Studies of and the -wave charmed-strange mesons are performed based on an collision data sample corresponding to an integrated luminosity of 567 pb collected with the BESIII detector at GeV. The processes of and are observed for the first time and are found to be dominated by the modes and , respectively. The Born cross sections are measured to be $\sigma^{B}(e^+e^-\to D_s^+ \overline{D}{*}^{0} K^-) = (10.1\pm2.3\pm0.8) pb$ and $\sigma^{B}(e^+e^-\to D_s^+ \overline{D}{}^{0} K^-) = (19.4\pm2.3\pm1.6) pb$, and the products of Born cross section and the decay branching fraction are measured to be $\sigma^{B}(e^+e^-\to D_s^+D_{s1}(2536)^- + c.c.)\cdot\mathcal{B}(D_{s1}(2536)^- \to \overline{D}{*}^{0} K^-) = (7.5 \pm 1.8 \pm 0.7) pb$ and $\sigma^{B}(e^+e^-\to D_s^+ D^*_{s2}(2573)^- + c.c.)\cdot\mathcal{B}(D^*_{s2}(2573)^- \to \overline{D}{}^{0} K^-) = (19.7 \pm 2.9 \pm 2.0) pb$. For the and mesons, the masses and widths are measured to be $M(D_{s1}(2536)^-) = (2537.7 \pm 0.5 \pm 3.1)~MeV/c^2,$ and $M(D^*_{s2}(2573)^-) = (2570.7\pm 2.0 \pm 1.7)~MeV/c^2,$ $\Gamma(D^*_{s2}(2573)^-) = (17.2 \pm 3.6 \pm 1.1)~\rm MeV.$ The spin-parity of the meson is determined to be . In addition, the process are searched for using the data samples taken at four (two) center-of-mass energies between 4.416 (4.527) and 4.575 GeV, and upper limits at the confidence level on the cross sections are determined.