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| _Rocks AND STONES:
on ee ee
earth mmalenial which are dl in fr 6
Rocks > he ib of the earth's crust having wo dil shape
| and shuclure.
Some’ &3 the rock. loving ontneralle are! quorly 1 {elspar, midi:
wat ek tog
The. various pes. o yooks ( hide 4 alt shones ore vsually
derived ave granile, Vn eee prorble ssl y acer and
limes
Rock - fo siienst
Some f the important vip fs rit vale ore,
(2) Hardness * dy is iascerel by serakeh! ing, the mineul with o
Sodas sabskanees knowin | Dorickion in hordness using
the following seale 4 Mohs . :
Tale, cosily sevalched ath “hee Bowl nail . 5
Gypsum, scratcked by: the} thumb -nait 2
Calcite, not seratched by Haba bak easily ct by bal 3
Flourile, can, be cut Booly with iifealhy i, knife Me
woh ct ealti e 2
— Apslil, coo be cab only ih duly by lene 8
| Orthoclase,. can be cul va nife, with great diff [fieuhy
on thin e es
 
Suovk, not ain by shee, xd dese ae
"Tepes . 8
Sopphive i q
Diamosd saree 10°"
Clave: 4 the measure Whe pal bili ome minckals
“He 1 cwlein planes tm gr 4a faThe vavious types heovage deen in the mineale ave Basa),
% malte, Cuble Then lel ond Oclahedsal a
OSheak : BY ts the tolour of the mineral in, pouty {oe
Stree ewe be veably shsewd by, seeing | 7 0
4 Sreak plate mode 4 anglaged lhe eo enel a,
elour 4h is a valuchle bropery. Yor maallte minerals , bub
i less -rchiable fr non-metallic minerals - :
} © tushre : 4 \ Wine on the rf ace a mineral & its ‘
! eee oe reflected we ia as vilveous Gli)
i greasy penly, resinous, dull, sie avd metellic. :
4 ® Cyst) : “The crystal form is ct imbortance when a mineral bas
| had: the oppor bunihy b devilop ils naluira shape - This ic,
not Ye ‘ose condi on i jock shudure »
Most comnion minexal constthients a bulldi ng stones +
CG) Quartz (Si0}) - gilicon'dtonde 2. ;
Gi) -Palspar —Alumino silicates wolff potosh (orthorlase)
£4+ Ks0-Ab Os B02.
Alumino Slicabes with soda (Plaigioclase
ae
(iif) Mica, ~ sibteales’ of ‘clurnina with hadrogen & bolash
ae Kal (alsis010) (O¥),
silicale alumina sith hydrogen “ivan and magnesia
j k (Mg, Fe! s (siz 00) (oH), : a
(iy Amphibole - silicats. ‘ft iron, One, magnesia or oluvatan
CHornblende) (Ca-Wa)o (Mgr fe, A1Ds 8: (311), Cn3(00),
Silicates of lime and “magnesia (ermolite)
: : Calg, Sis Oo oni
CY) Ryrorene - Silicakes of lime, alumina, magne sta and iron (tug
X,Sin06 : a
(Wi) Olivine - silhabe of iron ‘and magnesia (iMgiFe)> stow .(vil) Chlovales- Aluminium + silicates usith tron and rraginesi ame
(MaiFe, ade (Alix Ov (OW )e a Le
(vit) Gore + Siltcaba of iron and dlumina Xs Ys (Si00)s i ac ra
() Serpentine - Huydvous ailteale tf hag reac aq 3 8130s, (oH) 4
163) Tale - Hydroue silicale of magnesia 1g3 Sia O10 (oo
(xi) Calethe - Caltium carborale (Gods) : iy
(xi) Dolomite - Calelum magnesium eorbonate (MgCos Catos)
0) Gypsam— Ayhous ealetanc sul hate (C0304. 2440) |
(iv) Umome - Hydrous sesqulontde of jrod |
(wv) Magrelite - Ferrous and Panic oxide of iron Fes0u).,
(wi) Pyrite: ~ Son disulphide (Fess) 5 hog
Classi relton of Recs :
cha FM Racks
 
 
     
1 Quaint 2 ata fated
dyntous Sedimentary’ _shralified Fobiabed Argileteo us Cabeanious
tenis Bile 8s
Based on Geele gical Tormalicn s : 3 ues :
Ga Ae bolle ah gealogial laslon‘rocln anit casi
06 'gneous, hele 4 wd st : ar ‘|
().dqneous Rocks : allo: knewit asi, prlnary, ansled kifted” ot
_enuphive yorRs. are | voleante origin: and Vave* fornied
05 a tesalk o} solidification, af ‘molten ‘mass lying below’ or
above the earthrs " surfoce c : aes a on
| Me inner lowers of the eqrth are at o ve high Jemperalure
causing the masses of silicates to mdb ogee igekeeess
|. 6 Ris rollen mass called magma is foreel up as voleanie erup
Kansand apreade ower th lace of earth where it solidifi
?' e dur aeiuice
{ qn avd wep Te jbomy qfesive - ih {e mn
+ the magma solidifies below the earth's surface ill, thy of, a.
q Copal vork ts termed ae deep - seabed ms “f sl ee
i
  
* The exormples ave vanite syevile, dtorthe and gobliro. @nd
3 0 The principal vonslt sents af rmecqene ove quarks, tea: and {lbp te
e © He teakure of the vock ic qreally influence by the vale a ry 4
t of the magna.
: Classilicalion: +f Jqrecus Rocks +: : Ra
: Type tea, silica | ‘ i Example cok O
 
Aad Rocke 70-80 foi sit
bbe mediate works 60-707» |e -d » Syenite, a sate 3
Basie rocks 46-60 Gabbro & some vovibies of dt (|
Uta -basie voeks 30-us viddlite and some vavifieg |
i basalt & dolerite. Cit)
foes Rocks : Also: known as. digitove is shalifed ae
@ The various weathering agencies » eg: rain, sun) air, frost ‘ele. :
° bredle up the surface of earth. ‘ i B
5 ni) . as
Rain water carries down. these broken pieces fo the ‘rivers. As the COA
| therd ‘descerid down to the plains, ‘the velociby decreases gr ly . ;
| gd fee imine ibaa rock pines sand, slit, clog. debris, qi) s
Due bo the seasonal vari ion, b Asmentali in 1 kes (es 4
With Hime, the “cediwents se cralasdhidalg Jo hort Oi ee:
to the pressure enented by overlying inatenrial. § ;
+ The exams of sedimentary rocks vesullé “fom the preepitabin
of solls in drying woler basin (chemical deposi 3) bre qypse™>
anhydrite, raaanesite, dolomite, lime fafa. # ‘
*Sedirverdory. socks resulling from the accamulalion q link or Ee
Fay Crgpegenes rocks) ove limestone, Be chalk, f
ms examples ct rocks ronling from the deberionalion’ of diode. 3 J
(iC
 
 
 
   
  
sts forming © agyagnrttc ov sedimentary rocks Gragrertel socks) sro eonbslonts sand,
domingo tocde ol We
 
che. |Orece
the sali ce the "Tel om fowiad ‘ety igniove or ebienlen
" : fov'es pie aa af! the [| i the i toverninle, 2
: | semperal oe changes» lid) presores, ee.
and felspar | a: Shite, qneles, echist’ and phyallite or non-{olialed shuckure,
we coding | Teg roads, quan oc ape:
Basel on Physical Chavactenises:
| | shel Pe show dis Hnel- lagers, don ‘Whith the voces
el et  . greets oi cee) ner cla
# | i) Unade tilied Rocks do not “show a half ec and ‘amet be
Aas cota 7! |
a waton of 4. aes basalt! rap, ete
‘ ap ail 5 deliile
het = pe aes an Pode a a oa shuclae,
J socks exeph for quarkle ond marble which howe gronulose aheader.
ost ete
Sl acl a Chemical Characteristics .
foere. BS. the CoArgilaceous t The prinipal covsuenl. i ror (aos). The ‘ths
na peel | are hard and, brite, eq: slate, laterite
br
p day. debris,’ (5) gietous + The principal. constant te silea (3103); te.” sand. “The
det ar ay tal as Ped eg ve alae
i : layers. quartzite gretss, syenite , the.
i (tii) Calearious ? The piindpal cee 's Une, oe cbinestones marble,
iin lomite, ete. :
ge Some typical rocks 1 ’ n'*
© areous socks = Bo
Lat oy 1-(b Granile
: chalk, | * Origin i Granile is dg neous 4
| . : has low ot (hous much povous or yoids are the in
oe . We tere) alvin:* Seralch resistant
. haa shruchire ate
-odt te mote up a4 quetty. — a Hornble
Bre grain crystal » “
+ Comes in wuulliple etloura .
ttlod fo worl with and not for ornamental strucares.
* Generally used for flooring and kikhen tops and. albs. and
{> walls conshudton. :
* Nol very good in hol b climates .
a a.
* Compressive glvength fs fo~ldo tbo .
° oe vesishenee 4 chumieals a
t ean take Wighe issaee
(ii) Bosal » i ' 1s
* Teiture ts fine grain ae : x .
. High She 4 Een sett
* Range | ig 10-180 mpa a(Sor “sound wo) Frag
« Glour is ve aptly rey bo, bloc dt does, inch Odeuty..in mle colo
* Scratch vesista
eless borous:. i
. * Good resistance bo chennleals
* Typically locks blue when it ‘comes’ in ‘enlac with ata
7 Mainly used as; coarse’ aggregate ‘
© Ontatvales on Inqeous “rocks
edt j 1s also call called os blue iroekal
| | eae. rocks: : i ; ope :
C1) limestone (Cato3) :- we fo
| «Technical ial te, caleite’ “4.04 ‘
+ Originates {rom sedimentary: oe
  
   
  
   
* From marine ovigin -
* Calerous shells ave ils base .
. om marine environment .
. av " dig.
vos granular W deans fxlue- Cierra
Colour varies from while, grey fo blue. oe
Reackive to acidic solubions.
« Combressive slrenath- { sg~40 mpa Gor sound)GO Ouorkile ” i
   
edt is nol scratch. yestsd ath
* Used {or cement and nae’ monufachare .
a Bondslone -
| Se foenlrg a : ;
* Sand ei poshk ts viewed loqdher by bondin berial Like (sto. 5
| clay, th le) v 4 4d “
+ Glours vary fom reds red- aya brown, pick and blue. Most
Lo ut do: bom
* Rd ee alandebone are
* Easy: to work wi
Highly horous material»
° nae oh ahength . 26 mpa b ocr
Pre lagers ave corpse to fern sard lea
Used as pavement or In construdfon® of a bulding
Melamorphie rodks %
() Marbles =
. Ore is ‘nelamorphie
© Marble . i ie formal due be * intha morphism af limestone.
dt hos a sae fee
» Cai ig malay due is the priderninant ‘rateecal preenk in. Hhe.
marbles.)
° Green colour in ee fs. due to high regaian (m9) ee
« Black and 4 colour are due to gett .
Pink colour is due +o Manganese (Mn) .
Red salou 4 Is dus bo ron pales
od te eas fo work with,
ofl ts 18 at serateh ond chemical ratihaabe
oH has fodevale wea
. Cope deh is around - 30- 40 rapo « a
*Mainty ‘used for floosi wr bose cand ov ronaneol.
i Shean dee a {
1 shonget.
 
. Melarnor phic origin.»ot is formed i? metamorphism ef, sand stone i
#dt te herd ond has goed chemical resistance - Gaia)
. °
edt has a mosate denture elon tt i {
*Gorbressive shenath ie around 90-40 pa ; ‘
+ Typical vtolour is pink and reds i ; ‘
, . Mainly used a8 aggreqale in pave ments in 7 . &
: Quarrying of stones :
he y vom ¢ fone is
er rm part rt the natural rock { wohich sell eg
while selecking 4 quarry sile, the points fo be borne in mind: are, 4
. Availabilty sufficient quanlily of the stone of. destred gua - ¥
* Roper tonghortakon fois. : os
* Cheap local felon, .
+ Problems associated with drainage 4f vain water. ‘
“Erde import and pewnanent atrudures in the wciniby and site
or dumbing Yeluse, vo ;
> * Quarrying -To kta stone oy other idle), Srove,.quarr
f Stone “Gani Tools’ :. Grate rrmcholl) tend:
98 quarry. :
ee of the quawys tools are - wedge, m leawnmner: dtp ee:
i end" Weeds Pin, hammer, cipp:
Seabng hoon, Fambing ben viming needle, jumber, borer, claying fe
Methods of Suamying'. :
dy Encavaling 2 Stones burled “mm earth by lodse. overburden’ are excavated :
with pier anes, crow bars» ‘thisels, fanmens, ete :
ci) wedging : This methed uarying is” siitable lor costly » ; 86 (i : and
dtralefied aa: ary od sandshone ; ioe laivile i mravble
notew itabl fe javrast at tht ad
Git) Heabing + Gt is most suitable for quawrying amalls ttn :
: a regular blocks cA dtones from “yocke, such as, Aue gr
A heap offi piled and fied on. the surfoce af v0 ; fee
| emall ava, “The two consecubive fayers of the rock seperate |
becouse of uneven. expansion af fwo- layers. The loosened rock
portions ave broken info bieces of desived size and aveyenoved with He help of pike anes” arid crows bars - Slone blocks 55
ablained are very suitable” for coarse. rubble: mason). Somelimnes, intermediate
{ayers ove fo be seperated le the top and , belom layeve. Jn such a case,
the intermediale leer is heated elechically ond the expansion seperates it
fom the other two. :
Caer : ; i
welling: Enplosives suth as blocking pooter, blak edtlon, dynamite and
cordile ave used» The operations involued Save boring, charging
tamping and fring. i :
Wing: Hols ove dill ov bond the vec’ to be dislodged for haid
1 rocks, machine dvilling is employed “instead of hard drilling.
d,
charg’ The holes ave ‘died: -competel nd the ived ‘antount af cho,
pee ae hed in thejules Fo Bigg he, ay 0g fe LBA
cropper ord Is moved’ inthe Tale, {from where it absorbs the
~ moisture, tf any. Sn case ik ts. fou thak water is cogh
| into the hole, wooler —fghtness is enscred. inside the hole:
Beg :
(i) Tambing: A turn is a devise used fo. comback ‘or {latter an
bi ng: aggre i, ox another powdered or granular fate typically
t wtb hake it watstant to {ucther compression ‘ox sienply to
“focrease ‘ks: density. *
 
Waloral_ bed of atone + a
Sig, the original, bed, plane ov posihion oceupied ‘by a shone
ving its formalion tno, sedimentary rock The _atones' should be so
placed thot the food tine is at vight angles bo the nalural -bed+ Gn case 4
rnekamorphie rocks, the plane : foilalton or the plane of eleava é ls
assumed fo be its cad bed. Gt is vay ae to trace the natural bed
in the case q igneous rocks cand the natural bed is. pot qher due’ atenkon.
Beasonin of done: *
A freshly ‘al bn carries some natural moisture hnovon as
quay sap making it ofl and workable. “The! query dah isa mineral
solulton and reach chemicall wilh, the nuneral saouraee when ie alone
is exposed to atmo: here or quay ini Me tone becomes harder and
seers foie Ale ef 4 months for compete seasoning -when Mee quany sap evapovates » He leaves a ¢ shalline
\ of an ‘ke and wiakes them weother oc fibro on te
Yates
The dunt
semoning improves athe weather vesislance . e iresing blo
Dressing of alone:
pial eerie Get ele
veo Lele taal fe Bac Ett Me
pl clad Sip apd Paar cp ptt
Uses i hones: Pes 4 fey ‘ :
4) Poundalion nd“ Wall “Theis + Quarnj, split Land” sawn shones. Lom
| ec socks nae ‘used: fo erect That ablobucise of buildings es be
glonég Sawn ‘and split fe Umestone » sardstone, dolomite
; te walls, piers, abutments, ee.
| and volcanic tuff ave Us
ii) Fecing and Architectural Glens: Facing slabs and stones, slairs ard
ee tod ava ile: ave’ made ; slabs sawn or aplit fom
me: seni fad product blocks wt glossy, dull, ground, sauon,
pointed; luted oy rock finish. Foting “slabs of anil, gabhos basal,
movble, breccia, bimeslone, sandstone and voleante tn ave gherlly usd,
(iii) Building Stems : Elements of slats, landings, parapets find vais a
4 manupctured fom 4 , marbles bi ae iff el Relea sles
> and. hones: ! for So loorways, cornices and volndow- sill”
: - slabs are mode’ from the Same material os. the foctng slabs.
CW Road Construction ‘hems # Carb stones,- intended bs seperale odurys
hom sidewalks; 9. '" : oe -
Raving blocks - used for pavements ,
Gobble stone used to reinforce slopes of earth works and to
banks of water basins. 4 : é (
Cosh shone a vatelave f fog e stone vagments (<7.m™
Grove ~ Loose agglomeralfon of a Faq ren! Vio ine) and :
Sand = tosbe ross” af mineral ard. rock’ parties (ojxsm)
ablainel from natural stone are’ used tn road corshuelfor- :(vy Unde round Shruchues and “Bridges s They ave bill of slabs and shores
' " tgnevus and ee ie vhs. ‘Tonmls and’ above -dwaber
| elements of bridges are. built ‘f canite, diovite, gabbo and basalt.
| face slones and aula slabs ‘ et and bridges ore given
|
|
   
  
  
  
york face, grooved or {lute (irishes
(vi) dleat and Cheimically Resislant dhemns: These are manufacksred from
non- ated vo tks.
For high Jemperalure working eondibfons y they are ade [rom
nem basalt, andesite o fuffs. q 4 mm §
Building: elements ‘ave protected against al cot tude en
* acl a udsiltcte uals) $ wit slabs ‘mal 7 od so
: syeni and sibclous slonés Uinishoned, dolomies, marble 4
| : sragnesite show, excellent cesetance against olkalis-.
when zi emperalure-+ and chemical. flack “is expeded, cxushel
stone and atcand fw concrele, and mortay dre used -
| Aphlicalions of slones «
Naural skon pide ls}. possessin high resistance to atmos phe To
Nate hah Jakes ake a  eind he are vol i
| used In tonshuclion | as labs for walls and foundalione t
buildings ard installations, as fact slabs ‘and shones fox eocterior
and intentor walle buildin and installations , for roads,
side walks, piers, unloading’ walls and other structures, where
» mechanical Ling, duvabi ty and decoralive requirements ave of
concer, i, .
| oy Foundalfons and walls of under round parts of buildings are made
om quarry, split and sawn stones from igneous, sedimentary ant
one 4 4
metamorphic. rocks . :
By Slabs for floors and focin walls are -reckangular> their
an { ending J he ‘kind af rock ee the {roish.
4¥ Paetng slabs and shoes , parts af clatre and landings, parapets
a uard rails are made slabs sawn oy split from natural
‘glone® and worked. by mechdnical means.
5° Pedestal slhs and shones Jor Jraming: doorways, belts of cormices |
' corner, and uso ath “iat jb into ihe closer, phi i
fog elements.They ove Prana fachired
finished ma gree
8¥ The materials and hom natural stones used tn toad Consul,
ave unbstomes, paving blocke, bewn alone or obblestone , ovushed thoy
sand and mineral pide
vy Under round shrud Ures and bridges ave bet af slabs -and shone,
fen the same material as the foring slabs any
‘
vane! OP wayge ¢
|
foim “Taneous and sedimentary rocks, tunnele and above wal
‘ parte bridges are buill of res diorite , gabbro, diabase and
basalt wilh combressive sheng nok less then 100MPa.
8¥ flydraulie -dhruclares at generally built with the natural stones
ular_or irregular “shape “(heun, rolled, eut> sewn, ard alan
ow ‘shone) from ees = Geers or’ sedtmientary rocks.
1% Gushed ‘sone “and : sand is sed ' for preparing mortars and
coneretes, fp making “road ~ beds and “drainage. constructions.CEMENT
Crnenbs Ma general sense are adhesive and cohesive inihertate ahh are.
capable of bonding together particles of solid matter inko a compac- durable
mass. For dil oe works, they are restricted bo calcareous cemerits
cing cmpnde Loe. Aur chi onslaet he priory de
being fo bid the fine (Sond) sand. coarse (grils) aggreqole poli
togdher. : : ie
Gments ysed th conshuchin Induste be classified rouli
and non—h raul. ‘The latter does : { 4 a nl tS ee
non- hydra te Lime ‘ov which ave unstable. in water, eq. Plaster o
Te h draulte cement” set and hardin. in waiter and give a peduit ie
ts idle. Totland cement is one sath. ud
Cment can be rmonaadied either from natural aa stones ‘or
axl cal by usin calcareous and argillaceous materials. ; :
Foy example - natural ‘ceminle are Roman gemenk, Pugzolana cement
and Medina cement -
Arteliil cements are Rrtland cement and special cemenks.
Paatlend : Cement
Sis a cementing material ‘resenbling a natural stone quarsied
from ‘Patland ‘in Uk, Portland cement may be ve as a nak obtained
by finely pulveriging® clinker: produced by caleina tng to Incipient fusion,
an intimate and properly perbportioned maixture” of argillaceous and
caleartous materials.
Care must be exercised in proportiontng the raw materials’ co that the
clinker of peper conaldion moy qr PeUatnele dffr bortng. = ™
Palland ceme i is draulie cement Cor ed mainte caleiuma
silks, cba ‘y hela! mebcture, of Uimedlone and Lf tina kil -
at Ioo -1600'C..
Linestone (cacos) ts the most common sdurce ¢ caleium cade (lie Cad)
Gron-becxing alurninosificates ore used a8 the -primary sociree of silta
(803). Clays ore prefered due fo the finely divided Stake. The’ alutninum
| iron oxides ack as floreing agents (ten decrease the fusion temp:).) S lens in roduelion :
&) Selechon Ng mnaleriale
CH) Grind comet sige
G) v1] Sai : : ae
CW) Roduclion of cement clinker by kiln burnin if bleided ‘aw rch
(©) $rkrarinding with ue to produce Rattan Cement,
“The ordinary Paitland cement has been classified as 55 Grode,
43 Grade and ° 55° Grade :
OPc srtecssiee om A b F elissifibion bosed, on 28 day
 
Compressive’ ength .
: Category . di OStrenath (pa)
: A. 32-5. 375
8 375-428
é ADB-A75
a) ATE BBB.
E 52.5 - 575
E 578-625 - : :
oye, Tae ye ene ets Nee
{ However, most of the 43 ~-gieide cements available’ in the ;
market fall in ealaqory D: and thal? 83-grade cemenks in catagory
gy Pe ih cad meee aaa
Cement Composilion ° . * ¥
Chensical enepittion ef poland Cement
ade at Ramadan bast btn
tao (C) Conkols shength and soundness. - 60-6
(Gee, calcium onide) 4s dfdeney reduces shrergfh &
setting be: :
 
 
 
  
sio, G) ives’ shength. Excess “of tk causes Ar 98
(ao a sng cet AK
a eho eat x -
ona 3O3, 0D, esponsble for aletorselling bin guess, 9-8
‘tk lowersfos0s (P) Gives clour ond bulbs in fusion of
(eno fewie oxide) different a0
mao (M) ——dmborks colour ave baron df in 05-4
(Magnesian magnet’ — excess, tk causes cracke fn, mortor
oxide). aml concéle and unsound nese
Nos0 + KO (k,n)
ie 0.5-1-3
TO. These ave ves\durs, and | in excess 0-0-4
BOs cause (florescence and crac ing OA-0.2
305 Makes cement sound 1-2
WO. © 1 ee
(toaker eg = Fal
Nokes 5 (1) The vate of geting of cement be controlled b
: “lage ah ‘805 (00> *fes03). .
_ CB) Whee development ah much, heat of, hydrabion ty. undesirable
silica aay ig increas to, about “Ol per cent, and the
dlurina and ion onide contents ore Limibed to 6 per went
shoal coda ste ebyer de acest ue
“(lil) Resiclance fo the ction’ of sulphabe walete 12 trerased by
“raising ‘forther the silica conkent to 24 per cent and reducing
the dete and ‘on cine to 4 per | ines
© + Ct Gmall* percentage of tron on'de rehd exe, the i siliceous
oO By verals cae bo bard. Hewett AAG Se e
Cxcess 3 a‘ hard’. clinkes, difficile fo ground is produced.
s fon fest oie with lime and’ zine’ k
+ form CaAF, ib reubralinés some. “el the ‘undesirable properties
“contribuled: by alumina, thew met: Livne. alone.
When trononide Combines” with : ime alcve, it promotes
instability... *. sued
- (a) The alkalies * accelerates the selling rt cement poste .
Compson’ of Gmnnt Clinker
Chemical formula -« Nolalion Marre Typical why.1. 8G0.8i0, “Cs8 “Trtdadedum alteae , Mite 4-6,
9. &COO.8i05 C8 Dicaletum ailieate, Belibe 15430
3-3Xa0-Ah0s Cg” “Tlealelum Aluminake 6-1
4 400.AbOs fes03 Cear “phatalelam Alumin enite 6-8
&- Ca80y- 2420 csH, = C; sum, Caleurn sulphate 3-4
‘ar il
  
 
Nydbalion o af Cement Cinenk? :
Ee “© The chemical eal belueen cement and wader is hnoian ng
a ¢ cement. nk. takes place belween the aclive ‘oreo,
cement Guat, CsA, C38 and C8) a ated
© When the cement comes in contack: with waler, the hydration
ii start Beall onthe outer periphery of the nucleus 4
| we ole a Te Pe prowede duly p> 25 hours and i is vale induclon
' ds oo ralion voceeds, fy deposit bein lise on The
1 inet cement ro% of hes the di it iat Al Eh dvated 2
hablo a We and more. dif, oy cae “a vale et
At any 3 hudralion,, the, amet poske consists 4 ef (a ne~
| i welt ba eh te having large Seirface ared i dak fr
unreacked cereal, calcium hydroxide, water. and ‘some minor compounds, o
. The or stals. the various realle com ounde raduall tl ‘
the space sat ae by water,: vexing X the Mn
mass and subsequent, developinent © of the strength.
The reactions: “of the compounds and thelr preducls ave ‘as follows:
C58 + H20 —» C-8 -H* 4. Ca (oti),
O58 + Hi0 — C- 8-H! + Ca(on) a H ty who
CsA +40 —> Caf He [i ts hal
CsA + Ha04 Casog>CACS Hn
Caletum sulpho— olaminale
Fie CuAR + H2O —>CsAWe tCRH OO :product 0-8-4 tl vepresernts the calelam gilfeake hr drate aloo
oo oh ath W the gl shade.
Hydrabton ef cement
9 "rede cement wilh toaler
*Lxothermies heat released % called ‘Heat of Hydralion?”
Rate ef heat evolution ts faster f the reacton ts quicker.
* Heat , evolved depends on heal of hydralfon of individual’
| compounds! ‘
- Rate bylilon | Nye 4
o Th wearlon tombound CsA with weoter is ver fal and is
weapon fr iis ie cament (akthenin “aha sheng
development) and thes it will prevent the hydration af C38 and C3. :
. However, caletum sulphate (€as0s) pel in the take dissolves
immediately in water and forms insoluble caleiam sulphoalumina om
4 deposits on the surface ol, 3A forming. a colloidal membrane &
consequently velards Te hudrelion of C30. ;
othe amount 4 Ca$Ou is ousted to leave a Ute excess of C3A to
fnydrate diveely. pe cone ms
«This membrane. in the process breaks because of the preeessure
the compounds formed duiring hydralion and then again C3 becomes
active in the yeacton, Led : ¢
# The hardont 4 C33 con be sald tobe oa CaA and Css
becomes solely inp le for gain 4 atrength up ee by growth —
and intrecking of 6-3-H ‘ Te increase th shenglh at tie age is due
to hydvalion df C28. hee “ — ee
| fnew 8 Iobermortte
4
bor —
   
       
ia’
(
4 Sapa
ea m4 hag O08 (
fe a as—s |. =
. i 06 {
t |
40° , * if ot
( (
“20 i cE on
g \
be A ont slag Vine (days) (°°
& AP | Rate ath dralien of Pure
#0 aay Goren! Grmpounds
Gorhtbolim Comet Cot. 2 Foendhol cmanhWater vequirenrent fo hy hy dalton : i
|
* Abouk an auey J (ou nh C39, 9 percent 3)
age ¥ ane perce
wrk by wsighl of eb (r fr conplbe Iybbfon ihiond
cement.
om anhy combines chemically with the coment, _tornpounds and
& bee a boun water. .
*vome quanli f water, about 18 percent } it at
| reguired by it the 41 qd pores and i taut on dhe
* Therebove, a lola 38 po ent ct water " we'd b rp od
veghired to Com} ste the Nani reathton.
cemenk tg requir
Effect ond on bial propedigs:
| *GA* responsible for edling dnd early Strength ; poses a ty.
oe toe ae ay
C53: early strength gam; high HOH 2 raw
6G St allimale sbrength 5 low HOH”?
oe Fre the cement, faster the crate o f. heal Ile and wil
and setting and carly shrenglh gen - Z
Poduche of hy drabion of cement : ;
*Caleium shel fay drabe Lap vale cong ng sn
# Calcium | hydroxide GH) +
)
|
|
fownalion of Calei ume aa: fiydeabe’ ae :
C3 + 7H —> C3Sstls + SCH a i
Moderate reactton vale, gives hile shength and hea thera.
30,8 +51 —» CaSalla +cH (AN -250I/9)
Slow reackton vale, we how inital but high tater shang ond
fow heat lberalton :
Calcium silicates (C38 +003) + waler —> c-s- +cab%)s
 
Fovinabion f calcium sulphoaluminades : ve aeEAtringite formakion :
Caf + BCBN, + 96H ——» CcASs Has (n-- 1672 12 5fh)
Edvinghe, in the absence of gM 5 reacls further to become
monosul foaluminate baie
Bee aa 4 acgA +A —> 3CyASHn
Overall reathton +
CsA 4 CEH, + 10 ——> CyAS Hn (AR> tan 1g)
formal on eh Cal Calcium alumtnohydrate : :
CyuAF + H — +» CAH 4+CF
| Chebracaletum aluminate hydrate)
aa may also veacl with gypsum as C3A doce, bub it ic
much \ess veal ve.
Tests on’ leon’ hydvaulte sata :
Ci) Speci te ah
hes s ethic’ qravt hn dy juli ce > if blained usin
le Chale ia gravity of hydhdubie cement ts
© Geourd glass stopper
 
 
  
 
 
 
: i; ‘a capaci hy at 20%
 
Two 0.' rat e
graduation ‘extending
above and below
ee xe mark
Fig. le-chedtelier Flask
| for Specie. Graviy TekCondilions A cling Specific vavihy _
= Gounte i cal af won ontde have 0 tithe
Specific grauily.
«The fect , {ineness of rind upon pee
Very finely re cement h thay ‘ have lower specific grou,
Seasoning is the chit cause of a low spect tc graurfy }
ey nt 4 2 : 4 4 ‘
Tet bro cedure :
_ The flask sled with ether bersene fee of te,»
naphtha wing a a gravity nok less. than * o-taia to a point .,
Be slem belween Joo ands demnl mark . ia
* The flask is Immersed Ma constant temperature wale bh and
the reading is recorded. ents ae
A weighed guank E (about 64q of PorHand Cement) i
( 3 juan cemeni (al 10 of
Then introduced i me om at the fee fempeahe..as thal
of the gud. een Seg aed
+ After inbroducing all the ment, the stopper. k laced | the
and e flask dled? in an indindd Pia a pa “abil i
is drde, so as ng ’ :
gravihy Ic sh, n
te the erent - vom aly uniif ne fh
aw bubbles rise fo the -surlate Phe iad Sis. ie
+The ask ig Again immersed m the wanker -balh and the fia
i reading ds veorded. o , fe fe tt aoa
a. The difference blu the fies and The fal reabing epreserts he
Mi, of tiuid aig) ted by the sacight af the cement used in
Speci it
pect € WOU ry :
q ‘ ‘Displaced Valine of (qa in
  
 
(1H) Fineness 5 :
The degree of fineness
Size of grains in it.
 
of ument the’ measure of the mean
HellGlo Alfecking Prenese +
+The chemical composibion and the de ree. rt caltinalton.
sf the hardness of the clinker and Consequently the fineness to
hi e cement jg ground.
+ Clinker, high th tron or ailica
vt e re and ditle
grinds The same! 6 tue eth a hag} po ft hard ard diftadt to
ard - burne thinker.
/ eS 8 also in luenced the time of grinding and the
charockey of the ends machinery. im { 4 ga
°H hos been Jound that | becomes finer voifh age prowiled it
' does not absorb i uch mele Rent due fo the Lp Se
et e he grains resulling from: the hydralion of 7 bd
ina barkiles.
| mporkince : : :
| saber fe ermal more is the Areva Since surface area for
* Wilh i crease in lineness, the earl levelopmen trenglh is
olowid tub the “ined I oh eer tes
is not allected
An e‘e In the? Ineness of the een Increases the
ohisberes:o ‘onerele “min and Pt, luces the amount oe
r nak Sepert to the top a “tft Cleedi Sys ancl ‘t
a chr with vibralors. 4s ‘ ee eee
: «However, if te temenit is aad be yonal a certain limit, te
ementalive: ae ties are’ a. Ue due if the prekydralion by
a sp! erie moisture - %
Rner ‘icement: reocks yer dtronal in alkali vache 4
Also, the water rplament and oo IH
rin
re abe.
499 rte
higher drying th age and crack ing.
will be more ng
Sieve Mathod : 400 4 ‘ cement sample i IB ha ard ahead | wns, it
: any, in the Sample are roken ool fingers. “The sample 's
ploced on 6 0 micron sieve and continuously sieved for [5 minu
The residue should nee exceed the Uoriks vrei below :
ap=of Lerman!i Spectfie gure
Type 4 cernent aa Y hy. ve less Mane CH
q. Ordinary Rutland Cement (ore) -
> Rapid Hardening Cent (Ric) “8
3-Rrtlond ‘Pagzolana Cement (Pec) : 5 a
Gasistency Test: gh te. defined as thad pérentage wale regu
- ef the _ othe inal of, which will be such thed if
E  Vieadis plun er penehat bo a point. 5 to, 7mm trom the baton
the Vid adie | “ } :
Smportonce: Th ater vequi I ee tests cern }
F + the r Or vario vemnen’ nd.
on the saved donations aR pr vat vahich, its depends - :
the compound composilt'on i fineness of fhe cement.
atest Procedure: * B00g “6 cement Is mined with ‘98 per cent water. The
Paste is filled in the “mould 4 Vicad’s appratus and the.
rfoce of the {filled paske is amoothened and levelled. id
oA Square i needle 10mm x10. men, atlachedl to the:. plant er is
te ed gently over ‘the’ coment paste surface: and: is* televised
quicrly. ee, oe Be pe '
led il planger pines . ee pan * reading 7. the
is. recorded-
mould , the amoun} of waler odded is tonsidered”-4o° be th
Correct Percentage ef water. for normal : consisheney . *
Delerminalion a Snika and Final Sdling Times +! e
The inital setling fine may be d tned as the Hme taken to
tay by the ual to shifen +o Sud an extent that the Vieat's :
needle je not permitted to. move down through the paste to withtn
540.5 mm measured fiom: the bottom’ of the mould. : :
tke ffral och Hine ts the Hime affer which the aste becomes 30 hard
ot he a lar Hodhivert fo the needle, under dort weight, fouls fo
leave ane mark on the hardened concrele. . i
shill God’ Pcl alliage an Be thelial waplés- of Somat: ©
° When the reading is 5-7mm from the boom of theJ aportance > Ab is Ymporfant to know the inibiatl selling Woe, because
: of useful vin cries of conrertt if the cement mont or .
is place in moulds aller this Hime. The imborlance c fjral selling
He bes in the fret that the moulds san be vernoved alter this
fine The former defines the limit of handling Zthe later ddines
the beginning of development of mechanical Arength.
Cap se
Movable Red
  
 
 
   
   
rdtcaloe
 
 
“Final” Setting Needle
dried Sc Meedle
dem Square
-
: q 5omm
Cgebieh Mol gd ; i
i
lomm .
Plunger for Measuring
Noto roux ie Consistency -
skid
Scund ness Test & ‘ A 4 i 4 | Cf
gk k Kal that the cement concréke does not unde arge change
oles Sferthing. Tis enced by ining Ae weadin sf fo
Lime and magnesia wh which slake slowly causing c nge in volume of
cement (Known a8: unsound) + i i
*Soundness of cement may be tested by le-Chaletiér method or by
sulvelave muhod, For OPC, RHC, LHC and PPC it is limikd to Jomm,
wheeos for BAC ond s8¢. 1 should nol exceed Sem.
Conditions’ Alfeding Soundness + :
othe main cause fe ansoundness tn Porlland cement is the hydoaibion
tthe uncombinal lime encased within the cement parkeles.
+ Freshly ground } ts often unsound due to the presence
wronbined 3" fl ‘ : ee %Pr -Cemnerd ‘thus allowed 40 avale ( two fo three eke allosing
ime to hy vale, to overcome unsound ness .
clone BI is 9 vey jnportant fal fo aesure the mek
Soha | . pis rn ite cracks, dishor Kon an
disnke gabon, ullfmalely leading bo foi
 lenchabelies Mdhod »
‘ The mould is placed ona glass shee ond ig hed with pooh
"coment pashe formed by gaugin 150q cement with 0.78 Henes the og)
. required Oye a paste p consistenuy.. :
othe mould ts covered with a glass sheet and a small weight i
foced on the Covering dass sheet.
* The mould is then submerged tn the water at temperature
8T- 30%. offler 4 hours, the mould is taken out and the disharee
Sepevaling the indicator points “is measured. The mould) is again subrea,
én woke. ‘ 4
* The waler is néw boiled for 3 hours. The mould is removed {rors
waky- on is covled down. The distance beleocens’the «hi teator poinks is
measured ‘again. The difference between the! feo. nensiverents eepresenks
The soundness rt cement.
ure.
o
Brass npuld Thickness o.mm
  
Sndicabors with poled er
 
‘ Nati plate
Elevation
  
   
Compressive leength :
Dosis ch te bana Mls eu de cleedci,
wapre 5: 6 iS iS ra Co: gn oY
this teat, the al hy ro quanltly, sree en & controlled le and
he degree of adullevalion can be checkathe test specimens axe To.Gmm cubes having
5000 sqamm « lay size Specimen cubes cannot -be ma
| shrinks and cracks may develop.
j othe temporakne of waler ond test room should be 21+a'e.
| A visine ef cement and standard sond in the proportion 123 by
woth
_ ave of about
le dince cemen
is mined any wil afoul for one minube and then with
wattn unlil the mixture is of uniform colour. :
o Three ‘Specimen cubes ave speraked repared» The material ‘or cath cube
is mired — “The quanlilies sere standard om and water
| ove 1859, 5539 and (Phy) +3.5, res echively. Where Pe percentage of tooter
| required to produce a paske of Aordod consistency.
|e The mould & {ited compklely trith the cement paste and is placed on the
vibralion table. Ubralions ave ivnpar ke for dbout 2 minutes at o speed
id 17000 + 400 per minute. ‘| :
eo Whe cubes. are. then removed from the moulds and subrnerged in
clean fresh woler and aie taken oul just prior to tesling ina ie
compression eating machine. Compressive stren is taken bea duerage |
of the vesulbs ah the ree cubes. The load is applied starling frome
3e00 aka vate of 55) sq, erm] enlnute. |
(oo The compressive strength ts calculated {form the cxushing load divided
by the average ares over which the load is applied The vesull ts |
expressed in. Nmom™ The minienum apecified shength for some of the
 wement is “given below:
“Wpe Days i : 2§ day 3 days Tdays 238 days
Ordinary Portland coment = 16.0" 30-0 35.0
C33 grade) ‘ ;
Votland Paggolaria cement = 6.0 2D) 55-0
low heat Portland cement = 10.0 16-0 35-0
| ie hardening cement. 16.0 O15
Hig aluntna cement 30.0 35-0
ae A oe
Clow Heat Pearland: Cenment (18:t2600) 4-842
| To limit the teat of hydrabion ef low heat Portland cement
| CUR), the tricaleium aluminate component Yn=cement 1g minimised and
feole. and Jebacdiehim alinofesdle 4s
| “a Nigh! “beventaae of Mcaléhgn ill| added ‘Ihe heal of Iydralion should not be’ more than 212 and 34g
al the end of Yond 98 days vapalivel ye :
+The vale | drveopment of shenghh ie alow but the allimale sheng 3
of, ore. ‘to mel thts requivereat epriie stuloce of cemen|
h Ineveased to about 3200 en? Ih,
 
| dame as tha
"Bopostess less teal te evolued duty atlling tow tal Toland eernent ,
thon ested by le hatbey ridhod and autoclave test the pansion
thould nol be move than 1Ornm and 0.84 reapeclody. :
The minimum tribal dling Hone should not be less than 60 finds,
| cand the inal selling should’ not be more ‘than 60 minutes.
|
he Compressive ahrenglh should be os fpllouss:
; 19 £1 hour 410 lenro
168.49 houre 4 16M/row
. 6H hours 35 N/mm?
Uses: Jl ts most sullable fo lone mass concrete works such as dams,
lage roll foundalions, de. :
i : (0 "
PRopid Hardening Perlland Cement (ie:804iy hes high lime conkenk and
can be, eblained by ineveasing the C33 content but is normalky oblained
from oe cbinher by finer grinding (46000? 1¥g)-: ‘
othe baste of applicalion of vapid hardening cement (Rte) ts hardening
properlies and heat emtgsion rather ‘than adling rake.
# This permils addilon ct a lille more gypsum Ausing ‘manalockare to
contvol Ihe vale of selling. (aerate aie
#®HC allains same drench in one day which on ordinary cement mou
attain jn . a i ta beh \ ‘
etlowever, it ty subjected to larce ’ shrimka and water requirement for
worlabilily ig mone Te toot 0 mpl fo dement ny about 10 per
tent rior than the ordinan cemen
*Conerele made with ple ean ‘, 6ajtly expored to frost. aince tk mekves
4
move quickly.
Ropelies Anibal tdling line go minutes (mninuani)
final telling None 10 hours (manimurn) iCompressive shength
y Jdoy 16-0) from
5 day: 67.5 N/mm? »
tars + Jb is suilable fpr iepair of wake and bridges and when lood
  
applied in a short period 6 Hime
(iY Portfand Pagzolana Cement (18 1489) @-laT8 «
o db is manwlachured by grinding Portland cement clinker
eal pogplana (useally y ash 1-257 by mass of ppc) or by
intinalely and wl ormly lending Portlank cement and fine pusgolare
othe hardenin of Vordlant cement pug lana cement consiste jn
hydralion of Portlan cement clinker iat) and then in inberachox
the pug zolana twith caletam hydronide released during the hardening |
A clinker. At the same Hme, caleiumhydroride is bound into a
water-soluble calcium hydrosilicate according fo the reaclfon
Gol), + Si02 +(r-NH2O = Co0-Si02-9H20 .
vith the «effect that pe olana . Perl, id [ i hey
a 330lana Fortand eemen tives greater .
waber— resisling property Fn ordinary Retland puis i
Vepokis: Tse fave Lower seo donbpmect | thonth bul lle
: 4 renglh 6 comparable eoith ov fnary “Portland sarnint
Compressive Shengh + tbr 16-0.Ni fantn2
4 163 xo hrs 29-01) enn |
; 6ri4brs —  33.0N|/mm* |
The milial ond the tral selling Himes are 30 minubes (minimum) and
600 minukes (wantenum rresped ively oe
Tre duying chrinkage: should not be more then 0.157. and the
fineness should not be i than 300 a'}kq.
Uses 4} has low heat evolubon and is used in the places of mass
concrtle such as dams and i places of high temperabeve .
Civ) Rutland Slag Cement 18.488) (V6 3
J
# Gb is manuladured either by inkmalely tntergrinding a. mirture
4. Brlland cement linker and ranulated syle slag with addition of
ypsum oy caleturm sulphate, or . an inkimate and uniform blending
eg Portland cement and finely ground grancilaked leq.
betta# Slog & a non. metallic product consishing esserkially of gloss i
si x and alunino - silicates of ime and other bees as fe hen
blest furnace dla i which ts developed simultaneous y with hee » i
nace pic pig leon furnace . : r
Merah igh dled by Jeter eso the len
rat chilling oy quenching Yt with waler or i ond air.
“The slog cénstihvent ‘nm the cement varies belween 9 to 65 Pee
Repories : :
*The chemical Yequiremerts of Rutland ala cement ave Same as tl
35 grade Ritand cement. ie sped surface of alag cement should nd’
|, be less than 225m?/kg. : :
| ° Te: expansion af the cement should not be more than 10mm an
08 Per cent” wshien tested be le Chatelier method and autectave test,
respecliie : a j
ote initial and frxal “adking Hines and compressive strength
ee ore same as that for 3s grade ordinary Porlland cement.
Uses > This cement can be “used in all places where OPe ; d- However
Reams ais low at of lon tm abe baad
fe mass conereling: e.g dais, foundalions, ete. : :
ASTu Classiffalion (e 150)
elype tz General Purpose :
* pe W Moder ably silphale resislan, ‘and moderale heak of hyralion
pe ms High early vie ;
Type 1V: low: heat of hy valfon
o Type vi Sulphate resistant.
    
me
 
 
  
‘ “Typical : Gmposthion
 
 
 
ie a ASTM Compound composifton Y
; Wpe C3885 CsA uae
t T 48-63 | 20-30 | g-m2 | 6-10
? 40-50 | 95-35 | 5-7 | tori
ai 50-65 | 18-95 | 8-14 } 6-10
 
 
 
iv 95-35 4o-Bo 87 | to
a 40-50 | 38-35} 0-4 | (0-20:Win relation bo Type D cement... ere eee
i o Type 1 has marginally lower C38 and C3A
Fo Type has marginally higher 38s and a {ineness
ope v fas lower C38 (lower than “Type Ml) and coh
» Type V thas Cower CsA.
Blended cements (ASTM C545):
+e Torkland Blast -funace slag Cement = Type 18 (Slag ie 95-707 by mony
|e Portland - poggolan cement - Type IP (poggolan content, 15-407. by mass)
| eBeneits. fi .
a d3golanic reatlion 5 addional es
Pore refinement
~Gnereased Aurabilily
Special Cents =
(Based on plxpose or use)
nt) Supersulphaled cornet +
eBlast furnace slag + gypsum +emall amount af Pe clinker
es +707.
o Hig resistance to salphates ard marine environments
+ Very slow setting and hardening + low heat of hydrahton -
(8) tohite cement :
2 Architectural Purposes
+ lowered ivon contents in the clinker
+ Pigments an be added to get_ cleared cement .
 
 
Concrete ~ Papen Vs Cost
pS rh
Cement | 707.
 
 
 
 
Coarse
aggregate
VoluMEy = cost