Casting Repair PDF
Casting Repair PDF
in Cast Steels—Part II
Re 35, and all steel castings should be normalized before repair welding
ABSTRACT. Four different heats of cast 1. A metallurgical requisite. For crack- induced residual stresses in all but the
steel were used for hydrogen-induced ing to occur, a crack-sensitive microstruc- simplest of weldment geometries are
cracking studies using low- and high- ture must be present, and, in general, the usually sufficient in magnitude to initiate
hydrogen practice in simulated repair susceptibility to hydrogen-induced crack- cracking if the other requisites are met.
welds. It was shown that to prevent ing increases with increase in the hard- Furthermore, unless stress relief heat
hydrogen-induced cracking where good ness of the microstructure. treatment is performed after welding, the
low-hydrogen practice is not possible, 2. A chemical requisite. For cracking to addition of service usually raises the local-
the maximum "safe" level of hardness in occur, the level of diffusible hydrogen ized stresses in the weldment above the
the heat-affected zone should be below present in the crack-susceptible micro- critical level for crack propagation.
Re 35. structure must exceed a critical concen- Because most welded structures expe-
Metallographic examination of these tration, which decreases sharply as the rience service in the crack-sensitive tem-
cast-steel weldments showed seven dis- yield strength of the microstructure perature range, this requisite is usually
tinct regions from the fusion zone out present increases (Ref. 1). met. However, it is possible to take
toward and including the unaffected base 3. A mechanical requisite. Although advantage of this requirement in t w o
metal. These regions are: cracking has been shown to initiate at ways:
1. Fusion zone. lower stress levels, it appears that crack 1. Postweld soaking. It has been
2. Unmixed zone. propagation requires localized stresses of shown by Adams (Ref. 4) and others that
3. Coarse-grained homogeneous HAZ. approximately yield-strength magnitude an immediate postweld soak for 30
4. Fine-grained homogeneous HAZ. (Ref. 2). minutes (min) to one hour (h) at a temper-
5. Partially transformed region. 4. An environment requisite. Hydro- ature of above 390°F (200°C) will usually
6. Spheroidized region. gen-induced cracking has been shown to prevent hydrogen-induced cracking. This
7. Unaffected base metal. result from the extraordinary reduction in is attributed mainly to the reduction in the
All as-cast heats with carbon contents the notched-tensile strength of steels level of diffusible hydrogen made possi-
ranging from 0.21 to 0.32 wt-%, upon caused by the presence of a relatively ble by the greatly increased diffusivity of
exposure to a 5-second arc time, exhib- small amount of diffusible hydrogen (Ref. hydrogen at 390°F (200°C). Thus, by the
ited maximum hardness levels of about 3). Since this loss in strength in the pres- time the weldment is allowed to return to
70 Re in the networks of martensite ence of a notch occurs only in the range the crack-sensitive temperature range,
surrounding the islands of untransformed - 1 4 8 to 390°F ( - 1 0 0 to 200°C), hydro- the residual level of diffusible hydrogen is
ferrite in the partially transformed region. gen-induced cracking requires that the rendered below the critical level for crack
This was attributed to the inhomogeneity weldments be exposed to temperatures initiation.
of the as-cast structure. However, for within this range in the presence of the 2. Cryogenic storage. In conducting
low-carbon cast steels this problem was first three requisites. laboratory studies, it is convenient to be
eliminated by normalizing the alloy Although in theory hydrogen-induced able to store welded specimens under
before the welding operation. For cast cracking can be prevented by elimination conditions which preclude either loss of
steels of about 0.30 wt-%, in addition to of any one of the above requisites, in hydrogen or the formation of hydrogen-
homogenization, a postweld heat treat- practice it is usually possible to exert induced cracks until controlled experi-
ment would be advisable. control over only the first t w o . This ments can be initiated. This has been
results from the fact that the thermally- shown (Ref. 5) to be possible by transfer
of the weldments to liquid nitrogen
Introduction
(-320°F) (-195.8°C boiling point) as
D. K. AIDUN is Assistant Professor, Mechanical
It is generally recognized that four soon as they reach ambient temperature
and Industrial Fngineering Department, Clark-
requisites must be met simultaneously for son University, Potsdam, New York; and W. F. and storing under liquid nitrogen until the
hydrogen-induced cracking to occur. experiments begin.
SA VA GE is Professor Emeritus, Rensselaer Poly-
These can be summarized as follows: technic Institute, Troy, New York. The critical hardness level is influenced
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Fig. 5-Region A in Fig. 4 at X500 (reduced
fig. 4 — Microstructure of 5 s stationary repair weld in heat 27 with KHN (50 g load) hardnesses as 46% on reproduction). 2% nital etch
follows: A- 168; 6-280; C-403; D-403 prior pearlite, 197 prior ferrite; £-615 prior pearlite, 84
prior ferrite; F— 163 prior pearlite; C-(not stated). Nital etch, X50 (reduced 49% on reproduc-
tion)
the initial solidification process is accom- weldment shows seven distinct types of
panied by dendritic segregation with the microstructures labelled A through C in
dendrite interstices being enriched in Fig. 4:
those elements which depress the liquid- A — fusion zone. Figure 5 shows the
us temperature of the alloy. However, microstructure of this region as revealed
during soaking at high temperature in by a 2% nital etch at X500. The micro-
preparation for hot-working, partial structure consists of Widmanstatten fer-
homogenization occurs, and the pattern rite and finely laminated pearlite. The
of the residual segregation is altered by hardness of this low-carbon weld metal
the hot-working operations. Thus, in the was only 168 KHN.
case of hot-rolled plate products, the B — unmixed zone (Ref. 9). The top Fig. 6 - Region B in Fig. 4 at X500 (reduced
combination of thermal and mechanical section of Fig. 6 shows this zone at X500. 54% on reproduction). 2% nital etch
treatment forms alternating bands of sol- Because mechanical mixing is incomplete
ute-rich and solute-lean material parallel in this zone, the substitutional alloy con- mottled appearance is indicative of inho-
to the rolled surface. tent approximates that of the base metal. mogeneity. Figure 8 shows a portion of
In the case of steel castings, the pattern Carbon, on the other hand, diffuses so this region at X500. The light gray regions
of segregation is controlled by the den- rapidly that the carbon content is inter- are fully martensitic and exhibited a hard-
dritic-arm spacing, which increases as the mediate between that of the weld (0.07 ness of 403 KHN. The intermediate
section thickness increases. Since no wt-%) and that of the base metal (0.31 regions which consist of a mixture of
mechanical working is involved, homoge- wt-%). The region consists of bainite, elevated-temperature transformation
nization of castings can only be achieved Widmanstatten ferrite and very fine products exhibited a hardness of 197
by diffusion-controlled thermal treat- pearlite structures with measured hard- KHN.
ments. When the dendrite-arm spacings ness of only 280 KHN. Apparently region D experienced peak
are large, the increased diffusion dis- C—homogenized coarsed-grain re- temperatures above the effective A3 long
tances require longer times and higher gion. Figure 7 shows the microstructure enough to complete the transformation
temperatures to achieve a reasonable of this region at X500. The uniform to austenite but for too short a time to
degree of homogenization. Thus, it is response to the etchant within this region experience homogenization of even the
customary to normalize cast steels prior in Fig. 4 indicates it to be reasonably interstitial carbon. The austenite grain size
to the final heat-treatment operations homogeneous as a result of the high peak in this region ranges from slightly coars-
which are designed to control the temperatures experienced in this region. ened to fully refined and the hardenabili-
mechanical properties of the castings. The microstructure is fully martensitic and ty varies accordingly.
Figure 4 shows the microstructural exhibited a hardness of 403 KHN. E—partially transformed region (PTR).
changes from the fusion zone at the left D — inhomogeneous fully transformed This region is characterized by regions of
outward to the unaffected base metal at region. Within this region the response to nearly eutectoid carbon which corre-
the right. The panoramic view of the the etchant in Fig. 4 is uneven and the spond to the original networks of pearlite
Fig. 7—Region C in Fig. 4 at X500 (reduced Fig. 8 —Region D in Fig. 4 at X500 (reduced Fig. 9-Region E in Fig. 4 at X500 (reduced
52% on reproduction) 54% on reproduction). 2% nital etch 53% on reproduction). 2% nital etch
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.»: :,.**•£ - £• Fig. 14—Microstructure of 5 s stationary repair weld in heat 0. Nital etch, X75 (reduced 42% on
% . 10-Region F in Fig. 4 at X500 (reduced reproduction)
46% on reproduction). 2%, nital etch
untransformed ferrite islands. Figure 9 11 shows the microstructure of this zone
shows the location of E at X500. at X500. Note that the pearlite lamina-
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REGION OF
AS CAST STRUCTURE
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Fig. 13 — As-cast and normalized heat 0 micro-
DISTANCE FROM FUSION BOUNDARY-inches structures: A — as-cast; B —normalized. 2% nital
Fig. 12 -Results of hardness traverse across regions shown in Fig. 4 etch, X250 (reduced 44% on reproduction)
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Fig. 18 — Tempered martensite in Fig. 17 at
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DISTANCE FROM FUSION BOUNDARY-inches
Fig. 15 —Results of hardness traverse across the regions in Fig. 14
Fig. 16 —Microstructure of 5 s stationary repair weld in normalized heat Fig. 17 — Microstructure of 5 s stationary repair weld in normalized heat
27. Nital etch, X75 (reduced 55% on reproduction) 27 with postweld tempering at IIOVF (593°C) for 1 h. Nital etch, X75
(reduced 55% on reproduction)
virtually impossible to choose welding welding. Thus, 10 X 4 X V2 in. (254 X Figure 13 compares the as-cast and
conditions which provide cooling rates 102 X 13 mm) specimens from each heat normalized microstructures at X250. Note
sufficiently slow to prevent the formation were normalized at 1750°F (954°C) for 2 the complete elimination of the continu-
of continuous networks of crack-sensi- h. ous networks of pearlite that results from
tive microstructures in the regions which
experience partial transformation to aus-
tenite. n Q
The hardness levels identified in these CC UJv UJ
F- r-
regions are far above those shown to be Q. O UJ
acceptable for avoiding hydrogen- 5 w1 z ->
induced cracking even with good low- M
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hydrogen practice. Thus, it would be < UJ /
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difficult, if not impossible, to make repair r/
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welds in as-cast steels without the risk of CO z>
forming microcracks in the high-carbon
martensitic networks. In fact, hindsight
now suggests that the lack of quantitative
correlation between the acoustic-emis-
sion studies and identifiable hydrogen-
induced cracks is attributable to this phe-
nomenon.
Unfortunately, microcracks in these
hard brittle networks in the partially trans-
formed region can serve as nuclei for
slow crack growth even after postweld
heat treatments. Therefore, it appears ~I000°F
that the only sure way to avoid this Fig. 19—Schematic of various regions produced in steel casting repair welds: FZ—fusion zone;
problem would be to eliminate the net- UMZ — unmixed zone; PMZ—partially me/ted zone; HAR — homogeneous austenite region; HAZ—
works of interdendritic pearlite nodules heat-affected zone; CG—coarse grained; E.G.—fine grained; PTR — partially transformed
by a homogenizing treatment prior to region