Guan Xiao Tong, a matchmaker with chronically bad luck in life and love, is shocked when a divorce agency opens right across from her work, and the rick playboy who works there, Ji Jia Wei, begins entangling himself in her life.
On her boss's order, Xiao Tong must convince Jia Wei to attend the matchmaking agency's event as their Hot Pick. Meanwhile, Jia Wei takes up the false name 'Wayne' to seek love advice from Xiao Tong online.
Xiao Tong seems to have found the perfect 4G man. Meanwhile an incident with one of the divorce agency's clients leads Jia Wei to agree to the hop pick event.
Just as the event is about to fail, Xiang Zi Yang swoops in and saves the day. Jia Wei subsequently proposes a collaboration between the two agencies as an excuse to get closer to Xiao Tong.
A disgruntled client from the matchmaking event stalks Xiao Tong and threatens lawsuit against the company, causing Xiao Tong to doubt her own ability to continue being Dr. Love.
With Dr. Love's help, Jia Wei gets over his former girlfriend. Xiao Tong, through helping Wayne, reaches an epiphany of her own about her past relationship.
Jia Wei confronts his ex-girlfriend He Zhi Yu about what happened between them. But while he wants to part ways, Zhi Yu inexplicably starts showing up in parts of his daily life.