Chapter 23
Chapter 23
THEME
According to the number of working factories (as per Table 5.16 in Chapter-5) the chronological
order is as follows:
According to the number of workers employed, (as per Table 5.16 in Chapter-5) the chronological
order is as under :
1. Chemicals and Chemical Products.
2. Cotton textiles.
3. Wool, Silk and MMF.
4. Food Products.
5. Non-metallic Mineral Products.
6. Machinery and Parts.
7. Rubber, Plastic and Petroleum.
8. Basic Metal and Alloy industry.
9. Metal Products and Parts.
10. Electrical Machinery and Parts.
11. Paper and Paper Products.
12. Transport equipment & parts.
13. Other Manufacturing.
14. Repair services.
15. Textile Products.
16. Electricity, generation, transmission & distribution.
17. Wood and Wood Products.
18. Beverages, Tobacco.
19. Education, Science & Research Services.
20. Repair of Capital Goods.
21. Water Works & Supply.
According to the number of accidents in Gujarat and India, textile industry has the highest number
of accidents and injuries. But this trend is changeble.
Out of above industries, we have studied so far up to the last chapter, the cotton textiles,
chemicals, synthetic fibres, machinery, metal products, basic metals and alloy industries and electrical
machinery industries. Therefore the statutory provisions and the safety aspects with inspection
experience of the remaining main industries are given below in brief.
Asbestos dust causes lung damage. Fibrosis of the lung by asbestos was first described with PM
report by Montague Murray in 1899. The name asbestosis was given by Cooke in 1927.
Control of airborne contamination becomes difficult and costly. Therefore effective enclosures to
source of generation and local exhaust ventilation on machine, wetting of fibres before mixing, spinning
and weaving, vacuum cleaning instead of brushes and changing of clothing at the end of work are the best
controls. Dust masks are also essential.
The 2nd Sch. of the Factories Act gives this value as 2 fibres/ml (length 5 nm and breadth 3 )Lim
as respirable dust).
Asbestosis is an occupational disease specified in the 3rd Schedule of the Factories Act. See Part
4 of Chapter-24 for further details.
Statutory Provisions:
Summary of Schedule 17, rule 102, GFR i.e. Gujarat Factories Rules, Sch.17 u/r 114, MFR i.e.
Maharashtra Factories Rules and Sch.20 u/r 95 of the TNFR i.e. Tamil Nadu Factories Rules is as under :
Application :
This schedule is applicable to the process of asbestos in any form of making insulation slab or
mattresses, textile, cardboard, paper, cement goods consisting asbestos or spraying asbestos or cleaning
asbestos dust. Definitions:
Asbestos is a fibrous silicate mineral and any admixture of silica known by different names. Its
dust means airborne particles. Respirable asbestos fibres means those having diameter less than 3 m and
a length to diameter ratio greater than 3:1. Other terms are also defined.
They should not create asbestos dust above the permissible limit or they should be equipped with
efficient exhaust draught.
Prohibition :
Processes of tools releasing asbestos dust beyond the permissible limit, use of crocidolite,
spraying of asbestos and installation of friable asbestos insulation materials are prohibited.
Substitution :
Asbestos shall be used only when its risk can be prevented or controlled, otherwise it shall be
replaced by other less harmful or harmless material or technology.
Restriction :
Number of persons exposed to asbestos and their exposure time shall be kept minimum. Their
work area shall be 'demarcated by warning signs restricting unauthorised access.
Exhaust draught:
A responsible person shall inspect the system every week. A competent person shall test it every
year. Defects found shall be rectified forthwith. Test report shall be in form No. 26-A.
Segregation :
Dust creating work places shall be segregated from other work places to avoid exposure to other
workers.
An approved type of breathing apparatus and protective clothing shall be given to workers, for
working in chamber or cleaning dust or filling , beating or other operation where it is not possible to keep
the dust within permissible limit. Separate accommodation shall be provided to put on or take off such
apparatus and clothing and to store when not in use.
All protective clothing shall be deducted under an efficient exhaust draught or by vacuum
cleaning and shall be washed at suitable intervals. The cleaning schedule and procedure shall be
established to ensure the efficiency of protection.
They shall be cleaned and disinfected at suitable intervals and inspected every month by a
responsible person.
A record of cleaning and maintenance shall be maintained. Full instruction shall be given to the
user before employing in such work. No apparatus worn by a person shall be worn by another person
unless it has been thoroughly cleaned, disinfected and full instruction given to that person.
Separate accommodation other than that for breathing apparatus, shall be provided to store other
personal protective equipment or personal clothing.
Washing places shall be provided at the rate of I for 15 persons. Stand pipe separation shall be
more than a metre. Constant water, clean towels, soap, and nail brushes shall be provided. Washing
(bathing time of 30 minutes within working hours) shall be provided at the end of the shift.
Mess Room :
A suitable mess room with tables, benches (with back rest) and means to warm food shall be
placed under the charge of a responsible person and be kept clean.
Cautionary Notice :
Cautionary notices regarding (i) Health hazards from asbestos dust (ii) Need to use appropriate
equipment and (iii) Entry of authorised persons with protective equipment or no entry shall be displayed.
The container of asbestos or its products shall be labelled with warning of dust hazard and its
safety measures. MSDS shall be supplied to consumers.
Information regarding health hazards of home carrying contaminated clothing shall be given to
the families of the workers.
Air Monitoring :
Monitoring of asbestos fibre in air shall be carried out once in every shift. Time weighted average
concentration shall be calculated or measured by Membrane Filter Technique (MFT). Records shall be
preserved for thirty years.
1. A doctor shall be employed with the approval of the CIF*. Medical facilities shall be provided to
him.
2. The CS** will examine a new worker within 15 days of his first employment. This will include
pulmonary function tests, tests to detect asbestos fibres in sputum and chest X-ravs. No worker
shall be employed without: Fitness Certificate in Form No. 27 A by the CS.
3. Periodical tests every year by the CS.
4. Health Register in Form No. 20 to be signed by the CS. Reasons of unfitness shall be recorded in
it. Re-employment in the same process is possible with a Fitness Certificate from the CS.
5. Post Medical Examination shall also be carried out. No cost to the workers. Results shall not be
used to discriminate against the worker. Workers will be informed about the test results. If health
is impaired due to long time exposure, the worker shall be compensated to maintain his income.
6. Records of Medical Examinations shall be preserved for 30 years. On closure of the factory, the
records shall be deposited to the Office of the GIF.
Other Provisions :
IS : Safety and health requirements relating to exposure to asbestos 11451, Asbestos dust control
11770, cleaning premises 11767, airborne concentration 11450, chrysotile 9690, 11276, 11267,
Manufacturing premises - exhaust ventilation system 12080, packaging, transport & storage 12079,
personal protection of workers 12078, products safe use 11769, terminology 11707, workplace pictorial
warning 12081, products 5913, control recommendation 12082, corrugated sheets 459, 13008, asbestos
fibre 2712, 11275, 9745, yarn 13362.
3 AUTOMOBILE INDUSTRY
Fundamentals of Industrial Safety and Health 23- 6 Safety in Construction Industry
This is a part of an engineering industry and carries out various processes like casting, forging,
machining, electroplating, painting, assembly, testing etc. The safety measures include :
IS : Safety Code for industrial trucks 6305 (Part I & 2), life jackets 6685, protective helmets 4151,
stability testing of forklift trucks 4357, 5752, 5753, conveyor safety 7155 (Part I to 7), glossary of terms
7862, smoke emission for diesel vehicles 8118, CO emission limits 9057, braking system 11852 (Part I to
7), driver safety 11939, life saving equipment 10548, speed limiters 10144, automobile accessories 8925,
8098, control cables 5836, electric equipment 9175, light-reversing 9961, stop, tail & turn signal lights
10256, wiring cable terminations 8395, Automotive vehicles - accelerator control, safety requirements
14283, air brake system 11852, 12831, 12821, electronic flashers 13135, pneumatic tyres 10914, rear
view mirrors 14210, registration plate 14224, side doors safety requirements 12009, terms & definitions
13111, windows for buses, safety requirement 13944.
Manufacture :
Benzene is a solvent frequently used in many organic processes. It is also used as a fuel, additive
of motor fuel, chemical reagent and a raw material for large number of chemical synthesis.
Old process of obtaining benzene is from coal. Its line diagram is as under :
Coal (1 ton) Coke (1500 lb) + Light oil (3 gallons] + Coal tar (8 gallons) + Ammonium sulphate
(20 1b) + Illuminating gas (11200 cuft)
Benzene is lighter than water (sp'. gr. 0.88) and heavier than air (vd 2.8). Its other properties are
BP 80.1 °C, FP -II °C, explosive range 1.3-7.1 %. It is less soluble in water, but highly soluble in organic
solvents and oils.
Looking to its very hazardous nature, the ILO passed its Benzene Convention 1971 (No. 136) and
Recommendation 1971 (No. 144).
It is highly flammable, explosive and toxic, all at a time. It exerts acute as well as chronic
poisoning. Its TLV is 10 ppm (30 mg/m3), STEL 25 ppm (75 mg/m3) and IDLH 2000 ppm. ACGIH
booklet 2007 shows TLV (TWA) as 0.5 ppm and STEL as 2.5 ppm.
Fatal cases of blood disease - leukaemia - have been reported. It destructs bone marrow. Benzene
handling must be in a closed system. Its exposure must be measured in work areas and the affected
person (by medical examination) must be immediately removed from exposure. Less hazardous
substitutes like toluene, xylene, cyclohexane and other suitable solvents e.g. alcohol, ketones, esters etc.
should be used. Good ventilation including exhaust ventilation, plant enclosures, flameproof fittings, leak
detector with alarm, environmental and biological monitoring (estimation of urinary phenols), breath
sampling, dyke surrounding storage tanks, curbs round the process vessels, elimination of sparks, flames
and excessive heat and effective fire fighting arrangement are necessary.
Statutory Provisions:
Schedule-20 u/r 102, GFR, and also as Schedule20 u/r 114 of the Maharashtra Factories Rules,
1963, (MFR) and as Schedule-27 u/r 95 of the Tamil Nadu Factories Rules, 1950 (TNFR) gives safety
provisions regarding manufacture and use of Benzene or substances containing benzene.
Manner of using Benzene or its substitute (less harmful) includes enclosed system or equally safe
system.
Protection against inhalation prescribes enclosed system or efficient exhaust draft to remove
benzene vapours from the workroom so that its concentration in air does not exceed 25 ppm or 80 mg/ 3
Its measurement and report of concentration exceeding above limit to the Inspector are compulsory. The
workers exposed to such higher exposure shall be given necessary respirators.
To avoid skin contact suitable gloves, aprons, boots and vapour tight chemical goggles (not
affected by benzene) should be given to workers.
Other provisions include prohibition of employment of women and young persons, labelling of
name, danger symbol, toxicity and flammability, no misuse of benzene for hand cleaning etc., no food,
drink, smoking or chewing in the workroom, instruction regarding risks, cautionary notice (as per
Appendix-B), washing facilities, cloak room and mess room, medical examination, pre-employment and
six monthly medical examination including blood test and other biological tests and temporary shifting of
the exposed worker.
Appendix-A specifies the processes where benzene substitute is not possible i.e. its production,
chemical synthesis and motor spirit (use of fuel).
APPENDIX B
(D) The first aid measures to be taken in case of acute benzene poisoning:
1. Lay him down preferably on the left side with the head low.
2. Remove any false teeth, chewing gum, tobacco or other foreign objects which may be in
his mouth.
3. Provide him artificial respiration in case difficulty is being experienced in breathing.
4. In case of shallow breathing or cyanosis (bluish skin, lips, ear, finger, nail, beds), he
should be provided with medical oxygen or oxygen carbon dioxide mixture. If needed he
should be given artificial respiration.
IS : Benzene 534, safety code 4644, reagent grade 1840, insoluble matter determination 1214.
5 BEVERAGE INDUSTRY
Use of soft drinks (non-alcoholic carbonated and non carbonated or still drinks) is increasing day
by day. Industrial safety measures include :
1. Guarding of high speed bottling and canning machines.
2. Net or wire mesh screening under over head conveyors.
3. Nip guards on conveyor belts, drums and pulleys and frequent stop buttons for conveyors.
4. Ammonia respirators and water type fire extinguishers or sprinklers.
5. Bottling machines with strong shields to contain bursting bottles or siphons.
6. PPE to workers for protection against broken glass.
7. Containers for broken glass equipped with a hinged clover or long chute to prevent "fly back".
8. Mechanical handling.
9. Dry floors by proper draining and cleaning. Workers with safety shoes with tread type soles.
Tennis shoes and sandals not permitted. Waterproof aprons.
10. Fixed platforms (instead of portable ladders), catwalks and stair ways with open grating to mixing
tanks and elevated locations.
11. PPE and water showers for caustic splashes.
12. Waterproof and properly earthed electric fittings.
See also schedule I, Rule 102, GFR and also Sch.l u/r 114, MFR and Sch.l u/r 95 TNFR.
IS : Beverages (Aerated water)- protein based 7482, protein food 9038, carbonated 2346,
nonalcoholic 13019, sensory evaluation 8140, 8639.
Bricks and tiles are essential building materials. Their clay work should include :
Refractories (Substances with high melting point and good physical resistance) are of four types:
alumina-silicate, silica (or acid), basic and miscellaneous. Hazard control is as stated above. Here
chances of silicosis are more. Permissible concentration of fibrogenic dust should not be exceeded.
Manual breaking should be avoided. Mechanical crusher/ grinder with exhaust draft and dust collectors
or water or steam spray are essential. Floors should be cleaned by vacuum cleaning.
See Sch. 5 for grinding or glazing of metals and Sch. 18 for stone or other material containing free
silica, under Rule 102, GFR.
IS : Brickwork - measurement 1200, code of practice 2212, Brick-acid resistant 4860, alumina
8953, 14313, building heavy duty 2180, work with compressed air 4138, piling and deep foundations
5121, handling of building materials 7969, Falling hazards 13416 (Part I & 2), scaffolds and ladders 3696
(Part I & 2), Tiles cement concrete 10646, brick flooring laying 5766, insulating 2042, kiln, design and
construction 4805, paving 3583, sand lime 4139, silica mortar 1292, brick panel 14143.
There are six methods of food preservation heating, radiation sterilisation, antibiotic sterilisation,
chemical action, dehydration and refrigeration (frozen food industry). Industrial safety measures include :
1. Training for safe lifting, stacking and maintenance of good housekeeping. Mechanical
handling avoid manual hazards.
2. Machines designed for less spillage.
3. Floors clean, dry and drained.
IS : Canning fruit and vegetable hygienic code 6542, Food analysis handbook SP-18, bacterial
detection 5887, 7688, sampling and tests 1699, freezers, safety 10542, processing units 2491, 8077,
cereals, warning 1656, 1657, safe use of packing 7277, 7288, 7961, food colours 5346, test for dye
content 6120, food mixers, electric 4250, food container, metal 6093, hawker, hygienic conditions 10973,
plastic for packaging 10171, food poisoning bacteria 7688, food samples analysis 5404, food yeast 3839,
food service establishments 6074, 7021, 8220.
Carbon di or bisulphide, CS2 is found in coal tar and crude petroleum. It is produced by heating
charcoal with vaporised sulphur or by reacting sulphur with petroleum hydrocarbons. Reaction is C + S 2
= CS2 Pure product is obtained by distillation of crude CS2 and it is kept submerged in water.
Acute and chronic poisoning occurs in viscose rayon industry. CS, poisoning is a notifiable
disease in the 3rd Schedule of the Factories Act. It has toxic and fire hazard. It is a neurotoxin. Therefore
effect on CNS is the main symptom. It affects liver and kidneys also. Chronic poisoning begins with
headaches, fatigue, weakness and sleep disorder.
Safety measures require total enclosed system, general and local ventilation, exposure
measurement, iodine-azide test of urine (biological measurement), pre and periodic medical
examinations.
Statutory Provisions:
Amongst other definitions, 'efficient exhaust draught' is defined as localised ventilation effected
by mechanical means for the removal of gas or vapour, so as to prevent it, as far as practicable from
escaping into air of any occupied room. No draught shall be deemed to be efficient if it fails to remove
smoke generated at the point where such gas or vapour originates.
Looking' to the prescribed TLV 10 ppm for both CS 2 and H2S, under the Second Schedule of the
Factories Act, that limit of 20 ppm stated in the State Rules should be changed to 10 ppm on safer side
and to bring uniformity in the provisions of the Act and Rules.
Summary of Schedule 22, rule 102, GFR, Sch.l9 u/r 114, MFR and Sch.26 u/r 95, TNFR is as
under
(1) Application:
This schedule is applicable to CS„, manufacturing plant containing electric furnace, condenser,
refiner and storage.
(3) Electrodes:
Two rupture discs on each furnace to blow off at. twice the maximum operating pressure. Water
sealing arrangement between charcoal separator and sulphur separator.
Pyrometers on furnace with dials in control room to know temperature of the furnace and
manometers to know pressure (1) before and after the sulphur separator and (ii) in primary and secondary
condensers.
They are required on CS carrying piping to prevent back flow of gas in to the furnace in the event
of its shut down.
Sulphur dust being explosive, its clouds generation should be minimised and its contact with
spark, flame etc. should be prevented. Use non-sparking tools. Smoking, matches and sources of
ignition not allowed.
Dye or dyestuff are soluble colours and the textile fibre or other materials are immersed in their
solution for dyeing process. Pigments are insoluble and are applied externally on surfaces by dispersion
methods.
Auramine and magenta have caused bladder cancer to the workers. Azo dyes derived from
benzidine or other chemicals, benzyl violet 4B, 4 amino or nitro diphenyland beta-naphthylamine have
carcinogenic potential.
Dermatitis is possible due to skin contact. Respiratory disorders have also been reported.
Statutory Provisions:
Summary of Schedule II, Rule 102, GFR, Sch.22 u/r 114, MFR and Sch.22 u/r 95, TNFR is given
below.
Applicability:
This schedule applies to factories where following substances are formed, manufactured, handled
or used –
Other precautions:
1. PPE : Long trousers and shirts or overalls with full sleeves and head coverings, rubber gum boots,
rubber hand gloves, rubber aprons and respirator if required.
2. Prohibition: No women or young person shall be employed in such process. No person below the
age of 40 shall be employed in such process.
3. Floor: Smooth, impervious, no use of tar or asphalt, suitable slope, gutters and daily washing.
8. Food, Drinks etc. - Food, drinks, pan-supari, tobacco and smoking in. workroom are prohibited.
9. Clock room: Lockers with separate compartments for street clothes and work clothes.
Separate place from locker room and mess room to store PPE given to the workers:
10. Mess room - With tables, benches and means to warm food.
11. Washing time - 30 minutes for bathing before the end of each shift and 10 minutes for washing
before each meal.
IS : Carcinogenic substances, handling safety 14165, Dye application classes 4472, intermediates
sampling & tests 5299, pigment for paints 59, dyesbasic strength 12387, dye-hair, liquid 8481, disperse
dyes 11635, vat dyes 4394, 5970.
10 CEMENT INDUSTRY
Manufacture :
Cement is mainly made from limestone, clay and small amounts of other metallic oxides, which,
when mixed with a small amount of water, sets to a hard stone-like substance in a few hours. It is a main
building material working as a hydraulic bonding agent.
Types of cement are portland, pozzolana, calcium aluminate and special or corrosion-resistant
cement. Grades are more than fifty.
Manufacturing process is wet process (old one) dry process (new) or the combined process. The
raw materials are finely ground, mixed and heated (burned) in a rotary kiln to form cement clinker
During calcining, clinker compounds are also obtained. Various reactions such as evaporation of water,
evolution of CO and reaction between lime and clay take place during burning. Liquid formation begins
at 1250 °C and fusion occurs near the end of the process. Closed circuit grinding is preferred to open
circuit grinding. Process flow chart of the combined process is shown below.
In quarries where limestone, clay, gypsum etc. are extracted, hazards of dusts during drilling and
crushing, fall of rock and earth, blasting and bad weather conditions are obvious.
In cement processing area dust levels were found from 41 to 384 mg/m", the highest being at
sieving, cement packing and clinker grinding. Modern plants using wet process have 15-20 mg/nr" level.
Free silica content in dust is also possible. Electrostatic filters are useful to reduce the air pollution.
Cement Pneumoconiosis may appear after prolonged exposure. Silicosis may not occur in cement
plant (because of. absence of free silica) but may occur in refractory processes due to dust containing free
silica.
TLV (ACGIH) for Calcium oxide is 2 mg/ m 3 and Aluminium oxide 10 mg/ " USSR-MAC values
are as under-:
2nd Schedule of the Factories Act prescribes 10 mg/nr" total dust containing less than 1% quartz as
permissible TWA concentration/8 hours TLV for Portland cement.
Similarly, the same Schedule prescribes 2 mg/ m 3 respirable dust fraction containing less than 5%
quartz as TLV for coal dust.
Cabins of excavators in quarries should be fully closed and the drivers should be supplied fresh
air through respirators. Modern surface mining machines do many operations safely. They dig the
surface, collect extracted material in ,a trailer, resurface the dug land and utilise wet process and dust
suppression system. Dust suppression measures near drilling, crushing and blasting, keeping away (at a
distance) from CO possibility at blasting points (fumes), enclosures to dusty processes and to conveyor
belts including their drives and transfer points, electrostatic and bag filters at clinker kiln stacks, sieving
and packing processes, cold air flow (showers) at hot places, thermal screening, shower baths and barrier
creams for skin protection and desensitisation treatment in case of eczema are all important safety
measures.
IS : Cement, hydraulic - glossary 4845, sampling 3535, physical tests 4031, flow table 5512,
chemical analysis 4032, colorimetric analysis 12423, bag, jute cloth 12001, jute bag for packing 2580,
polypropylene 11653, high alumina for structural use 6452, masonary 3466, mastic 3709, test for
permeability 3085, oil-well 8229, paint 5410, pipeasbestos 9633, 9627, plants-emission limits for
particulate matter 10693, control of air pollution 12002, plaster finishes 1661, Portland - blast furnace
Slag 455, high strength 8112, hydrophobic 8043, low heat 269, 12600, pozzolana 1489, rapid hardening
8041, sulphate resisting 12330, white 8042, rotary kilns 8125, refractories for kilns 10607, standard sand
for testing 650, Testing apparatus -10078, 5516, 5514, 5536, 7509, 7510, 9350, 5724, 5513,
waterproofing compounds 2645, Coal for manufacture 12770, cement concrete 12727, tiles for canal
lining .10646, asbestos cement-2098, 1626, 3140, 7639, 11450, bone cement 8681.
11 CHEMICAL WORKS
Sch.l2, Rule 102, GFR, Sch.l2,Rule 114, MFR & Sch.21, Rule 95, TNFR :
Safety measures include acid and fireproof flooring, suitable PPE, safety showers, cautionary
notice, containers, crates and rubber-wheeled truck/ trolley to carry the containers safely, suitable tilling
or lifting device for emptying jars and carboys, scoop to handle alkalis, use of wooden implements to
clean acid tanks for prevention of arsine or H, production, storage of turpentine, carbides, metallic
powders and combustible materials not with acids and suitable fire extinguishers. 15 minutes washing is
suggested in case of acid or alkali burns.
It is applied to all manufactures and incidental processes carried on in industries listed in the First
Schedule of the Factories Act.
The terms defined here include toxic substances, emergency, dangerous chemical reaction,
manipulation and confined space.
1. House keeping :
Spillage to be cleaned. Floors, ways etc. free of obstruction. Easy means of access. Improper use
prohibited. No food, drink etc. in the work area. Cautionary notices and instructions regarding
fire, explosion, health hazard,' unsafe practices, symbols and colours used on labels. Undertaking
3. Authorised entry :
Only authorised persons shall be allowed to work at dangerous chemical reactions or storage.
5. Electrical installations :
Of appropriate type and conforming to IS.
7. Isolation:
Quick isolation facility with indication required.
9. Alarms :
Audible and visible alarms in control room as well as at strategic locations for process correction
to control the parameters. They should be checked daily and tested every month. The CIF has
power to direct.
13. Staging:
Structure erected for maintenance, repair or for entering into confined space should be safe and
with access with hand rails. Toe board to work at a height of 1 mt or more.
19. Ventilation :
Adequate ventilation at all times in process area to avoid any harmful concentration.
1. General:
Fire hazards area classification should be as per IS. Spark generating machines, equipment,
fittings etc. not permitted in fire prone area. Hot pipes either outside the plant or be protected.
Soles of footwear, wheels of trucks or conveyors and tools shall be of nonsparking type. Smoking
prohibited. Notices to that effect. Pipelines carrying flammable/ explosive substances shall be
protected, examined once a week and record kept of defects and repairs.
2. Static electricity:
Plant, machinery, pipelines, belt drives, receptacles of flammable liquids etc. shall be earthed and
humidity be regulated. Mobile tankers to be earthed before filling and discharge. Lightening
arrester shall be maintained where necessary.
3. Process heating :
Contact of flammable vapour and open flame should be prevented. Heating should be safe and
automatically regulated below danger point.
2. Vessel covers :
Be provided to avoid physical contact. Fence height 90 cm. or more.
3. Exhaust arrangement;
Required on gas evolving processes and be interlocked with process control where possible. In
case of its failure, the process should automatically stop.
4. Work benches :
Of smooth impervious surface and be washed daily after work.
5. Waste disposal:
Non absorbable receptacle with tight fitting cover to collect waste or rejected material soiled with
toxic substance. It shall be destroyed by burning or other safe way under supervision. Empty
containers be cleaned before disposal.
Dust or fume control and antidote methylene blue injection are suggested for Nitro or Amino
processes.
Wire mesh covering and spillage removal are necessary for all processes in glass vessels.
Chlorate manufacture requires use of hard, smooth, non-combustible surface or vessels, water
showers and daily cleaned PPE.
Plant and equipment made from reinforced plastics should be standard (IS), strong against loads,
pressure tested by a competent person and not allowing over filling or over loading.
1. Washing:
One tap for every 15 workers with liquid soap and nail brushes. They should be separate for males
and females.
2. Special bathing:
Are required for workers engaged in processes of nitro or amino compounds, chrome, tar,
cyanide, cyanate or cyanogen compounds, bleaching powder, chlorine, nickel and its compounds
or their derivatives. The CIF has power to direct other industry also. 1 bathroom for 25 workers.
Bath necessary at the end of shift.
3. Mess Room:
Required for factories employing 50 workers or more with good ventilation, furniture, drinking
water and washing facilities.
4. Cloak room:
Two lockers for each worker, one for work clothing and another for personal clothing.
Workers shall not make any safety device, guarding or fencing inoperative or defective. They
shall report malfunction or defect of machinery, equipment etc. immediately, use PPE, co-operate in
emergency duties, undergo medical examination and not do any unauthorised work to cause risk t
themselves or others.
The CIF may by an order in writing, restrict c prohibit employment of women and young person
below the age of 18, considering their health and safety aspect. Then such workers should be provide'
with alternate work not detrimental to their health c safety.
IS : See Chapter-18 exclusively for safety in chemical industry and its Part-5 for IS listed therein.
12 CLOTHING INDUSTRY
Garment making is an old and universal industry. Hazards are hand injuries, cuts, burns,
crushing, fire and chemicals. Preventive measures include :
IS : Washing machine 6930, lockers – metal 3314, wooden 5923, clothing - conductive for live
working at 800 KV 13771, leather protective 6153, safety industrial 8990, stains removal 11210,
clothessize designation 10015, body measurement sizing systems 10397, collar-white, handloom 2715.
1. Machine guarding of separators, centrifuges (with interlocking), rotary churns with bar fencing
interlocked with churn drive unit, icecrushers, cheese graters, bottling or filling machines, nip
between conveyor drums and pulleys etc.
2. Safety of boilers, steam receivers and pressure vessels.
3. Toxic hazard control of refrigerant used. Respiratory and other PPE are necessary.
4. Non-slip floor, non-slip footwear, cleanliness, good housekeeping, fixed stairs and platforms with
hand railings and guarding of open vats and vessels.
5. Chemical hazard control for acids and alkalis, use of PPE, first aid and medical care.
6. Double insulation and earthing of electrical machines and tools.
7. Explosion relief vents and temperature control in milk spray drying chambers to avoid fire and
explosion.
8. Veterinary medical supervision, personal hygiene, good washing facilities to prevent animal
infectious causing brucellosis and bovine TB.
See Part 10.9 (Micro-organism Rules) of Chapter28 for some statutory provisions.
IS : Dairy- floor finishes 7956, equipment, cleaning and sterilising 5253, industry '- rubbers 6450,
tests 1479, effluents guide 8682, laboratories, layout 2981, thermometers, floating 1672, farms, cattle
sheds 6027.
14 ELECTRONICS INDUSTRY
The use of electronic items is day by day increasing in industry, at homes and at many places.
Their manufacturing should include:
1. Exhaust ventilation for fumes of lead, zinc, rosin etc. and also for molten-solder tanks.
2. Eye protection for organic peroxide hardeners and respirators for quartz flour, epoxies with
phenol compound and airborne concentrations.
3. Prevention of flammable or explosive mixtures of solvents and source of ignition.
4. Exhaust ventilation for printing process.
5. Acid resistant and non-slip flooring, exhaust ventilation, eye bath and PPE in etching processes.
Use closed containers for etching liquids.
6. Good industrial hygiene.
IS : Electronic apparatus, safety requirements 616, climatic and durability tests 589, .gas lighters
9000, equipment - environmental tests 2106, reliability testing 8161, 7354, safety in use , maintenance,
manufacture 11743, measuring apparatus, safety requirements 9858, weighing systems 9281, 11547,
buzzers 12825, flash apparatus safety 12274, flashers 13135.
Electronic ear protectors 9167, assessment of noise exposure 7194, radiation protection for X-ray
tube, radio transmitting equipment, safety requirement 10437,6970, 6567, safety code for radiographic
practice 2598, safety of data processing equipment 10422, Hand/foot contamination monitors 11869,
Fire hazard testing 11000, protection against ionising radiation 11868.
15 ELECTROPLATING INDUSTRY
The electrolyte solutions may be acidic, alkaline o: alkaline/cyanidic. The safety measures include:-
1. Control against irritant and toxic chemicals acids, alkalis, dust, gases, fumes and vapouri of
organic solvents.
3. Ventilation system to carry exhaust air at a low level and supply of fresh air from upper level
4. Local exhaust ventilation near mechanical cleaning, polishing and grinding. Ergonomic designs
are necessary. Aluminium dust must be collected in wet trap to avoid explosion.
7. Sucking off heavier solvent vapours from below (where they are condensed) near degreasing
baths which should be installed with 1 mt safety zone between the worker and the edge of the
bath. Bench ventilation is also necessary for the after treatment of degreased parts. Benzene
should not be used.
8. Protection against acids and alkalis in pickling process. Nitrous fumes and HF fumes must not be
allowed in workroom. Their proper exhaust is necessary. Water showers and eye-washers for
treatment of burns and acid-proof PPE necessary. The acid should be poured into water while
stirring continuously, not the other way.
9. Cyanide poisoning may be fatal by breathing or skin contact. The process must be in closed
condition. The first-aid measures must be ready. Removal of contaminated clothing, washing with
water and fresh air or oxygen treatment will be helpful. Lunch should not be allowed in work
room. Optimum hygienic conditions necessary.
10. Chromium plating can cause burns, ulceration, nasal perforation and eczematisation. Powerful
exhaust ventilation with maximum closing surface hood and acid-proof PPE are necessary.
Exhaust ventilation at the rim of the bath is most effective. Air extraction per cm 2 bath surface
should be @ 1800-2700 m3/h. Non skid floors or plastic duck-boarding, electrical safety (see
Chapter-11) and environmental and biological monitoring are necessary.
Statutory Provisions:
Schedules 2, 10, & 12, u/r 102, GFR are relevant. Summary of Schedule-2 is as under :
Applicability:
This substituted schedule is applicable to electrolytic process which means electrolytic plating or
oxidation of metal articles by the use of an electrolyte containing acids, bases or salts of metals such a
chromium, nickel, cadmium, zinc, copper, silver, gold etc.
Fertilisers are natural (manure) or artificial. Artificial fertilisers are produced in chemical plants
and they may be organic or inorganic,
nitrogenous, phosphatic, potash and trace element
fertilisers. In the warehousing stage, phosphate.
potassium-salt and other dusts are released. In
chemical processing plant, air pollution by toxic
gases (Fluorine compounds, H2SO4, NO, HCI, CO
and NH3, gases) and dust, high air temperature
and noise are noticed. Closed and efficient
ventilation is necessary. In finishing processes,
weighing, bagging and storing, gaseous emissions
and fluorine compounds are released. Phosphates
and other raw materials contain 10% or more free
silica which may cause pneumoconiosis. The dust
of soluble fertilisers causes irritation. The safety
measures include:
IS : Fertiliser - Glossary 1304, sampling and tests 6092, bagged, handling and storage 5985,
mixtures 7863, 9024, effluents - tolerances 2590, treatment and disposal 9841, application equipment
glossary 9855, Metering mechanism plate type 12599, feed roller type 12613, Urea ammonium phosphate
based 8359, nitrophosphate based 7131, seed drills 6316, 6813, Phosphatic fertiliser industry. Limits of
emissions 8635. -
There are two types of matches, strike- anywhere matches and safety matches which strike only
on friction slips. Wood for its splint and phosphorus for its ignitable head pose fire and explosion
hazard. There are dust and fume hazard also. Employment of more number of children in poor working
conditions and exploitation increase more hazards. The safety measures include:
1. To prevent fire and explosion risk, manual handing should be replaced by mechanical handing,
sources of ignition and friction should be eliminated, fire-resisting PPE should be provided.
2. Good house keeping , gangways and exits.
3. Guarding of guillotine, splitting knives, rollers, printing press and other machinery.
4. Prohibition of white phosphorus. Use closed containers.
5. Good general ventilation and local exhaust ventilation near weighing, mixing splint polishing
drum and where chromium or lead compounds are used.
6. Strict cleanliness, sanitary and washing facilities for all workers and cloakroom, mess room or
canteen to be separated from process room.
7. Good sitting arrangement should be provided.
8. Only adult workers should be employed.
IS : Fireworks - aeroplanes 12975, rockets 12980, match box - paper 3303, safety 2653, 10373,
10374, 9600, log 1140, Match industry, animal glue 13254.
In December 1999, the Central Government declared prohibited production, sale and use of such
fire works which cause noise>123 dB within 4 mt from the point of their firing.
18 FOOD INDUSTRY
IS : Food poisoning bacteria 5887, 7688, cereals warning 1656, Foodgrain and pesticides residues
sampling 11380, Parathion residues 5952, malathion residues 5863, monocrotophos residues 11374, Safe
use of -PVC 7288, polyethylene 7277, styrene polymers 7961, Food colours 5346, tests for dye content
6120, dimethoate residue 11021, Sampling and tests 1699, sensory evaluation glossary 5126, effect of
packaging 8639, food yeast 3839.
19 GLASS INDUSTRY
Types of glasses are soda-lime-silica glasses, lead potash silica glasses and borosilicate glasses.
Regenerative or recuperative furnaces work upto 1500°C. After melting, other processes are annealing
(controlled cooling) manual and mechanical blowing, pressing, rolling, float glass process, grinding and
polishing, surface modification, pre-stressing for toughened glass and bonding for laminated glass.
Hazards are due to glass breaking and flying, silica, lead alkaline dusts, fuel and exhaust gases,
heat radiant energy, glass blowing, heat cataract and noise.
Statutory Provisions:
Floors mid workbenches should be smooth and impervious to water, cleaned daily and well
maintained where lead compound or silica dust are manipulated.
Other safety measures include safe handling of HF (cylinder made of lead), no food, drinks etc. in
workrooms, PPE, washing facilities and medical examination - pre employment and then at every month,
with record in Form No. 20.
IS : Glass - Glossary 1382, packing 6945, safety 2553, toughened 6180, sheet transparent 2835,
tableware 1961, tubing for laboratory 7374, thermometers solid stem 2480, protector for tubular gauge
5428, condenser 6052, containers - thermal shock test 11930, vertical load test 11539, electrode for direct
reading pH meters 6804, glass fibre chemical resistant test 10661.
See Chapter-18 for safety in chemical industry and Part-10.8 of Chapter-28 for statutory
provisions on hazardous processes.
Statutory Provisions:
Hazardous process is defined in section 2 (cb) of the Factories Act, a list of 29 hazardous process
industries is given in the 1st Schedule and detailed provisions are given m Chapter-4A (sections 41A to
H) of the Art
See foregoing part II of this chapter for general safety provisions for 'Chemical Works' also
applicable to hazardous chemicals and processes.
The Central Government u/s 6, 8 and 25 of the Environment (Protection) Act made the
Manufacture, Storage and Import of Hazardous Chemicals Rules 1989 (See Part 10.8 of Chapter-28).
Then similar Rule 68J was added to the Gujarat Factories Rules 1963 w.e.f. 15-2-95. It was substituted by
Notification dated 30-6-2004.
Definitions (Subrule-I)
Subrule-I defines hazardous chemical, industrial activity, isolated storage, major accident,
pipeline and Schedule.
1. This provision is applicable to an industrial activity of hazards chemical mentioned in Part1 'or II
of Schedule-1.
2. MSDS specified in Schedule -5 should be prepared for hazardous chemical. It should be shown to
workers on request.
The inspector shall inspect at least once in a year the industrial activity or isolated storage, send
annual status report and check major accident, site, safety report, safety audit report, onsite and offsite
emergency plans.
The CIF should be informed in Schedule -7 at least 3 months before commencing such activity. If
quantity of chemical mentioned in column 3 of schedule-2 & 3 exceeds the threshold quantity, it should
also be informed subsequently.
Information sent as above shall be updated and subsequent updated report shall be sent to the CIF.
No industrial activity, to which this sub-rule applies, will be undertaken unless a Safety Report is
sent in Schedule-8, three months before commencing that activity. Safety Audit report should be sent
subsequently. Frequency of safety audit report-internally every year and externally two years.
An occupier carrying an industrial activity to which this sub-rule applies shall prepare and submit
to the Inspector and the CIF an On site Emergency Plan in Sch-8A and rehearsal at every 6 months. For
its details see Part 6.2 of Chapter-19.
The occupier shall inform persons likely to be affected the nature of major accident hazard and
'DOS' and 'Donts' about it.
See Part 8.3.1 and 8.3.2 of Chapter-18 and Schedules 7, 13, 14, 16, 19, 20, 21, 22 and 24 u/r 102
of the Gujarat Factories Rules for statutory provisions pertaining to flammable liquids and gases.
As defined under MSIHC Rules highly flammable liquids and gases are classified as –
Difference between heat generated by the ignition source and heat generated by the burning
material is called the flammability index. This index of combustible material ranges from 0.5 to 2.1 and
that of highly flammable exceeds 2.1.
From flammability point of view, substances having melting (or dew) point above 50 °C are
considered as liquids and those having saturated vapour, pressure of 0.3 Pa or more at 50 °C are gases.
Properties of flammable substances are flash point, fire point, auto-ignition temperature,
flammable or explosive limits (range), maximum explosion pressure, maximum safe gap, minimum
ignition energy, minimum extinguishing concentration, rate of combustion, rate of total combustion, rate
of heating and type of reaction.
For the detailed definitions of above properties and evaluation of flammability of solids, liquids
and gases, reference No. 1 at the end of this chapter may be studied.
Therefore both these substances will ignite immediately on contact of a spark or static charge.
Hence precautions mentioned in Section-37 of the Factories Act must be strictly followed. These
provisions prescribe -
Statutory Provisions
Schedule 13 u/r 102, GFR, Sch.23 u/r 114, MFR and Sch.31 u/r 95, TNFR prescribe statutory
requirements. Their abstract is as under (G=Gujarat, M=Maharastra & TN=Tamilnadu):
This is regarding manufacture of bangles and other articles from cinematograph film and toxic
and inflammable solvents.
Here 'toxic inflammable solvents' mean solvents like acetone, tetrachloroethane, alcohol,
denatured spirit, phenol, amylacetate, butyl acetate, diacetone and such other substances which in the
opinion of the CIF are toxic and inflammable.
1. Prohibition to employment of woman and young persons in the storage or process of above
chemicals.
2. Medical examination - first within 7 days of the employment and then every month. Record in
Form No. 20.
3. Protective clothing including apron and head-coverings.
4. Efficient ventilation in workroom.
5. No smoking and no source of ignition.
6. Flameproof electrical installation and fittings.
7. Smooth and impervious floor and to be washed daily with water.
8. 10 minutes washing time before each meal and before the end of the day's, work.
9. Washing, bathing, cloak-room and mess-room facilities.
10 Fire-fighting appliances, means of escape in case of fire and doors/windows to open outwards
readily.
11 Cautionary notices regarding dangers to workers. Contents to be explained to illiterate person
carefully.
"Flammable compressed gas' mean» that defined u/ s 2 of the Static and Mobile Pressure Vessels
Rules, 1981.
1. Safe storage in a fixed tank or closed vessel or a room of fire resistant construction.
2. Enclosed system of pipes, pumps etc. so as to avoid leak or spillage.
3. Leakage shall be contained, drained off or diluted to prevent flammable air mixture.
4. Exclusion of source of ignition by flameproof electric apparatus, prevention of static charge, no
footwear with steel or iron, belts without iron fasteners and prevention of ignition sources such as
open flames, sparks, hot surface, heat generating reaction and radiant heat.
5. Prohibition of smoking.
6. Fixed and portable fire fighting systems, materials and procedures as prescribed by IS.
IS : Flammable gases and vapours classification 9570, Flammable liquids detection, storage,
construction safety 10386, Flammability test for aerosol products 8469, cables 10810, flame spread of
products 12777, flame resistant suit 7612, flame photometer 8651, flame safety lamps, gas testing 7577,
Flameproof - AC motors for mines 3682, electric lighting fittings 2206, enclosures of electrical apparatus
2148, transformers 11333, Compressed - oxygen 309, hydrogen 1090, argon 5760, carbon dioxide 307,
nitrogen 1747, solvent - for paints 82, insulating varnishes 10026, petroleum hydrocarbon 1745.
22 LEATHER INDUSTRY
Leather is the skin of animals when tanned and prepared for human or industrial use. Leather
processing includes cutting and incision, chasing, moulding, embossing, hammering, mosaic formation,
trimming, bonding, stitching and dyeing. Industrial safety measures include :
1. Benzene and any aromatic solvents containing benzene should be replaced with substances in the
aliphatic series.
2. Toxic concentrations should be controlled by efficient exhaust ventilation.
3. As the solvents may produce fire and explosion, flameproof electric fitting and elimination of
sources of ignition are necessary.
4. Dyeing operations should be fully mechanised or enclosed to avoid human contact.
5. Personal protective equipment.
6. Medical check-ups.
7. Guarding of machinery and safe use of knives and hammers etc.
Statutory Provisions:
Summary of Schedule-10, Rule 102,, GFR, Sch.9 u/r 114, MFR and Sch.9 u/r 95, TNFR on
liming and tanning of raw hides and skins and incidental processes is given below :
Cautionary notices regarding Anthrax, Chrome ulceration and the occupational diseases listed in
the 3rd Schedule of the Act, are compulsory.
Washing facilities of one place for 10 workers, one wash basin-for 10 workers, mess room and
cloak room are required. Foods and drink in work rooms are prohibited. Hands of workers coming in
contact with chrome solutions shall be checked twice a week and suitable ointment and waterproof
plaster shall be kept in a box readily available.
IS : Leather - glossary 1640, clothing protective 6153, garments 12718, chromed buff calf skin
8121, apron 3446, chemical testing, chrome- belt lace 575, high altitude gloves 5866, footwear sampling
2051, gas meter diaphragms 9155, leg guard 3946, oil seals and washers 3020, gauntlets - for steel
workers 2574, mittens for steel Workers 2575, welders 2573, harness 580, belting for power
transmission 2240, round for small machines 2241, V-open ended, cogged 10022, endless flat for lenix
drive system 12854, hydraulic 581, loom-pickers 8546, picking band 1225, shuttle cock caps 4102, laces,
footwear 7721, Safety-belt & strap, lineman's 3521, boots for miners 1989, boots for metal industry 3737,
shoes for women miners 11225, footwear with moulding sole 11226, 5677, industry effluent 5183, lining
3840, polish wax emulsion 6045, sampling 5868, sandal for men 6493, sole 579, boards for insoles 5867,
shoes non-slip 11543, leather cloth vinyl coated fabric 1259, leather roid for electrical purposes 4819,
leathers 3840, chemical testing of leather 582, physical testing of leather 5914, utility glove 11230,
slickers for leather industry 5712.
23 PAPER INDUSTRY
Paper is a thin felted matrix of interlacing cellulosic fibres made from wood pulp or rags, straw
and grass or waste paper.
In making paper, first raw material from wood pulp, west paper or grass is cut in to pieces. Then it
is soaked in water to make pulp. Necessary additives and bleaching agents like C1 2 or H2O2 are passed
through the pulp to make it white. It is passed through many tanks and pulper machine. Then
homogenous pulp is passed through paper mill where it is run on the felt through wet and dry (hot)
processes. A paper film is formed as a result of this process in the paper machine. Then continuous paper
is wound or reel and a papci roll is formed. The roll is removed from the re-winder machine and sent to
the cutting department. There if is cut in to the required sizes and packed in bundles.
1. Nip guards on various rolls and felt nips of drying and re-winders etc. Interlock guards for the
whole in running nip with additional side guards, efficient doctor blades, air feeds, belt feed and
well designed hand tools are necessary.
2. Manual straightening of paper should be replaced by mechanical straightening.
3. Sufficient stopping and breaking pushbuttons i.e. switches.
4. Operation with moving machinery at slow speed.
5. Automatic lubrication instead of manual while machinery is in motion.
6. Interlocked door on hopper of the baling press.
7. Pulpers should have strong fencing (railing) to prevent fall into the deep vessel and interlock door
near feed point.
8. Interlocked or photo cell guards on guillotine cutters and slitting machine.
IS : Glossary of terms relating to paper and packaging 4261, 4661, 7186, relating to paper sacks
9028, terminology 7186, methods of test for pulp 6213 (Part I to 21), methods of sampling and test for
paper and allied products 1060 (Part I to 3), methods of test for corrugated fibre board 7063 (Part I to 4),
methods of test for smoothness/roughness of paper 9894, Axial (end to end) compression strength of
composite cans, tubes and cores, method of test 13975, method of end blow-off pressure test for
composite cans 13976, corrugated fibre board boxes for packing and transportation 13228, for exporting
glass jars and bottles 9313, for packaging of apples 11844, for packing soaps 10176, fibre board drums
7601, general purpose packing/wrapping paper 6615, grease proof paper 6622, ice-cream cups and lids
10177, kraft paper 1397, packing paper, waterproof bitumen laminated 1398, aluminium foil laminates
for packaging 8970, waxed paper 3962, 3963, 7162, 9988, alkali resistant paper 3673, base paper - for
carbon paper 3413, for tracing paper 11687, for waxed paper 2991, blotting paper 1396, cover paper
6956, hand made drawing paper 3064, map printing paper 12765, newsprint paper 11688, paper for
permanent records 1774, paper sizes 1064, sizes of envelopes 3338, tracing paper 8431, tissue paper
8460, printing paper 1848, cellulosic paper for electrical purposes 9335 (Part I to 3), 2189, paper clip
5650, Cuttings 4356, germination 6671, insulated leadsheathed cables 3961, insulation, tear resistance
24 PESTICIDE INDUSTRY
Statutory Provisions:
Schedule 15, Rule 102, GFR, Sch.l5, Rule 114, MFR and Sch.29,Rule 95, TNFR give statutory
provisions for manufacture and handling of dangerous pesticides listed in Appendix-1 to that Schedule.
Appendix-11 gives cautionary placard.
The measures include prohibition of employment of women and young persons, air space of 500
3
m or more per person, efficient exhaust draft on charging, discharging, blending and powder or liquid
preparation, sound and sloping floor with gutters and drainage, daily washing, workbenches of stainless
steel, waste container with lid and waste disposal by burning, safe disposal of empty containers, no
manual or direct handling, protective clothing and their daily washing, medical facilities including doctor
and antidotes and medical examination - pre employment, quarterly examination and record in Form 20,
GFR additional rest interval of 10 minutes before each meal and before the end of the day's work,
washing and bathing facilities with at least 50% bathrooms and 1 place for 5 workers with clean towels,
soap and nail brushes, prohibition of food and drink in workrooms, cloak room for clothing and PPE,
mess room with incharge person and prior permission o? the CIF to start manipulation of a new pesticide
i.e. not listed in Appendix 1.
Sch.l5, u/r 102, GFR defines "pesticides" as agents used for the purpose of destroying or arresting
the growth or increase of harmful organism and defines "dangerous pesticides" as those listed in
Appendix-1 as under:
Sch.l5, u/r 114, MFR, defines "dangerous pesticides" as those defined in Sec. 3(e) of the
Insecticides Act 1968 or any other substance declared as such by the CIF in writing. List of Insecticides
u/ s 3(e) of the Act is very long with addition from time to time.
Sch.29, u/r 95, TNFR does not give Appendix1 i.e. a list of dangerous pesticides but defines
dangerous pesticides' as any product proposed or used for controlling, destroying or repelling any pest or
for preventing growth or mitigating effects of such growth including any of its formulations which is
considered toxic under and is covered by the Insecticides Act, 1968 and the rules made there under any
other products as may be notified from time to time by the State Government.
Appendix-11, Cautionary Placard is similar in all above three State Rules and is reproduced
below:
Cautionary Placard
Pesticides and agrochemicals enter into the body through inhalation, ingestion or skin absorption.
They are classified as toxic, harmful, corrosive, irritant, flammable, explosive or oxidising. Toxicity is
mostly denoted by LD,, or LC,, values. All agrochemicals should be labelled, transported safely and
correctly stored in a room (locked and cool). Containers should be opened only after wearing correct
respirator (positive air pressure), neoprene or plastic hand gloves, aprons, boots etc. Protective clothing
are always essential while handling pesticides. Inhalation of vapour should be avoided. Contact with skin,
eyes and clothing should also be avoided. Contaminated clothing should be immediately changed, the
entire body .should be thoroughly washed with soap and water. After working with pesticides, shower
Types of effects may be acute (immediate) or chronic (prolonged or slow delayed). Some
common symptoms are - dizziness, headache, shaking and weakness. More toxic effects may cause
convulsions, irrational behaviour or unconsciousness.
First-aid treatment includes - removal of affected person to a safe, clean and airy place, washing
of the part affected and to put the person in recovery position (slipping on shoulder). On swallowing,
vomiting should be induced if person is in consciousness. Medical charcoal and plenty of water may also
be 'given.
Blood cholinesterase activity test should be carried out every 15 days. If the level is found less
than 62.5%, the worker must be transferred to another place where no exposure is possible. After medical
treatment and. safe report he can be put back to his plant. But meantime the engineering controls should
be provided or revised to eliminate the exposure. Leakage and spillage must be removed. Defect in PPE
should be checked and removed.
An Office Circular dated 27-7-1995 of Factory Inspection Office, Bharuch, sent to pesticide
factories, seems to be more important and suggests following safety measures :
1. For filling bottles or small containers of liquid, granules or powder, automatic filling machines
with closed chamber and attached local exhaust ventilation must be used. Weighing, plugging and
sealing operations and conveyor movement should also be automatic and under suction chamber
so that a worker has not to touch any thing and no spillage, vapour or dust shall touch his body.
2. To fill barrel or big container a chamber with exhaust hood and ventilation should be used.
3. To contain or collect leaking liquid small bund and pit shall be provided.
Spilled pesticide should be neutralised or washed with dry clean cloth and stored in a dust-
bin with spring-lid. Then it should be safely disposed or burnt out.
4. Workers engaged to shift, move, clean or pack the filled (plugged) container or to clean any
spillage, shall be given goggles, long sleeved shirt and pent, good quality rubber hand gloves,
waterproof suit or apron, gumboot and air-line respirator. Safety showers and bathrooms shall be
provided.
5. Illiterate, untrained and temporary contract workers are exposed to more risk. Therefore such
training should be given to them so that they can read or understand the necessary precautions.
6. Pedestal or positive air fan removes the vapour or dust from one worker to another. Therefore it
is inadvisable. Exhaust or negative air suction and air-line respirators are the effective
remedies. Exhaled air should be passed through carbon bed filter or effective absorber and final
vent discharge should be within safe limit.
7. Regular air monitoring at work place, ppm record and leakage checking are necessary.
8. A record of full name, address, signature, date of joining and photograph of all the workers at the
time of first employment are useful to detect cases of delayed effects or after-service effects.
9. If pre-employment and subsequent medical examination shows blood cholinesterase level less
than 62.5%, that worker should not be employed in pesticide work. If RBC level is also low, the
worker should be kept away for 3 months from such process. Sufficient stock of PAN, Atropine
etc. (antidotes) should be kept in the factory first-aid centre.
Personal hygiene - to wash hands and mouth before and after lunch and bathing and changing
clothes at the end of the work - is highly essential.
See Part 4.1 & 4.2 of Chapter-28 for Insecticides Act & Rules.
IS : Handling cases of pesticide poisoning 4015 (Part I & 2), malathion- safety code 10872,
technical 1832, phorate G 9359, methyl parathion 10630, benonyl 13786, dodine 13784, diflubenzuron
14185, 14186, pesticide common names 885, determination of metalaxyl residues 14161, methods of test
6940, Residues determination in agriculture, food commodities, soil and water - 13830, 13831, aldicarb
10629, aldrin, dieldrin, aptafol 13245, in food 5863, organochlorine in tobacco products 11820, sampling
11380, solid and liquid packing requirements 8190 (Part I to 4), solid packaging 6604, zinc phosphide
9278, aluminium phosphide 9279, kitazin 13788 to 13790.
Packing containers - HDPE bags 8069, polyethylene 9754, aluminium bottles 9503, aluminium
containers (5 litres and above) 9445, tinplate cans 9992.
25 PETROCHEMICAL INDUSTRY
This is relatively a recent industry. The plants are modern, mostly automatic and totally enclosed.
It uses gaseous, liquid or solid hydrocarbons. Toxic and flammable exposures and high pressure- high
temperature reactions pose health, fire and explosion hazards. Proper FFE and PPE should be used. Pre
and periodical medical examinations are necessary. Other aspects similar to chemical industry (see
Chapter 18).
Statutory Provisions:
Summary of Schedule 7, Rule 102, GFR, Sch.7, Rule 114 MFR and Sch.7, Rule 95 TNFR is as
under:
For Sch.l3 GFR, Sch.23 MFR and Sch.SI TNFR see foregoing Part 21 on flammable liquids.
IS : Petroleum - glossary 4639, hydrocarbon solvents 1745, coke 1448, 8502, gas containers 4093,
gas measurement 8818, industry - pipe threads 3333, 9996, flanges, fitting and C.I. pipes 3516, bauxite
3605, jelly for cosmetic industry 4887, meters, accuracy requirements 2801, storage tank, maintenance &
operation 9964, fabrication 10987, sampling 1447, test methods 1448, gauging 1518, temperature
measurement 1519, filling machine 3047, measurement instrument 3032, vehicle tank for calibration
2383.
A simple refinery carries out atmospheric and vacuum distillation and produce naphtha and
limited products. Other refineries have more processing units such as cracking, alkylation, reforming,
isomerisation, hydro treating and lubricant processing. A refinery operation includes 7 areas
Detailed safety norms are prescribed by Oil Industry Safety Directorate and known as OISD
norms or standards. They are available in such oil industries.
OISD Standards :
LPG plant is having fully automated fire fighting facility in the form of sprinkler system and
hydrant network which is spread all over the plant. For fire fighting purpose, water is stored in separate
tanks which last for 4 hrs of fire fighting. For catering water to the sprinkler and hydrant system, fire
engines are provided alongwith jockey pumps which automatically maintains a water pressure of 8
kg/sqcm in the hydrant and sprinkler lines. All the Horton spheres. Pump House and Sheds are provided
with the sprinkler system which automatically operates if the temperature in these areas rise to 79 °C
during an emergency. The operation of sprinkler system will start the fire engines automatically and will
pump water in the sprinkler lines. All the facilities are covered with a well maintained hydrant and
monitor network which is again fully automatic. Besides this, fire extinguishers of DCP and CO, type are
provided near all the facilities as per OISD norms which are checked monthly.
For fire fighting purpose fire organisation chart is prepared which comprises of employees of the
plant itself. The fire organisation is basically divided into three teams viz. (1) Fire Fighting team (2)
Assisting team (3) Rescue team. All the employees working in the plant have been allocated a job to be
carried out during an emergency. For accessing the performance of the teams, Fire Drill is carried out
every month and Disaster Drill is conducted once in a year.
Plant is also equipped with fire fighting accessories like fire entry suit, fire proximity suit, water
gel blankets, different kinds of nozzles, low temperature clothing, breathing apparatus etc.
IS : Glossary 4639, ventilation in petrochemical plants and refineries 12332, refining industry,
effluent treatment 10044, air pollution in petroleum refineries 10179, limits of gaseous emission 8636,
LPG 4576, LPG storage installations 6044 (Part I & 2), jointing compounds 3465.
27 PHARMACEUTICAL INDUSTRY
Because of strict requirements of Drugs and Cosmetics Act and Rules, generally pharmaceutical
factories are neat and clean and the plants are properly laid out. Some safety measures include :
Mostly ovens and driers are used in pharmaceutical or bulk drug industries. Statutory provisions
for them are as under.
This rule is applicable to ovens and driers operating at a temperature higher than ambient
temperature and in which flammable/explosive air mixture may be evolved in an enclosed structure. It is
not applicable to those of capacity below 325 litres and used in laboratories or kitchens.
1. Separate Circuit:
Separate electrical power supply with isolation switch should be provided.
3. Safety Ventilation:
(1) Centrifugal fan/s for dilution of air mixture and speedy exhaust.
(2) Safe dilution level is less than 25% of its LEL. 50% of LEL can be allowed if continuous
monitor with alarm at 50% LEL is provided which shuts down heating system at 60% of
LEL.
(3) If above ventilation system is not efficiently working or dilution level is not as mentioned,
oven or drier shall not be operated.
(4) Exhaust of ventilation shall be away from the workroom. It should not re-enter through
windows/doors.
(5) Fresh air should be evenly circulated in oven/drier without any. air pocket.
(6) Throttling damper must allow minimum ventilation rate in its maximum throttling
position.
4. Explosion Panels :
(1) All ovens/driers of more than 0.5 nr" internal space shall have explosion panels (hinged or
fragile doors) to release the pressure of accidental explosion.
5. Interlocking arrangements:
(1) Ventilating fans must start first before the feed conveyor starts.
(2) Failure of ventilating fans will automatically stop the feed conveyor, fuel supply,
ignition and the heat source.
(3) Failure of the conveyor will close the fuel valve, ignition and the heat source.
6. Purging by pre-ventilation:
Automatic pre-ventilation system will change 3 times the fresh air volume before starting the
heating and conveyor feeding.
7. Temperature Control:
Automatic temperature control to ensure its safe limit. Multi stage temperatures will be
maintained within the designed limits.
8. Prevention of Dripping:
Dripping of combustible material on heaters or flame shall be prevented.
IS : Pharmaceutical products, packaging, code of practice 14233, plastic containers 7803, rubber
closures 3692, safe use in contact with - PVC 7288, 10148, 10151, polyethylene 7277, 10141, 10146,
styrene polymers 7961,10142,10149.
28 PLASTICS INDUSTRY
This is a fast growing industry. It has three sectors: (1) polymers and moulding compounds (raw
material) manufacturers, (2) processors and (3) machinery manufacturers.
Plastic Processing Industry converts bulk polymers into finished articles and includes :
1. Guarding of press platens of compression, transfer, injection and blow moulding machines.
Effective or double interlocking is essential.
2. Trip device at rollers and calendars with nip guards.
IS : Industry, glossary 2828, fire safety code 11457, Plastic - for food packaging 10172, container
for Vanaspati 10840, 11352, pouches for milk 11805, for edible oils 12724, 12883, 12887, brattice
sheeting, unsupported, fire resistant 11884, button 1461, 1465, .chair 13173, clays for ceramic industry
4589, container for fuel 7394, emulsion paint 4511, films for electrical purposes 11298, laminates 5746,
measuring cylinder, graduated 10073, mechanical properties test 8543, moulded briefcases 9848,
packaging material 10106, packaging terminology 7019, pipes farm drainage 9271, reflectors, lighting
fittings 3287, spectacle frame 3693, suitability for food packaging 10171, Surgery - scissors 4275, 4281,
needle holder 4245, respiratory 4587, dissecting 4282, forceps 9184, Tests 8543, use in instrument
industry 7078, welding, glossary 5687, transparent sheet 9035, 9036, water bottles 8688, wood 423,
adhesive tapes 7809, 13262, valves, float diaphragm type 13049, cartridge for shot guns 12497, strain
ratio V for sheet metals 11999, PVC lining for chemical process vessels 4682, method of testing 13360,
hoses and tubing, bending tests 112656, plasticiser 9591, 3672, 6627, 9572.
29 POLYMER PLANTS
In organic chemistry certain giant molecules such as starch, rubber, plastic .or resin, synthetic
fibres, cellulose, proteins are called polymers and plants manufacturing them are polymer plants. Thus
rubber manufacturing plant, synthetic yarn (nylon, terylene etc.) unit, plastic, resin or silicon making
factory or a starch manufacturing factory can be called a polymer plant.
The polymer (bigger) molecules are built up of smaller units joined together and form a repeating
structure. The repeating structure or the recurring unit in a given molecule is called the monomer, and the
entire molecule composed of several such repeating units is called a polymer. Thus we can say that
rubber is a polymer of isoprene, starch of a-glucose and cellulose of (3-glucose.
Polymerisation process is of three types (1) Addition polymerisation i.e. the combination of
monomers either of the same kind or different kind by a process of addition involving no loss of
fragments, for example, ethylene - polythene. (2) Copolymerisation involves two different types of
monomers, for example, vinyl chloride with vinyl acetate. (3) Condensation polymerisation means the
combination of monomers by a process involving loss of a simple fragment or a molecule of water. The
terminal units of the polymer chain may be different from the units inside. For example, polyester from a
dialcohol and diacid. The alkyd resins are such polymers obtained from phthalic acid and glycol or
glycerol. Linear polymers are thermoplastic and cross-linked polymers are thermosetting.
Mostly the polymerisation processes are carried out in totally enclosed system and therefore the
hazards are reduced to much extent. Machinery is also mostly enclosed. The hazards are possible from
exposure to raw materials, leakage and spillage, dusts and fumes, hot surfaces and radiant heat, noise and
vibration and heat and humidity.
Chemicals like formaldehyde andcaprolactam cause burning in eyes, nose and throat. High
temperature and pressure of thermic fluid (e.g. Dowtherm) in oil heating system may cause burn and
sometimes fire. Extrusion machines have hot surfaces which need insulation to prevent burn injury and
hopper feeder to prevent hand contact with screw conveyor inside. Cutting machines for plastic, rubber
and other hard substances need safety guard on cutting blade and machine drives. Charging of toxic
materials (powder or liquid) need enclosed system with local and room exhaust fans and necessary
respirators.
Polyamides used to manufacture epoxy resin are skin irritant. Acrylonitrile used in
polyacrylonitrile (PAC or acrylic) fibre is toxic, skin irritant and carcinogenic. This effect was noticed in
polymerisation workers. Another chemical dimethyl formamide (DMF) causes digestive effects,
abdominal pain, skin effect and pancreatitis to workers exposed to it. (e.g. spinning bath and solvent
tanks).
Styrene monomer, acetone (used in cleaning) and organic peroxide catalysts used in making
polyester resins may cause fire and explosion. Styrene vapour may cause narcosis (effects on head, nose
and throat).
To control such vapour, dilution ventilation and spray booth are necessary. TLV is more critical
than the LEL of styrene. (Styrene monomer-phenylethylene or vinylbenzol – C 8H8 TLV 50 ppm or 215
mg/ m3 STEL 100 ppm or 425 mg/m3, LEL 1.1%, UEL 6.1%, FP-33 °C, VD 3.6, poison via oral, ivn).
The inhalation dose of styrene can be measured by analysis of exhaled air (gas chromatography).
Solvent storage should be kept away, covered metal containers should be used to collect solvent
wastes, electric fitting should be flameproof and smoking must be prohibited. Direct contact of peroxide
catalysts should be avoided. Neoprene or plastic gloves are not affected by solvents.
Itching from fibrous glass particles can be minimised by good housekeeping, ventilation, use of
long sleeves, barrier creams and frequent washing with soap and water.
Ethylene, propylene and other olefin members to make polyolefins (polymer) are weak
anaesthetics at a concentration above 60%. Freezing burns due to liquid propylene and hyperplasia due to
prolonged exposure to diolefins have been reported. Aluminium alkyls are flammable in air and explosive
in water, their fumes may cause lung damage and in solution it causes burns. Adequate body PPE should
be given to workers.
Ethylene, propylene and butylene are gases at room temperature, highly flammable or explosive
when mixed with air or oxygen and large fires of olefins are difficult to extinguish. In case of fire, their
supply should be stopped, fire should be allowed to burn out and adjacent structures be cooled by water.
Small fires may be controlled with CO2 or DCP extinguishers.
In making various types of synthetic rubbers, solvents like hexane, styrene, butadiene,
chloroprene, acrylonitrile, toluene diisocyanate (TDI) and other isocyanates in making elastomers,
ethylene dichloride (EDC), methyl chloride, ethylene, propylene etc. are used. Safety measures are
required depending on properties of these dangerous chemicals, their splashes and leakage, pressure
release, machine parts, entry into vessels, cuts and burns, fall from height and on the floor.
Health hazards are possible in handling raw rubber containing extender oil and carbon black.
During fire CO hazard is also possible.
Workers should be made aware of all these hazards and properly trained. Gas detectors with
alarms, welding permit, vessel entry permit, exposure measurement, good ventilation, rubber gloves, eye
protection, hearing protection and washing facilities are also required.
Thus depending on a type of polymer plant, a variety of control measures are applicable.
IS : Styrene polymers, safe use in contact with foods etc., 7961, 10142,10149, styrene vinyl
benzene 4105, styrenated phenol 7351, styrene butadiene rubber (SBR) - latex 11356, latices, tests 4511
(Part I to 6), tests 4518 (Part I & 2), Polystyrene - for insulation 4671, wall tiles 3463, fixing 4112, sheets
5210, Polybutadiene rubber (PBR), test methods 10016, Polyester resin bath tubs 6411, tank, chemical
resistant 10661, Polyolefin - plastic container 7408, fibre analysis 9896, Polypropylene and its
copolymers, safe use with food stuffs, drinking water etc., 10909, 10910, thermoplastics 10951,
Polyurethane foam - domestic mattresses 7933, insulation, code of practice 13205. PVC - resin 4669,
sheeting, flexible 2076, boots, oil & fat resistant 13038.
30 POTTERY INDUSTRY
This is one of the oldest human crafts and many techniques have been changed during centuries.
The basic processes of modern industry are preparation of body ingredients, forming and shaping, biscuit
firing, glazing, glost firing and decoration. The product is classified as tableware, sanitary tiles and
industrial ceramics. The safety measures include :
Statutory Provisions :
Provisions of Schedule 25 Rule 102, GFR and Sch.lS, Rule 95, TNFR are summarised as under :
1. Applicability:
This schedule applies to all factories engaged in manufacture of pottery except where following
articles are made –
(1) Unglazed or salt glazed bricks and tiles.
(2) Architectural terra-cotta made from plastic clay and either unglazed or glazed with a
leadless glaze only.
2. Definitions:
The words pottery, leadless glaze, low solubility glaze, fettling, efficient exhaust draught, potter's
shop etc. are defined.
Many processes have been mentioned which cannot be carried out without efficient exhaust
draught. These include manipulation of dry and unfritted lead compound, fettling operations, shifting of
clay dust, pressing of tiles from clay dust, loading and unloading of saggars, brushing, crushing, dry
grinding, cleaning, lifting of materials, weighing, mould making etc. unless the machine is so enclosed or
material so damp that no dust can be given off.
(1) Processes giving dust or using dry lead compound should be separated. Women or
young persons cannot be employed in such processes.
(2) Use of leadless glaze or low solubility glaze is permitted and that of high lead content is
prohibited.
(3) Potter's wheel (Jolly and Jigger) should have screen to prevent clay scrapings being
thrown off.
(4) Damp saw dust or other moist method should be used to prevent flying dust during
cleaning of floors.
(5) PPE like overalls, head-coverings, aprons and dust respirator should be given as per need.
(6) One water tap or stand pipe for every five workers with their spacing 1.2 mt or more and
towels, soap and nail brushes should be provided. Washing time shall be allowed before
each meal and at the end of the shift.
IS : Clay - ball for ceramic industry 4589, bricks 6165, 5454, 3495, burnt 7556, Hollow bricks for
walls and partitions 3952, filler blocks for floor and roof 6061, pipe products glossary 2248, Tiles 3951,
3367, roofing tiles, half round flat 13317, china clay 2840.
Ceramic tiles - 13711, 13712, 13753 to 13756, Tests 7571, 13630, Tower packing 7087, water
filter 7402, components for thermocouples and thermometers 8495, Limits of toxic materials 9806,12038.
Ceramic grinding media and lining 7775, Earthenware & dinnerware 2857, 3149, bone china
crockeryware 6958, Glossary for - ceramicware 2781, enamelware 2717, stoneware 2839, stoneware,
crockeryware 11745, stoneware coatings 2838, colour test for vitreous enamel coatings 8709, methods of
test for vitreous enamels and frits 8687 (Part I & 2), 3972 (Part I, Part 2, Sec. I to II), plaster of Paris for
ceramic industry 2333, plastic clays for ceramic industry 4589, porcelain crockeryware 3505, powdered
talc for ceramic industry 10429, pyrophyllite for ceramic industry 11477, quartz for ceramic industry
11464.
31 RUBBER INDUSTRY
The rubber may be natural from rubber tree or synthetic classified as homopolymers and
copolymers. Safety measures include :
1. Fire prevention for flammable materials. Well trained fire fighters. Gas detectors with alarms.
2. Handling precaution of pyrophoric catalysts.
3. Handling of volatile monomers and solvents in closed system. Good general ventilation.
4. Self-breathing apparatus to handle large leaks and spills of toxic material.
5. Steam purging of vessel to remove chemical vapours.
6. Personal protective equipment.
7. Washing facilities.
8. Noise control.
Statutory Provisions:
For an abstract of Schedule 4, Rule 54, GFR see Part 4.4 of Chapter-14.
IS : Rubber - industry glossary 7503, acrylonitrile butadiene 8683, aprons for hospital 6407,
belting - transmission 1370, conveyor 1891, 14206, Boot 13695, 13995, 5557, knee boots 3738, bottle'
for hot water 1867, Compounds - sampling and tests 7086, vulcanised 5192, Hose, wire reinforced 7651,
Flooring materials 809, floors code for laying 1197, Footwear - sampling 6368, use at low temperature
14290, antistatic 13575, 13996, Rubber for dairy industry 6450, gasket 11149, for pressure cooker 7466,
Gloves for electrical purposes 4770, post mortem 4149, surgical 4148, hawai chappal 10702, seals 13249.
Rubber hose - agricultural spray 1677, air hose 446, hot water 5821, fire fighting 636, chemicals
7654, petroleum tankers 10733, fuel dispensing 2396, hydraulic 10660, oil and solvent resistant 635,
water - general purpose 444, sampling and test 443, sand blasting 5894, 6417, steam 10665, suction for
fire services 2410, water suction - light duty 2482, 8189, heavy duty 3549.
Rubber - ice bags 3867, insulated cable, current rating 3961, jointing 638, latex 5430, 11001,
foam products 1741, lining for chemical equipment 4682, mat for electrical purposes 5424, gaskets foe
joints with CI pipes 12820.
Rubber packaging - 5190, styrene - butadiene 11356, symbols 6611, tests 3708, 9316.
Natural- raw 4588, 5599, tests 3660, formula for evaluation 7499, latex based 9827.
Rubber - reclaimed 7490, tests 6306, rollers for offset printing 11610, sheetings, hospital 4135,
synthetic, test methods 11720, tests for feeding bottles 3565, tul)es, cycle 2415, Ttfcing for - LPG 10908,
general purpose 637, medical use 5680.
Rubber based adhesives for - tubes and tyres 2560 to 2562, PVC tiles 12830.
Rubberised - coil cushioning 11060, coir sheets 8391, fumigation sheets and covers 4810.
Ship building and breaking at shipyard or dock, engage many workers and attract provisions of
the Factories Act and Rules, though the Dock Workers (Safety, Health and Welfare) Act 1986 (and
Rules) is a specific legislation on the subject. See Part 8 of Chapter-28 for Dock Safety Laws.
In addition to the bad weather conditions and climatic effects, the working conditions are also
very risky as it involve handling of large sized heavy steel plates, pipes and other articles, fabrication,
machining, erection, welding, cutting and work in confined spaces as well as at heights. Welding and
cutting in oil tanks have caused many fatal accidents. Raising and lowering of heavy parts and materials
and mechanical lifting cause hazards. Falls from different levels, striking against objects, stepping on
objects, struck by falling bodies, injuries by hand and power tools, lifting gear, fire, explosion and
gassing, burns by hot surfaces, effects of noise and vibration, fumes and eye burning from organic
pigments, resin and solvents, loose or temporary wiring, inadequate lighting, dusts from asbestos
insulation and shot blasting are also possible. Most of the workers are employed through contractors
where training and supervision are poor.
Occupational diseases specific to this industry are : arc eye due to welding, deafness due to high
noise, white finger due to vibrating tools, lung irritation, narcosis from exposure to solvent fumes,
asbestosis, mesothelioma, carcinoma, asthma, siderosis a banign lung condition due to inhalation of iron
oxide dust or flue from welding or burning, dermatitis or skin rashes and cataracts due to ionising
radiation and lasers.
Statutory Provisions:
Rule 68H, GFR gives statutory provisions. Its summary is given below :
1. Applicability:
This rule is applicable to "operations" of construction, reconstruction, breaking, repairing,
refitting, painting and finishing of ship or vessel.
2. Definitions:
The terms certificate of entry, hot work, naked light certificate, oil, oil tank, tanker, shipyard,
stage and staging have been defined. Oil means any liquid having FP below 132 °C and also
includes lubricating oils, liquid methane, butane and propane.
Certificate of entry and naked light certificate are issued by a competent analyst after
testing the atmosphere in oil tank to allow a person to work.
3 Ladders:
Ship's accommodation ladders or sound gangways (width more than 55 cm. with each side railing
of 90 cm.) of adequate strength and securely fixed should be provided. Rope ladders and
boatswain's chairs, ropes, gears etc. should be of sound material and securely attached.
8. Cleaning of Oil-tanks:
Before a test for flammable vapour is carried out with a view to issue a naked light certificate, the
tank shall be cleaned and ventilated. First volatile oil shall be vaporised, then residual
sludge/deposit shall be removed and thoroughly ventilated by mechanical or effective means to
remove all oil vapour.
10. Others:
1. No young person shall be employed to clean, break , cut or spray asbestos.
2. An experienced supervisor shall be employed in a shipyard for exclusive observance of
these rules.
IS : Safety and health requirements in electric and gas welding and cutting operations 818, ship
geometry glossary 8214, ship building, noise level on board 13161, desk machinery 8650, 12719,
Ships - ventilation and pipeline systems 3733, 9423, 9752, window glossary 11914, ordinary
8886, safety glossary 6640, window positioning 12693, window gaskets 8809, air pipe hood 6636, AC
requirements 8434, 9114, binnacles - 5289, 4045, cabin ventilator 3941, derricks, 4478, 5521, direction
finder 4259, dog-step ladder 8450, doors 4384, electrical installation 10242, eye plates 6203, 6225, fire
appliances 3947, flag staff 7723, conventional signs 6737, hydrodynamic terms, glossary 8214, 5314,
marine engines, boilers and steel castings 2986, mechanical ventilation 5858, piping system 4693, 7304,
propellers 8215, 9126, scupper 5875, 5876, signalling whistle 11608, steel - ladder 6176, structure 2985,
wire reel for inland vessels 4659. .
Shipboard - AC system 8649, 9734, indicator lights 9421, lamps 2592, mechanical ventilation
4881, cables 10242.
Ships - international shore connections 12266, hull, steel plate 5488, structural steel 3039, tools
and outfits guidelines 11160, vibration guidelines 13121.
33 SILK INDUSTRY
Silk is a lustrous, tough, elastic fibre produced by the larvae of silk worms and includes the thread
of cloth made from it Similar synthetic fibre is known as artificial silk. In industrial use the hazards are
similar to those in' the textile industry (see Chapter-21). Shuttle and other guards for looms and good
lighting for spinning and weaving are necessary.
34 SOAP INDUSTRY
Soap is prepared from triglycerides (animal or vegetable oils and fats) by alkaline hydrolysis
(saponification). It is a water soluble salt of carboxylic acid and is extensively used for cleaning, washing
and textile processing. Safety measures include :
1. Guarding of stamping tools and other machinery. Interlocks and limit switches should be
regularly checked.
2. Follow Rule 61, GFR for steam pressure vessels, blow off valve should be used carefully.
3. Prevention of falls by non-slip floor, regular cleaning and good housekeeping.
4. Safe handling of materials and stacking.
5. Rubber gloves, aprons, boots and goggles or face shields to prevent burns from sodium hydroxide,
sodium silicate, cresylic acid, inorganic builders (alkali phosphates, silicates, carbonates etc.) and
organic builders (starch, cellulose ethers and esters).
6. Lagging of hot pipes and colour coding.
7. Good washing facilities, barrier creams and medical check-ups for dermatitis due to oils or rosin.
8. Temperature near boiling pan should be reduced by vessel lagging, exhaust ventilation and proper
roof height. Fencing of vessel and safe platforms are necessary.
Industrial solvents are generally organic liquids like benzene, hexane, xylene, CS,, petrol etc.
They dissolve many substances which may or may not be dissolved in water a fundamental solvent.
Uses of solvents are many, such as surface coatings, paints & thinners, synthetic fibres, to make
the material soft (plastic) for moulding, extrusion or shaping, to extract oil, fats and medicinal material
from seeds, nuts and bones, degreasing, dry-cleaning and for dissolving chemical reagents. It is used
directly as raw material in organic synthesis also.
Fire, explosion and toxicity are its main hazards. Less harmful solvent should be selected as far as
possible. Local exhaust ventilation to keep the material below its LEL, dyke walls to tanks, flame arrester
and cooling system, flameproof electric fitting and equipment, air as well as biological monitoring,
alarms and trips, respirators and other PPE, and work permit to work in confined spaces are necessary
safety measures.
Statutory Provisions:
Summary of Schedule 21, Rule 102, GFR, Sch.21, Rule 114, MFR and Sch.23, Rule 95, TNFR is
given below:
1. Definitions:
Solvent ex traction plan t means a plant where process of extracting oils and fats from vegetable
and animal sources by use of solvents is carried on. Solvent is a flammable liquid such as Pentane,
Hexane, Heptane used for the recovery of vegetable oils.
Competent person is specially defined for this Schedule. He should be (i) B.E. (Mech.) or
B.Tech. with special knowledge of oil and fat with 5 years experience or (ii) a member of
3. Electrical Installations:
They should be of flameproof construction. Metal containers of solvent and non energized
electrical equipment to be properly bonded and earthed.
5. Fire fighting:
Adequate number of portable extinguishers and automatic water sprinklers or open-head deluge
system over the plant are required.
6. Ventilation:
Plant building should have mechanical ventilation providing at least 6 air changes per hour.
7. Venting:
Solvent tanks should have emergency vent to relieve excess pressure in case of fire. Such vents
should open at least 6 mts. above the ground so that vapour should not re-enter the plant.
8. Others:
1. Automatic device to cut off steam and to supply cooling water from overhead tank by
gravity in case of power failure.
2. Magnetic separators on oil cake feeder to remove iron pieces.
3. Flash evaporator to remove solvent from process waste water located 8 mts away" from
the fence but within fenced area.
4. Solvents should not be stored in the plant building. Space of 15 mts within the plant shall
be kept free from combustible material. Spillage shall be cleaned immediately. Daily
removal of oily rags and wastes etc.
5. Trained operators certified by the competent person.
6. Women and young persons prohibited.
7. Vapour monitoring by a combustible gas detector. Sampling locations to be approved by
the CIF. Register is required for record.
8. Examination by the competent person every year. Repairs under the direct supervision of
the competent person.
9. Purging (with inert gas or steam) required before opening for cleaning or repairs or
introducing solvent after repairs.
IS : Solvent - for paints, sampling and test 82, insulating varnishes 10026, petroleum hydrocarbon
1745.
See also Part 5 of Chapter-18 and foregoing Part 20 and 21 of this Chapter.
36 SUGAR INDUSTRY
The growth of sugar factories is very wide and mostly in co-operative sector. Except some small
Khandsari units, generally the sugar mills are large factories running with heavy machinery and big-sized
vessels, employing more than 1000 workers and occupying a bigger area for the mill plant, sugar cane
transport vehicles, sugar godowns, bagasse (crushed fibrous waste) stocks and long conveyor belts,
molasses tanks, solvent extraction plant if provided, residential facilities for mill workers and offices for
other related activities.
The nature of sugar mill machinery pose mostly the mechanical hazards like crush injuries, falls
or slipping from heights, falling into pit or hot sugar juice, hurt by falling bodies or sugar bags, fumes and
gases (SO , HCI, CO, CO,), steam at many places, sugar cane dust (may cause bagassosis), noise and
vibration due to centrifuge machines and vibrating screens, packing machines and large size crushing
gears.
In the process, sugar canes are put on feed (rolling) carrier, pushed ahead by steel beaters and
crushed in two to three sets of heavy rollers. The initial juice contains bagass fibres, clay, grit, albumen,
pectin etc. Bagass fibres cause lung disease known as Bagassosis. The juice is then heated and chemical
agents are added to remove impurities and to get saccharose. After clarification (through heating) the
juice is concentrated in vacuum evaporators till it precipitates in the form of greyish crystals. The
concentrated juice (molasses) contains 45% water. By centrifuging the water is separated and brownish
granulated sugar (brown sugar) is filtered. White sugar is made by refining (Sulpher) process. The filtered
syrup is evaporated in quadruple effect evaporators, vacuum pans and crystallisers till it crystallises.
Centrifugation is again applied to get white crystalline sugar. Vibrating screens are used to separate sugar
crystals in different sizes (grades). It is then weighed, begged and sent to the sugar godowns.
II Clarification Plant:
1. Juice heaters with necessary valves, venting and condensate extraction device with collection
tanks and safety for steam use. Solid drawn brass tubes for heaters with 42 mm ID, 45 mm OD
and total length of tubes not exceeding 4.5 mt
2. Continuous juice sulphitation unit, with lime milk proportioning arrangement, guards on lime
slacker motors, couplings and gear drives and stirres drives. SO 2 absorption tower with safe vent,
effective stirrer, sulphur furnace with cooling water jacket for vertical gas pipes and scrubbers
made of cast iron.
3. Clarifier with flash tank, juice overflow box, scrapper drive, mud overflow box, liquidating pump
etc.
4. Vacuum rotary mud filter with bagacillo sifter, recirculation pump, juice trough, filtrate pumps
and receivers, mud conveyor belt, juice separator, air blower, cyclone separator for vacuum
filters, cake washing hot water pumps and guards for pump couplings and motor drives.
Vacuum pans are calandria of low head rapid boiling type with steam tubes (brass), compound
gauges, thermometers, various pipelines and fittings, connections with crystallisers and multi-jet
condensers, heavy molasses and hot water connection through nonreturn valves, guards on stirrer drives
and gears, the injection water pumps - centrifugal and directly coupled, are all necessary.
Heavy U-type air cooled and water cooled crystallisers are required with stirring arrangement,
guards on stirrer and gear drives and centrifugal machines (15 for 2500 T plant and 20 for 3500 T plant).
Superheated wash water or steam connection, timer controlled automatic brakes, solenoid and pneuma,tic
valves, ploughing speed not exceeding 60 rpm, connection with magma mixtures, guards on magma
mixture drives, guards on pug mill drives, reduction gears and air-compressor drives, steam connections
with NRV for magma and molasses lines, sugar melter, grass hoppers and conveyors, hot and cold air
blowing, sugar elevators and graders (vibrators) with dust catching arrangement, sugar weighing
machines, bag stitching machines, molasses weighing scale and final molasses storage tank (3 to 4) each
of 4000 m" capacity as per IS specification.
Other plants viz. Boiler and steam generating plant. Power generating plant and Miscellaneous
e.g. reducing valves, pipelines, supporting structure, service tanks, water pumps etc. also need due
consideration.
Dust, fume and gas extractors, noise and vibration dampers and medical examination of workers
are also required.
IS : Sugar laboratories 1679, 5527, godown construction 4772, vacuum pan grading 498, filter cloth
1178, inter-carrier chains 9069, sprockets 12198, effluent treatment 4903, crusher 1973, 6983, 6997, juice
hygienic code for sale 8124, stripper 7789.
Sugar confectionery- hard boiled 1008, sampling and analysis 6287, cube 1168.
37 TOBACCO INDUSTRY
1. Guarding of all machinery moving parts, drives, shafting, gearing and cutting knives.
2. Nip guards to conveyors and rollers.
3. Prevention of explosion due to tobacco dust.
4. Local exhaust ventilation to dust sources (respirable tobacco dust is 0.3 to 3.6 mg/m").
5. Good housekeeping and vacuum cleaning.
6. Good sanitary and washing facilities, personal, hygiene, protective clothing, dust masks and
medical supervision.
IS : Tobacco - glossary 10335, analytical test 7753, chewing (zarda) flake 2344, minced 3041,
moisture determination 9379, packaging code 10106, packing seaworthy 4698, paste hookah 14332,
sampling 8600, Virginia seedcake 10670.
38 WOODWORKING INDUSTRY
Woodworking industry includes wood cutting in sawmills, wood preservation and treatment and
making of panels (veneer plywood, chipboard, hardboard), furniture and other products by using
woodworking machines and tools which are mostly dangerous and need strict guarding. The safety
measures include :
For an abstract of Schedule 3, Rule 54, GFR see Part 4.4 of Chapter-14..
Woodwork - fire safety 6329, aluminium paint 3585, Wooden packaging - terminology 6703,
timber 6662, packing cases 1503, 6729, 8358, 4834, 3728, 8725, 8726, 7698.
Industries may be endless, as they are ever increasing with the human needs. A few are stated
above with more than 500 safety measures which give sufficient knowledge to find out safety measures
for other industries also. Chapters' 14,18,20,21 and 22 cover major part of machine guarding and safety
aspects of all mostly used processes and provide a data bank for effective safety inspection of any
industry.
EXERCISE
1. What are the health hazards of pesticides and methods of their control?
2. What are the main health hazards in cement industry? Briefly discuss the safety measures of safe
guarding the health of workers in this industry.
3. State the main hazards which are generally encountered in the storage and handling of solvents in
a petrochemical plant. Give their important preventive and control measures.
4. Explain the statutory provisions on manufacture of:
(1) Asbestos. (2) Benzene. (3) CSz (4) Glass. (5) Flammable liquids and Gases. (6) Rubber. (7)
Pottery. (8) Wood working. (9) Solvent Extraction plant.
5. Explain in details the health and safety measures on Chemical Works OR Hazardous Chemicals
and Processes.
6. Write short notes explaining safety measures :
(1) Types of industries needing attention. (2) Cement industry. (3) Electroplating industry. (4)
Fertiliser industry. (5) Leather industry. (6) Paper industry. (7) Plastics industry. (8) Polymer
plants. (9) Ship breaking industry. (10) Sugar industry. (II) Carcinogenic Dyeintermediates (12)
Tobacco industry.
7. Enumerate safety measures required in -
(1) Food industry. (2) Match factories. (3) Electronics industry. (4) Automobile industry. (5)
Beverage industry. (6) Brick or Tile industry. (7) Clothing industry. (8) Dairy industry. (9)
Petroleum refinery. (10) Ovens & Driers. (11) Soap industry (12) Silk industry.