Safety Data Sheet according to (EC) No 1907/2006

Page 1 of 11
SDS No. : 153486
V003.1
LOCTITE 290 250ML 2/CASE M/L Revision: 11.02.2015
printing date: 05.06.2015
Replaces version from: 13.10.2014

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
LOCTITE 290 250ML 2/CASE M/L

Contains:
Cumene hydroperoxide

1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use:
Adhesive

1.3. Details of the supplier of the safety data sheet

Henkel Limited
2 Bishop Square Business Park
AL109EY Herfordshire Hatfield

Great Britain

Phone: +44 1606 593933

Fax-no.: +44 1606 863762

ua-productsafety.uk@uk.henkel.com

1.4. Emergency telephone number

24 Hours Emergency Tel: +44 (0)1442 278497

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (CLP):
Serious eye irritation Category 2
H319 Causes serious eye irritation.
Specific target organ toxicity - single exposure Category 3
H335 May cause respiratory irritation.
Target organ: respiratory tract irritation

Classification (DPD):
Xn - Harmful
R20 Harmful by inhalation.
Xi - Irritant
R36/37 Irritating to eyes and respiratory system.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

2.2. Label elements

Label elements (CLP):

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Hazard pictogram:

Signal word: Warning

Hazard statement: H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

Precautionary statement: ***For consumer use only: P101 If medical advice is needed, have product container or
label at hand. P102 Keep out of reach of children. P501 Dispose of waste and residues in
accordance with local authority requirements***

Precautionary statement: P261 Avoid breathing vapours.

Prevention

Precautionary statement: P337+P313 If eye irritation persists: Get medical advice/attention.

Response

Label elements (DPD):

Xn - Harmful

Risk phrases:
R20 Harmful by inhalation.
R36/37 Irritating to eyes and respiratory system.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Safety phrases:
S23 Do not breathe vapour.
S25 Avoid contact with eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S51 Use only in well-ventilated areas.
S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.

Additional labeling:
For consumer use only: S2 Keep out of the reach of children.
S46 If swallowed, seek medical advice immediately and show this container or label.

Contains:
Cumene hydroperoxide

2.3. Other hazards

None if used properly.
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SECTION 3: Composition/information on ingredients

3.2. Mixtures

General chemical description:

Anaerobic Sealant

Declaration of the ingredients according to CLP (EC) No 1272/2008:

Hazardous components EC Number content Classification

CAS-No. REACH-Reg No.
Cumene hydroperoxide 201-254-7 1- < 2,5 % Acute toxicity 4; Dermal
80-15-9 H312
Specific target organ toxicity - repeated
exposure 2
H373
Acute toxicity 4; Oral
H302
Organic peroxides E
H242
Acute toxicity 3; Inhalation
H331
Skin corrosion 1B
H314
Chronic hazards to the aquatic environment 2
H411

N,N-Diethyl-p-toluidine 210-345-0 0,1- < 1 % Acute toxicity 3; Oral

613-48-9 H301
Acute toxicity 3; Dermal
H311
Acute toxicity 3; Inhalation
H331
Specific target organ toxicity - repeated
exposure 2
H373
Chronic hazards to the aquatic environment 3
H412

N,N-dimethyl-o-toluidine 210-199-8 0,1- < 0,3 % Specific target organ toxicity - repeated
609-72-3 exposure 2
H373
Chronic hazards to the aquatic environment 3
H412
Acute toxicity 3; Inhalation
H331
Acute toxicity 3; Dermal
H311
Acute toxicity 3; Oral
H301

1,4-Naphthalenedione 204-977-6 0,01- < 0,1 % Acute toxicity 3; Oral

130-15-4 H301
Skin irritation 2; Dermal
H315
Skin sensitizer 1; Dermal
H317
Serious eye irritation 2
H319
Acute toxicity 1; Inhalation
H330
Specific target organ toxicity - single
exposure 3; Inhalation
H335
Acute hazards to the aquatic environment 1
H400
Chronic hazards to the aquatic environment 1
H410
M factor: 10

For full text of the H - statements and other abbreviations see section 16 "Other information".
Substances without classification may have community workplace exposure limits available.
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Declaration of ingredients according to DPD (EC) No 1999/45:

Hazardous components EC Number content Classification

CAS-No. REACH-Reg No.
Cumene hydroperoxide 201-254-7 1 - < 2,5 % T - Toxic; R23
80-15-9 Xn - Harmful; R21/22, R48/20/22
C - Corrosive; R34
O - Oxidizing; R7
N - Dangerous for the environment; R51/53
N,N-Diethyl-p-toluidine 210-345-0 0,1 - < 1 % T - Toxic; R23/24/25
613-48-9 R33
R52/53
Cumene 202-704-5 0,1 - < 1 % R10
98-82-8 Xn - Harmful; R65
Xi - Irritant; R37
N - Dangerous for the environment; R51/53
N,N-dimethyl-o-toluidine 210-199-8 0,1 - < 0,3 % T - Toxic; R23/24/25
609-72-3 R33
R52/53
1,4-Naphthalenedione 204-977-6 0,01 - < 0,1 % T+ - Very toxic; R25, R26
130-15-4 Xi - Irritant; R36/37/38, R43
N - Dangerous for the environment; R50/53

For full text of the R-Phrases indicated by codes see section 16 'Other Information'.
Substances without classification may have community workplace exposure limits available.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:
Move to fresh air. If symptoms persist, seek medical advice.

Skin contact:
Rinse with running water and soap.
Obtain medical attention if irritation persists.

Eye contact:
Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist.

Ingestion:
Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed
EYE: Irritation, conjunctivitis.

RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness.

4.3. Indication of any immediate medical attention and special treatment needed
See section: Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media:
Carbon dioxide, foam, powder

Extinguishing media which must not be used for safety reasons:

None known

5.2. Special hazards arising from the substance or mixture

In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released.
5.3. Advice for firefighters
Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.
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Additional information:
In case of fire, keep containers cool with water spray.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Avoid skin and eye contact.
Ensure adequate ventilation.

6.2. Environmental precautions

Do not let product enter drains.

6.3. Methods and material for containment and cleaning up

For small spills wipe up with paper towel and place in container for disposal.
For large spills absorb onto inert absorbent material and place in sealed container for disposal.

6.4. Reference to other sections

See advice in section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Use only in well-ventilated areas.
Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation.

Hygiene measures:
Good industrial hygiene practices should be observed.
Wash hands before work breaks and after finishing work.
Do not eat, drink or smoke while working.

7.2. Conditions for safe storage, including any incompatibilities

Ensure good ventilation/extraction.
Store in original containers at 8-21°C (46.4-69.8°F) and do not return residual materials to containers as contamination may
reduce the shelf life of the bulk product.

7.3. Specific end use(s)

Adhesive

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational Exposure Limits

Valid for
Great Britain

Ingredient ppm mg/m3 Type Category Remarks

CUMENE 50 250 Short Term Exposure EH40 WEL
98-82-8 Limit (STEL):
CUMENE Skin designation: Can be absorbed through the EH40 WEL
98-82-8 skin.
CUMENE 25 125 Time Weighted Average EH40 WEL
98-82-8 (TWA):
CUMENE 50 250 Short Term Exposure Indicative ECTLV
98-82-8 Limit (STEL):
CUMENE 20 100 Time Weighted Average Indicative ECTLV
98-82-8 (TWA):
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Biological Exposure Indices:

None

8.2. Exposure controls:

Respiratory protection:
Ensure adequate ventilation.
An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly
ventilated area
Filter type: A

Hand protection:
Chemical-resistant protective gloves (EN 374).
Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30
minutes permeation time as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation
time as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
This information is based on literature references and on information provided by glove manufacturers, or is derived by
analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be
considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing
factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced.

Eye protection:
Wear protective glasses.

Skin protection:
Wear suitable protective clothing.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance liquid
green
Odor mild
Odour threshold No data available / Not applicable

pH not applicable
Initial boiling point > 150 °C (> 302 °F)
Flash point > 93,3 °C (> 199.94 °F); Tagliabue closed cup
Decomposition temperature No data available / Not applicable
Vapour pressure < 5 mm hg
(27 °C (80.6 °F))
Vapour pressure < 300 mbar
(50 °C (122 °F))
Density 1,07 g/cm3
()
Bulk density No data available / Not applicable
Viscosity No data available / Not applicable
Viscosity (kinematic) No data available / Not applicable
Explosive properties No data available / Not applicable
Solubility (qualitative) Slight
(Solvent: Water)
Solubility (qualitative) Miscible
(Solvent: Acetone)
Solidification temperature No data available / Not applicable
Melting point No data available / Not applicable
Flammability No data available / Not applicable
Auto-ignition temperature No data available / Not applicable
Explosive limits No data available / Not applicable
Partition coefficient: n-octanol/water No data available / Not applicable
Evaporation rate Not available.
Vapor density Not available.
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Oxidising properties No data available / Not applicable

9.2. Other information

No data available / Not applicable

SECTION 10: Stability and reactivity

10.1. Reactivity
Reaction with strong acids.
Reacts with strong oxidants.

10.2. Chemical stability

Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

See section reactivity

10.4. Conditions to avoid

No decomposition if used according to specifications.

10.5. Incompatible materials

See section reactivity

10.6. Hazardous decomposition products

Irritating organic vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

General toxicological information:

The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria
for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available
health/ecological information for the substances listed under Section 3 is provided in the following.

STOT-single exposure:
May cause respiratory irritation.
Oral toxicity:
This material is considered to have low toxicity if swallowed.

Skin irritation:
Although it is not a common sensitizer there may be a risk of sensitization on prolonged or repeated contact with damaged
skin

Eye irritation:
Causes serious eye irritation.

Acute oral toxicity:

Hazardous components Value Value Route of Exposure Species Method

CAS-No. type application time
Cumene hydroperoxide LD50 550 mg/kg oral rat
80-15-9

Skin corrosion/irritation:

Hazardous components Result Exposure Species Method

CAS-No. time
Cumene hydroperoxide corrosive rabbit Draize Test
80-15-9
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Germ cell mutagenicity:

Hazardous components Result Type of study / Metabolic Species Method

CAS-No. Route of activation /
administration Exposure time
Cumene hydroperoxide positive bacterial reverse without OECD Guideline 471
80-15-9 mutation assay (e.g (Bacterial Reverse Mutation
Ames test) Assay)
Cumene hydroperoxide negative dermal mouse
80-15-9

Repeated dose toxicity

Hazardous components Result Route of Exposure time / Species Method

CAS-No. application Frequency of
treatment
Cumene hydroperoxide inhalation: 6 h/d5 d/w rat
80-15-9 aerosol

SECTION 12: Ecological information

General ecological information:
The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria
for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available
health/ecological information for the substances listed under Section 3 is provided in the following.
Cured Loctite products are typical polymers and do not pose any immediate environmental hazards.

12.1. Toxicity

Ecotoxicity:
Do not empty into drains / surface water / ground water.

Hazardous components Value Value Acute Exposure Species Method

CAS-No. type Toxicity time
Study
Cumene hydroperoxide LC50 3,9 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline
80-15-9 203 (Fish, Acute
Toxicity Test)
Cumene hydroperoxide EC50 18 mg/l Daphnia 48 h Daphnia magna OECD Guideline
80-15-9 202 (Daphnia sp.
Acute
Immobilisation
Test)
Cumene hydroperoxide ErC50 3,1 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline
80-15-9 201 (Alga, Growth
Inhibition Test)
1,4-Naphthalenedione EC50 0,011 mg/l Algae 72 h Dunaliella bioculata OECD Guideline
130-15-4 201 (Alga, Growth
Inhibition Test)

12.2. Persistence and degradability

Persistence and Biodegradability:

The product is not biodegradable.

Hazardous components Result Route of Degradability Method

CAS-No. application
Cumene hydroperoxide no data 0% OECD Guideline 301 B (Ready
80-15-9 Biodegradability: CO2 Evolution
Test)
1,4-Naphthalenedione no data 0 - 60 % OECD 301 A - F
130-15-4

12.3. Bioaccumulative potential / 12.4. Mobility in soil

Mobility:
Cured adhesives are immobile.
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Bioaccumulative potential:
No data available.

Hazardous components LogKow Bioconcentration Exposure Species Temperature Method

CAS-No. factor (BCF) time
Cumene hydroperoxide 9,1 calculation OECD Guideline 305
80-15-9 (Bioconcentration: Flow-
through Fish Test)
Cumene hydroperoxide 2,16
80-15-9
1,4-Naphthalenedione 1,71
130-15-4

12.5. Results of PBT and vPvB assessment

No data available.

12.6. Other adverse effects

No data available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product disposal:
Dispose of in accordance with local and national regulations.

Disposal of uncleaned packages:

After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in
an authorised legal land fill site or incinerated.

Waste code
08 04 09 waste adhesives and sealants containing organic solvents and other dangerous substances
The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes
for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We
will be happy to advise you.
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SECTION 14: Transport information

14.1. UN number

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.2. UN proper shipping name

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.3. Transport hazard class(es)

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.4. Packaging group

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.5. Environmental hazards

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.6. Special precautions for user

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
VOC content <3%
(1999/13/EC)

15.2. Chemical safety assessment

A chemical safety assessment has not been carried out.
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SECTION 16: Other information

The labelling of the product is indicated in Section 2. The full text
of all abbreviations indicated by codes in this safety data sheet are as follows:
R10 Flammable.
R21/22 Harmful in contact with skin and if swallowed.
R23 Toxic by inhalation.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R25 Toxic if swallowed.
R26 Very toxic by inhalation.
R33 Danger of cumulative effects.
R34 Causes burns.
R36/37/38 Irritating to eyes, respiratory system and skin.
R37 Irritating to respiratory system.
R43 May cause sensitisation by skin contact.
R48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R7 May cause fire.
H242 Heating may cause a fire.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Further information:
This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety requirements and is not intended to guarantee any
particular properties.

Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document.
Corresponding text is displayed in a different color on shadowed fields.