴ sin2C + sin2A = 2sinA cosC + 2sinCcosA
               c     a
                                              3
            = 2sin(A + C) = 2sinB = 2 ×         = 3.
                                             2
                                                                    x y z
36.         Equation of the plane containing the straight line       = = and perpendicular to the plane containing the
                                                                    2 3 4
                          x y z    x y z
            straight lines  = = and = = is
                          3 4 2    4 2 3
            (A) x + 2y − 2z = 0                                        (B) 3x + 2y − 2z = 0
            (C) x − 2y + z = 0                                         (D) 5x + 2y − 4z = 0
Sol.        (C)
                                                       x y z
            Plane 1: ax + by + cz = 0 contains line       = =
                                                        2 3 4
            ∴ 2a + 3b + 4c = 0                       …(i)
                                                                                        x y z   x y z
            Plane 2: a′x + b′y + c′z = 0 is perpendicular to plane containing lines      = = and = =
                                                                                        3 4 2   4 2 3
            ∴ 3a′ + 4b′ + 2c′ = 0 and 4a′ + 2b′ + 3c′ = 0
                     a′       b′     c′
            ⇒             =      =
                   12 − 4 8 − 9 6 − 16
            ⇒     8a − b − 10c = 0              …(ii)
            From (i) and (ii)
                      a          b         c
                            =         =
                   −30 + 4 32 + 20 −2 − 24
            ⇒     Equation of plane x − 2y + z = 0.
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IITJEE2010-Paper 1-CMP-15
This section contains 5 multiple choice questions. Each question has four choices A), B), C) and D) out of which
ONE OR MORE may be correct.
37.         Let z1 and z2 be two distinct complex numbers and let z = (1 − t) z1 + tz2 for some real number t with 0 < t
            < 1. If Arg (w) denotes the principal argument of a non-zero complex number w, then
            (A) |z − z1| + |z − z2| = |z1 − z2|                   (B) Arg (z − z1) = Arg (z − z2)
                  z − z1 z − z1
            (C)                      =0                           (D) Arg (z − z1) = Arg (z2 − z1)
                 z 2 − z1 z2 − z1
                                       1                  4
                                           x 4 (1 − x )
38.         The value(s) of            ∫
                                       0
                                             1 + x2
                                                              dx is (are)
               22                                                                                 2
            (A) − π                                                                          (B)
               7                                                                                 105
                                                                                                 71 3π
            (C) 0                                                                            (D)    −
                                                                                                 15 2
Sol.        (A)
            1
                x 4 (1 − x) 4
            ∫
            0
                    1 + x2
                                  dx
                1
                                                                   4  
                ∫  x
                         6
            =                − 4 x 5 + 5x 4 − 4 x 2 + 4 −               dx
                                                                        2
                0
                                                                  1+ x 
                                                              1
               x 7 2x 6        4x 3      
            =  −        + x5 −      + 4x  − π
              7     3           3        0
              1 2        4           22
            = − +1− + 4 − π =           −π
              7 3        3            7
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IITJEE2010-Paper 1-CMP-16
                                                       π
39.         Let ABC be a triangle such that ∠ACB =       and let a, b and c denote the lengths of the sides opposite to A,
                                                       6
            B and C respectively. The value(s) of x for which a = x2 + x + 1, b = x2 − 1 and c = 2x + 1 is (are)
            (A) − ( 2 + 3 )                                               (B) 1 +    3
            (C) 2 + 3                                                     (D) 4 3
Sol.        (B)
            Using cosine rule for ∠C
               3 ( x 2 + x + 1) + ( x 2 − 1) − ( 2x + 1)
                                    2             2      2
                =
              2           2 ( x 2 + x + 1)( x 2 − 1)
                         2x 2 + 2 x − 1
            ⇒       3=
                          x2 + x + 1
            ⇒   (   3 − 2 ) x 2 + ( 3 − 2 ) x + ( 3 + 1) = 0
                  (2 − 3) ± 3
            ⇒x=
                     2 ( 3 − 2)
            ⇒ x = − (2 + 3) , 1 +            3 ⇒ x = 1 + 3 as (x > 0).
40.         Let A and B be two distinct points on the parabola y2 = 4x. If the axis of the parabola touches a circle of
            radius r having AB as its diameter, then the slope of the line joining A and B can be
                  1                                                      1
            (A) −                                                   (B)
                  r                                                      r
                2                                                          2
            (C)                                                     (D) −
                r                                                          r
                                                                                                  x
41.         Let f be a real-valued function defined on the interval (0, ∞) by f ( x ) = ln x +    ∫
                                                                                                  0
                                                                                                      1 + sin t dt . Then which of
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IITJEE2010-Paper 1-CMP-17
                 x                                1
              0
                  ∫
            =  1 + sin t dt − 1 + sin x  + ln x −
                                        
                                         
                                                    x
                                 x
            Consider g(x) =      ∫
                                 0
                                     1 + sin t dt − 1 + sin x
This section contains 2 paragraphs. Based upon the first paragraph 2 multiple choice questions and based upon the
second paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices A),
B), C) and D) out of WHICH ONLY ONE CORRECT.
                                                     x2 y2
The circle x2 + y2 − 8x = 0 and hyperbola              −   = 1 intersect at the points A and B.
                                                     9   4
42.         Equation of a common tangent with positive slope to the circle as well as to the hyperbola is
            (A) 2x − 5y − 20 = 0                                 (B) 2x − 5y + 4 = 0
            (C) 3x − 4y + 8 = 0                                  (D) 4x − 3y + 4 = 0
Sol.        (B)
                           x2 y2
            A tangent to       −     = 1 is y = mx + 9m 2 − 4, m > 0
                            9     4
            It is tangent to x2 + y2 − 8x = 0
                  4m + 9m 2 − 4
            ∴                   =4
                    1+ m2
            ⇒ 495m4 + 104m2 − 400 = 0
                     4           2
            ⇒ m2 = or m =
                     5            5
                                  2     4
            ∴ the tangent is y =     m+
                                   5     5
            ⇒ 2 x − 5y + 4 = 0 .
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IITJEE2010-Paper 1-CMP-18
Sol.        (A)
            A point on hyperbola is (3secθ, 2tanθ)
            It lies on the circle, so 9sec2θ + 4tan2θ − 24secθ = 0
                                                            2
            ⇒ 13sec2θ − 24secθ − 4 = 0 ⇒ secθ = 2, −
                                                           13
            ∴ secθ = 2 ⇒ tanθ = 3 .
            The point of intersection are A ( 6, 2 3 ) and B ( 6, − 2 3 )
            ∴ The circle with AB as diameter is
            (x − 6)2 + y2 = ( 2 3 )
                                      2
                                          ⇒ x2 + y2 − 12x + 24 = 0.
44.         The number of A in Tp such that A is either symmetric or skew-symmetric or both, and det(A) divisible by
            p is
            (A) (p − 1)2                                        (B) 2(p − 1)
            (C) (p − 1)2 + 1                                    (D) 2p − 1
Sol.        (D)
            We must have a2 − b2 = kp
            ⇒ (a + b) (a − b) = kp
            ⇒ either a − b = 0 or a + b is a multiple of p
            when a = b; number of matrices is p
            and when a + b = multiple of p ⇒ a, b has p − 1
            ∴ Total number of matrices = p + p − 1
            = 2p − 1.
45.         The number of A in Tp such that the trace of A is not divisible by p but det (A) is divisible by p is
            [Note: The trace of a matrix is the sum of its diagonal entries.]
            (A) (p − 1) (p2 − p + 1)                                (B) p3 − (p − 1)2
                        2
            (C) (p − 1)                                             (D) (p − 1) (p2 − 2)
Ans. (C)
Ans. (D)
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IITJEE2010-Paper 1-CMP-19
This section contains TEN questions. The answer to each question is a single digit integer ranging from 0 to 9. The
correct digit below the question number in the ORS is to be bubbled.
                                                                                                                    k −1
47.         Let Sk, k = 1, 2, ….. , 100, denote the sum of the infinite geometric series whose first term is             and the
                                                                                                                     k!
                                                                     100
                                       1                     1002
            common ratio is
                                       k
                                         . Then the value of      +  ∑
                                                             100! k =1
                                                                       ( k 2 − 3k + 1) Sk is
Sol.        (3)
                 k −1
                          1
            Sk = k ! =
                    1 ( k − 1)!
                1−
                    k
            100
                                           1
            ∑ (k
            k =2
                       2
                           − 3k + 1)
                                       ( k − 1)!
               100
                       ( k − 1) 2 − k
            =   ∑
                k =2
                          ( k − 1)!
                           k −1
                ∑ (k − 2)! − (k − 1)!
                                         k
            =
              2 3     3 4
            =   − + − + ⋅⋅⋅
              1! 2! 2! 3!
              2 1 2 3 3 4       99 100
            = − + − + − + ⋅⋅⋅ +    −
             1! 0! 1! 2! 2! 3!  98! 99!
                100
            =3−     .
                99!
48.         The number of all possible values of θ, where 0 < θ < π, for which the system of equations
                             (y + z) cos 3θ = (xyz) sin 3θ
                                         2 cos 3θ 2sin 3θ
                              x sin 3θ =         +
                                            y         z
                              (xyz) sin 3θ = (y + 2z) cos 3θ + y sin 3θ
            have a solution (x0, y0, z0) with y0z0 ≠ 0, is
Sol.        (3)
            (y + z) cos 3θ − (xyz) sin 3θ = 0                      … (1)
            xyz sin 3θ = (2 cos 3θ) z + (2 sin 3θ) y               … (2)
            ∴ (y + z) cos 3θ = (2 cos 3θ) z + (2 sin 3θ) y = (y + 2z) cos 3θ + y sin 3θ
            y (cos 3θ − 2 sin 3θ) = z cos 3θ and
            y (sin 3θ − cos 3θ) = 0 ⇒ sin 3θ − cos 3θ = 0 ⇒ sin 3θ = cos 3θ
            ∴ 3θ = nπ + π/4
49.         Let f be a real-valued differentiable function on R (the set of all real numbers) such that f(1) = 1. If the y-
            intercept of the tangent at any point P(x, y) on the curve y = f(x) is equal to the cube of the abscissa of P,
            then the value of f(−3) is equal to
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IITJEE2010-Paper 1-CMP-20
Sol.        (9)
            y – y1 = m(x – x1)
            Put x = 0, to get y intercept
            y1 – mx1 = x13
                      dy
            y1 – x1      = x13
                      dx
             dy
            x   − y = −x3
             dx
            dy y
              − = −x 2
            dx x
                  1
             ∫ − dx
            e x = e − ln x =
                             1
                                 x
                1          1
            y×
                x         ∫
                  = − x 2 × dx
                           x
                               x2
                      ∫
            y              y
              = − xdx ⇒ = − + c
            x              x   2
                      x3 3
            ⇒ f(x) = − + x ∴ f(–3) = 9.
                       2 2
                                                       π π                nπ
50.         The number of values of θ in the interval  − ,  such that θ ≠    for n = 0, ±1, ±2 and tanθ = cot 5θ as
                                                       2 2                 5
            well as sin 2θ = cos 4θ is
Sol.        (3)
            tanθ = cot 5θ
            ⇒ cos 6θ = 0
            4cos3 2θ − 3cos 2θ = 0
                                    3
            ⇒ cos 2θ = 0 or ±
                                   2
            sin 2θ = cos 4θ
            ⇒ 2sin2 2θ + sin2θ − 1 = 0
            2sin2 2θ + 2sin 2θ − sin2θ − 1 = 0
                                    1
            sin2θ = −1 or sin2θ =
                                     2
            cos2θ = 0 and sin2θ = −1
                      π             π
            ⇒ 2θ = −       ⇒θ=−
                      2             4
                         3             1
            cos2θ = ±      , sin2θ =
                        2              2
                     π 5π              π 5π
            ⇒ 2θ = ,          ⇒θ=        ,
                     6 6              12 12
                     π π 5π
            ∴ θ=− , ,
                     4 12 12
                                                                       1
51.         The maximum value of the expression                                          is
                                                       sin θ + 3sin θ cos θ + 5cos 2 θ
                                                           2
Sol. (2)
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IITJEE2010-Paper 1-CMP-21
                          1
                            3
             4 cos 2 θ + 1 + sin 2θ
                            2
                               1
            ⇒
                                       3
                 2 [1 + cos 2θ] + 1 + sin 2θ
                                       2
                            1     11
            lies between to
                            2      2
            ∴ maximum value is 2.
            Minimum value of 1 + 4 cos2 θ + 3 sin θ cos θ
                 4 (1 + cos 2θ ) 3
            1+                   + sin 2θ
                         2         2
                                     3
            = 1+ 2 + 2 cos 2θ + sin 2θ
                                     2
                                3
            = 3 + 2 cos 2θ +        sin 2θ
                                2
                             9          5 1
            ∴ = 3 − 4+ = 3 − = .
                             4          2 2
                                                    1
            So maximum value of                                is 2.
                                                       3
                                        4 cos 2 θ + 1 + sin 2θ
                                                       2
Sol.        (5)
            E = ( 2a + b ) ⋅  2 b a − 2 ( a ⋅ b ) b − ( a ⋅ b ) a + a b 
                                   2                                   2
                    2−2
             a⋅b =        =0
                     70
             a =1
            |b| = 1
             a⋅b = 0
            E = ( 2a + b ) ⋅  2 b a + a b 
                                   2       2
            = 4a
                    2    2
                        b +a
                                 2
                                     (a ⋅ b) + 2 b 2 ( b ⋅ a ) + a 2 b 2
                   2     2
            = 5a        b =5
                                                                                x2       y2
53.         The line 2x + y = 1 is tangent to the hyperbola                          −
                                                                             = 1 . If this line passes through the point of
                                                                     a 2 b2
            intersection of the nearest directrix and the x-axis, then the eccentricity of the hyperbola is
Sol.        (2)
                         a    
            Substituting  , 0  in y = − 2x + 1
                         e    
                  2a
            0 = − +1
                   e
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IITJEE2010-Paper 1-CMP-22
            2a
               =1
             e
               e
            a=
               2
            Also, 1 = a 2 m 2 − b 2
            1 = a2m2 − b2
            1 = 4a2 − b2
                 4e 2
            1=        − b2
                  4
            b2 = e2 − 1.
            Also, b2 = a2 (e2 − 1)
            ∴ a = 1, e = 2
                                                                                                            x −1 y − 2 z − 3
54.         If the distance between the plane Ax − 2y + z = d and the plane containing the lines                =     =
                                                                                                              2    3     4
                  x −2 y −3 z−4
            and       =    =    is 6 , then |d| is
                    3    4   5
Sol.        (6)
            2l + 3m + 4n = 0
            3l + 4m + 5n = 0
              l     m n
                  =   =
             −1 2 −1
            Equation of plane will be
            a (x − 1) + b (y − 2) + c (z − 3) = 0
            − 1 (x − 1) + 2 (y − 2) − 1 (z − 3) = 0
            − x + 1 + 2y − 4 − z + 3 = 0
            − x + 2y − z = 0
            x − 2y + z = 0
             |d|
                  = 6
                6
            d = 6.
55.         For any real number x, let |x| denote the largest integer less than or equal to x. Let f be a real valued
            function defined on the interval [−10, 10] by
                                       x − [x]       if [x ] is odd
                              f (x) = 
                                      1 + [ x ] − x if [x ] is even
                                      10
                                π2
            Then the value of
                                10    ∫ f (x) cos πx dx is
                                     −10
Sol.        (4)
                    x − 1, 1 ≤ x < 2
            f (x) = 
                    1 − x, 0 ≤ x < 1
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IITJEE2010-Paper 1-CMP-23
−2 −1 1 2 3
                  ∫
            = 2 f (x) cos πx dx = 2 × 5 f (x ) cos πx dx
                    0
                                                         ∫
                                                         0
                        1                           2     
                  0       ∫          1
                                                     ∫
            = 10  (1 − x ) cos πx dx + ( x − 1) cos πx dx  = 10 ( I1 + I 2 )
                                                           
                        2
                        ∫
            I 2 = ( x − 1) cos πx dx put x − 1 = t
                        1
                            1
                            ∫
            I 2 = − t cos πt dt
                            0
                        1                                1
                    ∫
            I1 = (1 − x ) cos πx dx = − x cos ( πx ) dx
                        0
                                                         ∫
                                                         0
                      1              
                      0             ∫
            ∴ I = 10  −2 x cos πx dx 
                                      
                                                     1
                   sin πx cos πx 
            = −20  x     +
                      π     π2  0
                   1     1  40                             π2
            = −20  − 2 − 2  = 2                        ∴      I=4
                   π    π  π                               10
                                                                   2π         2π
56.         Let ω be the complex number cos                           + i sin    . Then the number of distinct complex numbers z satisfying
                                                                    3          3
             z +1                 ω       ω2
              ω              z + ω2        1    = 0 is equal to
              ω2                  1       z+ω
Sol.        (1)
            ω = e i 2π / 3
             z +1                 ω       ω2
              ω              z + ω2        1    =0
                2
              ω                   1       z+ω
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IITJEE2010-Paper 1-CMP-24
           1      ω        ω2
         z 1 z + ω2         1    =0
           1      1      z+ω
         ⇒ z ( z + ω2 ) ( z + ω) − 1 − ω ( z + ω − 1) + ω2 (1 − z − ω2 )  = 0
         ⇒ z3 = 0
         ⇒ z = 0 is only solution.
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IITJEE2010-Paper 1-CMP-25
This Section contains 8 multiple choice questions. Each question has four choices A), B), C) and D) out of which
ONLY ONE is correct.
57.         Incandescent bulbs are designed by keeping in mind that the resistance of their filament increases with the
            increase in temperature. If at room temperature, 100 W, 60 W and 40 W bulbs have filament resistances
            R100, R60 and R40, respectively, the relation between these resistances is
                   1      1      1
            A)         =      +                                     B) R100 = R40 + R60
                  R100 R 40 R 60
                                                                           1      1      1
            C) R100 > R60 > R40                                     D)         >       >
                                                                         R100 R 60 R 40
Sol.        (D)
            Power ∝ 1/R
58.         To Verify Ohm’s law, a student is provided with a test resistor RT, a high resistance R1, a small resistance
            R2, two identical galvanometers G1 and G2, and a variable voltage source V. The correct circuit to carry out
            the experiment is
            A)          G1                                        B)          G1
                          R2                                                           R1
                                     G2                                                          G2
                        RT                 R1                                       RT                R2
                          V                                                            V
            C)                 R1                                       D)                  R2
                     G1                                                           G1
                                          G2                                                          G2
                        RT                                                          RT
                                          R2                                                          R1
                          V                                                            V
Sol.        (C)
            G1 is acting as voltmeter and G2 is acting as ammeter.
59.         An AC voltage source of variable angular frequency ω and fixed amplitude V0 is connected in series with a
            capacitance C and an electric bulb of resistance R (inductance zero). When ω is increased
            A) the bulb glows dimmer                               B) the bulb glows brighter
            C) total impedance of the circuit is unchanged         D) total impedance of the circuit increases
Sol.        (B)
                                      1
            Impedance Z =                  + R2
                                    (ωC) 2
            as ω increases, Z decreases.
            Hence bulb will glow brighter
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IITJEE2010-Paper 1-CMP-26
60.         A thin flexible wire of length L is connected to two adjacent fixed points and carries a current I in the
            clockwise direction, as shown in the figure. When the system is put in a uniform magnetic field of strength
            B going into the plane of the paper, the wire takes the shape of a circle. The tension in the wire is
                         ××××××××
                         ××××××××
                         ××××××××
                         ××××××××
                         ××××××××
                                                                                IBL
            A) IBL                                                     B)
                                                                                  π
                  IBL                                                           IBL
            C)                                                         D)
                   2π                                                            4π
Sol.        (C)
                  dθ                                                T cos (dθ/2)            T cos (dθ/2)
            2T sin   = BiRdθ
                   2
            Tdθ = BiRdθ                  (for θ small)                  T                     T
                      BiL                                                               2T sin (dθ/2)
            T = BiR =
                       2π
                                    P2
                         P1                P                                           P1        P2     P
C) f D) f
                         P1                                                            P1        P2
                                    P2     P                                                            P
Sol.        (A)
            Initially the frictional force is upwards as P increases frictional force decreases.
                  2GM                                                            2GM
            A)        (4 2 − 5)                                        B) −           (4 2 − 5)
                   7R                                                             7R
                  GM                                                            2GM
            C)                                                         B)            ( 2 − 1)
                  4R                                                             5R
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IITJEE2010-Paper 1-CMP-27
Sol.        (A)
                   4R
                        σ2πrdrG
            V=−    ∫
                   3R   r 2 + 16R 2
                                                                                      r      dr
Sol.        (C)
                  ρL
            R=
                  Lt
Sol. (D)
This section contains 5 multiple choice questions. Each question has four choices A), B), C) and D) out of which
ONE OR MORE may be correct.
65.         A point mass of 1 kg collides elastically with a stationary point mass of 5 kg. After their collision, the 1 kg
            mass reverses its direction and moves with a speed of 2 ms−1. Which of the following statement(s) is (are)
            correct for the system of these two masses?
            A) Total momentum of the system is 3 kg ms−1
            B) Momentum of 5 kg mass after collision is 4 kg ms−1
            C) Kinetic energy of the centre of mass is 0.75 J
            D) Total kinetic energy of the system is 4J
Sol.        (A, C)
            By conservation of linear momentum                                            1 kg       5 kg     2 m/s   5 kg
            u = 5v − 2                                          …(i)                             u                               v
            By Newton’s experimental law of collision
                                                                                           before collision    after collision
            u=v+2                                               …(ii)
            using (i) and (ii) we have
            v = 1 m/s and u = 3 m/s
                                                  1         2
            Kinetic energy of the centre of mass = msystem vcm = 0.75 J
                                                  2
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IITJEE2010-Paper 1-CMP-28
66.         One mole of an ideal gas in initial state A undergoes a cyclic process                V
            ABCA, as shown in the figure. Its pressure at A is P0. Choose the                                          B
                                                                                                4V0
            correct option(s) from the following
            A) Internal energies at A and B are the same
                                                                                                  V0     C             A
            B) Work done by the gas in process AB is P0V0 n 4
                                   P0                                                                             T0        T
            C) Pressure at C is
                                   4
                                        T0
            D) Temperature at C is
                                        4
Sol.        (A, B)
            Process AB is isothermal process
67.         A student uses a simple pendulum of exactly 1m length to determine g, the acceleration due to gravity. He
            uses a stop watch with the least count of 1 sec for this and records 40 seconds for 20 oscillations. For this
            observation, which of the following statement(s) is (are) true?
            A) Error ∆T in measuring T, the time period, is 0.05 seconds
            B) Error ∆T in measuring T, the time period, is 1 second
            C) Percentage error in the determination of g is 5%
            D) Percentage error in the determination of g is 2.5%
Sol.        (A, C)
             ∆T ∆ t 1
                =     =
             T     t    40
            ∆T = 0.05 sec
                4π2 Ln 2
            g=
                   t2
             ∆g 2∆t
                =
             g      t
                             2 ∆t
            ⇒ % error =           × 100 = 5%
                               t
68.         A few electric field lines for a system of two charges Q1 and Q2 fixed
            at two different points on the x-axis are shown in the figure. These
            lines suggest that
            A) Q1 > Q 2
                                                                                             Q1                                  Q2
            B)   Q1 < Q 2
            C) at a finite distance to the left of Q1 the electric field is zero
            D) at a finite distance to the right of Q2 the electric field is zero
Sol.        (A, D)
            No. of electric field lines of forces emerging from Q1 are larger than terminating at Q2
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IITJEE2010-Paper 1-CMP-29
Sol.        (A, B, C)
            Using snell’s law                                                   B
                   1           1
            sin −1    < sin −1                                          O           60°           135°
                    3           2
            Net deviation is 90°                                               P
                                                                                                            C
                                                                                              45°
                                                                                        90° 30°        75°
                                                                               A                                D
This section contains 2 paragraphs. Based upon the first paragraph 2 multiple choice questions and based upon the
second paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices A),
B), C) and D) out of WHICH ONLY ONE CORRECT.
70.         In the graphs below, the resistance R of a superconductor is shown as a function of its temperature T for
            two different magnetic fields B1 (solid line) and B2 (dashed line). If B2 is larger than B1 which of the
            following graphs shows the correct variation of R with T in these fields?
             A)      R                                                              B2
                                                                  B)      R
                          B2        B1
                                                                                                  B1
                      O                       T
                                                                                    O                       T
C) R D) R B1
B1 B2 B2
O T O T
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IITJEE2010-Paper 1-CMP-30
Sol.        (A)
            Larger the magnetic field smaller the critical temperature.
71.         A superconductor has TC (0) = 100 K. When a magnetic field of 7.5 Tesla is applied, its Tc decreases to
            75 K. For this material one can definitely say that when
            A) B = 5 Tesla, Tc (B) = 80 K                          B) B = 5 Tesla, 75 K < Tc (B) < 100 K
            C) B = 10 Tesla, 75K < Tc < 100 K                      D) B = 10 Tesla, Tc = 70K
Sol. (B)
Sol.        (C)
            Energy must be less than V0
73.         For periodic motion of small amplitude A, the time period T of this particle is proportional to
                     m                                                1 m
            A) A                                                 B)
                     α                                                A α
                           α                                                                     α
            C) A                                                                      D) A
                           m                                                                     m
Sol.        (B)
            [α] = ML-2T-2
            Only (B) option has dimension of time
            Alternatively
                               2
            1  dx 
             m   + kx 4 = kA 4
            2  dt 
                   2
             dx 
              =
              dt
             
                   2k 4
                   m
                     A − x4         (         )
                  m        A            dx
            4
                  2k   ∫
                       0
                                   A4 − x 4
                                              =   ∫   dt = T
                  m 1          1        du
            4
                  2k A     ∫   0
                                    1− u4
                                              =T                  Substitute x = Au
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IITJEE2010-Paper 1-CMP-31
Sol.        (D)
            As potential energy is constant for |x| > X0, the force on the particle is zero hence acceleration is zero.
This section contains TEN questions. The answer to each question is a single digit integer ranging from 0 to 9. The
correct digit below the question number in the ORS is to be bubbled.
                                                                       6
75.         Gravitational acceleration on the surface of a planet is     g, where g is the gravitational acceleration on
                                                                      11
                                                                                2
            the surface of the earth. The average mass density of the planet is   times that of the earth. If the escape
                                                                                3
                                                                    -1
            speed on the surface of the earth is taken to be 11 kms , the escape speed on the surface of the planet in
            kms-1 will be
Sol.        3
            g′   6 ρ′ 2
               =  ;  =
             g 11   ρ 3
                        R′ 3 6
            Hence,        =
                        R   22
            v′esc       R ′ 2 ρ′    3
                  ∝              =
            v esc       R ρ 2
                                   11
            v′esc = 3 km/s.
76.         A piece of ice (heat capacity = 2100 J kg-1 °C-1 and latent heat = 3.36 ×105J kg-1) of mass m grams is at
            -5°C at atmospheric pressure. It is given 420 J of heat so that the ice starts melting. Finally when the
            ice-water mixture is in equilibrium, it is found that 1 gm of ice has melted. Assuming there is no other heat
            exchange in the process, the value of m is
Sol.        8
            420 = (m × 2100 × 5 + 1 × 3.36 × 105 ) × 10−3
            where m is in gm.
77.         A stationary source is emitting sound at a fixed frequency f0, which is reflected by two cars approaching the
            source. The difference between the frequencies of sound reflected from the cars is 1.2% of f0. What is the
            difference in the speeds of the cars (in km per hour) to the nearest integer ? The cars are moving at constant
            speeds much smaller than the speed of sound which is 330 ms-1.
Sol.        7
                        c+v
            fapp = f0
                        c−v
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IITJEE2010-Paper 1-CMP-32
                   2f 0 c
            df =           dv
                 (c − v) 2
            where c is speed of sound
                 1.2
            df =      f0
                 100
            hence dv ≈ 7 km/hr.
78.         The focal length of a thin biconvex lens is 20 cm. When an object is moved from a distance of 25 cm in
                                                                                                   m
            front of it to 50 cm, the magnification of its image changes from m25 to m50. The ratio 25 is
                                                                                                   m50
Sol.        6
                     f
            m=
                   f +u
79.         An α- particle and a proton are accelerated from rest by a potential difference of 100 V. After this, their de
                                                                        λp
            Broglie wavelengths are λα and λp respectively. The ratio      , to the nearest integer, is
                                                                        λα
Sol.        3
            1
               mv 2 = qV
             2
                 h
            λ=
                mv
            λ= 8 3.
80.         When two identical batteries of internal resistance 1Ω each are connected in series across a resistor R, the
            rate of heat produced in R is J1. When the same batteries are connected in parallel across R, the rate is J2.
            If J1 = 2.25 J2 then the value of R in Ω is
Sol.        4
                           2
                  2E 
            J1 =      R
                 R+2
                               2
                  E 
            J2 =            R since J1/J2 = 2.25
                  R + 1/ 2 
            R = 4 Ω.
81.         Two spherical bodies A (radius 6 cm ) and B(radius 18 cm ) are at temperature T1 and T2, respectively.
            The maximum intensity in the emission spectrum of A is at 500 nm and in that of B is at 1500 nm.
            Considering them to be black bodies, what will be the ratio of the rate of total energy radiated by A to that
            of B?
Sol. 9
            λmT = constant
            λATA = λBTB
            Rate of total energy radiated ∝ AT4
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                                                      website: www.fiitjee.com.
IITJEE2010-Paper 1-CMP-33
                                                                                   π
82.         When two progressive waves y1 = 4 sin(2x - 6t) and y2 = 3sin  2x − 6t −  are superimposed, the
                                                                                   2
            amplitude of the resultant wave is
Sol.        5
            Two waves have phase difference π/2.                             5
                                                                                        3
83.         A 0.1 kg mass is suspended from a wire of negligible mass. The length of the wire is 1m and its cross-
            sectional area is 4.9 × 10-7 m2. If the mass is pulled a little in the vertically downward direction and
            released, it performs simple harmonic motion of angular frequency 140 rad s−1. If the Young’s modulus of
            the material of the wire is n × 109 Nm-2, the value of n is
Sol.        4
                    YA
            ω=
                    mL
84.         A binary star consists of two stars A (mass 2.2Ms) and B (mass 11Ms), where Ms is the mass of the sun.
            They are separated by distance d and are rotating about their centre of mass, which is stationary. The ratio
            of the total angular momentum of the binary star to the angular momentum of star B about the centre of
            mass is
Sol.        6
             L total m1r12
                    =         +1
              LB      m 2 r22
                                                             *******
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