Appeared as Jane Castle in a promotional film "Space Police", which helped sell the series that ultimately became Space Precinct (1994). Chloë was not cast in the series. The promotional film was directed by her father Paul Annett.
Chloe Annett replaced Clare Grogan as Kristine Kochanski in "Red Dwarf", when Kochanski became a regular character in Series 7. Annett continued to play the role until the end of Series 8 and made only a cameo in the role for the 2009 special "Back to Earth".