atom metal dßlitalao 3.
whih
oset
womUsm 9onibati
bn
s0, (wts),
Br (lo andSa,]Bn>otwt),
lomplris toluing
theanbiltd
ly isomcrism
ia Iype what
hleie N-lolalt
li) Pntaamncnitulo-
entaaminechlrcloplatnum
l)romde
kln (uD lobalt-damnl th-,ane Trusle
olen),
J
Chmomale
Potasiumtrnoxalals
Cl)
ksIolGo),)
b.
lbde dechltideCobalt Ttnaamnine
name UPAC e Give
mank One
Lompounds Coddinationquotionm:
Date
Page
Name the tupe o strutwral iom ensm Hot
0 t in "he cosdnation (ompound tontanny
amthdondate ligond
wnite the
thetnonucntgunt n q d in tonma f ag
land o in o~ahtdral tomplea when
-
6 low many dsonm
’3 to Cis and one tran)
’ 2(one cisio and one tran
7.
what is he coitdinatin numb of
Fe in [fecds len,Jd
Six
Sx
Two manks queslers
wbatane amlidenlale Lgands? fit llam
The ligand which an
dlferent atons is allid amtilen tale
what n homoleptc (omplex) Git ar Cocample
9n homalepti complexe metal is tound
enly one kind adon d qrdu
3.wkat in hetene lptic omplexp Gut an txagzle
9n hetoroleptic xompescen metadis bisadh
4lwhatis din kage isomeniom ) Gut an ezample
lo trolination compsunda hauing Jamt meeua
Jtmula tit dyor in the mode attachnint
amidot ligand o the (en nad mefain
what io ionisatoninemerism 2 qut an txanale
lobidinaton contund hauing hame meleulat
mla ht produes cencnt iens shen
doalrd in wito
Date
Page
Nta
Pt
Cis trans
t a w Cis and ana
Co
C Thans
)loly len),]
en
Cn
Sold yal
herion dot ion bee
larbinly
4
Energy
pltng dagnamfo ompliaoakedzal
aucd enagy the ite 9.
ynng acat oncing lgand mcttl The
carnujin
a hefintd
ty
onatn h fimtd
dy in
land M-Co The
chanato oandpobenoth
bod mal uo
dond Canlon metal- The
tanlenlo mfallonah M-co
8
Sptrochemical
ispectrohcmical
soin?the ia Jeri what
bate
Poge
Ie. wmide he enogy lcl da_pam fo ylWng in
octakekal complir
3/5A0
Energy -4,
Average energy of
the d orbitals in a
spherical crystal
field Splitting of d-orbitals
d orbitals
in free ion in an ochedral
crystal field
Thee manke quctiem
Meaien the pestulate o Weinen'a theuy
In co-thdinatien cenpsunda, mital pe
tuo typs 4 walenci, phimay valeny and
Sendy vnleny
Piimay valeny itnizable and yahiable,
and id..
Rrimaiy valencaa aatilid hy niqatie
Äbn, whenca
hacai iendany valenei az
nLgatin iens auaal elca
valenu ahe non-dihectienal
whheasthe seconday valencu ahe dihecled
tasands Lidd paltbns in upaee arsnd
the tenlhal ien
Based t VBT, plain the
agd magnetie prapey
- hexaammineobalt iu) ion
’ 3+
3d5
hen ataeng qand, NH,
appasacha h.
Cental mital ien, ahhangimint o
Tue d8hbitau, ernu stbital and tho
bitali undwnge hybidization iohn s
3d6
Thae aie hybidized ebitae
ith bitai e< Si
i pai igunda
armmene
dehen donatd bui
and
ammea
bend
d'sp hybud sbitali
d'sp kybhidiiatitn
tutahual qomey
Diamagnti (absune of wnpaied dacäen
Baud on VET, Crplain the hubidiatin,
guernby magnoti prepety
hnaliudecebaltali (ui) tn.
La Oxidatin tat Cebalt i t
45
Dote/
Page
wtak diqand, uasangrnent
e decsene aqaingt Hund' sude douHst.
kake plate. ne 4s the up and tuo Butu
Ld gibitali hybidie
hybid hbital
3d
spt
3+
Thse hybidized obitaly a! lo
F te Lofun Co-edinat band
3
3d Si pais H
Ectahachal gemtby
Based on VBT, plain the hybhidisatên,
qeornahy magneic phspety
- tetachlatidanickilate (n)in.
In (Nicd ridalion etat < nickal it t?
3d
cdectsen aqainet Huid'a sule da
ake plau. Oni 4s and thies Hp eibita
hybuidiae te
pbinting teasdith the
teaahdher
4s
Each clitn denats a pah o eeeen t
bita o Lem tebahid
panamagnctic (due loa the pruune le
wnpated
ltien)
Boud on VBT, Laplain the hubhidiatien,
gkrnaby and magotic pospeiy e
Ni (e-teayanenickulatt) ion
In Ni (ca)4Oaidatitn 3datati 4s
shun a sbeng aacd , CN appheathe te
cntal mital in, seassangmint et
ake plae aqaint Hund' 'ule.
unpad ileeto o< 3d obital ae
ae
Dote//
Page
bt atcemmedatad , nickd (n)ion undgs
dsp' hydidizatien
3d
dsp? hiyjbnidization
Thuxe tauh hybnidiid abita Ni
with the obittn t to
to leYm foh coehdinate bonde
3d'o CN
dsg hybsidiaisn
Squabe hlanai quemiy
NN
N N
Diamagne |No wapaiud elettoni
ai pndent)
