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Example 6.2-2 Geankoplis
Water in the bottom of a narrow metal tube is held at a constant temperature of 293 K.
The total pressure of air (assumed dry) is 1.01325 x 105 Pa (1.0 atm) and the
temperature is 293 K (20 °C). Water evaporates and diffuses through the air in the tube,
and the diffusion path z2-z1 is 0.1524 m (0.5 ft) long. The diagram is similar to Fig. 6.2-
2a. Calculate the rate of evaporation at steady state in lb mol/h.ft2 and kg mol/s.m2. The
diffusivity of water vapor at 293 K and 1 am pressure is 0.250 x 10-4 m2/s. Assume that
the system is isothermal. Use SI and English units.
Solution
• The diffusivity is converted to ft2/h by using the conversion factor:
• From Appendix A.2 the vapor pressure of water at 20 °C is 17.54 mm, or pA1 =
17.54/760 = 0.0231 atm = 0.0231(1.01325 x 105) = 2.341 x 103 Pa, pA2 = 0 (pure air).
Since the temperature is 20 °C (68 °F), T = (460 + 68) °R = 293 K. From Appendix
A.1, R = 0.730 ft3.atm/lb mol.°R . To calculate the value of pBM from Eq. (6.2-21)
• Since pB1 is close to pB2, the linear mean (pB1+pB2)/2 could be used and would be
very close to pBM.
• Substituting into Eq. (6.2-22) with z2-z1 = 0.5 ft (0.1524m),