- With his older brother, Ira Louvin, elected to the Country Music Hall of Fame in 2001.
- He and his older brother, Ira Louvin, parted ways on 18 Aug 1963.
- First cousin of John D. Loudermilk.
- He runs The Louvin Brothers Museum in Bell Buckle, Tennessee
- Along with his older brother, Ira Louvin, during their days as The Louvin Brothers, they recorded with legendary Nashville guitar player Hank Garland.
- Bell Buckle, Tennessee (March 2005)
- He died from complications of pancreatic cancer in the early morning of January 26, 2011, at his home in Wartrace, TN.
- He had three sons with his wife, Betty: Charlie "Sonny" E. Jr. (born July 25, 1954; died January 27, 2016), Glenn and Kenneth.
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