ABB Protection Solutions
ABB Protection Solutions
A P P L I C AT I O N G U I D E
                             On Earth, hydrogen exists combined with oxygen in                 Fuel for              Heat for         Feedstock for
                             water or with carbon, constituting hydrocarbons                   Transport                Industry         Chemicals
Carbon Capture
Hydrogen Storage
Hydrogen production
Hydrogen Consumption
—
ABB participates throughout
the hydrogen ecosystem
—
ABB Portfolio for the Hydrogen Ecosystem
                                                                                                                           HRS
     ABB Power                                                                         Drivers                                                                        Batteries/SC
                                                                                                                         Hydrogen
      Quality &
                                                                                                                         Refueling
      Rectifiers
                                                                                                                          Station          On board
                                                          Unit Operation & Control      Motor                                              H₂ Storage     Full Cell      Drives       Motor
                      Transmission Grid
     ABB Ports
    and Marine                                                  ABB Ability Platform - integrated Functional, technological and operational ecosystem
    ABB Offering
                                                                                                                        —
                                                                                                                        ABB IS PRESENT THROUGHOUT THE HYDROGEN ECO -
                                                                                                                        SYSTEM, WITH SOLUTIONS FOR HYDROGEN PRODUC-
                                                                                                                        TION, HYDROGEN STOR AGE, AND HYDROGEN DIS-
                                                                                                                        TRIBUTION AND CONSUMPTION. IN THIS DOCUMENT,
                                                                                                                        WE WILL FOCUS ON HYDROGEN PRODUCTION.
          Main concerns and problems                                          One kilogram of hydrogen contains 3.1 times the en-
                                                                              ergy of one kg of gasoline and 2.6 times the energy
          related with H₂                                                     of 1 kg of natural gas.
                                                                              What’s an Electrolyzer?
                                                                              An electrolyzer is a device that produces hydrogen
       Water 9 kg                                                  1 kg
                                                                              through a chemical process, namely electrolysis,
                                                                              which separates the hydrogen and oxygen mole-
                                   Electrolysis
                                                                              cules in water using electricity.
Total H+ H+
        SOEC process:
                                   U
                                                                                   87%   Direct          39%   Alkaline         100% Alkaline
                                                                                         renewables      58%   PEM
                                                                                   13%   Grid            3%    Solid-Oxide
  H²                         Electrolyte                                O₂
                             solid oxide
H₂O
                                                                                   6000 Alkaline         50    Alkaline
           Cathode                                 Anode                           7000 PEM              100   PEM
       steam electrode                         air electrode                       300 Grid              10    Grid
                           Op.   Op.
                         temp. press. Cathode            Anode
        Type               [°C] [Bar]     Gas              Gas          Cost
        Alkaline                                H₂            O₂
        (AEL)          15 – 220        <30     H₂O           H₂O      Lowest
        Acidic                                                O₂
        (PEM)            40 – 80       <30         H₂        H₂O        High
        Solid                                   H₂                       Not
        Oxide       500 – 1,000        <10     H₂O            O₂   commercial
Levelized Cost of Hydrogen                                              Currently, electricity costs account for more than
                                                                        60% of the Levelized Cost of Hydrogen (LCOH) share
(LCOH)                                                                  in Alkaline Electrolyzer (AEL) systems and more than
                                                                        40% in Proton Exchange Membrane (PEM) systems.
The 3 major factors affecting LCOH are:
—
Electrolyzer System
Electrolyze  System CAPEX
                    CAPEX Forecast
                          Forecast
1400
1200
1000
800
600
400
200
2020 2021 2022 2023 2024 2025 2026 2027 2028 2029 2030
                        —
                        Layout for an alkaline electrolyzer plant
                                                                                                                          High pressure
Feed water supply                       Vented oxygen          Gas/water separator     Deoxo             Buffer tank      compressor
                                           O₂       H₂
                         Electrolyzer
                                                                                               Dryer
                                                                                                                             High pressure
                                                                                                                             buffer tank
High voltage
supply
                                                                         Water/KOH
                                                                         Electrolyte Tank
                                           Lye
                                           Filter
Transformer      Rectifier
      Hydrogen
                                                                                               —
      Oxygen
                                                                                               NOTE: THIS CONFIGUR ATION IS FOR A GENERIC
      Water                                                                                    SYSTEM AND MIGHT NOT BE REPRESENTA-
                                                                                               TIVE OF ALL EXISTING MANUFACTURERS.
      Water/KOH
                                                                                               BASED ON IRENA ANALYSIS.
—
Layout for a PEM electrolyzer plant
                                                                      Condensate
                                         Low    High
                                     pressure   pressure                              Deoxo                Hydrogen
                                         side   side
                                                                                                             Dryer
                                                                             Gas
                       Gas                               Gas
                 O₂                                              H₂     reservoir
                       separator                    separator
                      Circulation                Electrolyzer
                      pump
Transformer Rectifier
                                                                                 —
                                                                                 NOTE: THIS CONFIGUR ATION IS FOR A GENERIC
        Hydrogen
                                                                                 SYSTEM AND MIGHT NOT BE REPRESENTA-
        Oxygen
                                                                                 TIVE OF ALL EXISTING MANUFACTURERS.
        Water                                                                    BASED ON IRENA ANALYSIS.
—
Layout for a SOEC electrolyzer plant
                                                                             Heater
                              Gas/Water                 Pre-heater                              Pre-heater
                         H₂   Separator                 Steam                                   Air
                                                                                                        O₂ Vented out
 Feed liquid
 water supply
                                Evaporator
                                                                                      Stack
Transformer Rectifier
                                                                                 —
        Hydrogen                                                                 NOTE: THIS CONFIGUR ATION IS FOR A GENERIC
                                                                                 SYSTEM AND MIGHT NOT BE REPRESENTA-
        Oxygen
                                                                                 TIVE OF ALL EXISTING MANUFACTURERS.
        Water                                                                    BASED ON IRENA ANALYSIS.
Different solutions – different                                             Typically, the DC energy consumption for 1 Nm³ of
                                                                            H₂ is around 4 – 6 kWh. Therefore, a 4,000 Nm³/h
production scales:                                                          plant is capable of producing 360 kg of H₂ per hour
                                                                            while consuming 20 MWh.
Commercially, PEM electrolyzers are available with
hydrogen production capacities ranging from 0.27
                                                                            Here are some examples of commercial
to 1.05 Nm³/h – suitable for replacing pressurized
                                                                            configurations:
hydrogen cylinders – to 10, 30, and even up to
30 Nm³/h.
                                                                            • Alkaline Electrolyzer (AEL):
                                                                            • 15 Nm³/h with 1 stack, energy consumption of
Medium-sized units fall within the range of 100 to
                                                                              5.4 kWh/Nm³, and a power rating of 80 kW.
800 Nm³, and large-scale plants with PEM electrolyz-
                                                                            • 100 Nm³/h with 6 stacks, energy consumption of
ers can generate up to 5,000 Nm³/h. Alkaline elec-
                                                                              5 kWh/Nm³, and a power rating of 500 kW.
trolyzers, on the other hand, can range from 50 to
                                                                            • Proton Exchange Membrane (PEM):
19,400 Nm³/h.
                                                                            • 300 Nm³/h with 1 stack, energy consumption of
                                                                              5 kWh/Nm³, and a power rating of 1.5 MW.
But what is Nm³? A normal cubic meter (Nm³) refers
                                                                            • 5,000 Nm³/h with 10 stacks, energy consumption
to the amount of gas that fits into the volume of one
                                                                              of 5 kWh/Nm³, and a power rating of 25 MW.
cubic meter at a temperature of 0 °C and one atmo-
spheric pressure (1 bar). Keep in mind: 1 kg of H₂ is
equal to 11.12 Nm³.
       To mitigate the effects of the converters’ reactive               For splitting liquid water, a voltage of 1.48 volts is
       power, filter circuits are incorporated into the sys-             required. This is the voltage at which an electrolysis
       tem. Additionally, the power grid needs to be stable              cell operating at 25 °C can function without produc-
       enough to endure the reactive power, potentially ne-              ing excess heat. However, commercial cells operate
       cessitating the installation of compensation sys-                 above this voltage and generate excess heat; in fact,
       tems such as Static Synchronous Compensators                      the actual cell voltage is typically around 1.8 V.
       (STATCOMs).
       —
       Power supply for a system with several electrolysis stacks;
       adapted from Energiepark Mainz
                                                                           High voltage
                                                                           transformer
                                                                           (110/30 kV)
30 kV
Circuit breaker
Balance of plant
  power supply
    transformer
                                                                                                      Power Supply Units
                                                                                            0.4 kV    (30/0.4 kV + rectifier)
                                                                                                  ~400 VDC
                                                                                                  -10.000 ADC
Electrolysis stacks
O₂
 Hydrogen
Production                                                                                                                                                      H₂
Equipment
                                              Stack                           Gas/Liquid Separation Skid              Hydrogen Purification Skid
 Auxiliary
  Units
                                                                                                                                            Alkaline Solution
                                      Compressor Air Unit       Cooling Water Unit      Deionized Water Unit   Nitrogen Purge Unit      Preparation/Recovery Unit
                The number of cells in today’s Proton Exchange                                         Given that 290 cm² × 1.5 A/cm² = 435 A and
                Membrane (PEM) stacks ranges between 30 – 220,                                         60 cells × 1.8 V/cell = 108 V, the resulting power
                each with an active area of up to 1,500 cm². Most                                      would be 435 A × 108 V = 46.9 kW.
                PEM electrolysis stacks feature a rectangu-
                lar-shaped cell design and operate at temperatures                                     In AEL stacks, the current density is much lower, in
                of 55 to 70 °C with current densities roughly varying                                  the range of 0.2 to 0.8 A/cm² and 1.8 V per cell, and
                between 1.4 – 2.5 A/cm².                                                               the active area is in the range of 10,000 to
                                                                                                       30,000 cm².
                Therefore, depending on the stack configuration,
                PEM stacks could require from 50 V to 400 V and up                                     Here an exemplary performance for a single AEL cell:
                to 3,800 A. For instance, a commercial PEM electro-
                lyzer, with an active area of 290 cm² and a stack
                composed of 60 cells, provides 10 Nm³/h at 46 kWe.
2.50
                                      2.00
              Unit Cell Voltage (V)
1.50
1.00
1.50
0.00
Compressor Transformers
                 —                                                        Scrubbers
                 Example of 2,425 Nm³/h block
                 made with 5 × 485 Nm³/h AEL electrolyzers
In total, there are 416 AEL stacks, each one compris-          This redundancy ensures that if one section encoun-
ing 258 cells. The cells are connected in series elec-         ters a problem, the other can continue to produce
trically and the fluids run in parallel.                       hydrogen. Hence, instead of 423 or 422 stacks, it is
                                                               more efficient to consider 420 ÷ 2 = 210 or 416 ÷ 2 =
In this case, the cell voltage is 1.75 V, the current          208 stacks per section.
density is 0.175 A/cm², and the active cell area is
29,077 cm². Therefore, the stack voltage is                    Moreover, the plant is segmented into power blocks,
258 × 1.75 = 452 V, and the stack current is                   each consisting of a transformer, a rectifier, and a
29,077 × 0.175 = 5,088 A, which gives a stack power            certain number of stacks in parallel. This arrange-
of 5,088 × 452 = 2.3 MW.                                       ment reduces the capital expenditure (CAPEX). The
                                                               design includes either 26 or 30 power blocks, each
The goal is to develop a plant of 1 GW, or close to            with 16 or 14 stacks, respectively.
that value, with an optimized layout. Given a security
factor of 20% (considering voltage variations due to           With this configuration, we have 2 × 13 groups of
the grid and the min-max voltage of cells during               16 stacks, totaling 416 stacks, or 2 × 15 groups of
lifespan), the High Voltage (HV) Transformer could             14 stacks, totaling 420 stacks. A group of 16 stacks
be 230 kV.                                                     requires a transformer and rectifier capable of sup-
                                                               plying 452 V and 16 × 5,088 A = 81,408 A, while a
So, 230 ÷ 1.2 = 191.6 kV, and 191.6 kV ÷ 452 V = 423,          group of 14 stacks necessitates a transformer and
which represents the maximum number of stacks.                 rectifier capable of supplying 452 V and
Hence, 2.3 MW × 423 stacks = 973 MW, providing the             14 × 5,088 A = 71,232 A.
total power output of the plant.
                                                               This solution could optimize the plant’s operation
Additionally, the plant includes various auxiliary             more effectively, compared to having a transformer
voltages. For reasons of security, resiliency,                 and rectifier for each stack.
—
Major stack specifications summary:
                                                             Alkaline Electrolyzer                      PEM Electrolyzer
Parameter                                   Current KPI                Future KPI         Future KPI          Future KPI
Plant size (MW, DC basis)                             957                     960                960                960
Stack size (MW)                                        2.3                     10                 2.5                10
# of stacks                                           416                      96                384                 96
Cell voltage (V)                                      1.75                   1.75                1.75               1.75
Current density (A/cm²)                              0.175                   0.75               1.50               2.50
# of cells                                            258                     258                258                258
Stack voltage (VDC)                                   452                     452                452                452
Stack Current (A)                                    5,088                 22,124              5,531             22,124
Cell active area (cm²)                           29,077                    29,499              3,687              8,850
Actual cell area (cm²)                           34,208                    34,704              4,852             11,644
Operating Pressure (barg)                             0.02                   0.06                 30                 30
Stack production volume (GW/year)                       1                       1                  1                   1
Purity (%)                                           99.99                  99.99              99.99              99.99
Oxygen limit                                    <5 ppm                    <5 ppm             <5 ppm              <5 ppm
Moisture content                        −65 °C dew point         −65 °C dew point    −65 °C dew point   −65 °C dew point
—
Current Alkaline: 1 GW Alkaline (2.3 MW stack), 2 sets of BOP, simplified layout
                                                                                                                                                                                       Vents to atmosphere
                                                                                   Valve                                                      Valve                            Valve
                                                                                                  Gas/Liquid                                                                                Outside facility
                               Rectifier                                                          Separator
                               Transformer                                                                                                                                                        O₂ Vent
      Power                    x28
      Transformer                                                                                                                                                              Valve
                               66 KV AC
      230 KV AC /
      66 KV AC                                                                         Valve                                                     Water filtration
                                                            16 stacks
                                                                                                                                                                    Valve Filter                   Transport
                                                                        Group 1
                                          Rectifier
                                                                                            Dry cooling/                                                                                          Tap water
                                          452 VDC                                          cooling tower Circulation
                                                                                                            pump
                                                                                                                                            Lye tank                                 Water
                                                            16 stacks                                                                                                              treatment
                                                                        Group 2
                                                                                                                                H₂ buffer
                                                                                             Gas/Liquid               Lye         tank
                                          Rectifier                                    Valve Separator Circulation scrubber                     Valve                  Valve                      H₂ Vent
                                          452 VDC                                                         pump                                          Compressor
                                                                                                                                      H₂
230 kV 3 phase
                                                                                                                              Valve
                                                                                                                                                          Deoxo                           Valve
                                                                                                          Valve
                                                            16 stacks
                                                                        Group 25
                                                                                                                                                                    Dryer
                                          Rectifier
                                                                                                                                                                                                  H₂ Storage &
                                          452 VDC                                                                                                                                                  Transport
                                                            16 stacks
Rectifier
24 VDC
                                                      110 VAC
                                      380 VAC
                   Auxiliary
                   Power
—
Current Alkaline: 1 GW Plant Layout
                                                                                                 KOH        KOH
                   Gas / liquid separation                 Gas / liquid separation             Scrubber   Scrubber                           DE-oxo        TSA Driver       TSA Driver
Compressor DI Water
Indoor
AEL stacks
Rectifiers
Transformers
                                                                                                                                                               Indoor
                                                                                                                                                               System Control &
                                                                                                                                                               Offices
               LV protections                                              In a 100 MW electrolyzer plant, the power consump-
                                                                           tion for different systems is as follows:
               Protection for low voltage components is primarily
               needed in the rectifier (on both the AC and DC              • Circulation pumps consume 98 kW of power,
               sides), the compressor, the cooling system, the             • The process cooling system consumes 892 kW
               heaters, and the water purification system. It’s also         of power,
               necessary for all motor starters required for the sys-      • The gas purification system consumes 207 kW
               tem’s pumps.                                                  of power,
                                                                           • The compression system consumes 2,600 kW of
               Typical voltage levels within the plant include               power (considering four four-stage reciprocating
               24 VDC, 110 VAC, 240 VAC, and 380 VAC. Depending              compressors, each using 650 kW).
               on the plant design and stack configuration, the rec-
               tifier might be designed for 400 VDC or even for
               voltages in the thousands.
Utility 1
Emax 2
Tmax XT
Molded
Case Circuit
Breaker
Tmax s800
AF
Contractors
                                                                   OS switch
                             EQmatic              Tmax             fuse unit                                            Tmax XT2
                                                                                                                    Ekim M Touch LRIU
Emax 2
Air Circuit
Breaker
                                                                   Pump or
                                                  Pump            compressor                                              Pump
Manual
Operated
Switch Fuses
               Measuring & monitoring                                                              Moreover, it’s vital to relay other key measurements
                                                                                                   to the control system, such as water consumption,
               Measuring voltage and current is crucial, particularly                              energy use, and the status of various devices,
               for monitoring the degradation of the stack and/or                                  among others.
               individual cells.
M4M
Network                ABB Ability™                                                                      ABB Ability™                     3rd Party System
Analyzer             Energy Manager                                                                     Edge Industrial
                       ABB Ability™                                                                        Gateway
                      Asset Manager
ABB EQmatic
Energy
Analyzer
                   >160A: M4M                     Energy meter                  <160A: CMS current sensors compa-                            EQmatic(1)
                analyzer with stan-                                             tible with any MCB (ABB or 3rd party)
                dard CTs compati-
                 ble with any load
S200
Miniature
Circuit
Breaker
                                         3rd Party Devices
Insite Bus - Plug & play flat cable (max 96 channels between sensors and I/O channels
ABB Ability™
Asset
Manager