We present a practical scheme for the efficient preparation of laser–cooled Ca ions in an ion trap. Our approach integrates two well-established methods: isotope-selective photoionization and isotope-specific parametric excitation. Drawing inspiration from the individual merits of each method, we have successfully integrated these techniques to prepare extended chains of Ca ions, overcoming the challenge posed by their low natural abundance of 0.135% in a natural source. Furthermore, we explore the subtleties of our scheme, focusing on the influence of different factors on the purification process. Our investigation contributes to a broader understanding of the technique and highlights the adaptability of established methods in addressing specific isotopic challenges.