Paten
Paten
carotenoid pigment, a phytochemical found in tomatoes and        can also be used to formulate cosmetic and/or dermatologi
other red fruits. Lycopene is a sub-category of tetraterpenes,   cal products according to embodiments of the invention. In
and tetraterpenes are a Sub-category of terpenes. Chloro         the context of this Application, “reformulate” means to alter
phyll pigment is present in vegetables Such as, but not          a plant product from its natural state to an altered State Such
limited to, green vegetables including beet greens, bok choy,    as a concentrate, flake or powder.
collards, dandelion greens, kale, mustard greens and blue         0015. In one example, to reformulate a vegetable into a
green algae and is responsible for their green color. Caro       powder, the following alternative processes can be used: (a)
tenoid pigment, a carotene, is present in, for example,          dry vegetable down to a final water content below 4%,
carrots and is responsible for their bright orange color.        followed by grinding, followed by sieving; or (b) boil
Anthoxanthin pigment is present in, for example, alfalfa         vegetable, followed by sieving into a puree, followed by
flowers and red cabbage and is naturally a white color.          drying on a heated Surface (preferably under vacuum) or
 0011. In some embodiments, the skin or pulp of fruit or         spraying in hot air. The drying processes can encompass one
vegetables can be processed to extract pigments such as          of the following: (i) dryers with plates under vacuum are
anthocyanins and lycopenes. The resulting pigment extract        equipped with plates heated with hot water; stainless steel
can be in liquid or Solid form. These various pigments in the    plates containing puree to be dried are placed on them;
form of extractions can be combined to produce numerous          process conditions are at low residual pressure (about 10 to
colors and used to formulate cosmetic and/or dermatological      20 mm Hg) and a product temperature of between 50° C. to
products according to embodiments of the invention. These        70° C.; (ii) drum dryers having one or two drums heated
plant products can be subjected to a process to isolate the      with hot water or steam as heating elements; feeding is
pigments therefrom to be used to formulate a cosmetic or         continuous between the two drums which can rotate in
dermatological product according to Some embodiments of          reverse direction (about 2-6 rotations per minute) and the
the invention.                                                   distance of which is adjustable and determines the thickness
                                                                 of layer to be dried; the product can be dried and removed
                       EXAMPLE 1.                                by mechanical means during rotation; or (iii) drying instal
                                                                 lations by spraying in hot air, the product is introduced in
 0012. In one example, a plant sample, such as the seed,         equipment and sprayed by a special device in hot air, drying
skin or pulp of fruit can be subjected to a “quick freeze' in    is instantaneous (1/50s) and therefore can be carried out in
liquid nitrogen and then Subsequently freeze-dried. The          a range of between 130° C. to 150° C.
sample can thereafter be subjected to at least 3 washes with
hexane. The hexane washes are used to remove lipid from           0016. In another example, to reformulate a fruit such as
the plant sample (if the sample contains lipids). The hexane     a tomato into a concentrate, the following process can be
should preferably be optima grade hexane (available from         used: pre-wash, wash and sort tomatoes, followed by tomato
Fischer Scientific, Waltham, Mass.) or equivalent. Polyphe       crushing and seed separation with a centrifugal separator.
nols in the sample can then be extracted using a solvent         The resulting tomato pulp is pre-heated at 55° C. to 60° C.
system such as methanol/water (75:25 V/v). The methanol          and then passed to an equipment group for sieving: pulper,
should preferably be high-performance liquid chromatogra         refiner and super-refiner with sieves of 1.5 mm, 0.8 mm and
phy (HPLC) grade methanol (available from Sigma-Aldrich,         0.4 to 0.5 mm, respectively. The resulting tomato juice is
St. Louis, Mo.) and the water should preferably be purified      concentrated by vacuum evaporation. For example, the
to about 18.2 megaohms per centimeter (MS2/cm). In some          tomato juice can be subjected to a 3-step evaporation
embodiments, the extraction step can be performed multiple       method: (i) pasteurize juice at between 85°C. to 90° C. for
times. The extract can then be filtered through a 0.45 micron    15 minutes at 330 mm Hg; (ii) heat resulting concentrate at
polytetrafluoroethylene (PTFE) membrane, or other size           between 42°C. to 46° C. at between 680 mm Hg to 700 mm
depending on the sample size.                                    Hg; and heat concentrate again at between 42°C. to 46° C.
                                                                 at between 680 mm Hg to 700 mm Hg. Force resulting
                       EXAMPLE 2                                 concentrate through tubular pasteurizer at between 90° C.
                                                                 and 92° C.
 0013 In another example, a plant sample such as the              0017 Alternatively, freeze drying or dehydration of a
seed, skin or pulp of fruit can be subjected to a “quick         fruit, vegetable, fruit skin or vegetable skin can result in fruit
freeze' in liquid nitrogen and then Subsequently freeze          or vegetable powder or flakes that can be used to formulate
dried. The sample can be ground down using a mortar and          cosmetic and/or dermatological products according to
pestle in optima grade hexane. The sample can then be            embodiments of the invention. “Freeze drying is the pro
washed with hexane and centrifuged for about 10 minutes at       cess of freezing a material and then reducing the Surround
a speed of about 4000 to 5000 rotations per minute. This         ing pressure and adding enough heat to allow the frozen
removes lipids from the sample (if the sample contains           water in the material to sublime directly from the solid phase
lipids). This can be done for at least 3 cycles, letting the     to gas. “Dehydration' is the process of removing water from
particulates settle between each wash/centrifugation. There      an object. Dehydration of fruits and methods can be per
after, the remaining precipitate is extracted using a solvent    formed by known methods. In some embodiments, the
system such as methanol/water (75:25 V/v) for about 24           dehydrated (or freeze dried) plant product can be micronized
hours at approximately 5 degrees Celsius.                        to create the powder. “Micronized” means to reduce to
 0014. In other embodiments, fruit or vegetables can be          particles that are only a few microns in diameter. In some
reformulated to obtain a powder, flake or concentrate (col       embodiments, the concentrate, powder or flakes can be the
lectively, plant product reformulation) of the fruit or veg      direct source of color transfer from the cosmetic and/or
etable, which also can include the pigments described pre        dermatological product, eliminating the need for color addi
viously. This plant product reformulation, or reformulant,       tives such as FD&C colors and/or Lake minerals. However,
US 2007/0166253 A1                                                                                              Jul. 19, 2007
those skilled in the art will appreciate that the use of FD&C      papaya, pineapple, broccoli, brussel sprouts, cabbage, cau
colors and/or Lake minerals in embodiments of the cosmetic         liflower, kale, rapini, arugula, pumpkin, tomato, spinach,
and/or dermatological formulations of the invention may            eggplant, corn, beets, peppers, black beans, azuki beans,
also be included.                                                  carrots, as well as flowers, tea leaves and seaweeds.
 0018. In some embodiments, the botanical product can be            0022. The pigment extracts and/or plant product refor
a flower. Examples of flowers which can be used according          mulations according to embodiments of the invention can be
to embodiments of the invention include, but are not limited       combined with, for example, a cosmetic carrier. A cosmetic
to, roses (all varietals), violets, lavender, tulips, chrysanthe   carrier is a formulation that can be safely applied to the skin
mums, petunias, daffodils, poppies, orchids, begonia, lilies,      of a person and is principally used for beautifying effects and
pansies, daisies, hibiscus, carnations, and blossoms includ        ease of application. The cosmetic carrier may be composed
ing cherry blossoms and jacqueranda blossoms. Such flow            of a wide variety of ingredients that are conventionally used
ers may include at least one pigment such as anthocyanins,         in cosmetics, e.g., waxes, mineral oils, fatty alcohols, glyc
flavones, carotenes and chlorophyll. Pigment extraction can        erine, and Sunscreens. In one embodiment, the cosmetic
be performed by the processes described previously.                carrier may be a combination of shea butter, cocoa butter,
                                                                   grapeseed oil, honey beeswax, Vitamin C, Vitamin E and a
 0019. In some embodiments, the botanical product can be           natural flavor. When the pigment extract or plant product
a seed, such as a coffee seed (commonly referred to as a           reformulation (e.g., powder, flakes, concentrate) are com
coffee bean) or a cocoa seed (commonly referred to as a            bined with a cosmetic carrier, the resulting formulation can
cocoa bean). In unfermented cocoa beans, pigment cells             be used to make a variety of cosmetic and/or dermatological
make up about 11-13% of the tissue. The pigments in                products, such as, but not limited to, lipstick, lip gloss, lip
unroasted cocoa seeds include both anthocyanins and                stain, lip liner, blush, face tint, cheek stain, cheek gel, cheek
polyphenols. During fermentation, polyphenols and antho            butter, eye shadow, eyebrow powder, eyeliner, mascara,
cyanins undergo different chemical reactions that lead to the      foundation, sheer foundation, bronzer, facial illuminator,
synthesis of flofabens, which contribute to the characteristic     facial highlighter, face powder, lotion and tinted moisturizer.
brown color of roasted cocoa seeds. Additionally, oxidation
and polymerization of polyphenols during the roasting pro           0023. According to some embodiments, pigment extracts
cess of cocoa seeds leads to their characteristic brown color.     or plant product reformulations (e.g., powder, flakes, con
Similarly, coffee seeds contain brown pigments. A pigment          centrate) in a range of between about 0.01% by mass (weight
extract derived from cocoa or coffee can be in liquid or solid     percent) and about 100% can be combined with a cosmetic
form and can be used to formulate a cosmetic and/or                carrier. For example, in one embodiment, a cosmetic? der
dermatological product according to embodiments of the             matological formulation includes about 83% vitamin E,
invention. Alternatively, concentrate, flakes or micronized        about 10% pigment extract or plant product reformulation
powder from the cocoa or coffee bean can be the direct             from pomegranate fruit, about 5% pigment extract or plant
Source of color transfer from the cosmetic and/or dermato          product reformulation from cherry fruit and about 2% pig
logical product, eliminating the need for color additives Such     ment extract or plant product reformulation from strawberry
as FD&C colors and/or Lake minerals.                               fruit, wherein the pigments are adapted to stain and/or color
                                                                   the skin of a person when applied. In some embodiments, the
 0020. In some embodiments, the botanical product can be           formulation can alternatively include at least one of grape
a bean, Such as a black bean or a red bean. Pigments can be        seed oil, honey, shea butter, honey beeswax, Vitamin C,
extracted from the hull, or coat, of red and black beans. The      natural fruit flavor, chili pepper or red wine. In one embodi
pigments cyanidin 3-O-B-D-glucoside (RPO) and pelargoni            ment, the formulation is a lip gloss.
din 3-O-B-D-glucoside (RP 1) can be extracted from the red          0024. In another embodiment, a face tint (commonly
bean, while the pigment delphinidin 3-O-B-D-glucoside
(BP1) can be extracted from the black bean. RPO is a               referred to as foundation) can include about 99.9% shea
flavonoid, more specifically an anthocyanin, and responsible       butter and about 0.01% cocoa bean pigment, wherein the
for the blue, purple and red color of many plant tissues. RP1      pigment is adapted to stain and/or color the skin of a person
is also a flavonoid, more specifically an anthocyanin, and         when applied. In another embodiment, a blush can include
responsible for the orange, pink, red and magenta color of         100% reformulated micronized fruit powder from raspberry
many plant tissues. Similarly, BP1 is a flavonoid responsible      fruit, wherein the pigment is adapted to stain and/or color the
for the purple color of, for example, black bean hull. The         skin of a person when applied. In another embodiment, a
resulting pigment extract can be in liquid or Solid form.          formulation includes In one embodiment, the formulation is
                                                                   a face tint which can be applied to the lips, checks or eyelids.
 0021. In sum, at least one of the following plant products         0025. In addition to the non-plant product ingredients
or constituent thereof (concentrate, flake, powder) can be         listed above, cosmetic? dermatological products formulated
used to formulate a cosmetic or dermatological product             according to embodiments of the invention can include a
according to embodiments of the invention: apricot, peach,         number of fillers and preservatives which are listed in the
nectarine, cherry, plum, raspberries, Strawberry, blackberry       examples that follow. Thus, the following are examples of
and derivative and hybrid species thereof, (e.g., dewberry,        cosmetic? dermatological products formulated in accordance
boysenberry, olallieberry and loganberry, wineberry, bear          with embodiments of the inventions (all percentages pro
berry, bilberry or whortleberry), blueberry, cranberry, lin        vided are by weight unless otherwise noted):
gonberry, currant (including red, black, and white types),
elderberry, grape, mulberry, persimmon, papaya, butternut           0026. A lipstick formula (pink shade) can include 4.72%
squash, pumpkin, acorn squash, Summer squash, rhubarb,             polyethylene, 5.67% White SP-1020, 8.06% diisostearyl
jujube, black mulberry, olive, pomegranate, guava, kum             malate, 12.6% dipentaerythrity1 hexahyrdroxystearate/hex
quat, passion fruit, guava, agai, durian, mango, mangosteen,       asterate/hexarosinate, 9.0% petroatum, 0.6% grapeseed oil,
US 2007/0166253 A1                                                                                            Jul. 19, 2007
16.41% diisospropyl dimer dilinoleate, 10.0% isononyl          vitamin E, 4.0% cranberry fruit pigment, 3.0% pomegranate
isononanoate, titanium dioxide, Stearic acid and aluminum      fruit pigment, 3.0% blackberry fruit pigment, 2.0% rasp
hyroxide, 8.0% diisospropyl dimer dilinoleate, 5.44% fruit     berry fruit pigment, 2.0% red wine fruit pigment, 2.0%
pigment extract and/or fruit product reformulation contain     vitamin C, 1.5% natural strawberry flavor and 0.5% straw
ing anthocyanins, 2.0% mica and isopropyl titanium triisos     berry fruit pigment.
tearate, 3.0% mica and titanium dioxide, 8.0% diisospropyl      0035. When applied, the fruit pigment formulated within
dimer dilinoleate, 5.0% silica and 1.5% peppermint essential   the cosmetic or dermatological product can stain the skin
oil.
                                                               immediately on application. In some embodiments, there is
 0027. A lipstick formula (red orange shade) can include       a time interval between the time the cosmetic and/or der
4.72% polyethylene, 5.67% White SP-1020, 8.06% diisos          matological product is applied to the skin and the time that
tearyl malate, 12.6% dipentaerythrity1 hexahyrdroxystear       a pigment in the product stains the skin. A representative
ate/hexasterate/hexarosinate, 9.0% petroatum, 0.6% grape       time interval from application to staining can be up to about
seed oil, 16.41% diisospropyl dimer dilinoleate, 10.0%         5 minutes, and, in one embodiment, 30 seconds to one
isononyl isononanoate, titanium dioxide, Stearic acid and      minute. In any case, the stain is temporary, not permanent.
aluminum hyroxide, 8.0% diisospropyl dimer dilinoleate,         0036). In the foregoing specification, specific embodi
5.44% pigment extract and/or fruit product reformulation       ments have been described. It will, however, be evident that
containing carotenoids and/or tetraterpenes (lycopene),        various modifications and changes can be made thereto
2.0% mica and isopropyl titanium triisostearate, 3.0% mica     without departing from the broader spirit and scope of the
and titanium dioxide, 8.0% diisospropyl dimer dilinoleate,     appended claims. The specification and drawings are,
5.0% silica and 1.5% peppermint essential oil.                 accordingly, to be regarded in an illustrative rather than a
 0028. A mascara formula (purple shade) can include            restrictive sense.
36.91% isododecano, 14.29% hydrogenated polycyclopeta
diene and isododecano, 2.0% lithium magnesium silicate,        What is claimed is:
1.0% SD Alcohol-39C, 13.25% pigment extract and/or fruit         1. A dermatological or cosmetic formulation comprising:
product reformulation containing anthocyanins, 0.25%
sodium chloride, 13.5% deionized water, 0.45% PHE                a pigment extracted from a botanical product; and
NONIPR), 5.0% C18-36% triglycerides, 6.0% beeswax,               a cosmetic carrier having admixed therein the pigment,
3.0% carnauba wax, 3.0% polyethylene and 0.35% pan                  wherein the pigment is adapted to stain skin.
thenol.                                                          2. The formulation of claim 1, wherein the botanical
 0029. A powdered blush formula (red shade) can include        product is suitable for human consumption.
72.85% kaolin powder, 3.1% pigment extract and/or fruit          3. The formulation of claim 2, wherein the botanical
product reformulation containing lycopene, 1.75% pigment       product is one of a fruit, a vegetable, a legume, a flower, leaf
extract and/or fruit product reformulation containing antho    or a seed.
cyanins, 9.0% mica and titanium dioxide, 0.30% vitamin E         4. The formulation of claim 3, wherein the fruit, the
and 13.0% dimethicone.                                         vegetable, the flower, the leaf or the seed is at least one of
                                                               apricot, peach, nectarine, cherry, plum, raspberry, Straw
 0030. An eye shadow formula (blue eye shadow) can             berry, blackberry and derivative and hybrid species thereof,
include 69.70% sericite and triethoxycaprylysilane, 7.0%       blueberry, cranberry, lingonberry, currant, elderberry, grape,
pigment extract and/or fruit product reformulation contain     mulberry, persimmon, papaya, butternut squash, pumpkin,
ing anthocyanins, 10.3% mica and titanium dioxide, 13.0%       acorn squash, Summer squash, rhubarb, jujube, black mul
dimethicone and triemethylsiolxysilicate.                      berry, olive, pomegranate, guava, kumquat, passion fruit,
 0.031) A powdered foundation can include 42.0% lecithin,      guava, agai, durian, mango, mangosteen, papaya, pineapple,
40.0% kaolin powder, 3.26% titanium dioxide and isoproryl      broccoli, brussel sprouts, cabbage, cauliflower, kale, rapini,
titanium triisosterate, 0.88% pigment extract and/or fruit     arugula, pumpkin, tomato, Spinach, eggplant, corn, beets,
product reformulation containing carotenoid, 5.76% silica      peppers, carrots, black beans, azuki beans, coffee seed,
and 8.0% pentaerythritol tetraoctanoate.                       cocoa seed, tea and a flower wherein the flower is selected
                                                               from the group consisting of roses, violets, lavender flowers,
 0032. A cheek tint (e.g., shimmery cocoa berry) can           tulips and chrysanthemums, and optionally includes one of
include 32.0% cocoa butter, 25.0% shea butter, 13.0%           chili powder, seaweed or red wine.
grapeseed oil, 10.0% honeybeeswax. 5.0% vitamin E, 4.0%          5. The formulation of claim 4, wherein the cosmetic
cocoa bean fruit pigment, 2.5% raspberry fruit pigment,        carrier further comprises at least one of shea butter, cocoa
2.0% blackberry fruit pigment, 2.0% vitamin C, 1.5% natu       butter, grapeseed oil, peppermint essential oil, honey bees
ral strawberry flavor, 1.0% pomegranate fruit pigment, 1.0%    wax, carnauba wax, kaolin powder, sericite, vitamin C,
red wine pigment and 1.0% strawberry fruit pigment.            vitamin E or a natural flavor.
 0033. A cheek tint (e.g., shimmery strawberry) can              6. The formulation of claim 5, wherein the formulation
include 32.0% cocoa butter, 25.0% shea butter, 13.0%           comprises one of a lipstick, a lip gloss, a lip stain, a lip liner,
grapeseed oil, 10.0% honeybeeswax. 5.0% vitamin E, 2.8%        a blush, a face tint, a cheek stain, a cheek gel, a cheek butter,
cranberry fruit pigment, 2.0% cherry fruit pigment, 2.0%       an eye shadow, an eyebrow powder, an eyeliner, a mascara,
vitamin C and 1.5% natural strawberry flavor.                  a foundation, a sheer foundation, a bronzer, a facial illumi
                                                               nator, a facial highlighter, a face powder, a lotion and a tinted
 0034. A cheek tint (e.g., Sugar plum sheer) can include       moisturizer wherein the pigment is present in an amount to
32.0% cocoa butter, 25.0% shea butter, 10.0% honey bees        stain a portion of skin of a person when the cosmetic product
wax, 5.0% plum fruit pigment, 5.0% grapeseed oil, 5.0%         is applied thereon.
US 2007/0166253 A1                                                                                                   Jul. 19, 2007
   7. The formulation of claim 1, wherein the pigment is in           moisturizer wherein the pigment is present in an amount to
a liquid form or a solid form.                                        stain a portion of skin of a person when the cosmetic product
   8. The formulation of claim 1, wherein the pigment is              is applied thereon.
non-permanent.                                                          16. The formulation of claim 15, wherein the cosmetic
  9. The formulation of claim 8, wherein the pigment stains           formulation is a lip gloss having at least 83% vitamin E.
the skin of a person immediately.                                       17. The formulation of claim 15, wherein the cosmetic
  10. The formulation of claim 8, wherein there is a time             formulation is a face tint having at least 32% cocoa butter
interval between application of the formulation to the skin of        and Suitable for tinting cheeks, lips or eyelids.
a person and the time the pigment stains the skin of a person.          18. A dermatological or cosmetic formulation comprising:
   11. A dermatological or cosmetic formulation comprising:
                                                                        a reformulated product of a plant product wherein the
   a reformulated product of a plant product; and                          reformulated product is one of a powder or a flake of
   a cosmetic carrier having admixed therein the reformu                   the plant product, the plant product selected from the
      lated product, wherein the reformulated product is                   group consisting of a fruit, a vegetable and a combi
      adapted to stain skin.                                               nation thereof and wherein the reformulated product is
  12. The formulation of claim 11, wherein the reformulated                adapted to stain skin.
product is one of a concentrate, a powder or a flake of the             19. The formulation of claim 18, wherein the fruit, the
plant product, the plant product selected from the group              vegetable, the flower, the leaf or the seed is at least one of
consisting of a fruit, a vegetable, a legume, a seed, a flower,       apricot, peach, nectarine, cherry, plum, raspberry, Straw
a leaf and a combination thereof.                                     berry, blackberry and derivative and hybrid species thereof,
  13. The formulation of claim 12, wherein the fruit, the             blueberry, cranberry, lingonberry, currant, elderberry, grape,
vegetable, the flower, the leaf or the seed is at least one of        mulberry, persimmon, papaya, butternut squash, pumpkin,
apricot, peach, nectarine, cherry, plum, raspberry, Straw             acorn squash, Summer squash, rhubarb, jujube, black mul
berry, blackberry and derivative and hybrid species thereof,          berry, olive, pomegranate, guava, kumquat, passion fruit,
blueberry, cranberry, lingonberry, currant, elderberry, grape,        guava, agai, durian, mango, mangosteen, papaya, pineapple,
mulberry, persimmon, papaya, butternut squash, pumpkin,               broccoli, brussel sprouts, cabbage, cauliflower, kale, rapini,
acorn squash, Summer squash, rhubarb, jujube, black mul               arugula, pumpkin, tomato, Spinach, eggplant, corn, beets,
berry, olive, pomegranate, guava, kumquat, passion fruit,             peppers, carrots, black beans, azuki beans, coffee seed,
guava, agai, durian, mango, mangosteen, papaya, pineapple,            cocoa seed, tea and a flower wherein the flower is selected
broccoli, brussel sprouts, cabbage, cauliflower, kale, rapini,        from the group consisting of roses, violets, lavender flowers,
arugula, pumpkin, tomato, Spinach, eggplant, corn, beets,             tulips and chrysanthemums, and optionally includes one of
peppers, carrots, black beans, azuki beans, coffee seed,              chili powder, seaweed or red wine.
cocoa seed, tea and a flower wherein the flower is selected             20. The formulation of claim 18, wherein the formulation
from the group consisting of roses, violets, lavender flowers,        comprises one of a lipstick, a lip gloss, a lip stain, a lip liner,
tulips and chrysanthemums, and optionally includes one of             a blush, a face tint, a cheek stain, a cheek gel, a cheek butter,
chili powder, seaweed or red wine.                                    an eye shadow, an eyebrow powder, an eyeliner, a mascara,
   14. The formulation of claim 13, wherein the cosmetic              a foundation, a sheer foundation, a bronzer, a facial illumi
carrier further at least one of shea butter, cocoa butter,            nator, a facial highlighter, a face powder, a lotion and a tinted
grapeseed oil, peppermint essential oil, honey beeswax,               moisturizer wherein the pigment is present in an amount to
carnauba wax, kaolin powder, sericite, Vitamin C. vitamin E           stain a portion of skin of a person when the cosmetic product
or a natural flavor.                                                  is applied thereon.
  15. The formulation of claim 14, wherein the formulation              21. The formulation of claim 18, wherein the formulation
comprises one of a lipstick, a lip gloss, a lip stain, a lip liner,   is a blush consisting of 100% of the reformulated plant
a blush, a face tint, a cheek stain, a cheek gel, a cheek butter,     product, wherein the reformulated plant product is micron
an eye shadow, an eyebrow powder, an eyeliner, a mascara,             ized raspberry powder.
a foundation, a sheer foundation, a bronzer, a facial illumi
nator, a facial highlighter, a face powder, a lotion and a tinted                             k    k   k   k   k