SCR Presentation
SCR Presentation
                                              .1
                    Agenda
Company Overview
Technology Review
Project Execution
Experience List
                                        .2
                            B&W is technically, financially
                      and strategically positioned to support you
                      through our nations energy transformation
                     Headquarters:             Charlotte, NC
                     Incorporation:            Delaware
     Company         CEO:                      E. James (Jim) Ferland
     Profile                                   12,700 plus 10,400
                     Employees:
                                               joint venture employees
                     Ticker Symbol:            NYSE: BWC
  A leader in clean energy technology and services, primarily for the fossil,
nuclear and renewable power markets, as well as premier advance technology
                    and mission critical defense contractor.
                                                                                .3
             A Global Business
                                                                                                       .5
  B&W Power Generation Group (B&W PGG)
         Business Footprint            Product Line Portfolio
                                       Utility and industrial boilers
                                        Firing fossil fuels
                                       Environmental products
                                        Control regulated emissions
                                       Construction
                                        Install all B&W supplied scope
                                       O&M services
                                                                          .6
Environmental Products and Services
                                                             .7
A Complete Environmental Technology Portfolio
 Mercury      Acid Gas       CO2         SCR / Low    Emissions    Aftermarket   Construction      Ash
 Control     Dry Sorbent    Control        NOX        Monitoring    Services                    Management
              Injection                   Burner
                                                                                                              .8
Extensive Environmental Field Service Capabilities
   150           Environmental
                                  Field Specialists  Support and train / retrain O&M
                                  personnel; Inspections and troubleshooting
 Field Service
 Organization    Equipment        Remote Consulting  Support for troubleshooting,
                                  O&M, process performance, over the phone
                                                                                            .9
      Babcock & Wilcox Research Center
 Modern laboratories for
  basic research on clean
  fuel utilization
 Pilot plants for combustion,
  oxy-firing, emissions
  control, and post-
  combustion CO2 capture
 Collaborations with
  universities, national labs,
  and industry
 Research focused by
  business vision and
  technology roadmaps
                                         .10
 Clean Energy Technology
                                                                    .11
           B&Ws SCR Qualifications
 Oldest domestic SCR technology supplier
                                                                      .12
                    Agenda
Company Overview
Technology Review
Project Execution
Experience List
                                        .13
What is Selective Catalytic Reduction (SCR)?
 A process for the control of
  nitrogen oxide emissions from
  stationary sources
 Catalyst is defined as a
  substance that causes or
  accelerates a chemical reaction
  without itself being affected
4 NO + 4 NH3 + O2 = 4 N2 + 6 H2O
                                            .15
             Typical Coal Fired SCR System
 Catalyst
 Ammonia injection grid (AIG)
 Static mixers
 Flow distribution devices
 Flow straightener
 Catalyst cleaning equipment
 Catalyst loading equipment
                                              .16
General System Design Parameters
   Operating temperature
     Min ~585 F
     Max 780 F
   Velocity in SCR fluework
     50 to 60 ft/sec
   Velocity through reactor
     < 18 ft/sec
   NOX performance (coal)
     Up to ~90+% reduction or ~0.05 lbs/MBtu
      NOX whichever is first achieved
   Ammonia slip (coal)
     2 - 5 ppm (dependent on fuel)
   SO2 to SO3 Conversion
      0.25% to 0.5% per layer
   Pressure drop
     As necessary for requisite
      system equipment
                                                .17
                    Agenda
Company Overview
Technology Review
Project Execution
Experience List
                                        .18
  Minimum Ammonia Injection Temperature
                                                                          .19
Options to Raise SCR Inlet Temperature
                                         .20
Maximum Temperature Control
  Upper temperature limit set to avoid impacts to:
        Catalyst
        Support structure
        Other affected materials
  Controlling temperature to achieve  780 can be achieved via:
        Boiler cleaning equipment modifications / revised protocol
        Economizer or other surface (superheater) modifications
        Addition of external heat trap
                                                                      .21
                    Agenda
Company Overview
Technology Review
Project Execution
Experience List
                                        .22
Ash Management
                 .23
Ash Types
Fly ash
    Small, light particles that remain entrained in flue gas
      May result in catalyst erosion
     May form layer on top of catalyst  typically managed with sonic horns,
      sootblowers or both
Bottom ash
                                                                           .24
         Ash Management  Design Options
        Solution                Function                   Application
                                                    Units w/ compatible
LPA baffle               Redirect LPA
                                                    economize outlet
LPA screen w/ rappers    Capture LPA                Any unit
                                                    Greater than 20% PRB
                         Eliminate ash build up
Scalloped vane slots                                and other high ash
                         on vanes
                                                    coals
                                                    Greater than 20% PRB
Boxed catalyst support
                         Prevent ash collection     and other high ash
beams
                                                    coals
                                                    Greater than 20% PRB
                         Allow ash to flow freely
Large pitch catalyst                                and other high ash
                         through bed
                                                    coals
Sootblowers/sonic        Avoid ash piling; move     All coal-fired
horns/air cannons        ash through bed            applications
                                                                           .25
Aerodynamic Approach to LPA Management
 Install baffle and/or adjust economizer outlet geometry such that
  large ash particles are aerodynamically captured in hoppers
 Dependent upon accurate measurement of the ash particles
  aerodynamic properties
    Density
    Drag
    Restitution
    Friction
 Designed using CFD modeling
                                                                      .26
.27
      Physical Barrier for LPA Management
                                                                             .29
               Large Particle Ash Screens
Considerations:
   Pitch
   Screen types
      Perforated plate
      Wedge wire
   Screen materials
        Carbon steel
        Stainless steel
        Conforma Clad coating
        UTEx TM 1-120LPA
   Cleaning methods
      Sootblowing
      Rapping
                                            .31
Large Particle Ash Screen  Cleaning Devices
Sootblowers
Rappers
                                               .32
                    Agenda
Company Overview
Technology Review
Project Execution
Experience List
                                        .33
                  Universal SCR Reactor
A reactor designed to
accommodate catalysts
from multiple suppliers for
the NOx reduction required.
Outliers may be excluded
from consideration.
 Catalyst support system based
  on heaviest catalyst module
 Reactor height based on tallest
  catalyst module
 Access and provisions for
  catalyst loading based on
  largest catalyst volume
 Equipment to handle each type
  of catalyst
                                          .34
                      Catalyst
                                 Corrugated
Active ingredients:
  V, Ti, W
Catalyst sizing based on:
  Inlet NOx concentration       Honeycomb
  NOx reduction level
  NH3 slip required
  Fuel constituents
  Gas flow
                                   Plate
  Operating temperature
  SO2 to SO3 conversion
  Required life
                                              .35
                   Catalyst Selection
 Fuel and ash characteristics
   Fuel type
      Bituminous
      Sub-bituminous
      Lignite
   Ash type
      Flow characteristics
      Hygroscopic
 Catalyst type and pitch
   Corrugated, honeycomb or plate
   Pitch
                                        .36
            Major Catalyst Suppliers
       Plate Type
          Ceram
          Hitachi
          Johnson Matthey
       Corrugated Type
          Haldor Topsoe
       Honeycomb Type
          Ceram
          Cormetech
          Johnson Matthey
                                                               .37
Catalytic DeNOX Reaction
Active sites constantly being
regenerated in a cycle
   Active site available
   Adsorb ammonia
   Reaction of NOX with NH3
   Regenerate site with O2
Sites busy with NOX reduction
(ammonia) not available
for oxidation
Poisons prevent active sites
from being regenerated in
the cycle
                                .38
            Catalyst Deterioration Issues
              Operating temperatures
Sintering      unacceptably above design
              Sintering > 800 to 850F
              Alkaline metals
Masking
              Ash
              Arsenic
Poisoning     Phosphorus
              Other ash constituents
                                            .39
                                      Typical Catalyst Management Plan
                                1.2
0.8
0.6
0.4
0.2
                                0.0
                                      0   1      2          3       4       5       6     7       8         9   10
                                                                Operating Time (Years)
                                                                                                                     .45
SO2 to SO3 Conversion
                                                N2
               NOX                                               H2SO4 Acid Plume
  Boiler                     SCR                NH3 Slip
  Outlet                    Catalyst            H2O
               SO2
                                                SO3
                                                                                    .46
                  Mercury Oxidation
                                                 .47
              Catalyst Cleaning
Sonic Horns     Purpose is to prevent ash from accumulating at all
                Uses small amounts of compressed air
               Cannot remove deposits that form due to improper operation
                Inexpensive system to install, operate, and maintain
Sootblowers    Purpose is to remove ash that has accumulated over 1 shift or 1 day
                Rake-type (multi-element) used
                Air or steam acceptable
                     Steam must be superheated to prevent condensate
                      on catalyst
               Can possibly remove deposits that form due to improper operation
                Expensive system to install, operate, and maintain
                                                                                   .50
 Catalyst Cleaning Equipment - Sonic Horns
Arrangement
      Spacing
      Single & multiple walls
      Flush or inset
      Level or sloped
      Insulation
Operation (PRB firing)
    Begin with 10 sec on / 10 sec off
    Pairing (1&2, 3&4)
    Sequencing (1&2, 2&3)
                                             .51
 Catalyst Cleaning Equipment - Sootblowers
Media may be either 
   Air
     Clean, dry & oil-free
     65-110 ft/sec
     ISO 8573-1
       Particulate (1  0.1 , 0.1 mg/m3)
       Moisture dew point (3  -20C, -4F)
       Oil content (2  0.1 mg/m3)
   Steam
     Superheated (dry)
     65-110 ft/sec
     Thermal drain
                                               .54
Catalyst Cleaning Equipment  Air Cannons
                                            .55
                    Agenda
Company Overview
Technology Review
Project Execution
Experience List
                                        .56
                        Ammonia Systems
       System                          Pros                              Cons
                     Easy to transport
                                                              Shipping traffic
Aqueous Ammonia      Not classified as hazardous material
                                                              Safety issues (19% vs 29%)
(19% or 29%)          if less than 20%
                                                              Vaporization costs
                     Safer than anhydrous
                                                                                               .57
Manifold Valve Station
                         .63
         Ammonia Injection and Mixing
B&W customizes injection zones and hybrid vane 
vortex mixers to enable
   Zone-by-zone control
   Straightforward initial tuning
   Infrequent future tuning
   Flexibility to accommodate
     unit operation changes
   Acceptable NH3/NOX and
     temperature distributions
     without unnecessary
     ash collectors
                                                   .64
Ammonia Injection and Mixing Equipment
Mixing Devices
Vortex            Blending from counter rotating downstream vortices
                   and general turbulence
                   Benefits: minimal equipment with low weight
                  Drawbacks: requires turbulent flow and significant
                   downstream flue length, P
                                                                       .65
                    Agenda
Company Overview
Technology Review
Project Execution
Experience List
                                        .66
                          Flow Modeling
Use both physical and Computational Fluid Dynamic (CFD) modeling
                                                                   .67
CFD Modeling of Flue Gas Velocity
                                    .68
CFD Modeling of NH3 / NOX Ratio
                                  .69
Physical & CFD Modeling of Ash
                                 .70
                    Agenda
Company Overview
Technology Review
Project Execution
Experience List
                                        .71
            SCR Reactor Design Options
An array of design options enables selecting an approach
that best fits the plant and its site.
 Flat panel delivery  for
  restricted delivery access,
  arrangement and erection
  challenges
 Truck-shippable modules  when
  there is adequate space for
  laydown and cranes; adequate
  access for placement
 Barge-shippable modules 
  when there is water access with
  unloading capability; open area
  for placement with large cranes
                                                           .72
Reactor Modularization
Design goals:
   Reduced cost
   Enhanced quality
   Enhanced safety
   Reduced schedule risk
   Reduced impact to plant operations
                                         .73
Completed Reactor
                    .107
Flue Arrangement
                   .112
        Do's & Don'ts of Flue Arrangements
 Flue gas velocity in general        Gas Speed Ft/Min)
                                                          .113
                    Arrangement Tips
FLOW
                               ASH BUILD
FLOW
                               UP AREA
FLOW
                                                                          .114
                         Arrangement Tips
FLOW
                                                                                     FLOW
      GOOD FLUE ARRANGEMENT
SAME CROSS SECTIONAL AREA MAINTAINED
                                                                                 ASH BUILD
                                                                                 UP AREA
                                                                            EQUIPMENT INLET
                                                                            OR OUTLET FLUE
                   .118
Catalyst Lifting Rig
Quick Disconnect
                                          .119
Hinged & Bolted Catalyst Loading Door
                                        .121
Catalyst Gas Seals - Ash Shields
                                   .122
Structural Support Steel
                                                    .125
                           Mirant Morgantown SCR  Feb. 3, 2005.
                     Structural Steel
Structural steel is the backbone of the project
    Significant cost, both material and erection labor
    Major project schedule impacts
    Coupled with the flues and the reactor, defines the
     complexity of the project
    Independent steel structure generally more cost-effective
    Required reinforcement of existing steel less favorable
                                                                                .126
                                                       Mirant Morgantown SCR  Feb. 3, 2005.
B&W Structural Steel Experience
                                  .129
                    Agenda
Company Overview
Technology Review
Project Execution
Experience List
                                        .130
        Retrofit SCR/Boiler Relationship
 The SCR is not simply an add on
 The SCR system must be designed to work efficiently
  with the boiler, other AQCS equipment and peripherals
 Boiler and boiler peripherals modifications may be
  necessary as part of SCR installation to achieve the
  optimum solution
 The SCR system must be integrated with boiler
  operation to achieve least-cost NOX compliance
                                                          .131
                    SCR Design Information
 Detailed and accurate information enables realistic project
  planning and precludes (or minimizes) false starts
    Boiler and peripherals  design and performance
     data including
          Gas flow
          Economizer exit gas temperature
          NOX in flue gas
          Ash carryover information
    Drawings  site plans, general arrangements, major
     equipment drawings
    Fuel analyses for fuel(s) that will be fired with SCR in place
    Performance goals
    Site constraints
    Future plans
                                                                      .132
             Integrated Design Process
The Steps:
1. Define scope  explicitly
2. Define arrangement - in concert with existing structures
   and equipment
3. Define construction approach  early
4. Perform joint project management, engineering and
   construction reviews
5. Iterate through 2 - 4 above to advance / evolve the design
                                                                .133
                    Agenda
Company Overview
Technology Review
Project Execution
Experience List
                                        .140
B&W SCR System Case Histories
                                                                  .141
    B&W SCR Case History, Bruce Mansfield 1 - 3
Bruce Mansfield 1 -   Boiler OEM:      Foster Wheeler
3
                      Boiler MW:       3 x 856
Sammis 6, 7
                      Boiler Fuel:     Bituminous coal / pet coke
                                                                                         .142
               B&W SCR Case History, Sammis 6, 7
Bruce Mansfield 1 -   Boiler OEM:      B&W
3
                      Boiler MW:       2 x 680
Sammis 6, 7
                      Boiler Fuel:     Bituminous coal / PRB
                                                                     .143
               B&W SCR Case History, Cheswick 1
Bruce Mansfield 1 -   Boiler OEM:      CE (Alstom)
3
                      Boiler MW:       580; corner-fired
Sammis 6, 7
                      Boiler Fuel:     Eastern bituminous
Sandow 4
                                                                                         .144
                B&W SCR Case History, Karn 1, 2
Bruce Mansfield 1 -   Boiler OEM:      CE / B&W
3
                      Boiler MW:       2 x 265
Sammis 6, 7
                      Boiler Fuel:     PRB blend
Cheswick 1 Inlet NOX: 0.45 lb/106 Btu (Unit 1), 0.38 lb/106 Btu (Unit 2)
                                                                                            .145
               B&W SCR Case History, Campbell 3
Bruce Mansfield 1 -   Boiler OEM:      Foster Wheeler
3
                      Boiler MW:       871
Sammis 6, 7
                      Boiler Fuel:     PRB
Sandow 4
                                                                .146
               B&W SCR Case History, Southwest 1
Bruce Mansfield 1 -   Boiler OEM:      Riley Stoker
3
                      Boiler MW:       1 x 195
Sammis 6, 7
                      Boiler Fuel:     PRB
                                                                .147
               B&W SCR Case History, J.T. Deely 2
Bruce Mansfield 1 -   Boiler OEM:      CE (Alstom)
3
                      Boiler MW:       1 x 446
Sammis 6, 7
                      Boiler Fuel:     PRB
                                                                .148
               B&W SCR Case History, Sandow 4
Bruce Mansfield 1 -   Boiler OEM:      CE (Alstom)
3
                      Boiler MW:       1 x 591
Sammis 6, 7
                      Boiler Fuel:     Texas Lignite
                                                                  .149
                    Take-Aways
 Complete portfolio of air quality control systems to achieve
  fully integrated solutions
                                                                 .150
Thank you.
             Questions?
.151