SAFETY DATA SHEET
1. Identification
Product identifier                 DEVCON® Plastic Steel® Putty (A) Resin
Other means of identification
    SKU#                           0100
Recommended use                    Not available.
Recommended restrictions           None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
  Company name                     ITW Performance Polymers
  Address                          30 Endicott Street
                                   Danvers, MA 01923
                                   United States
  Telephone                        Customer Service         978-777-1100
  Website                          www.itwperformancepolymers.com
  E-mail                           Not available.
  Contact person                   EHS Department
Emergency phone number             Chemtrec                 800-424-9300
                                   International            703-527-3887
2. Hazard(s) identification
Physical hazards                   Not classified.
Health hazards                     Skin corrosion/irritation                       Category 2
                                   Serious eye damage/eye irritation               Category 2A
                                   Sensitization, skin                             Category 1
                                   Specific target organ toxicity, single exposure Category 3 narcotic effects
Environmental hazards              Not classified.
OSHA defined hazards               Not classified.
Label elements
    Signal word                    Warning
    Hazard statement               Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May
                                   cause drowsiness or dizziness.
    Precautionary statement
        Prevention                 Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Use only
                                   outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the
                                   workplace. Wear eye protection/face protection. Wear protective gloves.
        Response                   If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable
                                   for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,
                                   if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If skin
                                   irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical
                                   advice/attention. Take off contaminated clothing and wash it before reuse.
        Storage                    Store in a well-ventilated place. Keep container tightly closed. Store locked up.
        Disposal                   Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise            None known.
classified (HNOC)
Supplemental information           None.
Material name: DEVCON® Plastic Steel® Putty (A) Resin                                                                            SDS US
0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019                                                                  1/7
3. Composition/information on ingredients
Mixtures
  Chemical name                        Common name and synonyms                              CAS number                        %
  Ferrosilicon, [with >= 30% But <=                                                            8049-17-0                    60 - 80
  70% Silicon]
  Epoxy Resin:--reaction Product Of    EPOXY RESIN                                            25068-38-6                    10 - 30
  Bisphenol A And Epichlorohydrin
  (refer To Epichlorohydrin)
  Fiberglass Fibers                                                                           65997-17-3                     0.1 - 1
  Other components below reportable levels                                                                                  2.5 - 10
4. First-aid measures
Inhalation                         Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
                                   center or doctor/physician if you feel unwell.
Skin contact                       Remove contaminated clothing immediately and wash skin with soap and water. In case of
                                   eczema or other skin disorders: Seek medical attention and take along these instructions. Wash
                                   contaminated clothing before reuse.
Eye contact                        Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
                                   present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion                          Rinse mouth. Get medical attention if symptoms occur.
Most important                     May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
symptoms/effects, acute and        Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
delayed                            cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Indication of immediate            Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special      Symptoms may be delayed.
treatment needed
General information                Ensure that medical personnel are aware of the material(s) involved, and take precautions to
                                   protect themselves. Wash contaminated clothing before reuse.
5. Fire-fighting measures
Suitable extinguishing media       Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing           Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from      During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment       Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting                      Move containers from fire area if you can do so without risk.
equipment/instructions
Specific methods                   Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards               No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,              Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and           appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
emergency procedures               or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
                                   Local authorities should be advised if significant spillages cannot be contained. For personal
                                   protection, see section 8 of the SDS.
Methods and materials for          Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
containment and cleaning up        possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
                                   recovery, flush area with water.
                                   Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
                                   remove residual contamination.
                                   Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions          Avoid discharge into drains, water courses or onto the ground.
Material name: DEVCON® Plastic Steel® Putty (A) Resin                                                                                  SDS US
0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019                                                                     2/7
7. Handling and storage
Precautions for safe handling       Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing.
                                    Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good
                                    industrial hygiene practices.
Conditions for safe storage,        Store locked up. Store in tightly closed container. Store away from incompatible materials (see
including any incompatibilities     Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
   The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
   At this time, the other constituents have no known exposure limits.
     US. NIOSH: Pocket Guide to Chemical Hazards
     Components                             Type                                          Value                 Form
     Fiberglass Fibers (CAS                          TWA                                  3 fibers/cm3          Fiber.
     65997-17-3)
                                                                                          3 fibers/cm3          Fibrous dust.
                                                                                          5 mg/m3               Fiber, total
                                                                                          5 mg/m3               fibers, total dust
Biological limit values             No biological exposure limits noted for the ingredient(s).
Exposure guidelines                 Occupational Exposure Limits are not relevant to the current physical form of the product.
Appropriate engineering             Good general ventilation should be used. Ventilation rates should be matched to conditions. If
controls                            applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
                                    maintain airborne levels below recommended exposure limits. If exposure limits have not been
                                    established, maintain airborne levels to an acceptable level. Provide eyewash station and safety
                                    shower.
Individual protection measures, such as personal protective equipment
    Eye/face protection          Wear safety glasses with side shields (or goggles).
     Skin protection
         Hand protection            Wear appropriate chemical resistant gloves.
         Other                      Wear appropriate chemical resistant clothing.
     Respiratory protection         In case of insufficient ventilation, wear suitable respiratory equipment.
     Thermal hazards                Wear appropriate thermal protective clothing, when necessary.
General hygiene                     Always observe good personal hygiene measures, such as washing after handling the material
considerations                      and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
                                    equipment to remove contaminants. Contaminated work clothing should not be allowed out of the
                                    workplace.
9. Physical and chemical properties
Appearance                          Paste.
     Physical state                 Not available.
     Form                           Paste.
     Color                          Dark grey
Odor                                Slight.
Odor threshold                      Not available.
pH                                  Not available.
Melting point/freezing point        Not available.
Initial boiling point and boiling   608 °F (320 °C) estimated
range
Flash point                         > 399.2 °F (> 204.0 °C) Pensky-Martens Closed Cup
Evaporation rate                    Not available.
Flammability (solid, gas)           Not available.
Upper/lower flammability or explosive limits
   Flammability limit - lower    Not available.
   (%)
Material name: DEVCON® Plastic Steel® Putty (A) Resin                                                                                SDS US
0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019                                                                   3/7
    Flammability limit - upper      Not available.
    (%)
    Explosive limit - lower (%)     Not available.
    Explosive limit - upper (%)     Not available.
Vapor pressure                      Not available.
Vapor density                       Not available.
Relative density                    Not available.
Solubility(ies)
    Solubility (water)              Not available.
Partition coefficient               Not available.
(n-octanol/water)
Auto-ignition temperature           Not available.
Decomposition temperature           Not available.
Viscosity                           Not available.
Other information
    Density                         2.80 g/cm3
    Explosive properties            Not explosive.
    Flammability class              Combustible IIIB estimated
    Oxidizing properties            Not oxidizing.
    Specific gravity                2.8
10. Stability and reactivity
Reactivity                          The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability                  Material is stable under normal conditions.
Possibility of hazardous            No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid                 Contact with incompatible materials.
Incompatible materials              Strong oxidizing agents.
Hazardous decomposition             No hazardous decomposition products are known.
products
11. Toxicological information
Information on likely routes of exposure
    Inhalation                    May cause drowsiness and dizziness. Headache. Nausea, vomiting.
    Skin contact                    Causes skin irritation. May cause an allergic skin reaction.
    Eye contact                     Causes serious eye irritation.
    Ingestion                       Knowledge about health hazard is incomplete.
Symptoms related to the             May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
physical, chemical and              Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
toxicological characteristics       cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Information on toxicological effects
Acute toxicity                      Not known.
Skin corrosion/irritation           Causes skin irritation.
Serious eye damage/eye              Causes serious eye irritation.
irritation
Respiratory or skin sensitization
   Respiratory sensitization      Due to partial or complete lack of data the classification is not possible.
    Skin sensitization              May cause an allergic skin reaction.
Germ cell mutagenicity              Due to partial or complete lack of data the classification is not possible.
Carcinogenicity                     Due to partial or complete lack of data the classification is not possible.
    IARC Monographs. Overall Evaluation of Carcinogenicity
       Not listed.
Material name: DEVCON® Plastic Steel® Putty (A) Resin                                                                            SDS US
0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019                                                                 4/7
   OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
       Not listed.
   US. National Toxicology Program (NTP) Report on Carcinogens
       Not listed.
Reproductive toxicity          Due to partial or complete lack of data the classification is not possible.
Specific target organ toxicity -   May cause drowsiness and dizziness.
single exposure
Specific target organ toxicity -   Due to partial or complete lack of data the classification is not possible.
repeated exposure
Aspiration hazard                  Due to partial or complete lack of data the classification is not possible.
12. Ecological information
Ecotoxicity                        The product is not classified as environmentally hazardous. However, this does not exclude the
                                   possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability      No data is available on the degradability of any ingredients in the mixture.
Bioaccumulative potential
Mobility in soil                   No data available.
Other adverse effects              No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
                                   potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions              Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
                                   contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations         Dispose in accordance with all applicable regulations.
Hazardous waste code               The waste code should be assigned in discussion between the user, the producer and the waste
                                   disposal company.
Waste from residues / unused       Dispose of in accordance with local regulations. Empty containers or liners may retain some
products                           product residues. This material and its container must be disposed of in a safe manner (see:
                                   Disposal instructions).
Contaminated packaging             Since emptied containers may retain product residue, follow label warnings even after container is
                                   emptied. Empty containers should be taken to an approved waste handling site for recycling or
                                   disposal.
14. Transport information
DOT
   Not regulated as dangerous goods.
IATA
    Not regulated as dangerous goods.
IMDG
     Not regulated as dangerous goods.
Transport in bulk according to Not established. Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
US federal regulations             This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
                                   Standard, 29 CFR 1910.1200.
    Toxic Substances Control Act (TSCA)
         TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
            Not regulated.
    CERCLA Hazardous Substance List (40 CFR 302.4)
       Not listed.
    SARA 304 Emergency release notification
       Not regulated.
    OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
       Not listed.
Material name: DEVCON® Plastic Steel® Putty (A) Resin                                                                             SDS US
0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019                                                                5/7
Superfund Amendments and Reauthorization Act of 1986 (SARA)
   SARA 302 Extremely hazardous substance
       Not listed.
    SARA 311/312 Hazardous             Yes
    chemical
         Classified hazard             Skin corrosion or irritation
         categories                    Serious eye damage or eye irritation
                                       Respiratory or skin sensitization
                                       Specific target organ toxicity (single or repeated exposure)
    SARA 313 (TRI reporting)
       Not regulated.
Other federal regulations
    Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
        Not regulated.
    Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
        Not regulated.
    Safe Drinking Water Act      Not regulated.
    (SDWA)
US state regulations
    California Proposition 65
                 WARNING: This product can expose you to chemicals including Benzene, which is known to the State of
                              California to cause cancer and birth defects or other reproductive harm. For more information go
                              to www.P65Warnings.ca.gov.
         California Proposition 65 - CRT: Listed date/Carcinogenic substance
             Benzene (CAS 71-43-2)                              Listed: February 27, 1987
         California Proposition 65 - CRT: Listed date/Developmental toxin
             Benzene (CAS 71-43-2)                              Listed: December 26, 1997
             Toluene (CAS 108-88-3)                             Listed: January 1, 1991
         California Proposition 65 - CRT: Listed date/Male reproductive toxin
             Benzene (CAS 71-43-2)                              Listed: December 26, 1997
         US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
         subd. (a))
             Fiberglass Fibers (CAS 65997-17-3)
International Inventories
    Country(s) or region               Inventory name                                                                     On inventory (yes/no)*
    Australia                          Australian Inventory of Chemical Substances (AICS)                                                    No
    Canada                             Domestic Substances List (DSL)                                                                            Yes
    Canada                             Non-Domestic Substances List (NDSL)                                                                        No
    China                              Inventory of Existing Chemical Substances in China (IECSC)                                                 No
    Europe                             European Inventory of Existing Commercial Chemical                                                         No
                                       Substances (EINECS)
    Europe                             European List of Notified Chemical Substances (ELINCS)                                                     No
    Japan                              Inventory of Existing and New Chemical Substances (ENCS)                                                   No
    Korea                              Existing Chemicals List (ECL)                                                                              No
    New Zealand                        New Zealand Inventory                                                                                     Yes
    Philippines                        Philippine Inventory of Chemicals and Chemical Substances                                                 Yes
                                       (PICCS)
    Taiwan                             Taiwan Chemical Substance Inventory (TCSI)                                                                Yes
    United States & Puerto Rico        Toxic Substances Control Act (TSCA) Inventory                                                             Yes
    *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
    A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
    country(s).
16. Other information, including date of preparation or last revision
Issue date                             04-01-2019
Revision date                          05-01-2020
Material name: DEVCON® Plastic Steel® Putty (A) Resin                                                                                          SDS US
0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019                                                                             6/7
Version #                          02
HMIS® ratings                      Health: 2
                                   Flammability: 1
                                   Physical hazard: 0
NFPA ratings                       Health: 2
                                   Flammability: 1
                                   Instability: 0
Disclaimer                         ITW Performance Polymers cannot anticipate all conditions under which this information and its
                                   product, or the products of other manufacturers in combination with its product, may be used. It is
                                   the user’s responsibility to ensure safe conditions for handling, storage and disposal of the
                                   product, and to assume liability for loss, injury, damage or expense due to improper use. The
                                   information provided in this Safety Data Sheet is correct to the best of our knowledge, information
                                   and belief at the date of its publication. The information relates only to the specific material
                                   designated and may not be valid for such material used in combination with any other materials or
                                   in any process, unless specified in the text. The information given is designed only as a guidance
                                   for safe handling, use, processing, storage, transportation, disposal and release.
Revision information               This document has undergone significant changes and should be reviewed in its entirety.
Material name: DEVCON® Plastic Steel® Putty (A) Resin                                                                           SDS US
0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019                                                              7/7
                                            SAFETY DATA SHEET
1. Identification
Product identifier                Putty Hardener
Other means of identification
    SKU#                          0200C
Recommended use                   Not available.
Recommended restrictions          None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
  Company name                    ITW Performance Polymers
  Address                         30 Endicott Street
                                  Danvers, MA 01923
                                  United States
  Telephone                       Customer Service         978-777-1100
  Website                         www.itwperformancepolymers.com
  E-mail                          Not available.
  Contact person                  EHS Department
Emergency phone number            Chemtrec                 800-424-9300
                                  International            703-527-3887
2. Hazard(s) identification
Physical hazards                  Not classified.
Health hazards                    Acute toxicity, oral                             Category 4
                                  Acute toxicity, dermal                           Category 4
                                  Skin corrosion/irritation                        Category 2
                                  Serious eye damage/eye irritation                Category 1
                                  Sensitization, skin                              Category 1
Environmental hazards             Not classified.
OSHA defined hazards              Not classified.
Label elements
    Signal word                   Danger
    Hazard statement              Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. May cause an allergic
                                  skin reaction. Causes serious eye damage.
    Precautionary statement
        Prevention                Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Do not eat,
                                  drink or smoke when using this product. Contaminated work clothing must not be allowed out of
                                  the workplace. Wear eye protection/face protection. Wear protective gloves/protective clothing.
        Response                  If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If on skin: Wash with
                                  plenty of water. If in eyes: Rinse cautiously with water for several minutes. Remove contact
                                  lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If skin
                                  irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it
                                  before reuse.
        Storage                   Store away from incompatible materials.
        Disposal                  Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise           None known.
classified (HNOC)
Supplemental information          None.
Material name: Putty Hardener                                                                                                     SDS US
0200C Version #: 05 Revision date: 01-12-2021   Issue date: 07-03-2019                                                             1/8
3. Composition/information on ingredients
Mixtures
  Chemical name                        Common name and synonyms                             CAS number                        %
  Aliphatic Amines                                                                               N/A                       40 - 60
  Benzyl Alcohol                                                                              100-51-6                     20 - 40
  TRIETHYLENETETRAMINE                 TETA                                                   112-24-3                     20 - 40
  Silicon Dioxide                      Silica, amorphous, fumed, cryst.-free                112945-52-5                    2.5 - 10
  Titanium Dioxide                   TITANIUM DIOXIDE                                        13463-67-7                    0.1 - 1
  Other components below reportable levels                                                                                 0.1 - 1
4. First-aid measures
Inhalation                         Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact                       Remove contaminated clothing immediately and wash skin with soap and water. Get medical
                                   advice/attention if you feel unwell. In case of eczema or other skin disorders: Seek medical
                                   attention and take along these instructions. Wash contaminated clothing before reuse.
Eye contact                        Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
                                   present and easy to do. Continue rinsing. Get medical attention immediately.
Ingestion                          Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
                                   Get medical advice/attention if you feel unwell.
Most important                     Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
symptoms/effects, acute and        vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness
delayed                            and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Indication of immediate            Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim
medical attention and special      under observation. Symptoms may be delayed.
treatment needed
General information                Ensure that medical personnel are aware of the material(s) involved, and take precautions to
                                   protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated
                                   clothing before reuse.
5. Fire-fighting measures
Suitable extinguishing media       Water spray. Alcohol resistant foam. Powder. Carbon dioxide (CO2).
Unsuitable extinguishing           Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from      During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment       Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting                      Use water spray to cool unopened containers.
equipment/instructions
Specific methods                   Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards               No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,              Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and           appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
emergency procedures               or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
                                   Local authorities should be advised if significant spillages cannot be contained. For personal
                                   protection, see section 8 of the SDS.
Methods and materials for          Large Spills: Stop the flow of material, if this is without risk. Following product recovery, flush area
containment and cleaning up        with water.
                                   Small Spills: Clean surface thoroughly to remove residual contamination.
                                   Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions          Avoid discharge into drains, water courses or onto the ground.
Material name: Putty Hardener                                                                                                         SDS US
0200C Version #: 05 Revision date: 01-12-2021   Issue date: 07-03-2019                                                                 2/8
7. Handling and storage
Precautions for safe handling      Do not get this material in contact with eyes. Do not taste or swallow. Avoid breathing
                                   dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. When using, do not
                                   eat, drink or smoke. Provide adequate ventilation. Wear appropriate personal protective
                                   equipment. Wash hands thoroughly after handling. Wash contaminated clothing before reuse.
                                   Observe good industrial hygiene practices.
Conditions for safe storage,       Store in tightly closed container. Store away from incompatible materials (see Section 10 of the
including any incompatibilities    SDS).
8. Exposure controls/personal protection
Occupational exposure limits
   The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
   At this time, the other constituents have no known exposure limits.
    US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
    Components                               Type                                        Value             Form
    Titanium Dioxide (CAS                         PEL                                    15 mg/m3          Total dust.
    13463-67-7)
    US. OSHA Table Z-3 (29 CFR 1910.1000)
    Components                                    Type                                   Value             Form
    Silicon Dioxide (CAS                          TWA                                    0.8 mg/m3
    112945-52-5)
                                                                                         20 mppcf
    Titanium Dioxide (CAS                         TWA                                    5 mg/m3           Respirable fraction.
    13463-67-7)
                                                                                         15 mg/m3          Total dust.
                                                                                         50 mppcf          Total dust.
                                                                                         15 mppcf          Respirable fraction.
    US. ACGIH Threshold Limit Values
    Components                                    Type                                   Value
    Titanium Dioxide (CAS                         TWA                                    10 mg/m3
    13463-67-7)
    US. NIOSH: Pocket Guide to Chemical Hazards
    Components                              Type                                         Value
    Silicon Dioxide (CAS                          TWA                                    6 mg/m3
    112945-52-5)
    US. Workplace Environmental Exposure Level (WEEL) Guides
    Components                             Type                                          Value
    Benzyl Alcohol (CAS                           TWA                                    44.2 mg/m3
    100-51-6)
                                                                                         10 ppm
    TRIETHYLENETETRAMIN                           TWA                                    6 mg/m3
    E (CAS 112-24-3)
                                                                                         1 ppm
Biological limit values            No biological exposure limits noted for the ingredient(s).
Exposure guidelines                Occupational Exposure Limits are not relevant to the current physical form of the product.
    US WEEL Guides: Skin designation
         TRIETHYLENETETRAMINE (CAS 112-24-3)                  Can be absorbed through the skin.
Appropriate engineering       Good general ventilation should be used. Ventilation rates should be matched to conditions. If
controls                      applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
                              maintain airborne levels below recommended exposure limits. If exposure limits have not been
                              established, maintain airborne levels to an acceptable level. Provide eyewash station and safety
                              shower.
Individual protection measures, such as personal protective equipment
    Eye/face protection          Wear safety glasses with side shields (or goggles) and a face shield. Face shield is
                                 recommended.
Material name: Putty Hardener                                                                                                     SDS US
0200C Version #: 05 Revision date: 01-12-2021   Issue date: 07-03-2019                                                             3/8
     Skin protection
         Hand protection            Wear appropriate chemical resistant gloves.
         Other                      Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
     Respiratory protection         In case of insufficient ventilation, wear suitable respiratory equipment.
     Thermal hazards                Wear appropriate thermal protective clothing, when necessary.
General hygiene                     Keep away from food and drink. Always observe good personal hygiene measures, such as
considerations                      washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
                                    work clothing and protective equipment to remove contaminants. Contaminated work clothing
                                    should not be allowed out of the workplace.
9. Physical and chemical properties
Appearance                          Paste.
     Physical state                 Solid.
     Form                           Paste.
     Color                          White
Odor                                Ammoniacal.
Odor threshold                      Not available.
pH                                  Not available.
Melting point/freezing point        4.64 °F (-15.2 °C) estimated
Initial boiling point and boiling   420.8 °F (216 °C) estimated
range
Flash point                         > 199.9 °F (> 93.3 °C)
Evaporation rate                    Not available.
Flammability (solid, gas)           Not available.
Upper/lower flammability or explosive limits
   Flammability limit - lower    Not available.
   (%)
     Flammability limit - upper     Not available.
     (%)
     Explosive limit - lower (%)    Not available.
     Explosive limit - upper (%)    Not available.
Vapor pressure                      5.73 hPa estimated
Vapor density                       Not available.
Relative density                    Not available.
Solubility(ies)
    Solubility (water)              Not available.
Partition coefficient               Not available.
(n-octanol/water)
Auto-ignition temperature           640 °F (337.78 °C) estimated
Decomposition temperature           Not available.
Viscosity                           Not available.
Other information
    Density                         1.00 g/cm3 estimated
     Explosive properties           Not explosive.
     Oxidizing properties           Not oxidizing.
     Specific gravity               1 estimated
10. Stability and reactivity
Reactivity                          The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability                  Material is stable under normal conditions.
Possibility of hazardous            No dangerous reaction known under conditions of normal use.
reactions
Material name: Putty Hardener                                                                                                   SDS US
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Conditions to avoid                 Avoid temperatures exceeding the decomposition temperature. Avoid temperatures exceeding the
                                    flash point. Contact with incompatible materials.
Incompatible materials              Peroxides. Phenols.
Hazardous decomposition             No hazardous decomposition products are known.
products
11. Toxicological information
Information on likely routes of exposure
    Inhalation                    No adverse effects due to inhalation are expected.
    Skin contact                    Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction.
    Eye contact                     Causes serious eye damage.
    Ingestion                       Harmful if swallowed.
Symptoms related to the             Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
physical, chemical and              vision. Permanent eye damage including blindness could result. Skin irritation. May cause
toxicological characteristics       redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Information on toxicological effects
Acute toxicity                      Harmful in contact with skin. Harmful if swallowed.
Components                             Species                                              Test Results
Benzyl Alcohol (CAS 100-51-6)
         Acute
         Dermal
         LD50                          Rabbit                                               2000 mg/kg
         Inhalation
         LC50                          Rat                                                  1000 mg/l, 8 Hours
         Oral
         LD50                          Rat                                                  1230 - 3100 mg/kg
Silicon Dioxide (CAS 112945-52-5)
         Acute
         Oral
         LD50                          Rat                                                  > 22500 mg/kg
TRIETHYLENETETRAMINE (CAS 112-24-3)
         Acute
         Dermal
         Liquid
         LD50                          Rat                                                  1465 mg/kg
         Oral
         Liquid
         LD50                          Rat                                                  1716 mg/kg
Skin corrosion/irritation           Causes skin irritation.
Serious eye damage/eye              Causes serious eye damage.
irritation
Respiratory or skin sensitization
   Respiratory sensitization      Not a respiratory sensitizer.
    Skin sensitization              May cause an allergic skin reaction.
Germ cell mutagenicity              No data available to indicate product or any components present at greater than 0.1% are
                                    mutagenic or genotoxic.
Carcinogenicity                     Not classifiable as to carcinogenicity to humans.
    IARC Monographs. Overall Evaluation of Carcinogenicity
       Silicon Dioxide (CAS 112945-52-5)                   3 Not classifiable as to carcinogenicity to humans.
       Titanium Dioxide (CAS 13463-67-7)                   2B Possibly carcinogenic to humans.
    OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
       Not listed.
Material name: Putty Hardener                                                                                                       SDS US
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   US. National Toxicology Program (NTP) Report on Carcinogens
       Not listed.
Reproductive toxicity          This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -   Not classified.
single exposure
Specific target organ toxicity -   Not classified.
repeated exposure
Aspiration hazard                  Not an aspiration hazard.
12. Ecological information
Ecotoxicity                        The product is not classified as environmentally hazardous. However, this does not exclude the
                                   possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability      No data is available on the degradability of any ingredients in the mixture.
Bioaccumulative potential
   Partition coefficient n-octanol / water (log Kow)
   Benzyl Alcohol                                                   1.1
Mobility in soil                  No data available.
Other adverse effects              No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
                                   potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions              Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
                                   material under controlled conditions in an approved incinerator. Dispose of contents/container in
                                   accordance with local/regional/national/international regulations.
Local disposal regulations         Dispose in accordance with all applicable regulations.
Hazardous waste code               D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]
                                   The waste code should be assigned in discussion between the user, the producer and the waste
                                   disposal company.
Waste from residues / unused       Dispose of in accordance with local regulations. Empty containers or liners may retain some
products                           product residues. This material and its container must be disposed of in a safe manner (see:
                                   Disposal instructions).
Contaminated packaging             Since emptied containers may retain product residue, follow label warnings even after container is
                                   emptied. Empty containers should be taken to an approved waste handling site for recycling or
                                   disposal.
14. Transport information
DOT
   Not regulated as dangerous goods.
IATA
    Not regulated as dangerous goods.
IMDG
     Not regulated as dangerous goods.
Transport in bulk according to    Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
US federal regulations             This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
                                   Standard, 29 CFR 1910.1200.
    Toxic Substances Control Act (TSCA)
        TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
           Not regulated.
    CERCLA Hazardous Substance List (40 CFR 302.4)
       Not listed.
    SARA 304 Emergency release notification
       Not regulated.
    OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
       Not listed.
Material name: Putty Hardener                                                                                                     SDS US
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
   SARA 302 Extremely hazardous substance
       Not listed.
    SARA 311/312 Hazardous             Yes
    chemical
         Classified hazard             Acute toxicity (any route of exposure)
         categories                    Skin corrosion or irritation
                                       Serious eye damage or eye irritation
                                       Respiratory or skin sensitization
    SARA 313 (TRI reporting)
       Not regulated.
Other federal regulations
    Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
        Not regulated.
    Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
        Not regulated.
    Safe Drinking Water Act      Not regulated.
    (SDWA)
US state regulations
    California Proposition 65
                 WARNING: This product can expose you to Titanium Dioxide, which is known to the State of California to
                              cause cancer. For more information go to www.P65Warnings.ca.gov.
         California Proposition 65 - CRT: Listed date/Carcinogenic substance
             Titanium Dioxide (CAS 13463-67-7)                 Listed: September 2, 2011
         US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
         subd. (a))
             Titanium Dioxide (CAS 13463-67-7)
International Inventories
    Country(s) or region               Inventory name                                                                     On inventory (yes/no)*
    Australia                          Australian Inventory of Chemical Substances (AICS)                                                   Yes
    Canada                             Domestic Substances List (DSL)                                                                            Yes
    Canada                             Non-Domestic Substances List (NDSL)                                                                        No
    China                              Inventory of Existing Chemical Substances in China (IECSC)                                                Yes
    Europe                             European Inventory of Existing Commercial Chemical                                                        Yes
                                       Substances (EINECS)
    Europe                             European List of Notified Chemical Substances (ELINCS)                                                     No
    Japan                              Inventory of Existing and New Chemical Substances (ENCS)                                                  Yes
    Korea                              Existing Chemicals List (ECL)                                                                             Yes
    New Zealand                        New Zealand Inventory                                                                                     Yes
    Philippines                        Philippine Inventory of Chemicals and Chemical Substances                                                 Yes
                                       (PICCS)
    Taiwan                             Taiwan Chemical Substance Inventory (TCSI)                                                                Yes
    United States & Puerto Rico        Toxic Substances Control Act (TSCA) Inventory                                                             Yes
    *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
    A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
    country(s).
16. Other information, including date of preparation or last revision
Issue date                             07-03-2019
Revision date                          01-12-2021
Version #                              05
HMIS® ratings                          Health: 3
                                       Flammability: 1
                                       Physical hazard: 0
Material name: Putty Hardener                                                                                                                  SDS US
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NFPA ratings                      Health: 3
                                  Flammability: 1
                                  Instability: 0
Disclaimer                        ITW Performance Polymers cannot anticipate all conditions under which this information and its
                                  product, or the products of other manufacturers in combination with its product, may be used. It is
                                  the user’s responsibility to ensure safe conditions for handling, storage and disposal of the
                                  product, and to assume liability for loss, injury, damage or expense due to improper use. The
                                  information provided in this Safety Data Sheet is correct to the best of our knowledge, information
                                  and belief at the date of its publication. The information relates only to the specific material
                                  designated and may not be valid for such material used in combination with any other materials or
                                  in any process, unless specified in the text. The information given is designed only as a guidance
                                  for safe handling, use, processing, storage, transportation, disposal and release.
Revision information              This document has undergone significant changes and should be reviewed in its entirety.
Material name: Putty Hardener                                                                                                   SDS US
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