- Graduated with a drama degree from Northwestern University in Evanston, Illinois.
- Release of her children's book, "Henry and the Hidden Veggie Garden" by Kimberly and her father, Gurney Williams. (2008)
- Gave her son the middle name Huckleberry after the Mark Twain book, "Huckleberry Finn".
- Second son, Jasper Warren Paisley, was born April 17, 2009. He weighed 9 lbs. 10 oz. Jasper got his middle name from Brad's grandfather who brought Brad his first guitar.
- Older sister of Ashley Williams and Jay Williams.
- Had her first child, a boy, named William Huckleberry. (February 2007)
- On February 22, 2007 she and husband ,Brad Paisley, had their first child, a boy named William Huckleberry Paisley (He goes by "Huck" for short). The boy was born at 5:20 am in Nashville, Tennessee and came into the world with black hair weighing in at 7 lbs, 7 oz. Kimberly was in labor for close to 10 hours.
- Engaged to country music star Brad Paisley. (October 2002)
- Daughter of Gurney Williams, a freelance medical journalist, and Linda Williams (June 22, 1943 - November 16, 2016), a fundraiser.
- Her son's first name, William, is from her maiden name, Williams.
- She has English, Welsh, and German ancestry.
- Her wedding was featured in the February 2004 issue of In Style Magazine, and also on the ABC special, Celebrity Weddings: In Style (2006).
- Once wanted to be a disc jockey.
- Member of Alpha Phi sorority at Northwestern University.
- She and her husband have a dog named Hollar whose name comes from the part of Nashville he was found in.
- Is a native of Rye, New York.
- Announced that she is expecting her second child, with husband Brad Paisley, in April 2009 [October 15, 2008].
- Sister-in-law of Neal Dodson.
- Supported then-Illinois Senator Barack Obama in the 2008 presidential election.
- Aunt of Gus Williams Dodson and Odie Sal Dodson.
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