Biology
Biology
- In absolute zero molecules don't make at all 0° K (not only water but all)
- melting point - solid to liquid,
- boiling point - liquid to gas,
- water can attract or repell water mollecules mealier
- water being polar can make hydrogen bonds
- one water molecule can make four hydrogen bond (intermollecter forces of ar attraction)
-hydrogen bonds are less strong than chemical bonds
- in freezing point every water molecule has 4 hydrogen bonds (form latice)
- in gas state there are almost no hydrogen bonds
- hydrogen bonds exist in solid and liquid hz0 state
- ice has lower density than water so it floats
- ice isolates lower layers of water from cold so that aquatic organisms can live
                        A 1.1 – Water
“What physical and chemical properties of water make it essential for life?”
“What are the challenges and opportunities of water as a habitat?”
                                                          Students should appreciate that the first cells originated in water and that
                                                          water remains the medium in which most processes of life occur. Students
A1.1.1   Water as the medium for life                     should understand that polarity of covalent bonding within water molecules is
                                                          due to unequal sharing of electrons and that hydrogen bonding due to this
                                                          polarity occurs between water molecules.
         Hydrogen bonds as a consequence of the           Students should be able to represent two or more water molecules and
                                                          hydrogen bonds between them with the notation shown below to indicate
A1.1.2   polar covalent bonds within water                polarity.
         molecules
         Cohesion of water molecules due to               Include transport of water under tension in xylem and the use of water surfaces
                                                          as habitats due to the effect known as surface tension.
A1.1.3   hydrogen bonding and consequences for
         organisms
         Adhesion of water to materials that are          Include capillary action in soil and in plant cell walls.
A1.1.4
         polar or charged and impacts for organisms
         Solvent properties of water linked to its role   Emphasize that a wide variety of hydrophilic molecules dissolve in water and
                                                          that most enzymes catalyse reactions in aqueous solution. Students should also
A1.1.5   as a medium for metabolism and for               understand that the functions of some molecules in cells depend on them being
         transport in                                     hydrophobic and insoluble.
                                                          The abundance of water over billions of years of Earth’s history has allowed
A1.1.7   Extraplanetary origin of water on Earth and      life to evolve. Limit hypotheses for the origin of water on Earth to asteroids
 AHL     reasons for its retention                        and reasons for retention to gravity and temperatures low enough to condense
                                                          water.
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        (cytoplasm) from the ocean water. Cell membranes                                             i
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Hydrogen bonds in water due to polar covalent bonds
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              electrons are pulled closer to the nucleus of the oxygen atom.
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                                         http://www.ces.fau.edu/nasa/images/module_3/WaterMolecule.gif
Hydrogen bonds in water due to polar covalent bonds
 The unequal sharing of electrons in the covalent bond
between oxygen and hydrogen causes a partial positive
charge over H: + and a partial negative charge over O:
                           -
Draw the structure of a water
molecule, clearly showing
electrons and covalent bonds:
Hydrogen bonds in water due to polar covalent bonds
 Hydrogen bonds are weak forces of attractions, which are
  formed between the opposite polarities (caused by polar
 covalent bonds) of adjacent water molecules. The partially
 positive ( +)end of one water molecule is attracted to the
   partially negative ( -) end of another water molecule.
https://youtu.be/0eNSnj4ZfZ8
Cohesion of water molecules due to hydrogen bonding
…. and consequences for organisms
                                                                                                Cohesive forces of water molecules are
                                                                                                caused by the hydrogen bonds between
                                                                                                them. A single hydrogen bond is a
                                                                                                weak intermolecular force of attraction,
                                                                                                but the summative force of all
                                                                                                hydrogen bonds is very strong.
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                      move above the water table and into the roots of a plant.   u
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Adhesion and its impacts for organism
Resurrection plants like the “rose of jericho” (Selaginella lepidophylla) is able
to dehydrate and completely rehydrate again. Rehydration involves water being
drawn rapidly through the desiccated cell walls, by capillary action.
Adhesion and its impacts for organism
Capillary action due to adhesion allows water to be drawn up in plants because
the cell walls are made of polar/hydrophilic cellulose fiber acting like wicks,
causing water to adhere to the cell walls.
                                                    Due to the capillary action,
                                                    plant cells that are exposed
                                                    to air (cells in the leaf) are
                                                      kept continously moist
                                                      drawing in water from
                                                     nearby xylem vessels as
                                                    long as there is a source of
                                                          water available.
https://1drv.ms/v/s!Au8ZKE_EDcrQhK5uRZYcPP4vl-MN6g?e=cFDSFW
https://1drv.ms/v/s!Au8ZKE_EDcrQhK9Kws7dlWuZnpkrKA?
Solvent properties of water
 Because water is a good solvent, it is a medium for metabolic and enzyme
  catalyzed reactions. Enzymes require some water to maintain shape and
stability, enabling them to function. Hydrogen bonds form between enzyme
     binding sites and their substrates allowing reactions to take place.
All reactants need                      Solutes such as amino
to be dissolved in                   acids, salts, sugar and ions
the cytoplasm of a                    needed for cell processes
cell to carry out                    are dissolved in the plasma
chemical and                         of blood, which is made up
enzymatic                                  mostly by water.
reactions.
                                     http://www.newhealthadvisor.com/images/1HT00352/low%20red%20blood%20cell%20count.jpeg
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     c water                                                                                                                        :
             hating
                                                                             hydrophobic and repel water molecules.
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                                                                           Hydrophobic molecules dissolve well in non-              .
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                                                                            polar solvents (e.g. acetone, chloroform).              q
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  Examples of                                                                                                                       c
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  hydrophobic
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   Lipids (fats and oils), fatty acids,                                                                                             y
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   cholesterol, waxes, nitrogen                                                                                                     c
  substances:
   gas…
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                                                                                                  Substances such as the phospholipid
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                                                                                                      bilayer of membranes have     /
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                                                                                                    hydrophobic (water hating) and  /
                                                                                                                                    2
http://test.classconnection.s3.amazonaws.com/823/flashcards/391823/jpg/phospholipid-bylayer.jpg   hydrophilic (water loving) features.
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Solvent properties of water
                       What are the features of
                       glucose and how does this
                       affect its issolubility
                           Glucose                  in water
                                     polar and hydrophilic,
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                              and when placed in water forms
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                              groups (-OH groups) of the polar
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                              glucose molecule and the polar sides
                              of the water molecules. This is
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                              essential for its transport in blood.
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Solvent properties of water
                                       Amino
    There are 20
  common amino
                                       acids
    acid, each is
characterized by a
   different side
  chain. The side
 chain (R-group)
  can be charged,
polar or nonpolar                         Side groups
 (hydrophilic and
   hydrophobic,       Depending on the properties of the side group
   respectively).      of the respective amino acid, it will dissolve
                     better or worse in water. All of them are soluble
                           enough to be carried in blood plasma.
Solvent properties of water  Oxygen, Nitrogen,
                          MostCarbondioxide
                               gases are entirely nonpolar and
                         hydrophobic, and dissolve very poorly
                            in water. To transport O2 and CO2
                          around the circulatory system, it must
                         be reversibly bound to the heme group
                         in hemoglobin of red blood cells. CO2
                        dissolves in water to form carbonic acid.
Solvent properties of water
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                                                 Fats & Fatty
                                                 acids
t
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                                                   Fat molecules are entirely
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                                                    nonpolar, are larger than
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                                                   water. They are carried in
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n                                                 the blood inside lipoprotein
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                                                    complexes, which pack
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                                                     them up and ship them
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                                                   around so that fat doesn’t
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Lipoproteins are composed of a single layer of
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ophospholipids on the outside and fats inside.
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t  The hydrophilic phosphate heads of the
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 contact with water in the blood plasma. The
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 hydrophobic hydrocarbon tails face inwards
p      and are in contact with the fats.
Solvent properties of water
http://www.physicsimplified.com/2016/08/24-buoyancy-force-upthrust-due-to.html
Physical properties - Buoyancy
                                                                                              Buoyancy depends on object density.
                                                                                                 Living organisms have an overall
                                                                                                 density close to water and tend to
                                                                                                   float, making water a suitable
                                                                                              habitat. This makes it easier for them
                                                                                               to use water as a habitat – it requires
Object density = fluid density   Object density < fluid density   Object density > fluid density
                                                                                                         less energy to float.
https://wiki.anton-paar.com/ch-de/grundlagen-der-viskositaetsmessung/##data-imagegroup-47192
    Physical properties -
    Viscosity
    Viscosity depends on the types of
    bonds or forces of attraction
    between particles. In liquids,
    water has relatively weak forces
    of attraction compared to olive oil
    or honey so viscosity is low.
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                                          A fluid moving relative to a body
t
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p
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                                            because of friction caused by
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                                          viscosity.
                                          Compare the
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                                          viscosity of air and
                                          water and how
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https://upload.wikimedia.org/wikipedia/commons/e/e0/Clouds_over_the_Atlantic_Ocean.jpg
Physical properties – Specific heat capacity
It takes a lot of energy for water to change temperature. This means
that, when water evaporates, a lot of energy is required to break the
hydrogen bonds between water molecules.
                                         Marine animals
                                         have adaptations
                                         to prevent heat
                                         energy to be lost to
                                         the surrounding by
                                         conduction.
Physical properties of air and water
   The physical properties of air and water are different – mostly
   because of their differing densities (air has an 800 times lower
   density of 1.2 kg/m-3 compared to water with 997.0 kg/m-3).
Compare the different physical properties in air and water
                   Ai                             Water
                    r
Buoyancy
Viscosity
  Thermal
conductivity
 Specific
   heat
 capacity
                                                                                                                       t
Adaptatations Adaptations
Buoyancy
Viscosity
   Thermal
 conductivity
Specific heat
  capacity
Physical properties of air and water
Complete the table to compare animal adaptations to the physical properties of air and water
                The mammal: Ringed seal (Pusa hispida)                                     The bird: Arctic loon (Gavia artica)
                                       Adaptatations                                                            Adaptations
                •      Floating is difficult because seals are heavy but assisted by   •    Big airy feathers make wings very buoyant in air when
                    the large fat storage (blubber) under the skin which is less         flying
                    dense and makes the seal more buoyant.                             •    Buoyancy in water is aided by air sacs which can be inflated
  Buoyancy                                                                               and which keep the loon on the surface of water.
                                                                                       •    For diving, air sacs can be compressed
                                                                                       •    Denser, heavier bones than what birds normally have help
                                                                                         with reducing buoyancy to help with diving.
                •   Heavy body weight so not much effort is needed when                •       Powerful muscles in legs help with diving
                  penetrating the viscosity of water.                                  •       Webbed toes for effective swimming with powerful strokes
                •   Streamlined bodyshape reduces drag when swimming                   •       Torpedo-like body shape (hydrodynamic)
  Viscosity                                                                            •       In air perfectly sized wings help with uplift because viscosity
                •   Flippers to propel themselves forward
                                                                                           is lower
                                                                                       •     Fast flapping of wings helps with keeping loons in air
                •     Heat from the seal is easily conducted to water                  •   Thick dense body feathers help to keep the loon
   Thermal      •     A thick layer of blubber below the skin provides insulation        waterproof
 conductivity       against the cold temeprature in water and on ice.                  •   Oil from oil glands in the skin acts as insulator
                                                                                       •   Thick plumage helps against cold air temperatures
                •     Water is used as a stable habitat                                •     Water is a stable habitat due to the high specific heat
Specific heat   •     Ice caves can be used as lairs and nesting sites, because            capacity.
                                                                        e
                 does
  Scientists believe      it have
                     that water sourcesits origin?
                                        on Earth are a consequence of
                                                                        n
                                                                        m
                                                                        e
   asteroid collision, which have taken place in the first few 100      n
                                                                        t
https://www.youtube.com/watch?v=vjDnh7zfO98
Extraplanetary origin of water on Earth
For water to stay on Earth (or any planet) after its appearance, it must be at the right temperature,
   as if the temperature is to high water would evaporate. If it were too low, all the water would
freeze. The right temperature is therefore the one which allows water to stay at a liquid zone. The
               temperature is determined by the distance of a planet away from a star.
                                              Goldilock
                                              zone
The habitable zone is often referred to as the Goldilock zone, after the Goldilock fairy tale
Extraterrestrial life and the presence of water
   Planets in the Goldilock zone (the habitable zone) often show a presence of water or an
  atmosphere. However, this relationship does not automatically imply the existence of life.
Extraterrestrial life and the presence of water
 When astrobiologists
 search for signs of life on
 distant planets, the look for
 evidence of water. Why?
https://science.nasa.gov/exoplanets/habitable-zone/