Page 1/9

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 03.03.2022 Version number 1 Revision: 03.03.2022

* SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name: MANNOL 9912 Silicone-Gasket schw. 85g
· UFI: 00FV-902N-100R-5JEP
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Sealant
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
SCT-Vertriebs GmbH
Feldstrasse 154
22880 WEDEL
DEUTSCHLAND
+49 (0)4103 1211 0
info@sct-germany.de
· Further information obtainable from: Product safety department.
· 1.4 Emergency telephone number:
National Poisons Information Service
+44 121 507 4123
Members of the public seeking specific information on poisons should contact:
In England and Wales: NHS 111 - dial 111
In Scotland: NHS 24 - dial 111

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS07

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2 H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS07

· Signal word Warning

· Hazard-determining components of labelling:
POLY(DIMETHYLSILOXANE) hydroxy terminated
· Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
(Contd. on page 2)
IE

54.0.10
 Page 2/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.03.2022 Version number 1 Revision: 03.03.2022

Trade name: MANNOL 9912 Silicone-Gasket schw. 85g

(Contd. of page 1)
H335 May cause respiratory irritation.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves / eye protection / face protection.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P321 Specific treatment (see on this label).
P362+P364 Take off contaminated clothing and wash it before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Labelling of packages where the contents do not exceed 125 ml
· Hazard pictograms

GHS07

· Signal word Warning

· Hazard-determining components of labelling:
POLY(DIMETHYLSILOXANE) hydroxy terminated
· Hazard statements
H335 May cause respiratory irritation.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves / eye protection / face protection.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
(Contd. on page 3)
IE

54.0.10
 Page 3/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.03.2022 Version number 1 Revision: 03.03.2022

Trade name: MANNOL 9912 Silicone-Gasket schw. 85g

(Contd. of page 2)
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

· 3.2 Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 70131-67-8 POLY(DIMETHYLSILOXANE) hydroxy terminated 30–37.3%
EC number: 615-070-3 Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335
CAS: 2031-67-6 triethoxy(methyl)silane 0.1–2.5%
EINECS: 217-983-9 Flam. Liq. 3, H226
CAS: 1067-53-4 tris(2-methoxyethoxy)vinylsilane 0.1–0.25%
EINECS: 213-934-0 Repr. 1A, H360FD
· Not dangerous substances
CAS: 471-34-1 calcium carbonate 22–32%
EINECS: 207-439-9
CAS: 63148-62-9 Dimethyl siloxane 8–18%
EC number: 613-156-5
CAS: 68611-44-9 Silane, dichlorodimethyl-, reaction products with silica 1–10%
EINECS: 271-893-4
· SVHC
1067-53-4 tris(2-methoxyethoxy)vinylsilane
· Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation: In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2. Do not use water.
Use fire extinguishing methods suitable to surrounding conditions.
Foam
Fire-extinguishing powder
Sand
(Contd. on page 4)
IE

54.0.10
 Page 4/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.03.2022 Version number 1 Revision: 03.03.2022

Trade name: MANNOL 9912 Silicone-Gasket schw. 85g

(Contd. of page 3)
· For safety reasons unsuitable extinguishing agents: Water
· 5.2 Special hazards arising from the substance or mixture No further relevant information available.
· 5.3 Advice for firefighters
· Protective equipment: No special measures required.
· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Particular danger of slipping on leaked/spilled product.
Wear protective clothing.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
· Information about fire - and explosion protection: Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· 8.1 Control parameters
· Additional information about design of technical facilities: No further data; see item 7.
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· Additional information: The lists valid during the making were used as basis.
(Contd. on page 5)
IE

54.0.10
 Page 5/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.03.2022 Version number 1 Revision: 03.03.2022

Trade name: MANNOL 9912 Silicone-Gasket schw. 85g

(Contd. of page 4)

· 8.2 Exposure controls

· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has
to be observed.
· Eye protection:

Tightly sealed goggles

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Pasty
Colour: Black
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/freezing point: Undetermined.
(Contd. on page 6)
IE

54.0.10
 Page 6/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.03.2022 Version number 1 Revision: 03.03.2022

Trade name: MANNOL 9912 Silicone-Gasket schw. 85g

(Contd. of page 5)

Initial boiling point and boiling range: 101 °C

· Flash point: 115 °C
· Flammability (solid, gas): Not applicable.
· Ignition temperature: 210 °C
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not determined.
· Density: Not determined.
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent content:
VOC (EC) 0.00 %
Solids content: 35–45 %
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products:
Carbon monoxide
Aldehyde
Poisonous gases/vapours
Carbon dioxide
IE
(Contd. on page 7)

54.0.10
 Page 7/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.03.2022 Version number 1 Revision: 03.03.2022

Trade name: MANNOL 9912 Silicone-Gasket schw. 85g

(Contd. of page 6)

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
471-34-1 calcium carbonate
Oral LD50 6,450 mg/kg (rat)
2031-67-6 triethoxy(methyl)silane
Oral LD50 15,700 mg/kg (rat)
· Primary irritant effect:
· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation
Causes serious eye irritation.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Additional toxicological information:
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure
May cause respiratory irritation.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 8)
IE

54.0.10
 Page 8/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.03.2022 Version number 1 Revision: 03.03.2022

Trade name: MANNOL 9912 Silicone-Gasket schw. 85g

(Contd. of page 7)
· European waste catalogue
HP4 Irritant - skin irritation and eye damage
HP5 Specific Target Organ Toxicity (STOT)/Aspiration Toxicity
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, ADN, IMDG, IATA not regulated
· 14.2 UN proper shipping name
· ADR, ADN, IMDG, IATA not regulated
· 14.3 Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class not regulated
· 14.4 Packing group
· ADR, IMDG, IATA not regulated
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Not applicable.
· Stowage Category B
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· UN "Model Regulation": not regulated

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
· DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in
electrical and electronic equipment – Annex II
None of the ingredients is listed.
· REGULATION (EU) 2019/1148
· Annex I - RESTRICTED EXPLOSIVES PRECURSORS (Upper limit value for the purpose of
licensing under Article 5(3))
None of the ingredients is listed.
· Annex II - REPORTABLE EXPLOSIVES PRECURSORS
None of the ingredients is listed.
(Contd. on page 9)
IE

54.0.10
 Page 9/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.03.2022 Version number 1 Revision: 03.03.2022

Trade name: MANNOL 9912 Silicone-Gasket schw. 85g

(Contd. of page 8)
· Regulation (EC) No 273/2004 on drug precursors
None of the ingredients is listed.
· Regulation (EC) No 111/2005 laying down rules for the monitoring of trade between the
Community and third countries in drug precursors
None of the ingredients is listed.
· National regulations:
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57
1067-53-4 tris(2-methoxyethoxy)vinylsilane
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H360FD May damage fertility. May damage the unborn child.
· Classification according to Regulation (EC) No 1272/2008
The classification of the mixture is generally based on the calculation method using substance data
according to Regulation (EC) No 1272/2008.
· Department issuing SDS: Product safety department.
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 3: Flammable liquids – Category 3
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Repr. 1A: Reproductive toxicity – Category 1A
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
· * Data compared to the previous version altered.
IE

54.0.10