… By factorizing 1`(n+l) by (3) we obtain another homogeneous cn-2.c * geometry of order 2.
We denote this quotient by 1`(n+l)/2. It is flag-transitive, with automorphism group …

… through a substitution method with the knowledge of isoelectronic SiP 2 structure in order
to investigate the release of N 2 from the CN x compounds. Four-coordinated N and six-…

… be tetrahedral, as observed for Zn[N(CN) 2 ] 2 , 23 in contrast to 2a. On the basis of this
tetrahedral geometry and stoichiometry, [N(CN) 2 ] 2 - is assumed to bridge in a trans-μ fashion, ie…

… For both systems, CN 2 and CP 2 , we report geometries, … Table 2 collects all our numerical
results on the five … , Ã 3 Π, and c̃ 1 Π in ascending energy order along with the “best” ab initio …

… effects on the geometry as those described above. Comparing the calculated C s and C 2
geometries reveals that the … Bond orders were calculated according to the Hirshfeld scheme. …

… 1-N(CN) 2 and 2-B(CN) 4 were not used because of … order of the salts with B(CN) 4 − >
C(CN) 3 − > N(CN) 2 − , indicating that the coordination ability of the anion increases in this order. …

Synthetic strategies have been developed for the synthesis of complexes of the types {[Re 2
Cl 3 (μ-dppm) 2 (CO) 2 ] 2 [μ-Y]} + , where dppm = Ph 2 PCH 2 PPh 2 and Y = [N(CN) 2 ] or […

… have their expected geometry, and the average Ni-C distance is1.866 (5) Á. The central two
atoms of the tetracyano- … 3 A CH distance of 1.00 A and tetrahedral geometry were assumed. …

… ) 2 linkers and hydrogen-bonding interactions. All of the metal centres have very distorted
coordination geometries. Hg(L)(CN) 2 (L = terpy, bbp) and Pb(terpy)Br 2 [Hg(CN) 2 ] 0.5 show …

… The observed relative rate of the reaction agrees well with the order of the M 2 \M 4 … equatorial
TPA ligands and two axial cyanide groups giving a trigonal bipyrimidal geometry. A search …