SHS
General Chemistry 1
Quarter 3: Week 1 - Module 1
  Kinetic Molecular Model
General Chemistry 1
Grade 11 Quarter 3: Week 1 - Module 1: Kinetic Molecular Model
First Edition, 2021
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Region I
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    General
  Chemistry 2
Quarter 3 – Week 1 - Module 1
  Kinetic Molecular Model
                  Target
              The lesson explores the kinetic molecular theory and how it pertains
to the properties of solids and liquids. You'll learn the Kinetic Molecular Theory
explains the properties of solids and liquids in terms of intermolecular forces of
attraction and the kinetic energy of the individual particles. After reading this
learning material, you are expected to:
             Use the kinetic molecular model to explain properties of liquids and
             solid STEM_GC11IMFIIIa-c-99)
              Describe and differentiate the types of intermolecular forces
             (STEM_GC11IMFIIIa-c-100)
                    Before going on, check how much you know about this topic.
                    Answer the pretest on the next page and write your answer in
                    ¼ sheet of paper.
                    JUMPSTART
   Direction: Select the letter of the correct answer and write in ¼ sheet of paper.
1. Which of the following is NOT a characteristic of liquids?
      A. Liquids have the ability to flow.
      B. The particles of a liquid are not attracted to each other.
      C. The particles of liquids are closer together than particles of gases.
      D. Liquids conform to the shape of their container.
2. Which of the following explains that liquids cannot be compressed easily?
      A. The particles are too far apart.
      B. The particles are arranged in a fixed position.
      C. The particles are too close together to be squished any closer.
      D. The particles are free to move and simply move away from each
         other when we try to squish them
3. When NaCl dissolves in water, aqueous Na+ and Cl ions result. What do you
     call the force of attraction that exists between Na+ and H2O?
         A. dipole-dipole                              C. hydrogen bonding
         B. ion-ion                                    D. ion-dipole
4. Which of the following is NOT a characteristic of liquids?
      A. Liquids have the ability to flow.
      B. The particles of a liquid are not attracted to each other.
      C. The particles of liquids are closer together than particles of gases.
      D. Liquids conform to the shape of their container.
5. Kinetic-molecular theory makes several assumptions about _______________.
         A. The size and energy of the molecules.
         B. The motion and energy of the molecules.
         C. The motion and size of the molecules
         D. The size and weight of the molecules
                 Discover
                             Kinetic Molecular Theory
Take a glass of water. Drop a few drops of red food coloring in it. What happens?
The red food coloring drops should make their way down the glass of water slowly,
spread out and finally tint all of the water a reddish color. Why does this happen?
It happens because both substances are made out of molecules that are constantly
moving. These molecules have energy; one of the fundamental principles of the
kinetic molecular theory.
          The Kinetic Molecular Theory (KMT) is a model used to explain the
   behavior of matter. It is based on a series of postulates.
   Some of the postulates of KMT are as follows:
      •   Matter is made of particles that are constantly in motion. This energy in
          motion is called kinetic energy.
      •   The amount of kinetic energy in a substance is related to its temperature.
      •   There is space between particles. The amount of space in between particles
          is related to the substance's state of matter.
      •   Phase changes happen when the temperature of the substance changes
          sufficiently.
      •   There are attractive forces in between particles called intermolecular
          forces. The strength of these forces increase as particles get closer together.
   Now, let us investigate two kinds of forces, or attractions, that operate in a
   molecule—intramolecular and intermolecular. Intramolecular forces are the
   forces that hold atoms together within a molecule. Intermolecular forces are forces
   that exist between molecules.
                  INTERMOLECULAR FORCES (IMF) are relatively weaker than the
   forces within the molecules forming bonds (intramolecular forces) Intramolecular
   Forces hold atoms together in a molecule. The intermolecular forces of attraction in
   a pure substance are collectively known as van der Waals forces; Dipole-dipole,
   Hydrogen bonding, Ion-dipole, London dispersion
1. Dipole-dipole forces. These forces occur when the partially positively charged part
   of a molecule interacts with the partially negatively charged part of the neighboring
   molecule. The prerequisite for this type of attraction to exist is partially charged
   ions—for example, the case of polar covalent bonds such as hydrogen
   chlorideDipole-dipole interactions are the strongest intermolecular force of attraction.
2. Hydrogen bonding: This is a special kind of dipole-dipole interaction that occurs
   specifically between a hydrogen atom bonded to either an oxygen, nitrogen, or
   fluorine atom. The partially positive end of hydrogen is attracted to the partially
   negative end of the oxygen, nitrogen, or fluorine of another molecule. Hydrogen
   bonding is a relatively strong force of attraction between molecules, and
   considerable energy is required to break hydrogen bonds. This explains the
   exceptionally high boiling points and melting points of compounds like water and
   hydrogen fluoride. Hydrogen bonding plays an important role in biology; for
   example, hydrogen bonds are responsible for holding nucleotide bases together
   in and RNA.
   3. Ion-dipole . The ions and the oppositely charged ends of the polar water
        molecules overcome the attraction between ions themselves. Each ion becomes
        separated and water molecules cluster around it.
   4.
1. London dispersion forces, under the category of van der Waal forces: These are
   the weakest of the intermolecular forces and exist between all types of molecules,
   whether ionic or covalent—polar or nonpolar. The more electrons a molecule has,
   the stronger the London dispersion forces are. For example, bromine has more
electrons than chlorine, so bromine will have stronger London dispersion forces
than chlorine, resulting in a higher boiling point for bromine, compared to
chlorine.. Also, the breaking of London dispersion forces doesn’t require that much
energy, which explains why nonpolar covalent compounds like methane oxygen,
and nitrogen—which only have London dispersion forces of attraction between the
molecules—freeze at very low temperatures.
              The types of intermolecular forces in a liquid depend on the chemical
make up of the liquid itself. Strength of intermolecular force is related to the type of
intermolecular force, but it is also affected by the amount of kinetic energy in the
substance. The more kinetic energy, the weaker the intermolecular forces. Liquids
                                                                have    more     kinetic
                                                                energy than solids, so
                                                                the      intermolecular
                                                                forces between liquid
                                                                particles tend to be
weaker. Liquids do not have       a simple or regular structure, but many of their
properties can be explained qualitatively by viewing them at the particulate level.
Below are the properties of liquids and their intermolecular forces.
1. Surface tension allows needles and paper clips to float in water if placed carefully
on the surface. It also explains why drop of water are spherical in shaped. These
intermolecular forces tend to pull the molecules into the liquid and cause the surface
to tighten like an elastic film or “skin”. Molecules within a liquid are pulled in all
directions by intermolecular forces. Molecules at the surface are pulled downward
and sideways by other molecules, not upward away from the surface. The liquids
that have strong Intermolecular forces also have high surface tension
2. Capillary action is the tendency of a liquid to rise in narrow tubes or be drawn
into small openings such as those between grains of a rock. Capillary action, also
liquid to rise, is a result of intermolecular attraction between the liquid and solid
   materials. Example of capillary actions.
                             There are two types of forces are involved in capillary action:
                    Cohesion is the intermolecular attraction between like molecules (the
   liquid molecules).And Adhesion which is an attraction between unlike molecules
   (such as those in water and in the particles that make up the glass tube).
   3.Viscosity. The viscosity of liquid Depends on their intermolecular attraction. The
   stronger the intermolecular force, the higher is the liquid’s viscosity. Example is oil
   which has long-chained substances that has greater intermolecular forces because
   there are more atoms that can attract one another, contributing to the substance’s
   total attractive forces. Also with honey, a concentrated solution of sugar, is also highly
   viscous because of the hydrogen bonding that forms as a result of the numerous-
   OH groups of sugar molecule.
   Substances with relatively strong intermolecular forces will have low vapor
   pressure because the particles will have difficulty escaping as a gas.
   Example:
   1.Wate (H O),          (Hydrogen Bonding) has vapor pressure of 0.03 atm.
            2
   2.Ethyl Ether          (C H O), dipole-dipole & London Force ) has vapor pressure at 0.68
                            4 10
   atm.
   4. Boiling point. The boiling point of a liquid is the temperature at which its vapor
   pressure is       equal to the external or atmospheric pressure .Increasing the
   temperature of a liquid raises the kinetic energy of its molecules, until such point
   where the energy of the particle movement exceeds the intermolecular forces that
   hold them together.The greater intermolecular force, the higher the energy needed to
   increase the kinetic energy of the molecules to break these forces.
5. Molar Heat of vaporization ( H             ) is the amount of heat required to vaporize one
                                        vap
   mole of substance at its boiling point.T he application of heat disrupts the
   intermolecular forces of attraction of the liquid molecules and allows them to
   vaporize. Boiling point generally increases as molar heat of vaporization increases.
6. The          H         is also determined by the strength of intermolecular forces between
                    vap
   molecules.
       Let us continue on the properties of solids and their intermolecular forces. As
you should remember from the kinetic molecular theory, the molecules in solids are
not moving in the same manner as those in liquids or gases. Solid molecules simply
vibrate and rotate in place rather than move about. Solids are generally held together
by ionic or strong covalent bonding, and the attractive forces between the atoms,
ions, or molecules in solids are very strong. In fact, these forces are so strong that
particles in a solid are held in fixed positions and have very little freedom of
movement. Solids have definite shapes and definite volumes and are not
compressible to any extent.
There are two main categories of solids—crystalline solids and amorphous
solids. Crystalline solids are those in which the atoms, ions, or molecules that make
up the solid exist in a regular, well-defined arrangement. The smallest repeating
pattern of crystalline solids is known as the unit cell, and unit cells are like bricks
in a wall—they are all identical and repeating. The other main type of solids are called
the amorphous solids. Amorphous solids do not have much order in their
structures. Though their molecules are close together and have little freedom to
move, they are not arranged in a regular order as are those in crystalline solids.
Common examples of this type of solid are glass and plastics.
There are four types of crystalline solids:
Ionic solids—Made up of positive and negative ions and held together by electrostatic
attractions. They’re characterized by very high melting points and brittleness and are
poor conductors in the solid state. An example of an ionic solid is table salt, NaCl.
Molecular solids—Made up of atoms or molecules held together by London
dispersion forces, dipole-dipole forces, or hydrogen bonds. Characterized by low
melting points and flexibility and are poor conductors. An example of a molecular
solid is sucrose.
Covalent-network (also called atomic) solids—Made up of atoms connected by
covalent bonds; the intermolecular forces are covalent bonds as well. Characterized
as being very hard with very high melting points and being poor conductors.
Examples of this type of solid are diamond and graphite, and the fullerenes. As you
can see below, graphite has only 2-D hexagonal structure and therefore is not hard
like diamond. The sheets of graphite are held together by only weak London forces!
                         EXPLORE
                       Here are some enrichment activities for you to strengthen the
                             basic concepts you have learned from this lesson
Activity 1. Travelling Water Experiment! Property of Liquid and their Intermolecular
Forces.The concept of the following experiment can be used in our day to day
activities.
   I.       To demonstrate cohesion and adhesion of water.
   II.      Materials: Two large plastic cups, Thick cotton string of length 2 ½ feet to
            3 feet.
   III.     Procedure:
    1. Fill one of the beaker with ¾ full of water.
    2. Soak the thick cotton string in water until it is completely wet.
    3. Put one end of the string into the cup with water and the other end in the
          empty cup.
    4. Add a little food colour to water in the cup so that we can see water travelling
          through the string. Raise the cup with water slightly.
          Observation:
          __________________________________________________________________________
          __________________________________________________________________________.
Activity 2. Intermolecular Forces
    I.        To demonstrate the types of intermolecular forces.
    II.       Materials: Liquids: water, alcohol and honey/shampoo
              3 droppers, 3 pcs coins, 3 paint brush (small), bond paper, 10 g of sodium
              chloride (NaCl)/ salt, 3 small glass containers, spatula
   III.      Procedure:
             1. Put several drops of water to cover the whole coin. Continue putting
                drops of water until it spills. Do the same with another coin using honey
                and on the third coin using alcohol.
                Observations:
                ____________________________________________________________________
                ____________________________________________________________________
             2. Brush s strip of water on the clean sheet of bond paper and observe
                how long it will evaporate. Do the same procedure using honey and
                alcohol.
                Observations:
                ____________________________________________________________________
                ____________________________________________________________________
             3. Using the three different liquids, add the sodium chloride separately
                and    observe   if   it   dissolves   in   each   liquid.   Observations:
                ___________________________________________________________________
                ___________________________________________________________________
                      You are really doing great! That’s amazing!
                        Deepen
          At this point, continue assessing your learning by accomplishing the activity
below.
Enrichment Activity: “The Scientist Got Talent”.
          Compose a poem or a song (indicate the tune), at least 2 stanzas having four
lines, showing or applying the concepts about Kinetic Molecular Theory or
intermolecular force and bonding.
                                  POEM/SONG RUBRIC
                 Beginning             Developing        Accomplished               Exempler
                  (7 pts)              (8 points)               (9 pts)                (10 pts)
Organiz    The sequencing of The sequencing The                                  The
ation      words             and of     words     and sequencing            of sequencing          of
           phrases            is phrases is very the words and words                              and
           random.           The confusing,       and phrases               is phrases             is
           reader can find the reader may somewhat                               logical, and the
           no     evidence    of need to use his logical, and the reader is able
           thoughtful             or     her     own reader is able to                 follow     the
           ordering of ideas.     knowledge          to to to follow the ordering                  of
                                  determine         the ordering            of ideas easily
                                  ordering           of ideas             with
                                  ideas.                 minimal efforts
Word       The    poem      uses The poem uses The poem uses The poem uses
Choice     general            or general             or several                  many      precise,
and        ordinary terms to ordinary           terms descriptive                and descriptive
Main       describe          the to develop main words                      to words               to
Idea       object; the words idea.                       develop a main develop a main
           do     not   develop                          idea               or idea                or
           main idea.                                    message                 message.
Spelling   Numerous               Numerous               There             are There are very
           spelling      errors spelling        errors   spelling errors, few              spelling
           impede the reader impede                 the which may or errors.                    They
           from                   reader         from may         not      be are
           understanding          understanding          developmentall          developmentall
           the          poem’s the             poem’s y        appropriate. y          appropriate
           message.Errors         message.      Some However, they and                   do       not
           are                    of the errors are      do not impede impede                     the
           developmentally        developmentally        the       reader’s reader’s
           appropriate       and appropriate, but understanding                  understanding
           should have been others             should of the poem                of the poem.
           noticed           and have            been
           corrected.             noticed         and
                                  corrected.
                Gauge
Direction: Read carefully each question. Use a separate sheet of paper for your
          answer. Write the letter of the best answer.(15 pts)
 1. Kinetic-molecular theory makes several assumptions about _______________.
         A. The size and energy of the molecules
         B. The motion and energy of the molecules
         C. The motion and size of the molecules
         D. The size and weight of the molecules
 2. What do you call the force when the partially positive end of one molecule is
    attracted weakly to partial negative end?
      A. coulomb's force                    B. electrostatic force
      C. dipole-dipole interaction          D. ionic bond
3. Which of the following is NOT a characteristic of liquids?
      A. Liquids have the ability to flow.
      B. The particles of a liquid are not attracted to each other.
      C. The particles of liquids are closer together than particles of gases.
      D. Liquids conform to the shape of their container.
4. Which of the following explains that liquids cannot be compressed easily?
      A. The particles are too far apart.
      B. The particles are arranged in a fixed position.
      C. The particles are too close together to be squished any closer.
      D. The particles are free to move and simply move away from each
         other when we try to squish them.
5. In liquids, the attractive intermolecular forces are __________.
      A. very weak compared with kinetic energies of the molecules
      B. strong enough to hold molecules relatively close together
      C. strong enough to keep the molecules confined to vibrating about their
          fixed lattice points
      D. not strong enough to keep molecules from moving past each other
6. When NaCl dissolves in water, aqueous Na+ and Cl ions result. What do you
    call the force of attraction that exists between Na+ and H2O
       A. dipole-dipole            B. hydrogen bonding
       C. ion-dipole               D London dispersion force
7. Which of the following contribute to the reason behind the origin of surface
   tension?
        A. only cohesive forces
        B. only adhesive forces
        C. neither cohesive forces nor adhesive forces
        D. both cohesive forces and adhesive forces
8. What do you call the weakest type of intermolecular forces and solely for
    nonpolar molecules and noble gases?
       A. Dipole-dipole force              B. Hydrogen bonding
       C. Ion-dipole force                 D. London dispersion force
9. Which statement is true about the viscosity of a liquid?
       A. The stronger the intermolecular forces, the more viscous the liquid.
       B. The smaller the molecules, the more viscous the liquid.
       C. The higher the temperature, the more viscous the liquid.
       D. All of the answers are true.
10. What do you call the force that polar molecules containing H chemically
   bonded to a small and highly electronegative nonmetal atom such as N, O,
    and F?
       A. dipole-dipole                    B. hydrogen bonding
       C. ion-dipole                       D. London dispersion force
11.What was the Kinetic Molecular Theory designed to explain?
       A. the behavior of matter                 B. what temperature measures
       C. types of intermolecular forces         D. crystalline structure of solids
12. What is a dipole-dipole force?
      A. The force that occurs between the oppositely charged poles of polar
          molecules.
      B. The force that occurs within a polar molecule because of the oppositely
          charged poles.
      C. The attractive force that occurs between an ion and a dipole.
      D. The force that occurs between non-polar molecules.
13. By which phenomenon does the water rise from the roots to leaves of plants?
      A. heat of vaporization            B. capillary action
      C. surface tension                 D. viscosity
14. Which of the following describes surface tension in water?
      A. surface tension occurs due to ionic bonding
      B. surface tension is caused by water molecules repelling one another
      C. surface tension allows water to support small objects if they are placed
         carefully on its surface
      E. surface tension of water is weakened by hydrogen bonding
15. Which of the following scenarios is an example of cohesion?
      A. water molecules stick to the surface of a mirror.
      B. water sticks to the walls of blood vessels.
      C. water molecule stay on the tip of the needle because the water is attracted
         to the surface of the needle.
      D. water molecules stick to one another and form a bead.
Pre-Test
1.B     2.D      3. D     4. B   5. B
Explore
Activity 1. Observation : Water will cling to the string. We will see water droplets entering
slowly in the empty cup. Water will start collecting in the empty cup drop by drop. The level of
water in the cup with water will decrease and the level of water in the empty cup will increase.
Activity 2.
Observation 1: Water – intact and creates a dome forming on top due to hydrogen bonding
                   Honey -intact due to dipole-dipole force/hydrogen bonding
                   Alcohol- dispersed or scattered due to London Dispersion Force
Observation 2: Water -second to evaporate
                 Honey-3rd or last
                 Alcohol -1st to evaporate
Observation 3: Water – salt dissolves in water – ion-dipole
                 Honey – insoluble               - dipole-dipole
                 Alcohol – insoluble             - London Dispersion
Deepen Answers may vary
Gauge
1.B       2. C     3. B      4. D       5.A      6. C       7. D       8. D        9. A      10. C
11. A     12. A 13. B        14. C      15. D
                                                                   ANSWER KEY
References
  A. Books
  Cervantes, Charry Vida R. and Dizon, Reynald D. General Chemistry 1 for Senior
  Highj School (Specialized Subjects for STEM Strand). Manila, Philippines:
  LORIMAR Publishing Inc.2008.
  Ilao, Lacsamana V., Betty M.Lontoc, and Edwehna Elinore S. Paderna-Gayon.
  General Chemistry 1. Sampaloc, Manila: Rex Bookstore, Inc. 2016.
  B. Website
  study.com/academy/lesson/the-kinetic-molecular-theory-properties-of-solids-
  and-liquids.html
  https://reviewgamezone.com/mc/candidate/test/?test_id=12019&title=Bondin
  g%20%20Intermolecular%20Forces
  https://www.slideshare.net/marvinnbustamante1/general-chemistry-2-
  chapter-1-the-kinetic-molecular-model-and-intermolecular-forces-of-attraction-
  in-matter?from_action=save
 https://www.khanacademy.org/science/class-11-chemistry-
 india/xfbb6cb8fc2bd00c8:in-in-states-of-matter/xfbb6cb8fc2bd00c8:in-in-
 intermolecular-forces/a/intramolecular-and-intermolecular-forces
 http://kayjayr-akshay.blogspot.com/2016/09/a-simple-activity-on-cohesion-
 and.html
 http://content.sandbox-njctl.org/courses/science/chemistry/intermolecular-
 forces/intermolecular-forces-multiple-choice-2/intermolecular-forces-multiple-
 choice-2009-05-13.pdf
 https://www.sanfoundry.com/fluid-mechanics-questions-answers-surface-
 tension/