SUMANDEEP CLASSES
TOPIC NAME:- Atomic Physics
Subject : - Physics Date :
Time:- 60 Min (Solution) Marks :- 180
1. (a) 1 1 7
But n1 3 and n2 = 4
Sol. For n=1, maximum number of states 2n2 2 and for n 32 4 2 144
= 2, 3, 4, maximum number of states would be 8, 18, 32 (Paschen series)
respectively, Hence number of possible elements 16. (b)
= 2 + 8 + 18 + 32 = 60. Sol. Potential energy of electron in n th orbit of radius r in H-
n 2 h2 e2
2. (d)Sol. Bohr radius r 0 2 ; r n2 . atom U (in CGS)
Zme r
3. (a)Sol. 1 e2
∵ K.E. | P.E. | K
2 2r
17. (b)
Sol. Let the energy in A, B and C state be EA. EB and EC, then
from the figure
E12 3.4 (13.6) 10.2 eV .
1 1 1
4. (d) Sol. RZ 2 2 2
1 2
For di-ionised lithium the value of Z is maximum.
5. (c) Sol. Lyman series lies in the UV region. hc hc hc
(EC EB ) (EB EA ) (EC EA ) or
6. (b) Sol. The size of the atom is of the order of 1Å = 10 –10m. 1 2 3
7. (b) Sol. Balmer series lies in the visible region. 12
8. (c) Sol. Transition A (n = to 1) : 3 .
1 2
Series limit of Lyman series
18. (c)
Transition B (n = 5 to n = 2) :
Sol. According to Bohr’s second postulate.
Third spectral line of Balmer series
19. (c)
Transition C (n = 5 to n = 3) :
1 1 1 3R 16 16
Second spectral line of Paschen series Sol. R 2 2 105 cm
9. (a) 2 4 16 3R 3
Sol. D is excitation of electron from 2nd orbit c 3 1010 9
Frequency n 1015 Hz
corresponding to absorption line in Balmer series and E is the 16 5 16
energy released to bring the electron from to ground state 10
3
i.e. ionisation potential. 20. (d)
10. (b) Sol. Energy required to remove electron in the n = 2 state
Sol. Paschen series lies in the infrared region. 13.6
11. (b) 3.4 eV
(2)2
Sol. Linear momentum
21. (d)
mv 9.1 10 31 2.2 10 6
Sol. (Eion)Na Z 2(Eion )H (11)213.6 eV
2.0 1024 kg m / s
22. (d)
12. (c)
hc hc
Sol. r n2 rn n2a0 ( r1 a0 ) Sol. 2E E E
13. (c) 4E hc E hc '
Sol. For the ionization of second He electron. He will act as E 3 ' 3 .
3 ' 3 '
hydrogen like atom.
23. (b)
Hence ionization potential
Sol. Because atom is hollow and whole mass of atom is
Z 2 13.6 volt (2)2 13.6 54.4 V concentrated in a small centre called nucleus.
14. (c) 24. (d)
Sol. Energy required n 2 h2 n2
13.6 13.6 Sol. r 0 2 ; r
0.136 eV Zme Z
n2 102 25. (b)
15. (c) r(n 2) 4 9
1 1 1 1 1 1
Sol. r n2 r(n 3) R 2.25 R
Sol. R 2 2 2 2 r(n 3) 9 4
n1 n2 n1 n2 R 26. (a)
1 7 Sol. In the revolution of electron, coulomb force provides the
7 10
0.0486 .
1.097 10 18752 10 144 necessary centripetal force
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4
ze 2 mv 2 ze 2
2
mv 2
r r r
1 ze 2
K.E. mv 2 .
2 2r
39. (c)
1 1 1
Sol. Wave number R 2 2
n1 n2
27. (d) For first Balmer line n1= 2, n2=3
Sol.According to Bohr’s theory 1 1 9 4 5R
Wave number R 2
2 R .
h 2 3 9 4 36
mvr n
2 40. (a)
h Sol. Energy required to ionise helium atom
Circumference 2r n n . = 24.6 eV
mv
41. (b)
28. (c)
Sol. From diagram
kZe 2 kZe 2 K.E. 1
Sol. K.E and P.E. ; .
2r r P.E. 2
29. (d)
Sol.Lyman series lies in the UV region.
30. (d)
Sol.If E is the energy radiated in transition
then ERG EQS ERS EQR EP Q E1 13.6 (3.4) 10.2 eV
For getting blue line energy radiated should be maximum E2 13.6 (1.51) 12.09 eV
1 E3 1.51 (0.85) 0.66 eV
E . Hence (d) is the correct option.
E4 3.4 (1.51) 1.89 eV
31. (b) E3 is least i.e. frequency is lowest.
Sol.Energy released 42. (a)
1 1
13.6 2 2 2.55 eV . ke 2 e2 1 e2
(2) (4) Sol. P.E. ; K.E. (P.E.)
r 4 0r 2 8 0r
32. (c) nh h
Sol.The absorption lines are obtained when the electron jumps 43. (c) Sol. mvr , for n =1 it is .
2 2
from ground state (n = 1) to the higher energy states. Thus
only 1, 2 and 3 lines will be obtained. 44. (d) Sol. Minimum energy required to excite from ground state
33. (c) 1 1
13.6 2 2 10.2 eV
Sol.Wave number 1 2
1 1 1 1 1 3R 45. (d)
R 2 2 R . 2
n1 n2 4 16 16 2 2k 2e 4 m 1 2 2me 4
Sol. R
ch3 4 ch3
34. (a) 0
Sol. K.E. = – (T.E.) 46. (d)
35. (d) Sol. -particles cannot be attracted by the nucleus.
13.6 47. (c)
Sol.Required energy 3 E 2
1 .51eV
3 1 1
36. (d) Sol. By using RC 2
2
Sol.As n increases P.E. also increases. n1 n2
37. (a) 1 1
107 (3 108 ) 2 2 = 6.75 1013 Hz.
Sol.When an electron jumps from the orbit of lower energy 4 5
(n=1) to the orbit of higher energy (n=3), energy is absorbed. 48. (c) Sol. For M shell (n = 3), orbital quantum number l = 0, 1, 2.
38. (a) n(n 1)
Sol. E1 E2 49. (d) Sol. Number of possible emission lines
2
1 2 Where n = 4; Number
4(4 1)
6.
i.e. photons of higher frequency will be emitted if transition 2
takes place from n = 2 to 1. 50. (a) Sol. Diameter of nucleus is of the order of 10–14m and radius
of first Bohr orbit of hydrogen atom
r 0.53 10 10 m.
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