Reaction Summary: ALKENES
Reagent                       Conditions                  Products                        Observations                  Example/Diagram
Br(l)                                 Room temperature          Vicinal dibromide       Bromine decolorized
                                      No light
Br(aq)                                Room temperature          Vicinal dibromide       Bromine decolorized
NB: CAPE just uses the dibromide                                  (minor product)
as the product. They disregard the                               Bromoalcohol (major
alcohol.                                                          product)
Hydrogen halide                       Room temperature          Halogenoalkane
HX where X is F, Cl, Br, I            Hydrogen halide either
                                       dissolved in ethanoic
                                       acid or gaseous HX
                                       bubbled through alkene
H+(aq)/KMnO4(aq)                      Cold dilute               Vicinal diol            Purple colour of KMnO4(aq) decolorized
                                       H+(aq)/KMnO4(aq)
H+(aq)/KMnO4(aq)                      Hot concentrated          Mixture of compounds Purple colour of KMnO4(aq) decolorized
                                       H+(aq)/KMnO4(aq)           containing a carbonyl
                                                                  group (C=O) (ketones,
                                                                  carboxylic acids,
                                                                  aldehydes which are
                                                                  oxidized to acids)
                                                                 Sometimes CO2 and
                                                                  H2O formed as well
Hydration                             Acidic catalyst           Alkyl hydrogensulfate
                                       (concentrated H2SO4)       which is then
                                                                  hydrolyzed with H2O to
                                                                  an alcohol and the
                                                                  sulphuric acid is
                                                                  regenerated
Hydrogenation                         Room temperature          Corresponding alkane
(addition of hydrogen)                 (150oC)                    (unsaturated
                                      High pressure              compound)
                                      Catalyst – nickel or
                                       platinum