- Speaks four languages: Russian, Ukrainian, German, and English.
- Mayor of Kiev (2014-).
- Older brother of Wladimir Klitschko, WBO heavyweight champion, and companion of István Kovács, WBO featherweights champion.
- He and his brother, Wladimir, grew up as the sons of a helicopter pilot in the Soviet Union's armed forces.
- He and his younger brother, Wladimir Klitschko, have protested and demonstrated in the Ukraine for democracy and for the re-vote election of Viktor Yushchenko.
- Has three children with wife Natalia: Egor-Daniel Klitschko (b. 16 May 2000), Elizabeth-Victoria Klitschko (b. 23 November 2002), and Maxim Klitschko (b. 1 April 2005).
- (11 October) Regained the WBC belt by TKO against Samuel Peter in Berlin. (2008)
- Fourth boxer besides Muhammad Ali, Evander Holyfield and Lennox Lewis to win a heavyweight belt for the third time.
- Has a doctorate degree from Perevaslav-Khmelnitsky Teacher Training Institute (1996). His PhD is in Sport Science and Philosophy.
- Lives mainly in Los Angeles, California, USA. He also has houses in Hamburg, Germany and Kyiv, Ukraine.
- Although he and his wife are both citizens of Ukraine, his children are American citizens, as they were all born at Cedars-Sinai Medical Center in Los Angeles, CA, USA.
- During a sparring match that was meant to prepare him for his scheduled 12 November 2005 fight with Haseem Rhamin, Vitali's knee was injured. He had surgery on 8 November 2005 for a rupture in the torn anterior cruciate ligament (ACL) and damage to the medial meniscus on his right knee. After learning that it would be a fairly long time before he would be allowed to fight again, Vitali made his announcement to retire on 9 November 2005.
- Before losing to Chris Byrd was 27-0(27), a Heavyweight record for consecutive knockout wins from the beginning of a career.
- Vitali and Natalia are expecting their third child, a boy, in March. (January 2005)
- Vitali Klitschko retired from professional boxing at the age of 34 on Wednesday, 9 November 2005. He is set to work on social issues, and possibly politics, in his native Ukraine. (November 2005)
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