Revision date: 10/12/2022                                    Revision: 6
SAFETY DATA SHEET
                                                       ENSURE
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name                     ENSURE
Product number                   A053 EV
Internal identification          Professional Hygiene
UFI                              UFI: 1PPE-R1AD-6G0C-CDH2
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses                  Alcohol sanitiser Suitable for use in the food Industry.
1.3. Details of the supplier of the safety data sheet
Supplier                         UK Supplier:                                  EU Supplier:
                                 Evans Vanodine International plc              Evans Vanodine Europe
                                 Brierley Road,                                6-9 Trinity Street, Dublin 2.
                                 Walton Summit,                               D02 EY47.
                                 Preston. UK. PR5 8AH                         Republic of Ireland.
                                 Tel: 01772 322 200
                                 e-mail: productcompliance@evansvanodine.co.uk
1.4. Emergency telephone number
Emergency telephone              New Safety Data Sheets - 01772 322 200 - Mon to Thur. 8.30am to 4.30pm - Fri 8.30am to
                                 1.30pm (Also available 24/7 from our website www.evansvanodine.co.uk) For Technical
                                 Advice about this SDS - 01772 318 818 - Mon to Thur 8.30am to 4.45pm - Fri 8.30am to
                                 1.30pm
National emergency telephone For Health Care Professionals only -
number                       For use in UK: Contact the National Poisons Information Service for further advice.
                             For use in the Republic of Ireland: To report a poisoning incident contact The National
                             Poisons Information Centre, Beaumont Hospital, Dublin (01-8092166). .
                             For use in Malta: Emergency services (Ambulance, Fire and Rescue, Police) : 112
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification (SI 2019 No. 720)
Physical hazards                 Flam. Liq. 3 - H226
Health hazards                   Eye Irrit. 2 - H319
Environmental hazards            Aquatic Chronic 3 - H412
2.2. Label elements
Hazard pictograms
                                                             1/9
Revision date: 10/12/2022                                   Revision: 6
                                                          ENSURE
Signal word                     Warning
Hazard statements               H226 Flammable liquid and vapour.
                                H319 Causes serious eye irritation.
                                H412 Harmful to aquatic life with long lasting effects.
Precautionary statements        P102 Keep out of reach of children.
                                P280 Wear eye protection.
                                P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
                                smoking.
                                P233 Keep container tightly closed.
                                P301 IF SWALLOWED:
                                P313 Get medical advice/ attention.
                                P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
                                contact lenses, if present and easy to do. Continue rinsing.
                                P337+P313 If eye irritation persists: Get medical advice/ attention.
                                P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
                                P403+P235 Store in a well-ventilated place. Keep cool.
                                P501 Dispose of contents/ container in accordance with local regulations.
Contains                        PROPAN-2-OL
2.3. Other hazards
This product does not contain any substances classified as PBT or vPvB. Including - Endocrine disrupting properties: None
known.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
 PROPAN-2-OL                                                                                                       15-20%
 CAS number: 67-63-0                       EC number: 200-661-7
 Classification
 Flam. Liq. 2 - H225
 Eye Irrit. 2 - H319
 STOT SE 3 - H336
 N-(3-AMINOPROPYL)-N-DODECYLPROPANE-1,3-                                                                            <0.1%
 DIAMINE
 CAS number: 2372-82-9                     EC number: 219-145-8
 M factor (Chronic) = 10
 Classification
 Acute Tox. 3 - H301
 Skin Corr. 1B - H314
 Eye Dam. 1 - H318
 STOT RE 2 - H373
 Aquatic Chronic 1 - H410
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
                                                            2/9
Revision date: 10/12/2022                                     Revision: 6
                                                          ENSURE
Inhalation                       If spray/mist has been inhaled, proceed as follows. Move affected person to fresh air and
                                 keep warm and at rest in a position comfortable for breathing.
Ingestion                        Do not induce vomiting. Give plenty of water to drink. Get medical attention if any discomfort
                                 continues.
Skin contact                     Wash with plenty of water.
Eye contact                      Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
                                 apart. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort
                                 continues.
4.2. Most important symptoms and effects, both acute and delayed
General information              The severity of the symptoms described will vary dependent on the concentration and the
                                 length of exposure.
Inhalation                       No specific symptoms known.
Ingestion                        No specific symptoms known. But - May cause discomfort if swallowed.
Skin contact                     No specific symptoms known. But prolonged or excessively repeated skin contact could lead
                                 to removal of natural oils from skin.
Eye contact                      May cause temporary eye irritation. Prolonged contact may cause redness and/or tearing.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor             Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media     Extinguish with the following media: Extinguish with foam, carbon dioxide, dry powder or
                                 water fog.
5.2. Special hazards arising from the substance or mixture
Specific hazards                 Thermal decomposition or combustion products may include the following substances:
                                 Irritating gases or vapours. May explode when heated or when exposed to flames or sparks.
5.3. Advice for firefighters
Special protective equipment     Keep containers cool by spraying with water to reduce explosion risks. Wear positive-pressure
for firefighters                 self-contained breathing apparatus (SCBA) and appropriate protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions             No smoking, sparks, flames or other sources of ignition near spillage. Avoid contact with eyes.
6.2. Environmental precautions
Environmental precautions        Spillages or uncontrolled discharges into watercourses must be reported immediately to the
                                 Environmental Agency or other appropriate regulatory body.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up          Small Spillages: Flush away spillage with plenty of water. Large Spillages: Contain and
                                 absorb spillage with sand, earth or other non-combustible material. Collect and place in
                                 suitable waste disposal containers and seal securely.
6.4. Reference to other sections
Reference to other sections      For personal protection, see Section 8.
                                                              3/9
Revision date: 10/12/2022                                     Revision: 6
                                                            ENSURE
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Usage precautions                 Eliminate all sources of ignition. Avoid contact with eyes.
7.2. Conditions for safe storage, including any incompatibilities
Storage precautions               Keep away from heat, sparks and open flame.
7.3. Specific end use(s)
Specific end use(s)               The identified uses for this product are detailed in Section 1.2.
Usage description                 See Product Information Sheet & Label for detailed use of this product.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters
Occupational exposure limits
PROPAN-2-OL
Long-term exposure limit (8-hour TWA): WEL 400 ppm 999 mg/m³
Short-term exposure limit (15-minute): WEL 500 ppm 1250 mg/m³
WEL = Workplace Exposure Limit.
8.2. Exposure controls
Protective equipment
Appropriate engineering           This product must not be handled in a confined space without adequate ventilation.
controls
Eye/face protection               Eyewear complying with an approved standard should be worn if a risk assessment indicates
                                  eye contact is possible.
Hand protection                   No specific hand protection noted, but protection for the skin is advisable to prevent removal
                                  of natural oils from skin.
Other skin and body               None required.
protection
Respiratory protection            Respiratory protection not required.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance                        Liquid.
Colour                            Clear. Colourless.
Odour                             Alcoholic.
pH                                pH (concentrated solution): 8.50
Melting point                     -5°C
Initial boiling point and range   Not available.
Flash point                       29°C
Flammability (solid, gas)         Flammable liquid and vapour.
                                                              4/9
Revision date: 10/12/2022                                    Revision: 6
                                                           ENSURE
Upper/lower flammability or      Not available.
explosive limits
Vapour pressure                  Not available.
Vapour density                   Not available.
Relative density                 0.972 @ 20°C
Solubility(ies)                  Soluble in water.
Partition coefficient            Not applicable.
Auto-ignition temperature        Not applicable.
Decomposition Temperature        Not applicable.
Viscosity                        Not available.
9.2. Other information
Other information                None.
Particle size                    Not applicable.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity                       There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stability                        No particular stability concerns.
10.3. Possibility of hazardous reactions
Possibility of hazardous         See sections 10.1,10.4 & 10.5
reactions
10.4. Conditions to avoid
Conditions to avoid              Avoid heat, flames and other sources of ignition.
10.5. Incompatible materials
Materials to avoid               No specific material or group of materials is likely to react with the product to produce a
                                 hazardous situation.
10.6. Hazardous decomposition products
Hazardous decomposition          No known hazardous decomposition products.
products
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological effects            We have not carried out any animal testing for this product. Any ATE figures quoted below are
                                 from Toxicity Classifications that have been carried out using ATE (Acute Toxicity Estimate)
                                 Calculation Method using LD50 or ATE figures provided by the Raw Material Manufacturer.
Other health effects             Low oral toxicity, but ingestion may cause irritation of the gastro-intestinal tract.
Acute toxicity - oral
Summary                          Not applicable.
Acute toxicity - dermal
                                                             5/9
Revision date: 10/12/2022                                     Revision: 6
                                                            ENSURE
Summary                           Not applicable.
Acute toxicity - inhalation
Summary                           Not applicable.
Skin corrosion/irritation
Summary                           Not applicable.
Serious eye damage/irritation
Serious eye damage/irritation     Causes serious eye irritation.
Respiratory sensitisation
Summary                           Not applicable.
Skin sensitisation
Summary                           Not applicable.
Germ cell mutagenicity
Summary                           Not applicable.
Carcinogenicity
Summary                           Not applicable.
Reproductive toxicity
Summary                           Not applicable.
Specific target organ toxicity - single exposure
Summary                           Not applicable.
Specific target organ toxicity - repeated exposure
Summary                           Not applicable.
Aspiration hazard
Summary                           Not applicable.
11.2 Information on other         None known.
Hazards 11.2.1 Endocrine
disrupting properties
SECTION 12: Ecological information
Ecotoxicity                       Harmful to aquatic life with long lasting effects.
12.1. Toxicity
Toxicity                          We have not carried out any Aquatic testing, therefore we have no Aquatic Toxicity Data
                                  specifically for this product. The Aquatic Toxicity Data, where provided by the raw material
                                  manufacturer for ingredients with aquatic toxicity, can be made available on request.
12.2. Persistence and degradability
Persistence and degradability This product, at use dilutions, is readily broken down in biological effluent treatment plants.
12.3. Bioaccumulative potential
Bioaccumulative potential         The product does not contain any substances expected to be bioaccumulating.
Partition coefficient             Not applicable.
12.4. Mobility in soil
                                                              6/9
Revision date: 10/12/2022                                 Revision: 6
                                                        ENSURE
Mobility                        Not known.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB         This product does not contain any substances classified as PBT or vPvB.
assessment
12.6 Endocrine disrupting       None known.
properties
12.6. Other adverse effects
Other adverse effects           Now section 12.7: None known.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Disposal methods                Small amounts (less than 5 Litres) of unwanted product may be flushed with water to sewer.
                                Larger volumes must be sent for disposal by approved waste contractor. Rinse out empty
                                container with water and consign to normal waste.
SECTION 14: Transport information
Road transport notes            750ml & 5L As supplied, this product is consigned under the Limited Quantities provisions.
14.1. UN number
UN No. (ADR/RID)                1987
UN No. (IMDG)                   1987
UN No. (ICAO)                   1987
14.2. UN proper shipping name
Proper shipping name            ALCOHOLS, N.O.S. (isopropanol)
(ADR/RID)
Proper shipping name (IMDG) ALCOHOLS, N.O.S. (isopropanol)
Proper shipping name (ICAO) ALCOHOLS, N.O.S. (isopropanol)
14.3. Transport hazard class(es)
ADR/RID class                   Class 3: Flammable liquids.
ADR/RID label                   3
IMDG class                      Class 3: Flammable liquids.
ICAO class/division             Class 3: Flammable liquids.
Transport labels
14.4. Packing group
ADR/RID packing group           III
IMDG packing group              III
ICAO packing group              III
14.5. Environmental hazards
                                                          7/9
Revision date: 10/12/2022                                  Revision: 6
                                                         ENSURE
Environmentally hazardous substance/marine pollutant
No.
14.6. Special precautions for user
EmS                             F-E, S-D
Tunnel restriction code         (D/E)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not relevant. for a packaged product.
Annex II of MARPOL 73/78
and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation                  Safety Data Sheet prepared in accordance with EU Regulation: "REACH Commission
                                Regulation (EU) No 2020/878 (which amends Regulation (EC) No 2015/830, 453/2010 &
                                1907/2006)." and UK Regulation: "SI 2020 No. 1577 - The REACH etc. (Amendment etc.) (EU
                                Exit) Regulations 2020.”.
                                The product is as classified under - EU GHS: CLP - "Regulation (EC) No 1272/2008
                                classification, labelling & packaging of substances & mixtures." and UK GHS: "SI 2020 No.
                                1567 - The Chemicals (Health and Safety) and Genetically Modified Organisms (Contained
                                Use) (Amendment etc.) (EU Exit) Regulations 2020.".
                                Ingredients are listed with classification under - EU GHS: CLP - "Regulation (EC) No
                                1272/2008 classification, labelling & packaging of substances & mixtures." and UK GHS: "SI
                                2020 No. 1567 - The Chemicals (Health and Safety) and Genetically Modified Organisms
                                (Contained Use) (Amendment etc.) (EU Exit) Regulations 2020.".
15.2. Chemical safety assessment
No chemical safety assessment has been carried out as not applicable as this product is a mixture.
SECTION 16: Other information
Abbreviations and acronyms      PBT: Persistent, Bioaccumulative and Toxic substance.
used in the safety data sheet   vPvB: Very Persistent and Very Bioaccumulative.
                                ATE: Acute Toxicity Estimate.
                                ADR: European Agreement concerning the International Carriage of Dangerous Goods by
                                Road.
                                IMDG: International Maritime Dangerous Goods.
                                ICAO: Technical Instructions for the Safe Transport of Dangerous Goods by Air.
                                REACH: The REACH etc. (Amendment etc.) (EU Exit) Regulations 2020 No. 1577.
                                GHS: Globally Harmonized System.
Classification abbreviations    Acute Tox. = Acute toxicity
and acronyms                    Aquatic Chronic = Hazardous to the aquatic environment (chronic)
                                Eye Dam. = Serious eye damage
                                Eye Irrit. = Eye irritation
                                Flam. Liq. = Flammable liquid
                                Skin Corr. = Skin corrosion
                                STOT RE = Specific target organ toxicity-repeated exposure
                                STOT SE = Specific target organ toxicity-single exposure
Key literature references and   Material Safety Data Sheet, Miscellaneous manufacturers. CLP Class - Table 3.1 List of
sources for data                harmonised classification and labelling of hazardous substances. ECHA - C&L Inventory
                                database.
                                                           8/9
Revision date: 10/12/2022                                 Revision: 6
                                                        ENSURE
Classification procedures      Calculation Method.
according to SI 2019 No. 720
Revision comments              New Format Safety Data Sheet prepared in accordance with REACH Commission Regulation
                               (EU) No 2020/878 (which amends Regulation (EC) No 453/2010 & 1907/2006). - No change
                               in Product Classification. (Changes made to sections 2,3,9,11,12,15+16)
Revision date                  10/12/2022
Revision                       6
SDS status                     The Hazard Statements listed below in this Section No 16 relate to the Raw Materials
                               (Ingredients) in the Product (as listed in Section 3) and NOT the product itself. For the Hazard
                               Statements relating to this Product see Section 2.
Hazard statements in full      H225 Highly flammable liquid and vapour.
                               H226 Flammable liquid and vapour.
                               H301 Toxic if swallowed.
                               H314 Causes severe skin burns and eye damage.
                               H318 Causes serious eye damage.
                               H319 Causes serious eye irritation.
                               H336 May cause drowsiness or dizziness.
                               H373 May cause damage to organs through prolonged or repeated exposure.
                               H410 Very toxic to aquatic life with long lasting effects.
                               H412 Harmful to aquatic life with long lasting effects.
                                                          9/9