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Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
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translucent materials as well as for those with transmittances                           It is recommended that a freshly coated sphere be used
reduced by highly reflective coatings. Method B is particularly                          especially when measuring translucent or specularly reflecting
suitable for the measurement of transmittance of inhomoge-                               specimens.
neous, patterned, or corrugated materials since the transmit-                               6.3 Calibration:
tance is averaged over a large area.                                                        6.3.1 Photometric— The calibration of the photometric
                                                                                         scale shall be done as recommended by the manufacturer. It
6. Method A—Spectrophotometric Method                                                    shall be carefully executed at reasonable time intervals to
   6.1 Apparatus:                                                                        ensure accuracy over the entire range.
   6.1.1 Spectrophotometer—An integrating sphere spectro-                                   6.3.2 Wavelength—Periodic calibrations should be made of
photometer, by means of which the spectral characteristics of                            the wavelength scales. Procedures for wavelength calibration
the test specimen or material may be determined throughout                               may be found in Recommended Practice E 275. A didymium
the solar spectrum. For some materials the spectrum region                               filter has also been used for this purpose. Although the
from 350 to 1800 nm may be sufficient. The design shall be                               absorption peaks have been defined for specific resolution in
such that the specimen may be placed in direct contact with the                          the visible spectrum it also has peaks in the near infrared;
sphere aperture for both transmission and reflection, so that the                        however, the wavelength of the peaks must be agreed upon,
incident radiation is within 6° of perpendicularity to the plane                         using a specific instrument.
of the specimen.4                                                                           6.4 Procedure:
   6.1.2 Standards:                                                                         6.4.1 Transmittance— Obtain spectral transmittance data
   6.1.2.1 For transmitting specimens, incident radiation shall                          relative to air. For measurement of transmittance of translucent
be used as the standard relative to which the transmitted light                          specimens, place freshly prepared matched smoked MgO
is evaluated. Paired reflecting standards are used, prepared in                          surfaces at the specimen and reference ports at the rear of the
duplicate as described below.                                                            sphere (Note 1). The interior of the sphere should be freshly
                                                                                         coated with MgO and in good condition.
   6.1.2.2 For reflecting specimens, use smoked magnesium
oxide (MgO) as a standard as the closest practicable approxi-                               NOTE 1—Magnesium oxide standards may be considered matched if on
mation of the completely reflecting, completely diffusing                                interchanging them the percent reflectance is altered by no more than 1 %
surface for the region from 300 to 2100 nm. The preferred                                at any wavelength between 350 and 1800 nm.
standard is a layer (at least 2.0 mm in thickness) freshly                                  6.4.2 Reflectance— Obtain spectral directional reflectance
prepared from collected smoke of burning magnesium (Rec-                                 data relative to MgO. Include the specular component in the
ommend Practice E 259). Pressed barium sulfate (BaSO4) or                                reflectance measurement. Back the test specimen with a black
MgO are not recommended because of poor reflecting proper-                               diffuse surface if it is not opaque. Depending on the required
ties beyond 1000 nm.                                                                     accuracy, use the measured values directly or make corrections
   6.1.3 Specimen Backing for Reflectance Measurement—                                   for instrumental 0 and 100 % lines (see Method E 308).
Transparent and translucent specimens shall be backed by a                                  6.5 Calculation— Solar energy transmittance or reflectance
light trap or a diffusing black material which is known to                               is calculated by integration. The distribution of solar energy as
absorb the near infrared. The backing shall reflect no more than                         reported by Parry Moon6 for sea level and air mass 2 shall be
1 % at all wavelengths from 350 to 2500 nm as determined                                 used.
using the spectrophotometer.5                                                               6.5.1 Weighted Ordinates—Obtain the total solar energy
   6.2 Test Specimens:                                                                   transmittance, T se, and reflectance, Rse, in percent, by integrat-
   6.2.1 Opaque specimens shall have at least one plane                                  ing the spectral transmittance (reflectance) over the standard
surface; transparent and translucent specimens shall have two                            solar energy distribution as follows:
surfaces that are essentially plane and parallel.                                                           Tse or Rse 5 (ll 5 2100 nm
                                                                                                                             5 350nm Tl ~or R l ! 3 El                  (1)
   6.2.2 Comparison of translucent materials is highly depen-
dent on the geometry of the specific instrument being used. It                             El for air mass 2, at 50-nm intervals, normalized to 100, is
is recommended that the specimen be placed in direct contact                             given in Appendix X1.
with the sphere to minimize and control loss of scattered                                  6.5.1.1 This integration is easily programmed for automatic
radiation.                                                                               computation.
   6.2.3 For specularly reflecting specimens the sphere condi-                             6.5.2 Selected Ordinates—Integration is done by reading
tions, especially where the reflected beam strikes the sphere                            the transmittance or reflectance at selected wavelengths and
wall, shall be known to be highly reflecting (95 % or higher).                           calculating their average. Appendix X2 lists 20 selected ordi-
                                                                                         nates for integration.7
                                                                                           6.6 Report—The report shall include the following:
                                                                                           6.6.1 Complete identification of the material tested, and
    4
      The Beckman DK-2 Recording Spectrophotometer available from Beckman                whether translucent, clear, or specularly reflecting,
Instruments, Inc., Fullerton, CA and the Cary 14 and 17 Recording Spectrophotom-
eter available from Varian Assoc., Palo Alto, CA, have been found satisfactory for
this purpose. For additional apparatus specifications see Recommended Practice
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E 308.                                                                                       Journal of the Franklin Institute, Vol 230, 1940, p. 583, or Smithsonian
    5
      A piece of velvet sprayed with Nextel velvet coating 101-C10 Black available       Physical Tables, Table 1, Vol 815, 1954, p. 273.
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from 3M Company; Parson’s Black available from Eppley Laboratories, Newport,                 Olson, O. H., “Selected Ordinates for Solar Absorptivity Calculations,” Applied
RI or Krylon Flat Black have been found satisfactory for this purpose.                   Optics, Vol 2, No. 1, January 1963.
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  6.6.2 Solar T percent or Solar R percent, or both, to the                                  7.1.2.2 The pyranometer has a viewing area of 180°. An
nearest 0.1 %,                                                                            Eppley pyranometer with its 25-mm (1-in.) diameter sensing
  6.6.3 Specimen thickness,                                                               disk, when placed in the center of the box, views the midpoint
  6.6.4 Identification of the instrument used, and                                        of the edges of the test specimen as a cone of 160°; the
  6.6.5 Integration method.                                                               diagonal of the specimen is viewed as a cone of 166° when the
                                                                                          thermopile is 50 mm (2 in.) below the bottom of the specimen.
7. Method B—Pyranometer Method                                                               7.1.2.3 Read-Out Instrumentation—A recorder, or a nonre-
   NOTE 2—The pyranometer is used to measure total global (sun and sky)                   cording meter capable of indicating in the 0.2 to 15-mV range
radiation (previously designated a 180° pyroheliometer; presently the                     are permissible for use. The output voltage of the pyranometer
latter word refers to a normal incidence measurement of direct solar                      will be affected by the input impedance of the meter to which
radiation). See IGY Instruction Manual, Part VI, Radiation Instruments,                   it is connected. Thus, the meter used to indicate solar intensity
Pergamon Press, New York, NY.                                                             should have a very high input impedance, such as a precision
   7.1 Apparatus:                                                                         vacuum-tube voltmeter, or a meter which has been calibrated
   7.1.1 Enclosure—The apparatus that has been used success-                              for one particular sensing element, thus compensating for any
fully is a box capable of supporting a 0.61-m2 (24-in.2)                                  loading effects on that element.
specimen. The box, which would normally be about 0.66-m2                                     7.2 Specimens—The test specimens should be not less than
(26-in.2) outside, should be capable of being faced in any                                0.61 by 0.61 m (24 by 24 in.). If the cross-sectional shape of
direction, as on a universal mount. The inside of the box should                          the specimen is not flat, care must be taken to prevent the
be painted flat black.4 A typical unit is shown in Fig. 1.                                possibility of light leaks at the edges such as are caused by the
   7.1.2 Sensor:                                                                          use of oversize specimens.
   7.1.2.1 The sensing element of this instrument is a pyra-                                 7.3 Procedure:
nometer consisting of concentric rings, or wedges of thermo-                                 7.3.1 Conduct the tests on a clear sunny day with no cloud
piles, colored alternately black and white.8 The voltage output                           cover interruptions during the individual tests. Conduct testing
of this sensor is proportional to the intensity of the total                              between the hours of 9 a.m. and 3 p.m. local standard time; this
incident solar irradiation. The spectral sensitivity of this                              is when the solar radiation is at least 80 % of the value obtained
instrument extends from the ultraviolet to infrared wavelengths                           at solar noon for that day. In the Northern hemisphere take
(280 to 2800 nm), thus encompassing all the solar spectrum.                               readings between November and February only between 10
The pyranometer should be located inside the box so that the                              a.m. and 2 p.m. Expose the test specimen approximately
sensing thermopile is approximately 50 mm (2 in.) from the                                normal to the sun for 15 min prior to testing. Next, align the
center of the bottom plane of the sample.                                                 box normal to the sun’s rays and take the average incident
                                                                                          solar-energy reading over a period of time (normally several
                                                                                          minutes) until a steady trace, or reading is obtained. Then place
   8
     An Eppley 50-Junction Pyranometer, Serial No. 9624 (6.66 mV/cal·cm 2·min)            the test specimen on the box and again record the average solar
and an Eppley 10-Junction Pyranometer, Serial No. 8553 (2.21 mV/cal·cm2·min)              energy reaching the sensor. When the test specimen has a
available from Eppley Laboratories, Inc., Newport, RI, have been found satisfactory       corrugated or irregular surface move it across the sensing
for this purpose. Various other Eppley Pyranometers have also been successfully
used.                                                                                     element, and take readings at 10-mm (1⁄2-in.) intervals for the
                                                                                          width of one corrugation or irregularity, and average the
                                                                                          readings. Also measure corrugated specimens with the corru-
                                                                                          gations in the North-South direction and in the East-West
                                                                                          direction.
                                                                                             7.3.2 The solar energy transmittance of the test specimens is
                                                                                          the ratio of the energy measured when the test specimen is
                                                                                          placed between the sun and the sensor and the energy measured
                                                                                          by the sensor with no test specimen in place.
                                                                                             7.4 Report—The report shall include the following:
                                                                                             7.4.1 The source and identity of the test specimen,
                                                                                             7.4.2 A complete description of the test specimen, that is,
                                                                                          thickness, cross-sectional shape, color, size, translucent or
                                                                                          transparent, type of material,
                                                                                             7.4.3 The percent solar energy transmittance to the nearest
                                                                                          1 %,
                                                                                             7.4.4 The place, date, and time of the test,
                                                                                             7.4.5 The intensity of the solar radiation,
                                                                                             7.4.6 Type of sensing unit used, and
                                                                                             7.4.7 Ambient air temperature.
                                                                                          8. Keywords
                                                                                             8.1 pyranometer; reflectance; solar energy; spectrophotom-
   FIG. 1 Typical Unit with Pyranometer Mounted in Black Box                              eter; terrestrial reflectance; transmittance
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APPENDIXES
(Nonmandatory Information)
Total 100.00
Table X2.1
                                                     Wavelength,                        Wavelength,
                                        No.                                No.
                                                        nm                                 nm
                                          1              390               11               745
                                          2              444               12               786
                                          3              481               13               831
                                          4              511               14               877
                                          5              543               15               959
                                          6              574               16              1026
                                          7              606               17              1105
                                          8              639               18              1228
                                          9              669               19              1497
                                         10              705               20              1722
   X3.1 Solar energy poses a complex problem to architects             tance (TSER) of the materials surrounding the space.
and engineers concerned with maintaining a comfortable
indoor space condition. The problem exists when solar energy             X3.3 With homogenous materials the percent of solar
is admitted into a space which must be thermally and optically         energy reflected, R, absorbed, A, and transmitted, T, can be
controlled, that is, temperature, humidity, and brightness.            determined by the following equation:
                                                                                              100 % 5 R 1 A 1 T                      (X3.1)
  X3.2 The amount of solar-energy admitted into a space can
be calculated with the solar-admittance parameters, total solar-         X3.4 For transparent materials, such as glass and clear
energy transmittance (TSET), and total solar-energy reflec-            plastics, the total solar energy transmittance is significient and
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environmental control systems must be designed to handle the                                                1.46/@~1.46 1 4.0! ~0.48 3 230!#
changing solar load.                                                                                        ~ASHRAE Handbook, 1967, p. 480! Eq 19              (X3.3)
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