Colla 2016
Colla 2016
Key words:                              Abstract – In the international steel market, competitiveness is crucial since the market is
Steel making; smelting reduction;       increasingly complex and dynamic. The steel companies face ever more stringent environ-
direct reduction; EAF; BF/BOF           mental regulations pushing toward process improvements focused on increasing resource
                                        efficiency while keeping economic sustainability. Investing in new and promising technolo-
                                        gies when the current equipment and machinery become obsolete or unproductive is a task
                                        of utmost importance although not always easy to achieve. In Italy a steelwork located in
                                        Piombino produces high steel quality products but is currently undergoing an important
                                        revamping and renovation process. The case of the Piombino steelwork is an interesting
                                        example of the opportunities faced nowadays by European steel industry in the challenge
                                        of increasing global competition. An overview of some combinations among the possible
                                        and fruitful commercialized technologies that can be implemented in the specific situa-
                                        tion and location of Piombino are presented and analysed. Each alternative technology is
Received 10 July 2015
                                        briefly depicted as well as some economic and environmental aspects of the possible mix
Accepted 9 March 2016
                                        combination.
last Furnace (BF)-Basic Oxygen Fur- it is at the end of its operative life and within
             Western Europe. The steelworks that instead          in order to mantain the market share of high
             have preserved the sinter plants thanks to           quality products. According to [5], the pres-
             investments in technological improvement             sure to restructure and reduce production
             acquired a great competitive advantage in            capacity will remain one of the main chal-
             the market. Moreover, if appropriate mate-           lenges for the steelmaking industry in the
             rial is used, sinter plants are in compliance        foreseeable future. The creation of a center
             with environmental regulation on air emis-           in Lucchini spa for disposal of military ships
             sions as demonstrated by several examples            and handling of large cruise ships is another
             in Europe [2]. In Lucchini spa, part of the pro-     essential element in view of the reorganiza-
             cess gases coming from the BF and coke oven          tion planning of Piombino steelplant. The
             plant is sold to the three power plants (one is      recovered steel scrap from the ship disman-
             currently being closed) producing an impor-          tling can maintain a stable flow estimated
             tant source of income. This is a benefit also        approximately 100–200 kt per year. The steel
             in terms of CO2 allowance saving as they             scrap to be purchased on the market for
             are considered as avoided emissions. In this         some technical reasons can be imported by
             article, an overview of the possible and reli-       ship through the available port instead of
             able steelmaking alternative technologies al-        by truck and this can be considered as an
             ready used at industrial scale which could be        alternative and additional supply channel
             implemented in Lucchini spa in place of the          with respect to some Italian and European
             current facilities will be presented and anal-       steelworks.
             ysed. In the literature, several studies can be          Section 2 presents a general overview
             found where different steelmaking technolo-           of the ironmaking technologies that are al-
             gies have been compared. Barella et al. [3]          ternative to the traditional BF/BOF route.
             have analyzed new innovative steelmaking             Section 3 depicts some case studies, which
             activities in order to increase competitive-         will be analysed and compared from eco-
             ness while complying with environmental              nomic and environmental points of view. Fi-
             regulations. Hasanbeigi et al. [4] describe          nally, the main conclusions of the work are
             and compare the most important emerging              summarized in Section 4.
             alternative technologies in terms of energy
             and environmental benefits as well as infor-         1 Alternative ironmaking
             mation on costs and commercialization sta-             technologies
             tus. The revamping of Lucchini is and must
             remain fully consistent with the environ-            1.1 Direct reduction processes
             mental regulation of the Integrated Pollution
             Prevention and Control authorization duly            There are several processes for direct re-
             issued by the Environmental Minister [2]. At         duction (DR) of iron ore which use coal or
             the same time, Lucchini’s sustainable com-           natural gas as fuel. Table 1 summarizes all
             petitive position on the international and           the most important commercial technolo-
             global steel market should be preserved.             gies for direct reduction as well as emerging
             For such purposes, a technological restruc-          technologies.
             turation, which allows for a highly flexible             The product of direct reduction is a
             production with respect to the consumed              spongy spheric iron pellet, called Cold Di-
             raw materials ensuring the continuation of           rect Reduced Iron (CDRI) or a solid ingot
             high quality special steel production (i.e. for      called Hot Briquetted Iron (HBI), which is
             railway use) should be adopted. In such a            denser than CDRI. CDRI worldwide pro-
             way the considerable know-how achieved               duction is about 8 times greater than the
             through the years will not be lost, but rather       HBI production, but HBI production covers
             the economic sustainability and the future           45% of the traded market, due to less restric-
             of such facility in the European steel mar-          tive regulations for shipping [7]. DRI/HBI
             ket will be guaranteed. The steel production         is a flexible raw material because it can be
             which is currently 1.6 Mt/year has to be re-         charged hot in the EAF with significant en-
             duced to approximately 1 Mt/year: this is the        ergy saving or in the BOF as coolant sub-
             minimum steel production level to be kept            stituting steel scrap without affecting the
                                                                  chemical quality of steel [3,8]. Natural gas as
401-page 2
                          V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
reducing agent is used by MIDREX NGTM ,               of all forms of DRI products. It often consists
     r                  r                r
HyL   /ENERGIRON          and FINMET     pro-      of four stages: (1) reduction gas; (2) reform-
                    r
                    
cesses. MIDREX Process Technology is                  ing; (3) heat recovery; and (4) briquette mak-
the world’s leading technology and cur-               ing. DRI is produced by reacting iron oxide
rently it has evolved in two main configu-            with a hot reducing gas containing mainly
rations: MIDREX NGTM (using natural gas)              hydrogen (H2 ) and carbon monoxide (CO).
               r
and MXCOL         (using coal) [9]. MIDREX           H2 and CO reduces Fe2 O3 into metallic iron
plants produce about 60% of the entire                (Fe) and the by-products of this reaction are
                      r             r
world’s DRI, HyL         /Energiron accounts        CO2 and H2 O [13, 14]. Iron oxide is reduced
                                                                        r
for 15% and the remaining 25% accounts                in the MIDREX      Shaft Furnace by the re-
                                                                                                r
for the coal-based technologies [10, 11]. In          ducing gas generated in the MIDREX         Re-
                                                                                   r
                                                                                   
order to achieve a better environmental               former [9]. In the MIDREX Reformer natu-
performance, this analysis considers only             ral gas is heated and catalytically reformed
the processes exploiting natural gas. Cir-            along with recycled CO2 and H2 O from the
cored process uses pure hydrogen as re-               reduction process to generate a rich reduc-
                                                                                               r
ductant and since hydrogen is not natu-               ing gas to make DRI [13]. MIDREX           Re-
rally available, it has to be obtained through        former also provides the energy needed for
                                                                                                    r
some processes consuming energy [12]. In              the reduction reactions within the MIDREX
the case of Circored, the EAF melting has             Shaft Furnace [13]. DRI yield can be up
to be adapted as there is no transfer of coal         to 99%. Some MIDREX plant/EAF facilities
in the iron during the reduction. The Cir-            emit only one-third of the CO2 per tonne of
cored process is not operating anymore and            steel of a BF/BOF complex [15, 16]. The high
in the present analysis it will not be consid-        simplicity using natural gas and agglomer-
ered. Finmet too is not widely spread: there          ated iron ore and flexibility about iron ore
is only one plant in Venezuela [12] and, like         reducing gas sources are the main benefits
Circored, it will not be included in this study.      of this technology. Unfortunately, the need
                                                      to use a large amount of natural gas approx-
                                                      imately between 260–280 Nm3 /t DRI is the
1.1.1 MIDREX NGTM process                             main obstacle to its diffusion in the European
MIDREX NGTM , the natural gas-based con-              Union [6]. An annual production of 500 kt
figuration of MIDREXr
                       process, is the most           of DRI would require a supply of natural
widely-used technology for the production             gas (with a calorific value of 8490 kcal/Nm3 )
                                                                                                        401-page 3
                                      V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
             between 130 and 140 million Nm3 /year. The           ENERGIRON ZR. H2 O and CO2 are re-
             only DRI-making plant in Europe is located           moved through top gas scrubbing and CO2
             in Germany near Hamburg and operates                 removal systems, respectively [22]. The CO2
             since 1971. In 2013 DRI production was               absorption system captures even the sulfur,
             nearly 500 kt [17, 18]. According to [19], DRI       whenever present in the process gas stream,
             worldwide production increased from less             reducing the overall SO2 emissions from
             than one million tonnes per year in 1971 to          the plant around 99% [24]. Some significant
             over 70 million tonnes forty years later and         achievements have been reached also in the
             it is expected to continue this rapid increase       reduction of NOx emissions. By adopting
             for years to come.                                   ultra-low NOx burners, the NOx emissions
                                                                  can be reduced to values below 25 ppmv
                                                                  (50 mg/Nm3 as NO2 ) [26]. Table 2 compares
             1.1.2 ENERGIRON
                            R
                              process                             MYDREX     r
                                                                                 and ENERGIRON      r
                                                                                                       ZR in terms
                                                                  of facilities, type of feedstock, operating con-
                            r
             ENERGIRON        process uses a H2 -CO re-          ditions and related flexibility [6].
                                                 r
             ducing gas as in the MIDREX           process.          Midrex and HYL Energiron are the lead-
                            r                          r
             ENERGIRON is the innovative HyL
                            
                                                         di-      ing technologies in shaft furnace direct re-
             rect reduction technology developed jointly          duction, and they account for about 76%
             by Techint and Danieli, which merged                 of worldwide production [27]. They are the
             their knowledge and previous technolo-               most competitive ways to obtain high qual-
                                         r
             gies (Danarex and HyL        ). Very recently       ity direct reduced iron (DRI) for steelmaking.
                            r
                            
             ENERGIRON has introduced a reformer-
                                                 r
             less version called ENERGIRON        ZR (Zero
             Reformer) [20] which uses a combination              1.1.3 ULCORED process
             of partial oxidation of natural gas with
                                                                  ULCORED is a breakthrough technology
             oxygen and in situ reforming [10, 21].
                            r                                     identified within the ULCOS consortium
             ENERGIRON        ZR provides a self (auto/in
                                                                  and, like MIDREX and HyL, it produces di-
             situ)-reforming of natural gas which directly
                                                                  rect reduced iron from direct reduction of
             occurs within the Vertical Shaft Furnace
                                                                  iron ore (in form of lumps or pellets) by
             (VSF) using DRI as catalyst. The reducing
                                                                  gas-based direct reduction in a shaft fur-
             gases are generated by “in-situ” reforming
                                                                  nace [28]. An experimental direct reduction
             within the reduction reactor, feeding nat-
                                                                  pilot is planned to be erected in Lulea, but
             ural gas as make up to the reducing gas
                                                                  it is not yet confirmed [28–30]. This process
             circuit and injecting oxygen at the inlet of
                                                                  uses oxygen instead of air and the concept
             the reactor [22]. Other reducing agents such
                                                                  includes also a POX (partial oxidation) in-
             as hydrogen gas, coal, pet-coke and similar
                                                                  stead of reformers, shifter for production of
             fossil fuel and coke oven gas, among oth-
                                                                  CO2 free reduction/excess gas and the reduc-
             ers, are also potential sources of reducing
                                                                  ing agent being either natural gas or syn-
             gas depending on the particular situation
                                                                  gas from coal/biomass [31]. With respect to
             and availability. HBI and DRI with a low                        r
                                                                  MIDREX      , it is able to reduce natural gas
             or high carbon content are the main prod-
                                    r                             consumption by 20–25% and CO2 emissions
             ucts of ENERGIRON        [23]. A high reduc-
                                                                  by 15–20% [32]. There is also some signif-
             tion temperature (above 1050 ◦ C), “in-situ”
                                                                  icant savings in terms of electrical energy
             reforming inside the shaft furnace and the
                                                                  consumption [33, 34], even if its industrial
             various energy recovery units in the plant
                                                                  scale and feasibility are yet to be proved.
             are the most important features in order
                                        r                         This process needs to be supplied with iron
             to optimize ENRGIRON         ZR’s overall en-
                                                                  ore of high quality [35].
             ergy efficiency [24]. Therefore, DRI prod-
             uct takes most of the energy supplied to
             the process, with minimum energy losses              1.2 Smelting reduction processes
             to the environment [25]. The selective re-
             moval of both by-products, water and car-            The Smelting Reduction (SR) process is an
             bon dioxide, generated from the reduction            alternative to BF route and to DRI produc-
             process is one of the distinctive feature of         tion. The final product is liquid pig iron or
401-page 4
                           V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
                                  r              r
Table 2. Comparison between MIDREX and ENERGIRON ZR.
in some cases, liquid steel [16]. It omits coke (2) a stage of gasification of coal and
production by combining the gasification of           smelting reduction in the melter-gasifier,
                                                                                                r
non-coking coal with the reduction of iron            which is the main reactor of the COREX
ore in a liquid bath [36]. SR includes several        technology.
processes, some of which have been com- In the first step, lump iron ore and/or pel-
                                  r
mercially proven e.g. COREX         (where pel- lets and additives are loaded into the top of
 lets and lump ores are reduced in a shaft), a reduction shaft. In the second stage, the
        r
 FINEX     (where fines ore are reduced in a reduced iron is melted in a melter-gasifier
series of fluidized bed reactor) and ITmk3 unit using the energy generated from the
while others are still under development gasification (and partial combustion) of coal.
                                       r
(e.g. Hismelt). However COREX           , among Reducing gas (CO and H2 ) from the melter-
SR technologies, appears to be the most ma- gasifier is injected into the lower part to re-
ture one [4].                                     duce the iron ore to sponge iron. Hot metal
                                                  and slag are tapped at the bottom through
                                                  a similar procedure used in the BF conven-
1.2.1 COREX     R
                   process
                                                  tional tapping [39]. The two stages allow to
         r                                       use a wide range of low cost coals (steam
COREX is a promising alternative emerg-
                                                  coal) directly (if the particle size is greater
ing ironmaking technology currently com-
                                                  than 8 mm) or in briquettes (if the parti-
mercially proven [37], even if there is a
                                                  cle size is less than 8 mm). As an alterna-
low adoption rate in the steel industry
                                                  tive to the coal, a 5% maximum amount
worldwide [4]. It allows for cost-efficient
                                                  of rigid plastics can also be fed directly
and environmental friendly production of                        r
                                                  into COREX     . The process takes place at
hot metal directly from iron ore and non-
                                                  high pressure up to 5 bar and the reducing
coking coal [4,38]. SIEMENS VAI develops it.
          r                                       gas composition is 65–70% CO, 20–25% H2
COREX       process is a two-stage direct smelt-
                                                  and 2–4% CO2 . The hot gas leaving from
ing processes:
                                                  the melter-gasifier unit is cooled to 800–
(1) a pre-reduction stage;                        900 ◦ C and cleaned in a hot cyclone to recycle
                                                                                                               401-page 5
                                        V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
                                          r
             entrained fines [40]. COREX   export gas can          lump form and the rest (35%) is fed as pul-
             be utilized in several ways:                           verized coal along with oxygen in the lower
                                                                    part of the melter-gasifier. The conversion of
             (a)    directly within the cycle;
                                                                    coal into char and its gasification is similar
             (b)    DRI production;                                                 r
                                                                    to the COREX     processs [44]. The hot DRI is
              (c)   electric energy generation;
                                                                    compacted and charged into a melter gasi-
             (d)    heating;
                                                                    fier unit [45].
             (e)    steam production;
              (f)   chemical processes [41].                            HIsarna (“HI” from HIsmelt and “sarna”
                       r
                                                                    from the Celtic for iron isarna) is one of
             COREX       uses approximately one tonne of           the different processing methods selected
             coal per tonne of hot metal with approxi-              within the ULCOS project [28, 29, 46]. The
             mately 45% of the total energy input used              HIsarna process produces liquid hot metal
             in ironmaking while the rest goes to the ex-           from iron ore fines using non-coking coal as
             port fuel gas [42]. The produced hot metal             reductant. There is no need for ore agglom-
             has carbon and silicon content similar to BF           eration or coking. It is a two-step process: a
             hot metal, while the sulfur content is much            cyclone where the fine ore is prereduced and
             higher [40,42]. The coal particle size used by         melted and an iron bath reactor where the
                       r
             COREX      is moderately higher than BF, gen-         ore is finally reduced. The reactor uses the
             erating a 30–35% of discard with respect to            heat generated by degassing the coal [47].
             the standard coal supply. There is a negative          It requires considerably less carbon than a
             impact on the production costs if the inter-           conventional BF with a significant CO2 emis-
             nal re-use or the selling of this coal is not          sions reduction. It is also a flexible process
             possible [43]. A comparison between a con-             allowing a partial substitution of coal by
                                           r
             ventional BF and a COREX       process shows          biomass, natural gas or hydrogen [32]. A
                            r
                            
             that COREX uses more additives and more                HIsarna pilot plant with a nominal capacity
             oxygen (from 12 to 24 times more) and it               of 60 000 t/year (8 t/h) is located in the Tata
             consumes more nitrogen (3.6 times more). It            Steel site of Ijmuiden (The Netherlands) [32].
             consumes less iron ore (–6%) and less electri-         This pilot plant has been constructed by a
             cal energy (–11%) than the BF/BOF route. As            Consortium of European steelmakers united
                                                          r
             far as the process gas is concerned, COREX            in the ULCOS project with the support of Rio
             generates the same amount as the BF, but               Tinto [48].
             with a higher calorific value (approximately
             2.2 times). With regard to CO2 emissions, a                The REDSMELTTM process can treat
             total reduction is generated, as some plants           most iron-bearing materials such as iron ore
             i.e. the sinter plant and coke oven plant are          fines, iron and steel mill solid and liquid
             missing.                                               wastes to produce hot metal [49]. It cou-
                                                                    ples a Rotary Hearth Furnace (RHF) and
                                                                    an EAF smelter to convert recycle iron ore
             1.2.2 FINEX, HIsarna and REDSMELT                      fines into hot metal or alloys and slag. Re-
                                                                    duction takes place in a RHF which can
                                r                 r
             Like the COREX      process, FINEX   is a two-       use a variety of carbon-containing materi-
             stages melting reduction method of iron-               als such as anthracite, pet coke and ground
             making. It is based on direct use of non-              electrodes as reductant to produce DRI for
             coking coal and fine ore and with respect              recycling or smelting in a submerged arc fur-
                        r
             to COREX     it can directly use iron ore sin-        nace. This technology has been developed
             ter feed (up to 0.012 m) without agglomera-            to meet a growing demand of low-cost and
             tion [4]. A series of successive fluidised bed         environment-friendly production process of
             pre-reduction reactors in which ore fines are          hot metal due to its low emission levels, but
             reduced in three or four stages to DRI and a           it has not yet reached the necessary consoli-
             melter-gasifier are the main units of this iron-       dation of its economic viability [50, 51]. Cur-
             making system. The iron ore passes through             rently this process has a range of production
             4 reactors where it is heated and reduced by           of 0.3–1.0 Mt/year of hot metal and may be
             a reduction gas also produced by coal gasifi-          used to treat a wide range of fine iron ores
             cation. The major part of coal (65%) is fed in         and steelmaking residues [52].
401-page 6
                          V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
             crisis. Such economic crisis has then led to         stall more plants can negotiate the invest-
             a marked downturn in steel manufacturing             ment cost. The analysis of very specific situ-
             and to an associated steel demand which re-          ations deriving e.g. from particular commer-
             mains 27% below pre-crisis levels [5].               cial framework agreements requires ad-hoc
                                                                  data and information and is thus out of the
                                                                  scope of the present paper.
             2.1 Economic analysis
Table 3. CAPEX expressed in Mc.                      and reduction technologies. All the calcula-
       CAPEX                  Mc                     tion have been carried out considering as the
       BF+BOF                  295                   final output a ton of liquid steel. In particu-
     Sinter plant               40                   lar, in order to have an idea of the unitary
     SR process                132                   cost of each scenario, the cost analysis has
     DR process                 92                   been carried out estimating the consumed
                     Brownfield Greenfield           raw materials, energy consumption as well
    EAF scenarios       60         300
                                                     as labor cost. The EAF main raw materials
                                                     and consumed energy taken into consider-
should be minimized [56]. According to the           ation are electrical energy, oxygen, fluxes,
above assumptions and hypothesis, Table 3            graphite and refractories. In the direct re-
shows the estimated CAPEX for the consid-            duction technology, the amount of iron ore
ered technologies.                                   is estimated as 1.42 t/t DRI. Natural gas, air
     The above estimated CAPEX for each              compressed and water have been estimated
technology have then been merged in order            too. In the smelting reduction technology,
to find the CAPEX of each above depicted             the estimated coal consumption is 1.30 t/t
scenario. Figure 1 shows the total CAPEX             hot metal, while estimates for iron ore and
for the five production scenarios. The over-         additives are 1.51 t/t hot metal and 0.24 t/t hot
all implementation of the Greenfield 5th sce-        metal, respectively. Other elements, i.e. oxy-
nario has the highest CAPEX with 524 Mc              gen, water, nitrogen, air compressed have
whereas the lowest one is observed at the            been taken into account. As far as the unit
brownfield 2nd scenarios with 60 Mc. EAF             prices values are concerned, raw materials
greenfield requires more CAPEX than EAF              and energy have been estimated according
brownfield scenarios since all the necessary         to [32,57]. In the estimation of labor cost, the
equipment and facilities for the steel produc-       workers in all five scenarios are subdivided
tion have to be acquired. BF/BOF requires            as follows: 69% workers, 30% employees and
less CAPEX with respect to the EAF Green-            1% managers. The following average hourly
field scenarios due to the fact that CAPEX in-       costs for each category have been consid-
cludes a new BF/BOF plant and a new sinter           ered: 20 c/h for workers, 35 c/h for employ-
plant, but it does not take into consideration       ees and 55 c/h for managers. An EAF steel
a coke plant and the rest of the necessary           scrap load of about 1.1 k/t LS [2] has been
equipment since they are in a good working           considered, in accordance to the BREFs, and
condition. Nevertheless BF/BOF CAPEX is              its composition on all scenarios is as follows:
higher than EAF Brownfield scenarios. The            (i) 70% shredded steel scrap (E40 Cate-
Brownfield 2nd scenario seems the most fea-               gory);
sible from a CAPEX point of view: this is            (ii) 30% steel scrap coming from ships dis-
clearly due to the fact that only the EAF has             mantling.
to be built but in a long term vision such sce-
                                                     In case of the steel scrap coming from
nario is strictly connected to the DRI prices
                                                     ships dismantiling, a reduction of 20% on
and its variations in the market.
                                                     the scrap prices with respect to the shred-
                                                     ded scrap prices has been assumed. Table 4
2.1.2 OPEX                                           summarizes the details of hypothesis and
                                                     assumptions taken into consideration for
After an estimation of the CAPEX of each             OPEX calculation. In both “SR+EAF” and
scenario, a simple preliminary cost analysis         “SR+DR+EAF” scenarios a power reduction
for all five scenarios has been performed by         as well as a reduction on the refractory and
estimating OPEX. Each scenario was based             graphite consumption have been assumed
on a plant capacity of 1 Mt/year of liquid           due to the fact that hot metal is charged.
steel and operating working hours were as-              According to the above assumptions, the
sumed to be 2080 h/y. In EAF scenarios, the          breakdown of OPEX for each scenario is
OPEX calculation has been carried out con-           shown in Figure 2.
sidering the main component of EAF cou-                 There is a significant increase in OPEX
pled with the main factors of the smelting           of BF/BOF scenario with respect to EAF
                                                                                                         401-page 9
                                                       V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
401-page 10
                        V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
scenarios: about 40% more with respect to           adopted technology and the annual produc-
“SR+DR+EAF” scenario. According to the              tion costs. The obtained values are shown in
Figure 2, the scenarios associated to an EAF        Table 5.
are the most convenient. In “50% EAF” sce-              The Greenfield scenarios obtain lower
nario the main cost component is the pur-           values with respect to the Brownfield scenar-
chasing of DRI (about 40%): the DRI price           ios: this is due as the CAPEX of Greenfield
has been retrieved in reference [62] and, ob-       scenarios is higher than the brownfield
viously, if different prices are used, OPEX          ones causing a reduction on the values.
result will change. In the scenarios where          In the Greenfield scenario, the combination
smelting reduction is implemented, an im-           of smelting and reduction technologies ob-
portant assumption is the sales of the dis-         tains a better value than the “DR+EAF” and
carded coal. In fact such sales and the recov-      “SR+EAF” ones since the plant obtains addi-
                r
ery of COREX     gas in place of natural gas       tional revenues from the selling of hot metal
reduce OPEX about 4% in “SR+EAF” and                and DRI surplus.
8% in “SR+DR+EAF” with respect to “50%
EAF”. From an economic point of view, it
seems that “SR+DR+EAF” is the most con-             2.1.3 Sensitivity analysis
venient due to the combination of savings
of smelting and direct reduction technology.        In this section, the effect of influence of vari-
However, a complete economic estimation             ous parameters on the convenience to invest
of OPEX and CAPEX depends on many                   in some scenarios is discussed. In the first
factors which may also change from loca-            sensitivity analysis, which compares “50%
tion to location as, for instance, energy and       EAF” vs. “SR+EAF” scenario, the effects that
raw materials prices [38]. A profitability in-      the fluctuations of DRI/hot metal prices in
dicator called Return On Investment (ROI)           “50%EAF” scenario have on the convenience
which is the percentage of the money re-            to invest in “SR+EAF” scenario in terms of
covered annually from the plant (ROI% =             payback period are investigated. DRI and
Profit/CAPEX) has also been estimated ac-           hot metal prices varied in a limit range in
cording to the above assessed CAPEX and             order to understand when it becomes more
OPEX. The annual profit has been computed           profitable to purchase DRI or hot metal in the
as the difference between a rough estimation         market than to produce them. The cost re-
of the annual revenues produced from the            lated to DRI or hot metal purchasing would
                                                                                                       401-page 11
                                                        V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
                            be saved if “SR+EAF” scenario would be                  projects [63]. The results of Simple and Ac-
                            implemented, but the convenience to invest              tualised PBP are shown in Figures 3a and 3b.
                            in “50%EAF” scenario is strictly related to                 According to the above assumptions,
                            DRI/hot metal market price. According to                Figures 3a and 3b demonstrate that the
                            the approach adopted for OPEX calculation,              higher the hot metal or DRI price, the shorter
                            the following additional assumptions have               the time to recover the “SR+EAF” invest-
                            been made:                                              ment as more savings would be cumulated
                                                                                    through the years. If the DRI market price
                              – source of Financing: 100% Equity                    is higher than 370 c/t the Actualised PBP to
                                Capital;                                            recover the “SR+EAF” investment would be
                              – investment depreciation (years): 20;                lower than 10 years as shown in Figure 3a.
                              – DRI to be purchased (kt/year): 510;                 When the variations are applied to the hot
                              – hot Metal to be purchased (kt/year): 510;           metal prices, PBP is more sensible as it can
                              – DRI market basic price (c/t): 291 [15];             be seen from Figure 3b: in order to get a
                              – hot metal market basic price (c/t):                 short actualised PBP (i.e. less than 10 years),
                                358 [15];                                           the hot metal market price should exceed c
                              – interest rate: 4%;                                  370/t, which is not very far from the current
                              – hot metal cost estimation (c/t): 328;               market price according to [15]. However,
                              – DRI cost estimation (c/t): 273;                     in terms of profitability, the “SR+EAF” sce-
                              – steel production (Mt/year): 1;                      nario becomes profitable and cost-effective
                              – surplus hot metal to sell (kt/year): 135;           when simple or actualised PBP is shorter
                              – surplus DRI to sell (kt/year): 131;                 than 5 years. The second sensitivity analysis
                              – taxes: 40%.                                         considers the “50% EAF” vs. “DR+SR+EAF”
                                                                                    scenarios. In this case, not only DRI and hot
                            Mortgage and financial charges are not in-              metal savings, but also the selling of DRI
                            cluded as the capital equity is supposed                and hot metal surplus not used in EAF (as-
                            to finance all the investment amount. The               suming that the steel production is fixed to 1
                            discounted cash flows have been estimated               Mt) have been considered. In this case, DRI
                            starting from the net operating result (differ-          and hot metal prices variations have been
                            ence between revenues and operating costs,              combined among them in order to deter-
                            but after the taxes) and considering the de-            mine the trend of the actualised PBP of the
                            preciation as a positive variation. In this             “DR+SR+EAF” scenario (Fig. 4). Not only
                            analysis, the taxes were set at 40% which               can DRI and hot metal prices variations af-
                            is an average value representing the Italian            fect the PBP, but also the amount of invest-
                            tax system, but it can change according to              ment: for instance, if a 20% reduction is ap-
                            the value adopted in the considered coun-               plied on CAPEX of both Smelting and Direct
                            try. Obviously the lower the tax value the              Reduction process, PBP results decrease fur-
                            higher the net operating result. The cash               ther as shown in the Figure 4b. Any variation
                            flows are discounted with an interest rate              in the input data as well as in the estimated
                            of 4% according to the Net Present Value                assumptions can affect the final results of the
                            (NPV) method. The interest rate, in such                analysis and obviously the results of PBP.
                            cases, usually corresponds to the Minimum                   All the above assumptions, especially the
                            Acceptable Rate of Return (MARR), i.e. the              decisions on how to finance CAPEX (debt or
                            minimum rate of return on a project that                equity capital) are an important weight on
                            a manager or company are willing to ac-                 the final results obtained as they affect the
                            cept before starting a project, given its risk          investment recovery time and therefore the
                            and the opportunity cost of forgoing other              simple or actualised PBP duration.
401-page 12
                          V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
Fig. 3. Sensitivity Analysis in terms of Simple and Actualised PBP: sensitivity with respect to DRI prices (a) and
sensitivity with respect to hot metal prices (b).
Fig. 4. Actualised PBP Results: CAPEX without any reduction (a) and CAPEX with a reduction of 20% (b).
              mance with respect to the current situation.           of natural products such as vegetable oil and
              A particular importance should be given to             animal fats. The iso-butilene is very impor-
              atmospheric emissions, especially the ones             tant in the petrochecmical sector for the pro-
              related to greenhouse gases (GHG Gas), due             duction of fuels, plastics materials, organic
              to the ambitious targets set in Europe (–20%           glass and elastomers. Lanzatech process is
              by 2020 and –87% in 2050 compared with                 already applied in the steel industry claim-
              1990) [71]. However, other types of emis-              ing that CO2 emissions are reduced by one
              sions, e.g. particulate matter and dioxins, are        third with respect to using the process gases
                                                                                               r
              extremely important, especially considering            as fuel [73]. LanzaTech     company claims
              the impact at local level and the potential ef-        that globally up to 150 million tonnes of CO2
              fects on the workers’ health as well as on the         emissions could potentially be avoided by
              community living in the surroundings of the            re-using available steel mill gas residues us-
              steelmaking plant.                                     ing LanzaTech’s process [74].
power plant could be completely collected               in order to implement new measures to in-
and used for the preparation of conglom-                crease the energy efficiency and the reduc-
erates by a local company which is already              tion of specific consumptions. In the 4th sce-
a partner of Piombino steelwork for wastes              nario it is necessary to consider not only the
and by-products management. Moreover, a                 time and costs related to the implementation
portion of the electrical energy produced               but also the construction and the impact of
could be sold in an internal network system             the external related infrastructures to sup-
to several companies located in the vicinity            ply and guarantee a large amount of natural
of the Piombino industrial area possibly at             gas. It is important to point out that in an
favourable conditions, with a considerable              Italian scenario the natural gas has a high-
competitive advantage for them. If all the              volatility price due to a great dependence
above assumptions are feasible, the 3rd sce-            from two important supplier countries, i.e.
nario could be considered self-sustainable              Libya and Russia, which held respectively
from an energy point of view. The energy                a 9% and 38% share on 2013 imports. Rus-
interactions among the various plants in the            sia became the main supplier in 2013 [75].
industrial area is very important as well as            DRI production process has been success-
the introduction of advanced technologies               fully implemented where there are large iron
and the research for energy recovery solu-              ore mines and natural gas reserves.
tions and for re-use of off-gas and other sec-
ondary energy sources, by improving the
environmental sustainability of the selected            2.2.3 Comparison summary among
steelmaking production route. For instance,                   the different options
a series of innovative technologies for recov-
ery and reuse of waste heat can be deployed             Table 6 shows the final overall compari-
both inside and outside the industrial area             son among the five alternatives considered
                                                                                                                                401-page 15
                                        V. Colla et al.: Metall. Res. Technol. 113, 401 (2016)
              for Piombino steelwork according to the as-           worldwide are considered. This case-study
              sumptions and hypothesis previously de-               and the considered factors as well as the re-
              picted. As far as the economic indicators are         sults obtained are related to the steelwork
              concerned, the assumptions related to the             operating in Piombino and its particular col-
              EAF location (i.e. close to the hot area or in        location in Italy. For instance, the factors re-
              a different area) can greatly affect CAPEX in           lated to the needs to continue to produce
              the EAF-based scenarios. The highest OPEX             a certain amount of high quality steel for
              is associated to the BF/BOF scenario and the          railway products and, simultaneously, to ex-
              highest reduction with respect to BF/BOF is           ploit the steel scrap flow coming from the
              obtained in the 5th scenario. The 5th sce-            ship dismantling could be a significant crite-
              nario allows savings of about 26% with re-            ria which the investor should not neglect. In
              spect to the 4th scenario due to the fact             any case, the selected steel production pro-
                              r                             r
              that MIDREX       process is fed by COREX           cesses will need to be flexible enough to meet
              gas and not by natural gas. From an envi-             not only the fluctuation on the prices of the
              ronmental point of view, SO2 and NOx are              raw materials market but also those related
              significantly lower than in a conventional            to the sale of finished products.
              BF/BOF route: this is primaly based on the
              fact that the coke oven plant and the sinter
              plant in all the 4 scenarios are definetely dis-      Acknowledgements
              mantled. The best results in terms of CO2
              emissions are achieved in the 2nd scenario,
                                                                    The authors gratefully acknowledge Eng.
              although the 3rd one obtains better results           C.Motto and Eng. S.Simoni of Lucchini Spa for
              in terms of PCCD/PCFD and SO2 emissions.              their helpful and valuable comments on a draft
              However, the environmental impact of all              version of the manuscript. The sole responsibility
              the alternative scenarios appear significantly        of the issues treated in the present paper lies with
              advantageous with respect to the conven-              the authors.
              tional BF/BOF route. The results shown in
              the 5th scenario are an average estimation of
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