MATHEMATICS - III

(Math-201E)
L T P Sessional : 50 marks
3 2 1 Theory : 100 marks
Total : 150 marks
Time : 3 hours

Euler's formulae, Conditions for Fourier Expansions, change of interval, Fourier expansion of
odd and even functions, Fourier expansion of square Wave, half & full rectified wave, half range
sine and cosine series. Fourier integrals Fourier transforms, (Shifting theorem (both on time and
frequency axes). Fourier transforms of derivative, Fourier transforms of integrals, Convolution
theorem, Fourier transforms of Dirac Delta function.
(Part - B)

Definition, Exponential function, Trigonometric and Hyperbolic functions, logarithmic

functions, Limit and Continuity of functions, Differentiability and Analyticity. Cauchy -
Riemann equations, necessary and sufficient conditions for a function to ne analytic, polar form
of the Cauchy - Riemann equations. Harmonic functions application to flow problems,
lntegration of compiled functions Cauchy integral theorem and formula. Power series, radius and
circle of convergence, Taylor's Maclaurin's and Laurent's series, zeroes and singularities of
complex functions, Residues, Evaluation of real integralising residues (around unit and semi
circle only.

(Part - C)

Probability, Distribution and Hypothesis Testing :

Condition probability, Bayes theorem and its applications expected value of a random variable
Properties and applications of Binomial, Poission and Normal distributions. Testing of
hypothesis, tests of significance for large sample, Chisequare test of goodness of fit, Discrete &
continued Probability, Properties & applications of Binomials, Moment generating function.

Linear Programming :
Linear programming problems formulation, Solving linear programming using (i) Graphical
method (ii) Simplex methods (iii) Dual simplex method.

Text Books :

1. Advanced Engg. Mathematics : E Kreyzing

2. Higher Engg. Mathematics : B.S. Grewal.

Reference Books :

1. Complex variables and Application : R.V. Churchill:

2. Advanced Engg. Mathematics : Michael D. Greenberg.
3. Operation Research : H.A. Taha.
4- Probability and statistics for Engineer : Johnson PHI.
 CHEMISTRY - II

L T P Sessional : 50 marks
3 1 - Theory : 100 marks
Total : 150 marks
Time : 3 hours

UNIT- I

Classification of organic reactions- Types of mechanism, types of reactions, Reaction

intermediates, the mechanism of the following type of reactions. substitution - Electrophiilic,
nucleophiilic, fee radical, Addition- Electrophilic, nucleophillic, free radical Elimination-
Elimination ( E1 and E2 type) Rearrangement, Migration with electron (electrophillic).

Chemistry of Hydrocarbons : sources, preparation and uses of alkanes, alkenes, alkynes,

cracking & reforming aromatic hydrocarbons, concept of aromaticity (Huckel rule, 4n+2) rule)
and directive effect.
UNIT.II

chromatography : Introduction, classification, solid, Liquid chromatography (LSC)_ TLC,

Liquid - Liquid Chromatography (LLC), Column, GPC, HPLC, Gas-Liquid Chromatography
(GLC).
UNIT.III

chemical Kinetic : Rate expression of reactions of various orders, rate mechanism, kinetics of
complex reactions, molecularity, order of reaction, concept of energy barrier and activation
energy theories of reaction rates, Arhenius equation'
 UNIT .IV

chemical Equilibrium : Equilibrium constant, Factors affecting, Ka, Kp, Standard free energy
and equilibrium constant, homogeneous and heterogeneous chemical equilibria, lechtelier's
principle and its applications' Relation between Kp and Kc'

Text Books :

1. Advanced organic chemistry (Reaction Mechanism and structure) by Jerry

March (WilleY Easern 3rd edition)
2. Text Book of Organic Chemistry by R'K' Bansal' (T'M'H')
3. Organic Chemistry by Morrison, Bayd (P'H'L')
4. Chromatography by B'K' Sharma ((Goel Publishing' Merrut')

Reference Books :

1. Organic Chemistry Vol' I By l'L' Finar (ELBS)'

2.schaum's solved Problems series,organic chemistry(T'M'H')
3.organic Reaction Mechanism,3rd edition(T.M.H')by R.K.Bansal.
 CHEMISTRY.II LAB
(CHE-203E)
L T P Class Work : 25 marks
- - 3 Practical : 50 marks
Total : 75 marks
Time : 2 hours

UNIT.I

ldentification of organic compounds :

1. Preliminary tests (elemental analysis, lgnition, colour, odour and
determination of physical constants) functional group analysis, preparation
of derivatives, Organic Acids, Aldehydes, Ketones, Amides, .Phenols,
amines, Carbohydrates, Hydrocarbons.
Preparation of aspirin, 2,4, 6- tribromoaniline, picric acid from phenol,
iodoform, Sbenzyl isothio urounimchloride.

Quantitative organic analysis :

2. Estimation of phenol,aniline,formaldehyde
3 To determine kinetics of reaction between ethyl acetate and sodium hydroxide at
Room temp. by method of half life period.
4' To determine the activation energy for reaction between ethyl acetate and sodium hydroxide
by integral and differential method.

Books Recommended :

1. Qualitative Organic analysis by A.I. Vogel ( ELBS) Longman.

2. Advanced organic analysis by satish Aggarwal & R.c. Aggarwal (pargati prakashan)
3. Practical Organic Chemistry by G.Mann Longman
 CHEMICAL ENGINEERING PROCESS CALCULATION
(CHE-201E)
L T P Sessional : 50 marks
4 2 - Theory : 100 marks
Total : 150 marks
Time : 3 hours

UNlT I

Brief introduction of chemical engineering unit processes and unit operations' Units and
dimensions, dimensional groups and constant, Stoichiometric relationships, Conservations of
mass in chemical reactions, Excess reactants' Degree of completion, Behaviour of ideal gases,
Gaseous mixtures, vapour pressure, clausius clapeyron equation, cox chart, Duhring's plot,
Raoult's law & Henry law.

UNlT – ll

Humidity and saturation, Relative humidity, Humid heat, Humid volume, Dew point, Humidity
chart and its use.

UNlT- lll

Material balance problems with and without chemicals Rxn's Recycle, By-pass
and Purge Calculations.

UNIT.IV

lnternal Energy, Heat capacity, calculation of enthalpy changes, Energy balances with chemical
reaction, Heat of vaporization, Heat of formation, Heat of combustion , Heat of reaction.
Text Books :

1.Chemical process principles, D.A. Hougen & K.M. WatSon VOl. I Asia Publishing House'
2. "Basic Principles and calculations in chemical Engineering D'M' Himmelblau, Prentice Hall'

Reference Books :
1. "Chemical Process Analysis, Mass and Energy'
2. Balance..W.L'LuybenandL.A.Wenzel,PrenticeHall'
3. "Chemical Calculation' D.P. Tiwari, Vrinda Publications (Zalgaon)'
 FLUID FLOW CALCULATION
(CHE-203E)
L T P Sessional : 50 marks
3 1 - Theory : 100 marks
Total : 150 marks
Time : 3 hours

UNIT.I
Properties of fluids, Classification of fluid-forces, Normal forces on fluids, Pressure depth
relation for compressible and incompressible fluids, Forces on submerged bodies, Pressure
measurement by manometers, Kinematics of flow, lrrotational flow, Types of flow, velocity
distribution for laminar flow in conduits, Reynold's number and its signifiiance.

UNIT.II
Conservation of mass, momentum and energy, Euler's equation. Energy losses in fittings, valves
etc.
UNlT – lll
Hagen- Poiseuille equation, Friction factor, Friction factor equations, Dimensional analysis of
fluid flow problems. FIow through beds of solids : Kozney carman and Burke Plummer equation.
Energy losses in fittings, valves etc.
UNIT- IV
Compressible fluid flow in pipes, Flow measuring devices Mixing of fluids, Power requirements,
pumps, Blowers Valves and their characteristics.

Text Books :
1' "chemicar Engineering" J.M. Coulson and J.F. Richardson Vol-1.Pergamon.
2. "Unit Operations of Chemical Engineering”, W.L. McCabe and J.C. Smith. McGraw Hill.
References :

1' "Fluid Mechanics". A.K. Jain Khanna publishers, New Delhi.

2' "Hydraulics & Fluid Mechanics”, Jagdish Lal, Metro-polliton Books co. pvt. Ltd. Delhi
 BASIC THERMODYNAMICS
(CHE-205E)
L T P Sessional : 50 marks
3 1 - Theory : 100 marks
Total : 150 marks
Time : 3 hours

UNIT.I
P-V-T Behaviour of Pure Fluids- Virial equations, cubic equations, generalized correlations,
Concept of entropy, Work and heat, Cp, CV open system and closed system, extensive and
intensive properties Throttling process, joules Thompson coefficient.

UNIT - II
Laws of thermodynamics- Energy equations for close system and steady flow processes,
Limitations of first law, carnot cycles, concept of available energy and dead state availability and
irreversibility.
UNIT - lll
lnternal Energy, enthalpy, Thermodynamics relations: Maxwell relations, Helmholtz and Gibbs
function, Tds equations, clausius clapeyron equation.

UNIT.IV
Rankine cycle, Air standard cycles, vapour compression cycle, otto cycle, Brayton cycle,
regrigerant and their properties, Liquifaction of gases, generation of power from heat.
Text Books :

1. Engineering Thermodynamics by p.K. Nag.

2. Chemical Engineering Thermodynamics By y.V.c. Rao, Universities press (India) Ltd.

Hyderabad India.
References
1' chemical and process Thermodynamics by B.G. Kyle, prentice Hall of India Pvt. New Delhi.
2' Engineering Thermodynamics by Gordon Rogers and yon Mathews,
Pearson Education
 MATERIAL TECHNOLOGY
(CHE-207E)
L T P Sessional : 50 marks
3 1 - Theory : 100 marks
Total : 150marks
Time : 3 hours
UNIT.I
Factors affecting the selection of material for constructional purposes in chemical industries,
Mechanical properties of various materials, various modes of deformation, crystal defects, cold
and hot working of metals and their effects on mechanical properties.

UNIT - II
Corrosion, Various types, Mechanism, Factors affecting corrosion, Methods of prevention and
control.
UNIT - III
Heat treatment : General principles, TTT-curves, Annealing, normalizing, hardening, tempering
and age hardening, critical cooling rate, flame hardening, lnduction hardening.

UNIT- IV
Material of construction : Ferrous Metals, Grey and white castiron, Plain Carbon steels :
Classification, properties and applications, Alloy steels : Stainless steels, applications of stainless
steels in chemical industries, Ceramics- Various types, Speciality glasses and refractories,
properties and applications. Polymers : Classifications, comparison and properties, of various
polymers and their relationship with chain structure.
Text Books :
1. "Material Science & Engineering", V. Raghawan Prentice Hall.
2. "Material Science" O.P. Khanna, Dhanpat Rai Publications, New Delhi.
Reference Books :
1. .Engineering Material", Longman Vol. ! & ll.
2. "Material of Engineering : Concepts and Application, Van Vlack, V.L.,Addison Wesley
 FLUID FLOW LAB
(CHE-209E)

L T P Class Work : 50 marks

- - 3 Practical : 100marks
Total : 150 marks
Time : 3 hours

List of Experiments :
• Flow measurement by Venturimeter.
• Flow measurement by Orificemeter.
• Calibration of Rotameter.
• Flow measurement by V-notch.
• Pressure drop in pipe flow.
• Verification of Bernoulli's Theorem.
• Determine friction factor in pipes of different material.
• Flow measurement by pitot tube.
• To obtain the equivalent length of various fittings.
 BASIC THERMODYNAMICS LAB
(CHE-211E)
L T P Class Work : 50 marks
- - 3 Practical : 100 marks
Total : 150 marks
Time : 3 hours
List of Experiments :
1. To study 4-Stroke Petro,l Engine.
2. To study 4-Stroke Diesel Engine.
3. To study 2-Stroke Petrol Engine.
4. To study 2-Stroke Diesel Engine.
5. To study the Babcock and Wilcox boiler.
6. To study the Cochran boiler.
7. To study the Lancaschire boiler.
8. To study Vapour compression refrigeration cycle.
9. To study steam engine model.
10. To study a trial on the water cooler and to determine its C.O.P