All About Eve

First time Lucifer's liquor wall is seen almost entirely denuded of alcohol without anyone having been thrown into it.

Charlie is said to be the world's first human/angel child, but Lucifer mentioned the nephilim (human/angel beings) as though they already exist in Sympathy for the Goddess (2017). However, given that the show is largely its own creation and isn't meant to be anything like a literal representation of Christian theology, it's possible that in-universe, nephilim are something other than human/angel beings. As in the case of Lucifer here also having the name Samael, which is said to mean Lightbringer. In "real-world" Christian theology, Samael is a different angel whose name means Venom or Poison of God.

References All About Eve (1950)