Biology
Biology
- In absolute zero molecules don't make at all 0° K (not only water but all)
- melting point - solid to liquid,
- boiling point - liquid to gas,
- water can attract or repell water mollecules mealier
- water being polar can make hydrogen bonds
- one water molecule can make four hydrogen bond (intermollecter forces of ar attraction)
-hydrogen bonds are less strong than chemical bonds
- in freezing point every water molecule has 4 hydrogen bonds (form latice)
- in gas state there are almost no hydrogen bonds
- hydrogen bonds exist in solid and liquid hz0 state
- ice has lower density than water so it floats
- ice isolates lower layers of water from cold so that aquatic organisms can live
A 1.1 – Water
“What physical and chemical properties of water make it essential for life?”
“What are the challenges and opportunities of water as a habitat?”
Students should appreciate that the first cells originated in water and that
water remains the medium in which most processes of life occur. Students
A1.1.1 Water as the medium for life should understand that polarity of covalent bonding within water molecules is
due to unequal sharing of electrons and that hydrogen bonding due to this
polarity occurs between water molecules.
Hydrogen bonds as a consequence of the Students should be able to represent two or more water molecules and
hydrogen bonds between them with the notation shown below to indicate
A1.1.2 polar covalent bonds within water polarity.
molecules
Cohesion of water molecules due to Include transport of water under tension in xylem and the use of water surfaces
as habitats due to the effect known as surface tension.
A1.1.3 hydrogen bonding and consequences for
organisms
Adhesion of water to materials that are Include capillary action in soil and in plant cell walls.
A1.1.4
polar or charged and impacts for organisms
Solvent properties of water linked to its role Emphasize that a wide variety of hydrophilic molecules dissolve in water and
that most enzymes catalyse reactions in aqueous solution. Students should also
A1.1.5 as a medium for metabolism and for understand that the functions of some molecules in cells depend on them being
transport in hydrophobic and insoluble.
The abundance of water over billions of years of Earth’s history has allowed
A1.1.7 Extraplanetary origin of water on Earth and life to evolve. Limit hypotheses for the origin of water on Earth to asteroids
AHL reasons for its retention and reasons for retention to gravity and temperatures low enough to condense
water.
h
The cytoplasm and organelles t
a
b
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are fluid filled with 85% of that l
e
p
s fluid being water. Chemical and /
t
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metabolic reactions work best o
p
w
w
in an aqueous environment. i
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y Early cells evolved membranes to separate their insides -
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(cytoplasm) from the ocean water. Cell membranes i
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o (phospholipid bilayers) naturally form in aquaeous medium. -
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f 0
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Hydrogen bonds in water due to polar covalent bonds
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t
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p H
: (+ O (-
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w
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l H
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)
b
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y Water molecules have polar covalent bonds – this is due to the
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o unequal attraction of electrons towards the nuclei of the
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g involved atoms. The oxygen atom has a larger nucleus with 8
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i protons than hydrogen with only 1 proton. Because of this, the
m
a
shared electrons from the covalent bond and unshared
g
e
electrons are pulled closer to the nucleus of the oxygen atom.
s
http://www.ces.fau.edu/nasa/images/module_3/WaterMolecule.gif
Hydrogen bonds in water due to polar covalent bonds
The unequal sharing of electrons in the covalent bond
between oxygen and hydrogen causes a partial positive
charge over H: + and a partial negative charge over O:
-
Draw the structure of a water
molecule, clearly showing
electrons and covalent bonds:
Hydrogen bonds in water due to polar covalent bonds
Hydrogen bonds are weak forces of attractions, which are
formed between the opposite polarities (caused by polar
covalent bonds) of adjacent water molecules. The partially
positive ( +)end of one water molecule is attracted to the
partially negative ( -) end of another water molecule.
https://youtu.be/0eNSnj4ZfZ8
Cohesion of water molecules due to hydrogen bonding
…. and consequences for organisms
Cohesive forces of water molecules are
caused by the hydrogen bonds between
them. A single hydrogen bond is a
weak intermolecular force of attraction,
but the summative force of all
hydrogen bonds is very strong.
h
t
t
p
s
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meniscus. c
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t
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move above the water table and into the roots of a plant. u
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Adhesion and its impacts for organism
Resurrection plants like the “rose of jericho” (Selaginella lepidophylla) is able
to dehydrate and completely rehydrate again. Rehydration involves water being
drawn rapidly through the desiccated cell walls, by capillary action.
Adhesion and its impacts for organism
Capillary action due to adhesion allows water to be drawn up in plants because
the cell walls are made of polar/hydrophilic cellulose fiber acting like wicks,
causing water to adhere to the cell walls.
Due to the capillary action,
plant cells that are exposed
to air (cells in the leaf) are
kept continously moist
drawing in water from
nearby xylem vessels as
long as there is a source of
water available.
https://1drv.ms/v/s!Au8ZKE_EDcrQhK5uRZYcPP4vl-MN6g?e=cFDSFW
https://1drv.ms/v/s!Au8ZKE_EDcrQhK9Kws7dlWuZnpkrKA?
Solvent properties of water
Because water is a good solvent, it is a medium for metabolic and enzyme
catalyzed reactions. Enzymes require some water to maintain shape and
stability, enabling them to function. Hydrogen bonds form between enzyme
binding sites and their substrates allowing reactions to take place.
All reactants need Solutes such as amino
to be dissolved in acids, salts, sugar and ions
the cytoplasm of a needed for cell processes
cell to carry out are dissolved in the plasma
chemical and of blood, which is made up
enzymatic mostly by water.
reactions.
http://www.newhealthadvisor.com/images/1HT00352/low%20red%20blood%20cell%20count.jpeg
/
c water :
hating
hydrophobic and repel water molecules.
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Hydrophobic molecules dissolve well in non- .
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polar solvents (e.g. acetone, chloroform). q
n
.
Examples of c
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hydrophobic
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Lipids (fats and oils), fatty acids, y
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cholesterol, waxes, nitrogen c
substances:
gas…
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1
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Substances such as the phospholipid
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bilayer of membranes have /
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hydrophobic (water hating) and /
2
http://test.classconnection.s3.amazonaws.com/823/flashcards/391823/jpg/phospholipid-bylayer.jpg hydrophilic (water loving) features.
/
Solvent properties of water
What are the features of
glucose and how does this
affect its issolubility
Glucose in water
polar and hydrophilic,
h
and when placed in water forms
t
t hydrogen bonds between hydroxyl
p
:
/
groups (-OH groups) of the polar
/
4
glucose molecule and the polar sides
of the water molecules. This is
.
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essential for its transport in blood.
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J http://www.metallacycle.com/chemistry/aqueous-solutions/solvation-models/img/glucose-solvation.png
Solvent properties of water
Amino
There are 20
common amino
acids
acid, each is
characterized by a
different side
chain. The side
chain (R-group)
can be charged,
polar or nonpolar Side groups
(hydrophilic and
hydrophobic, Depending on the properties of the side group
respectively). of the respective amino acid, it will dissolve
better or worse in water. All of them are soluble
enough to be carried in blood plasma.
Solvent properties of water Oxygen, Nitrogen,
MostCarbondioxide
gases are entirely nonpolar and
hydrophobic, and dissolve very poorly
in water. To transport O2 and CO2
around the circulatory system, it must
be reversibly bound to the heme group
in hemoglobin of red blood cells. CO2
dissolves in water to form carbonic acid.
Solvent properties of water
h
t
Fats & Fatty
acids
t
p
Fat molecules are entirely
s
:
nonpolar, are larger than
/
/ oxygen and are insoluble in
water. They are carried in
d
2
g
n the blood inside lipoprotein
e
9
7
complexes, which pack
v
d
them up and ship them
u
m
around so that fat doesn’t
g
n coalesce into bulky droplets.
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.
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Lipoproteins are composed of a single layer of
f
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ophospholipids on the outside and fats inside.
n
t The hydrophilic phosphate heads of the
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n phospholipids face outwards and are in
e
t
contact with water in the blood plasma. The
/
a
hydrophobic hydrocarbon tails face inwards
p and are in contact with the fats.
Solvent properties of water
http://www.physicsimplified.com/2016/08/24-buoyancy-force-upthrust-due-to.html
Physical properties - Buoyancy
Buoyancy depends on object density.
Living organisms have an overall
density close to water and tend to
float, making water a suitable
habitat. This makes it easier for them
to use water as a habitat – it requires
Object density = fluid density Object density < fluid density Object density > fluid density
less energy to float.
https://wiki.anton-paar.com/ch-de/grundlagen-der-viskositaetsmessung/##data-imagegroup-47192
Physical properties -
Viscosity
Viscosity depends on the types of
bonds or forces of attraction
between particles. In liquids,
water has relatively weak forces
of attraction compared to olive oil
or honey so viscosity is low.
h
A fluid moving relative to a body
t
t exerts a drag force on the body, partly
p
:
/
because of friction caused by
/
viscosity.
Compare the
e
c
o
u
r
viscosity of air and
water and how
s
e
s
https://upload.wikimedia.org/wikipedia/commons/e/e0/Clouds_over_the_Atlantic_Ocean.jpg
Physical properties – Specific heat capacity
It takes a lot of energy for water to change temperature. This means
that, when water evaporates, a lot of energy is required to break the
hydrogen bonds between water molecules.
Marine animals
have adaptations
to prevent heat
energy to be lost to
the surrounding by
conduction.
Physical properties of air and water
The physical properties of air and water are different – mostly
because of their differing densities (air has an 800 times lower
density of 1.2 kg/m-3 compared to water with 997.0 kg/m-3).
Compare the different physical properties in air and water
Ai Water
r
Buoyancy
Viscosity
Thermal
conductivity
Specific
heat
capacity
t
Adaptatations Adaptations
Buoyancy
Viscosity
Thermal
conductivity
Specific heat
capacity
Physical properties of air and water
Complete the table to compare animal adaptations to the physical properties of air and water
The mammal: Ringed seal (Pusa hispida) The bird: Arctic loon (Gavia artica)
Adaptatations Adaptations
• Floating is difficult because seals are heavy but assisted by • Big airy feathers make wings very buoyant in air when
the large fat storage (blubber) under the skin which is less flying
dense and makes the seal more buoyant. • Buoyancy in water is aided by air sacs which can be inflated
Buoyancy and which keep the loon on the surface of water.
• For diving, air sacs can be compressed
• Denser, heavier bones than what birds normally have help
with reducing buoyancy to help with diving.
• Heavy body weight so not much effort is needed when • Powerful muscles in legs help with diving
penetrating the viscosity of water. • Webbed toes for effective swimming with powerful strokes
• Streamlined bodyshape reduces drag when swimming • Torpedo-like body shape (hydrodynamic)
Viscosity • In air perfectly sized wings help with uplift because viscosity
• Flippers to propel themselves forward
is lower
• Fast flapping of wings helps with keeping loons in air
• Heat from the seal is easily conducted to water • Thick dense body feathers help to keep the loon
Thermal • A thick layer of blubber below the skin provides insulation waterproof
conductivity against the cold temeprature in water and on ice. • Oil from oil glands in the skin acts as insulator
• Thick plumage helps against cold air temperatures
• Water is used as a stable habitat • Water is a stable habitat due to the high specific heat
Specific heat • Ice caves can be used as lairs and nesting sites, because capacity.
e
does
Scientists believe it have
that water sourcesits origin?
on Earth are a consequence of
n
m
e
asteroid collision, which have taken place in the first few 100 n
t
https://www.youtube.com/watch?v=vjDnh7zfO98
Extraplanetary origin of water on Earth
For water to stay on Earth (or any planet) after its appearance, it must be at the right temperature,
as if the temperature is to high water would evaporate. If it were too low, all the water would
freeze. The right temperature is therefore the one which allows water to stay at a liquid zone. The
temperature is determined by the distance of a planet away from a star.
Goldilock
zone
The habitable zone is often referred to as the Goldilock zone, after the Goldilock fairy tale
Extraterrestrial life and the presence of water
Planets in the Goldilock zone (the habitable zone) often show a presence of water or an
atmosphere. However, this relationship does not automatically imply the existence of life.
Extraterrestrial life and the presence of water
When astrobiologists
search for signs of life on
distant planets, the look for
evidence of water. Why?
https://science.nasa.gov/exoplanets/habitable-zone/