TRM 12
TRM 12
4
He 49Be126C 01n A and charge conserved in nuclear reactions, first an
2 2
alpha particle, last a neutron
12.2: Nuclear Properties
The nuclear charge is +e times the number (Z) of protons.
Hydrogen’s isotopes:
Deuterium: Heavy hydrogen. Has a neutron as well as a proton in its
nucleus.
Tritium: Has two neutrons and one proton, is radioactive, about 40 tons
on earth.
The nuclei of the deuterium and tritium atoms are called deuterons
and tritons.
Atoms with the same Z, but different mass number A, are called
isotopes.
3
Nuclear Properties
The symbol of an atomic nucleus is .
where Z = atomic number (number of protons)
N = neutron number (number of neutrons)
A = mass number (Z + N)
X = chemical element symbol
Each nuclear species with a given Z and A is called a nuclide.
Z characterizes a chemical element.
The dependence of the chemical properties on N is negligible,
certain physical properties, e.g thermal expansion show
measurable differences due to isotope effects.
Nuclides with the same neutron number are called isotones and
the same value of A are called isobars.
4
Sizes and Shapes of Nuclei
Rutherford concluded that the range of the nuclear force must be le
ss than about 10−14 m.
Assume that nuclei are spheres of radius R.
Particles (electrons, protons, neutrons, and alphas) scatter when pr
ojected close to the nucleus.
5
Sizes and Shapes of Nuclei
The nuclear radius may be approximated to be R = r0A1/3
where r0 ≈ 1.2 × 10−15 m.
6
Note the three orders of magnitude
difference between μnuclear and μBohr
7
Positrons have same
mass and spin as
electron but positive
charge
8
12.1: Discovery of the Neutron
Rutherford proposed the atomic structure with the massive nucleu
s in 1911.
the components of nucleus were known only in 1932
Three reasons why electrons cannot exist within the nucleus:
1) Nuclear size
The uncertainty principle puts a lower limit on its kinetic energy tha
t is much larger that any kinetic energy observed for an electron e
mitted from nuclei (its actually the result of β-decay).
2) Nuclear spin
If a deuteron nucleus were to consist of protons and electrons, the
deuteron must contain 2 protons and 1 electron. A nucleus compo
sed of 3 fermions must result in a half-integral spin. But it has bee
n measured to be 1. So no electrons can possible in the nucleus
(but they apparently come out of atoms or their nucleus)
9
Discovery of the Neutron
In 1930 the German physicists Bothe and Becker used a
radioactive polonium source that emitted α particles. When
these α particles bombarded beryllium, the radiation penetrated se
veral centimeters of lead but was readily absorbed
by paraffin wax,
4
2 He Be C n
9
4
12
6
1
0
10
Discovery of the Neutron
In 1932 Chadwick proposed that the new radiation produced by α
+ Be consisted of neutrons. His experimental data estimated the n
eutron’s mass as somewhere between 1.005 u and 1.008 u, not fa
r from the modern value of 1.0087 u.
11
Intrinsic Magnetic Moment
The proton’s intrinsic magnetic moment points in the same direction as its i
ntrinsic spin angular momentum (as it is positive).
Nuclear magnetic moments are measured in units of the nuclear magneton
μN.
The divisor in calculating μN is the proton mass mp, which makes the nuclea
r magneton 1836 times smaller than the Bohr magneton of the electron.
The proton magnetic moment is μp = 2.79 μN.
The magnetic moment of the electron is μe = −1.00116 μB. (1 in last chapter wh
ere quantum electrodynamics had been ignored)
The neutron magnetic moment is μn = −1.91 μN.
The nonzero neutron magnetic moment implies that the neutron has negati
ve and positive internal charge components.
Complex internal charge distribution, just like the proton.
12
Deep
A few muons (-1e
charge, ½ spin) are
created from the energy
in the inelastic collision
and the release of
nuclear binding energy,
which gets converted
into mass
Relative
cross
sections
13
Nuclear Properties
Atomic masses are denoted by the symbol u.
1 u = 1.66054 × 10−27 kg = 931.49 MeV/c2
Add an electron mass to each side but ignore its binding energy
16
The binding energy of any nucleus = the energy required to
separate the nucleus into free neutrons and protons.
scatter gamma rays from free deuteron gas and look for the breakup of
a deuteron into a neutron and a proton:
icates also the neutron and proton spins are aligned parallel to eac
h other, add up
The nuclear magnetic moment of a deuteron is 0.86 μ ≈ the sum o
N
f the free proton and neutron 2.79 μN − 1.91 μN = 0.88μN (difference
due to mass equivalent of binding energy)
18
12.4: Nuclear Forces
Neutron + proton (np) and proton + proton (pp) elastic collisions.
Very high density in the nucleolus, all nuclei are constantly moving about and
scatter of reach other
In reality
indistinguishable
Electrostatic hump
The nuclear potential energy function for two particles, similar for
many particles
19
Nuclear Forces
The inter-nucleon potential has a “hard core” that prevents the nucle
ons from approaching each other closer than about 0.4 fm.
20
12.5: Nuclear Stability
The binding energy of a nucleus
against dissociation into any
other possible combination of
nucleons. Example nuclei R and S.
21
Nuclear Stability
The “line” representing the stable nuclides is the line of stability.
It appears that for A ≤ 40, nature prefers the number of protons a
nd neutrons in the nucleus to be about the same Z ≈ N.
However, for A ≥ 40, there is a decided preference for N > Z beca
use the nuclear force is independent of whether the particles are
nn, np, or pp.
Only four stable nuclides have odd Z and odd N (odd-odd nuclides).
23
The Liquid Drop Model
Treats the nucleus as a collection of interacting particles in a liquid drop.
The total binding energy, the semi-empirical mass formula (due to
Weizäcker) is
The volume term (av) indicates that the binding energy is approximately
the sum of all the interactions between the nucleons.
The second term is called the surface effect because the nucleons on
the nuclear surface are not completely surrounded by other nucleons.
The third term is the Coulomb energy (4th and 5th term next slide)
24
The Liquid Drop Model
The fourth term is due to the so called “symmetry energy”, has a quantu
m-mechanical origin, consequence of exclusion principle. In the absence
of Coulomb forces, the nucleus prefers to have N ≈ Z.
The last term is due to the pairing energy and reflects the fact that the nu
cleus is more stable for even-even nuclides. Use values given by Fermi t
o determine this term.
where Δ = 33 MeV·A−3/4.
No nuclide heavier than has been found on earth. If they ever exist
ed, they must have decayed so quickly that quantities sufficient to meas
ure no longer exist.
25
one low energy (room-temperature) neutron
being absorbed by 235U, kaboom, and two to
three more medium energy neutrons to make
more “kabooms” if more fissionable uranium is
around
26
Who is the greatest person that history has forgotten
?
Marc Morgenstern, Updated July 6, 2019 · Upvoted by Travis Perry, M.A. History,
Wayland Baptist University (2020) and Brayden Swanson, Studied history
extensively for six years
You’ve probably never even heard of this man, but he’s responsible for saving
billions of lives, as well as civilization as we know it:
27
At the time, nuclear retaliation required that multiple sources confirm an attack
before launching retaliatory strikes against the offending nation. Petrov knew that
any nuclear strike from the US would be massive, and concluded that the system
had triggered a false alarm, that no missiles had been launched from the U.S., and,
disobeying orders from his superiors, stood down the retaliatory launch.
“It was subsequently determined that the false alarms were caused by a rare
alignment of sunlight on high-altitude clouds and the satellites' Molniya orbits, an
error later corrected by cross-referencing a geostationary satellite.”
Petrov’s quick thinking, as well as his refusal to obey orders, prevented what would
have most assuredly been the start of World War III, a devastating nuclear
holocaust would have ensued, and billions of people might have died, as well as
ending civilization as we know it on the Earth.
Petrov had, indeed, saved the world.
So why do we not hear more about this brave man? The glitches in the Soviets’
early-warning system embarrassed military higher ups, and the entire episode was
kept quiet until the incident became known publicly in the 1990s upon the
publication of the memoirs of Colonel General Yuriy Vsyevolodich Votintsev, a
retired commander of the Soviet Air Defense's Missile Defense Units and the officer
who had been in charge at the time of the incident.
28
“Petrov was neither rewarded nor punished for his actions, but was reassigned to
a less sensitive post, took early retirement (although he emphasized that he was
not "forced out" of the army, as is sometimes claimed by Western sources), and
suffered a nervous breakdown.”
29
October 11, 1986, halfway between Moscow and Washington, D.C. … 30
Binding Energy Per Nucleon
31
32
Nuclear Models
Current research focuses on the constituent quarks and
physicists have relied on a multitude of models to explain
nuclear force behavior.
1) Independent-particle models:
The nucleons move nearly independently in a common
nuclear potential. The shell model has been the most
successful of these.
2) Strong-interaction models:
The nucleons are strongly coupled together. The liquid drop
model has been successful in explaining nuclear masses as
well as nuclear fission.
33
Nuclear Models
The nuclear potential felt by the neutron and the proton
The difference of the shape between the proton and the neutron are due
to the Coulomb interaction on the proton.
Nuclei have a Fermi energy level which is the highest energy level filled
in the nucleus.
In the ground state of a nucleus, all the energy levels below the Fermi
level are filled.
34
Nuclear Models
Energy-level diagrams for 12C and 16O.
Note that the
Both are stable because they are p energy
even-even. levels are
higher
Filling up energy
levels up to the
Fermi level Case 2: If we add one
stable
neutron to 12C to make 13C:
35
Nuclear Models
when we add another neutron to produce 14C, we find it is
unstable.
36
12.6: Radioactive Decay
An empirical law that is fulfilled only statistically
Marie Curie and her husband Pierre discovered polonium and radium in
1898.
The simplest decay form is that of a gamma ray, which represents the nucle
us changing from an excited state to lower energy state.
Other modes of decay include emission of α particles, β (– and +) particles,
protons, neutrons, and fission.
37
Radioactive Decay
SI unit of activity is the Becquerel: 1 Bq = 1 decay / s.
In common use is the Curie (Ci) 3.7 × 1010 decays / s equivalent t
o 1 g Ra (typically micro Ci to milli Ci)
If N(t) is the number of radioactive nuclei in a sample at time t, an
d λ (decay constant) is the probability per unit time that any give
n nucleus will decay:
If we set N(t = 0) ≡ N0
----- radioactive decay law
38
Radioactive Decay
The number of radioactive nuclei as a function of time
39
Radioactive Decay
The activity R is also
The half-life is
40
41
42
Radioactive Carbon Dating
Radioactive 14C is produced in our
atmosphere by the bombardment of 14N by
neutrons produced by cosmic rays.
12
6 C is stable
46
12.7: Alpha, Beta, and Gamma Decay
Linear momentum
Angular momentum
Electric charge
Conservation of nucleons
47
Alpha, Beta, and Gamma Decay
Let the radioactive nucleus be called the parent and have the
mass
48
Alpha Decay
The nucleus 4He has a binding energy of 28.3 MeV.
If two protons and two neutrons in a nucleus are bound by less
than 28.3 MeV, then the emission of an alpha particle (alpha
decay) is possible.
49
Alpha Decay
In order for alpha decay to occur, two neutrons and two protons
group together within the nucleus prior to decay and the alpha
particle overcomes the nuclear attraction from the remaining
nucleons and escapes through the potential energy barrier by
tunneling.
51
Alpha Decay
Assume the parent nucleus is initially at rest so that the total mome
ntum is zero.
The final momenta of the daughter pD and alpha particle pα have th
e same magnitude and opposite directions.
So all alpha particles have “about” the
same momentum and kinetic energy
52
accumulated per year
αdecay
Note that the total number of nucleons does not change, we discussed
α-decay in the context of tunneling and Rutherford’s scattering
experiments
55
Beta Decay
Unstable nuclei may
move closer to the line
of stability by
undergoing beta
decay.
The decay of a free
neutron is
That particle will actually be much later, 1956, experimentally observed, 1995 Nobel priz
57
Frederick Reines
Beta Decay
58
β- Decay
There are actually antineutrinos . (In beta-minus decay)
The beta decay of both a free neutron and 14C is written as
59
β+ Decay
Is what happens for unstable nuclides with too many protons
Positive electron (positron) is produced.
Positron is the antiparticle of the electron.
A free proton might decay with t1/2 > 1032 y, nobody knows for sure
The nucleus 14O is unstable and decays by emitting a positron and
a neutrino to become stable 14N.
60
Electron Capture
Classically, inner K-shell and L-shell electrons are tightly bound a
nd L-orbits are highly elliptical, possibility of atomic electron capt
ure.
The reaction for a proton is p + e− n+v
The general reaction is
61
Gamma Decay
If the decay proceeds to an
excited state of energy Ex
rather than to the ground
state, then Q for the
transition to the excited
state can be determined
with respect to the
transition to the ground
state. The disintegration
energy Q to the ground
state Q0.
62
63
Gamma Decay
The excitation energies tend to be much larger, many keV or
even MeV.
The possibilities for the nucleus to rid itself of this extra energy is
to emit a very high energy photon (gamma ray).
The gamma-ray energy hf is given by the difference of the higher
energy state E> and lower one E<.
64
Gamma Decay
The gamma rays are normally emitted soon after a nucleus is put
into an excited state.
65
12.8: Radioactive Nuclides
The unstable nuclei found in nature exhibit natural radioactivity.
66
Radioactive Nuclides
There are only four paths that the heavy naturally occurring
radioactive nuclides may take as they decay.
Mass numbers expressed by either:
4n
4n + 1
4n + 2
4n + 3
67
Radioactive Nuclides
The sequence of one of the radioactive series Th
232
68
Time Dating Using Lead Isotopes
A plot of the abundance ratio of 206Pb / 204Pb versus 207Pb / 204Pb
can be a sensitive indicator of the age of lead ores. Such
techniques have been used to show that meteorites and the earth,
believed to be left over from the formation of the solar system, are
4.55 billion years old.
69
70
71
A Z N
Z Atomic _ symbol
72
73
Thermal Neutron Fission
Fission fragments are highly unstable because
they are so neutron rich.
Prompt neutrons are emitted simultaneously
with the fissioning process. Even after prompt
neutrons are released, the fission fragments
undergo beta decay, releasing more energy.
Most of the ~200 MeV released in fission goes
to the kinetic energy of the fission products, but
the neutrons, beta particles, neutrinos, and
gamma rays typically carry away 30–40 MeV of
the kinetic energy.
74
75
Chain Reactions
Because several neutrons are produced in
fission, these neutrons may subsequently
produce other fissions. This is the basis of the
self-sustaining chain reaction.
If slightly more than one neutron, on the
average, results in another fission, the chain
reaction becomes critical.
A sufficient amount of mass is required for a
neutron to be absorbed (a statistical process),
called the critical mass.
If less than one neutron, on the average,
produces another fission, the reaction is
subcritical.
If more than one neutron, on the average,
produces another fission, the reaction is
supercritical.
An atomic bomb is an extreme example of a
supercritical fission chain reaction.
76
Chain Reactions
A critical fission reaction can be controlled by absorbing
neutrons. A self-sustaining controlled fission process requires
that not all the neutrons are prompt. Some of the neutrons are
delayed by several seconds and are emitted by daughter
nuclides. These delayed neutrons allow the control of the
nuclear reactor.
77
13.5: Fission Reactors
Several components are important
for a controlled nuclear reactor:
1) Fissionable fuel
2) Moderator to slow down neutrons
3) Control rods for safety and to
control criticality of reactor
4) Reflector to surround moderator
and fuel in order to contain
neutrons and thereby improve
efficiency
5) Reactor vessel and radiation shield
6) Energy transfer systems if
commercial power is desired
78
Core Components
Fission neutrons typically have 1–2 MeV of kinetic energy, and because
the fission cross section increases as 1/v at low energies, slowing down
the neutrons helps to increase the chance of producing another fission.
A moderator is used to elastically scatter the high-energy neutrons and
thus reduce their energies. A neutron loses the most energy in a single
collision with a light slow moving particle. Heavy hydrogen (in heavy
water), carbon (graphite), and beryllium are all good moderators.
The simplest method to reduce the loss of neutrons escaping from the
fissionable fuel is to make the fuel zone larger. The fuel elements are
normally placed in regular arrays within the moderator.
79
Core Components
The delayed neutrons produced
in fission allow the mechanical
movement of the rods to control
the fission reaction. A “fail-safe”
system automatically drops the
control rods into the reactor in
an emergency shutdown.
If the fuel and moderator are
surrounded by a material with a
very low neutron capture cross
section, there is a reasonable
chance that after one or even
many scatterings, the neutron
will be backscattered or
“reflected” back into the fuel
area. Water is often used both
as moderator and reflector.
80
Energy Transfer
The most common method is to pass hot
water heated by the reactor through some
form of heat exchanger.
In boiling water reactors (BWRs) the
moderating water turns into steam, which
drives a turbine producing electricity.
In pressurized water reactors (PWRs) the
moderating water is under high pressure and
circulates from the reactor to an external
heat exchanger where it produces steam,
which drives a turbine.
Boiling water reactors are inherently simpler
than pressurized water reactors. However,
the possibility that the steam driving the
turbine may become radioactive is greater
with the BWR. The two-step process of the
PWR helps to isolate the power generation
system from possible radioactive
contamination.
81
Types of Reactors
Power reactors produce commercial electricity.
Research reactors are operated to produce high
neutron fluxes for neutron-scattering experiments.
Heat production reactors supply heat in some cold
countries.
Some reactors are designed to produce radioisotopes.
Several training reactors are located on college
campuses.
82
Nuclear Reactor Problems
The danger of a serious accident in which radioactive elements are
released into the atmosphere or groundwater is of great concern to
the general public.
Thermal pollution both in the atmosphere and in lakes and rivers
used for cooling may be a significant ecological problem.
A more serious problem is the safe disposal of the radioactive wastes
produced in the fissioning process, because some fission fragments
have a half-life of thousands of years.
Three widely publicized accidents at nuclear reactor facilities—one
at Three Mile Island in Pennsylvania in 1979, the others two at
Chernobyl in Ukraine in 1986 and Fukushima in Japan in 2011 —
have significantly dampened the general public’s support for nuclear
reactors.
Large expansion of nuclear power can succeed only if four critical
problems are overcome: lower costs, improved safety, better nuclear
waste management, and lower proliferation risk.
83
≈ 5,000
Bq
inside an
healthy
adult
1
0 n Li H He
6
3
3
1
4
2
86
The European Fusion project, 1991 87
1
0 n Li H He
6
3
3
1
4
2
89
Formation of Elements
As the reaction proceeds, however, the temperature increases, and
eventually 12C nuclei are formed by a process that converts three 4He
into 12C.
Another cycle due to carbon is also able to produce 4He. The series of
reactions responsible for the carbon or CNO cycle are
Proton-proton and CNO cycles are the only nuclear reactions that can
supply the energy in stars.
90
91
92
93
Alpha Decay
From the conservation of energy and conservation of linear
momentum, determine a unique energy for the alpha particle.
94
Sizes and Shapes of Nuclei
The shape of the Fermi distribution
95
96